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In the title compound, [Ni(C15H14N3O2S)2], the NiII atom lies on a center of symmetry. The deprotonated ligands act as N,S-donors, forming five-membered metalla-rings. The NiII atom is four-coordinated in a slightly distorted square-planar environment. In the crystal, the discrete complex molecules are linked by weak N-H...O hydrogen bonds, generating chains along [110]. The chains are further connected via weak O-H...N interactions into a layered network extending parallel to (001).
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This page is a summary of: Bis(4-hydroxy-3-methoxybenzaldehyde 4-phenylthiosemicarbazonato-N1,S)nickel(II), Acta Crystallographica Section E Structure Reports Online, April 2014, International Union of Crystallography,
DOI: 10.1107/s1600536814009027.
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