Chiral Dawson-Type Hybrid Polyoxometalate Catalyzes Enantioselective Diels-Alder Reactions

What is it about?

We demonstrate in this publication how a chiral POM, in which only the inorganic framework is chiral, induces good enantioselectivities in C-C bond formation.

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Why is it important?

Usually, organic-inorganics are chiral due to the organic side chain. We are demonstrating that the chiral inorganic part alone is enough!