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Why is it important?
First study demonstrating syn-conformation as against normally expected (bookish chemistry) anti-conformation for-1,2-diaryl-ethanes in solid state by X-ray crystallography.
Perspectives
Uniquely, demonstrate selection of electron deficient nucleic bases (especially purines) for intra- and inter-molecular stacking in DNA/RNA structures over electron rich aromatics (like benzenoids) by nature.
kamlakar avasthi
Central Drug Research Institute
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This page is a summary of: Role of arene interactions and substituent effects in conformational (syn/anti) control of 1,2-diarylethanes, CrystEngComm, January 2012, Royal Society of Chemistry,
DOI: 10.1039/c1ce06001e.
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