All Stories

  1. Exposing the Origins of Irreproducibility in Fluorine NMR Spectroscopy

    Article • Angewandte Chemie, May 2018, Wiley

    Professor Antonio Togni

  2. Fluor-NMR-Spektroskopie rekalibriert

    Article • Angewandte Chemie, May 2018, Wiley

    Professor Antonio Togni

  3. Exposing the Origins of Irreproducibility in Fluorine NMR Spectroscopy

    Article • Angewandte Chemie, May 2018, Wiley

    Professor Antonio Togni

  4. Fluor-NMR-Spektroskopie rekalibriert

    Article • Angewandte Chemie, May 2018, Wiley

    Professor Antonio Togni

  5. Supramolecular Aggregation of Perfluoroorganyl Iodane Reagents in the Solid State and in Solution

    Article • European Journal of Organic Chemistry, March 2018, Wiley

    Professor Antonio Togni

  6. Perfluoroalkyl Cobaloximes: Preparation Using Hypervalent Iodine Reagents, Molecular Structures, Thermal and Photochemical Reactivity

    Article • Organometallics, February 2018, American Chemical Society (ACS)

    Professor Antonio Togni

  7. Importance of Nonclassical σ-Hole Interactions for the Reactivity of λ3-Iodane Complexes

    Article • The Journal of Organic Chemistry, October 2017, American Chemical Society (ACS)

    Professor Antonio Togni

  8. Synthesis and Characterization of Fluorinated Hypervalent Tellurium Derivatives

    Article • Organometallics, September 2017, American Chemical Society (ACS)

    Professor Antonio Togni

  9. Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes

    Article • Journal of the American Chemical Society, September 2017, American Chemical Society (ACS)

    Professor Antonio Togni

  10. Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles

    Article • Chemistry - A European Journal, April 2017, Wiley

    Professor Antonio Togni

  11. Cover Picture: Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles (Chem. Eur. J. 35/2017)

    Article • Chemistry - A European Journal, April 2017, Wiley

    Professor Antonio Togni

  12. Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles

    Article • Chemistry - A European Journal, March 2017, Wiley

    Professor Antonio Togni

  13. S-Trifluoromethylation of Thiols by Hypervalent Iodine Reagents: A Joint Experimental and Computational Study

    Article • Chemistry - A European Journal, January 2016, Wiley

    Professor Antonio Togni

  14. Synthesis of quaternary α-perfluoroalkyl lactams via electrophilic perfluoroalkylation

    Article • Chemical Communications, January 2016, Royal Society of Chemistry

    Professor Antonio Togni

  15. P-Trifluoromethyl ligands derived from Josiphos in the Ir-catalysed hydrogenation of 3,4-dihydroisoquinoline hydrochlorides

    Article • Dalton Transactions, January 2015, Royal Society of Chemistry

    Professor Antonio Togni

  16. “Why and How it Works”: The Development of Hypervalent Iodine Reagents as an Illustration for the Collaboration of Chemical Synthesis with Modeling and Simulation

    Article • CHIMIA International Journal for Chemistry, September 2014, Swiss Chemical Society

    Professor Antonio Togni

  17. The solvent effect on two competing reaction mechanisms involving hypervalent iodine reagents (λ3-iodanes): Facing the limit of the stationary quantum chemical approach

    Article • Journal of Computational Chemistry, September 2014, Wiley

    Professor Antonio Togni

  18. Rapid and Selective Electrophilic Trifluoromethylation of the 4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) Scaffold

    Article • European Journal of Organic Chemistry, September 2014, Wiley

    Professor Antonio Togni

  19. Vanadium-Catalyzed Solvent-Free Synthesis of Quaternary α-Trifluoromethyl Nitriles by Electrophilic Trifluoromethylation

    Article • Angewandte Chemie, August 2014, Wiley

    Professor Antonio Togni

  20. O-Trifluoromethylation ofN,N-Disubstituted Hydroxylamines with Hypervalent Iodine Reagents

    Article • European Journal of Organic Chemistry, March 2014, Wiley

    Professor Antonio Togni

  21. Synthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3 H -1λ 3 ,2-benziodaoxol-3-one

    Article • Beilstein Journal of Organic Chemistry, January 2014, Beilstein Institut

    Professor Antonio Togni

  22. Confusing Quantitative Descriptions ofBrønstedLowryAcidBase Equilibria in Chemistry Textbooks - A Critical Review and Clarifications for Chemical Educators

    Article • Helvetica Chimica Acta, January 2014, Wiley

    Professor Antonio Togni

  23. Enantioselective 1,3-Dipolar Cycloaddition of C , N -Cyclic Azomethine Imines to Unsaturated Nitriles Catalyzed by Ni II –Pigiphos

    Article • The Journal of Organic Chemistry, October 2013, American Chemical Society (ACS)

    Professor Antonio Togni

  24. One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation

    Article • The Journal of Organic Chemistry, June 2013, American Chemical Society (ACS)

    Professor Antonio Togni

  25. Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Rhenium Complexes with Chiral Ferrocenylphosphane Ligands

    Article • European Journal of Inorganic Chemistry, September 2012, Wiley

    Professor Antonio Togni

  26. Additive Effects of Amines on Asymmetric Hydrogenation of Quinoxalines Catalyzed by Chiral Iridium Complexes

    Article • Chemistry - A European Journal, August 2012, Wiley

    Professor Antonio Togni

  27. Reductive Eliminations from λ 3 -Iodanes: Understanding Selectivity and the Crucial Role of the Hypervalent Bond

    Article • Organic Letters, August 2012, American Chemical Society (ACS)

    Professor Antonio Togni

  28. Direct Electrophilic N-Trifluoromethylation of Azoles by a Hypervalent Iodine Reagent

    Article • Angewandte Chemie, May 2012, Wiley

    Professor Antonio Togni

  29. Gold(I) Complexes of Conformationally Constricted Chiral Ferrocenyl Phosphines

    Article • Organometallics, May 2012, American Chemical Society (ACS)

    Dr King Kuok Hii, Professor Antonio Togni

  30. Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents

    Article • ACS Catalysis, April 2012, American Chemical Society (ACS)

    Professor Antonio Togni

  31. Substrate Range of the Titanium TADDOLate Catalyzed Asymmetric Fluorination of Activated Carbonyl Compounds

    Article • Helvetica Chimica Acta, March 2012, Wiley

    Professor Antonio Togni

  32. Reactivity of an electrophilic hypervalent iodine trifluoromethylation reagent with hydrogen phosphates—A mechanistic study

    Article • Journal of Fluorine Chemistry, March 2012, Elsevier

    Professor Antonio Togni

  33. P-Stereogenic Trifluoromethyl Derivatives of Josiphos: Synthesis, Coordination Properties, and Applications in Asymmetric Catalysis

    Article • Chemistry - A European Journal, December 2011, Wiley

    Professor Antonio Togni

  34. Synthesis of α-CF3-Substituted Carbonyl Compounds with Relative and Absolute Stereocontrol Using Electrophilic CF3-Transfer Reagents

    Article • Organic Letters, November 2011, American Chemical Society (ACS)

    Professor Antonio Togni

  35. Development of the titanium–TADDOLate-catalyzed asymmetric fluorination of β-ketoesters

    Article • Beilstein Journal of Organic Chemistry, October 2011, Beilstein Institut

    Professor Antonio Togni

  36. Secondary Ferrocenyl Phosphines: Versatile Precursors for the Synthesis of Bi- and Tridentate Ligands

    Article • Organometallics, September 2011, American Chemical Society (ACS)

    Professor Antonio Togni

  37. Rhenium Complexes Containing the Chiral Tridentate Ferrocenyl Ligand Pigiphos

    Article • Organometallics, September 2011, American Chemical Society (ACS)

    Professor Antonio Togni

  38. Probing the interactions of an acyl carrier protein domain from the 6-deoxyerythronolide B synthase

    Article • Protein Science, June 2011, Wiley

    Professor Antonio Togni

  39. Iron(II)-Catalyzed Asymmetric Hydrosilylation of Acetophenone

    Article • European Journal of Organic Chemistry, June 2011, Wiley

    Professor Antonio Togni

  40. Electrophilic Trifluoromethylation of S -Hydrogen Phosphorothioates

    Article • The Journal of Organic Chemistry, May 2011, American Chemical Society (ACS)

    Professor Antonio Togni

  41. Josiphos Ligands: From Discovery to Technical Applications

    Article • April 2011, Wiley

    Professor Antonio Togni

  42. Chiral trifluoromethylphosphines: a new stereoselective synthesis of Josiphos-type ligands containing two stereogenic phosphorus atoms

    Article • Chemical Communications, January 2011, Royal Society of Chemistry

    Professor Antonio Togni

  43. PREPARATION OF A TRIFLUOROMETHYL TRANSFER AGENT: 1-TRIFLUOROMETHYL-1,3-DIHYDRO-3,3-DIMETHYL-1,2-BENZIODOXOLE

    Article • Organic Syntheses, January 2011, Organic Syntheses

    Professor Antonio Togni

  44. A Ritter-Type Reaction: Direct Electrophilic Trifluoromethylation at Nitrogen Atoms Using Hypervalent Iodine Reagents

    Article • Angewandte Chemie, December 2010, Wiley

    Professor Antonio Togni

  45. P-Stereogenic Ferrocene-Based (Trifluoromethyl)phosphanes: Synthesis, Structure, Coordination Properties and Catalysis

    Article • European Journal of Organic Chemistry, November 2010, Wiley

    Professor Antonio Togni

  46. Organofluorine Chemistry: Taking the Next Steps

    Article • Advanced Synthesis & Catalysis, November 2010, Wiley

    Professor Antonio Togni

  47. Electrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagents

    Article • Journal of Fluorine Chemistry, September 2010, Elsevier

    Professor Antonio Togni

  48. New hypervalent iodine reagents for electrophilic trifluoromethylation and their precursors: synthesis, structure, and reactivity

    Article • Tetrahedron, July 2010, Elsevier

    Professor Antonio Togni

  49. Remote C−F−Metal Interactions in Late-Transition-Metal Complexes

    Article • Organometallics, June 2010, American Chemical Society (ACS)

    Professor Antonio Togni

  50. Electrophilic Trifluoromethylation of Primary Phosphines: Synthesis of a P -Bis(trifluoromethyl) Derivative of BINAP

    Article • Organometallics, April 2010, American Chemical Society (ACS)

    Professor Antonio Togni

  51. Reactivity of a Hypervalent Iodine Trifluoromethylating Reagent toward THF: Ring Opening and Formation of Trifluoromethyl Ethers

    Article • The Journal of Organic Chemistry, March 2010, American Chemical Society (ACS)

    Professor Antonio Togni

  52. NMR-Solution Structures and Affinities for the Human Somatostatin G-Protein-Coupled Receptors hsst1–5 of CF3 Derivatives of Sandostatin® (Octreotide)

    Article • Helvetica Chimica Acta, December 2009, Wiley

    Professor Antonio Togni, Prof daniel hoyer

  53. Asymmetric oxidative α-fluorination of 2-alkylphenylacetaldehydes with AgHF2 and ruthenium/PNNP catalysts

    Article • Journal of Fluorine Chemistry, August 2009, Elsevier

    Professor Antonio Togni

  54. A Concise Synthesis of ortho-Iodobenzyl Alcohols via Addition of ortho-Iodophenyl Grignard Reagent to Aldehydes and Ketones

    Article • Synthesis, June 2009, Thieme Publishing Group

    Professor Antonio Togni

  55. Zinc-Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents

    Article • Angewandte Chemie, June 2009, Wiley

    Professor Antonio Togni

  56. Acid-mediated formation of trifluoromethyl sulfonates from sulfonic acids and a hypervalent iodine trifluoromethylating agent

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Professor Antonio Togni

  57. ElectrophilicS-Trifluoromethylation of Cysteine Side Chains inα- andβ-Peptides: Isolation of Trifluoro-methylatedSandostatin®(Octreotide) Derivatives

    Article • Helvetica Chimica Acta, November 2008, Wiley

    Professor Antonio Togni

  58. Asymmetric hydroamination of acrylonitrile derivatives catalyzed by Ni(II)-complexes

    Article • Tetrahedron Asymmetry, November 2008, Elsevier

    Professor Antonio Togni

  59. Reactivity of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With Phenols

    Article • The Journal of Organic Chemistry, October 2008, American Chemical Society (ACS)

    Professor Antonio Togni

  60. Palladium-Catalyzed Enantioselective Allylic Phosphination

    Article • Angewandte Chemie, June 2008, Wiley

    Professor Antonio Togni

  61. Recent Advances in Electrophilic CF3-Transfer Using Hypervalent Iodine(III) Reagents

    Article • CHIMIA International Journal for Chemistry, April 2008, Swiss Chemical Society

    Professor Antonio Togni

  62. Ni(ii)-catalyzed enantioselective Nazarov cyclizations

    Article • Chemical Communications, January 2008, Royal Society of Chemistry

    Professor Antonio Togni

  63. Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents

    Article • Chemical Communications, January 2008, Royal Society of Chemistry

    Professor Antonio Togni

  64. TiIV-Catalyzed Asymmetric Sulfenylation of 1,3-Dicarbonyl Compounds

    Article • Chemistry - A European Journal, November 2007, Wiley

    Professor Antonio Togni

  65. Ruthenium-Catalyzed Asymmetric Electrophilic Fluorination of 1,3-Dicarbonyl Compounds

    Article • Organometallics, November 2007, American Chemical Society (ACS)

    Professor Antonio Togni

  66. Gold(I)- and Brønsted Acid-Catalyzed Ring-Opening of Unactivated Vinylcyclopropanes with Sulfonamides

    Article • Advanced Synthesis & Catalysis, July 2007, Wiley

    Professor Antonio Togni

  67. Synthesis and Characterization of Palladium(II) π-Allyl Complexes with Chiral Phosphinocarbene Ligands. Kinetics and Mechanism of Allylic Amination

    Article • Organometallics, July 2007, American Chemical Society (ACS)

    Professor Antonio Togni

  68. Cationic Vanadium(IV) Complexes as Efficient Catalysts for Nazarov Cyclizations

    Article • European Journal of Organic Chemistry, June 2007, Wiley

    Professor Antonio Togni

  69. Asymmetric Electrophilic Fluorination of α-Nitro Esters

    Article • Synlett, April 2007, Thieme Publishing Group

    Professor Antonio Togni

  70. Asymmetric Catalytic Hydroamination of Activated Olefins in Ionic Liquids

    Article • Helvetica Chimica Acta, February 2007, Wiley

    Professor Antonio Togni

  71. Mild Electrophilic Trifluoromethylation of Carbon- and Sulfur-Centered Nucleophiles by a Hypervalent Iodine(III)–CF3 Reagent

    Article • Angewandte Chemie, January 2007, Wiley

    Professor Antonio Togni

  72. Phthalimide-N-sulfenyl chloride in the Ti-catalyzed asymmetric sulfenylation of β-keto esters

    Article • Tetrahedron Asymmetry, October 2006, Elsevier

    Professor Antonio Togni

  73. Structural and stereochemical aspects of the enantioselective halogenation of 1,3-dicarbonyl compounds catalyzed by Ti(TADDOLato) complexes

    Article • Tetrahedron, July 2006, Elsevier

    Professor Antonio Togni

  74. Interactions of Cationic Palladium(II)- and Platinum(II)-η3-Allyl Complexes with Fluoride: Is Asymmetric Allylic Fluorination a Viable Reaction?

    Article • European Journal of Inorganic Chemistry, April 2006, Wiley

    Professor Antonio Togni

  75. Novel 10-I-3 Hypervalent Iodine-Based Compounds for Electrophilic Trifluoromethylation

    Article • Chemistry - A European Journal, March 2006, Wiley

    Professor Antonio Togni

  76. Enantioselective Palladium-Catalyzed Hydrosilylation of Styrene:  Influence of Electronic and Steric Effects on Enantioselectivity and Catalyst Design via Hybrid QM/MM Molecular Dynamics Simulations

    Article • Organometallics, February 2006, American Chemical Society (ACS)

    Professor Antonio Togni

  77. Consecutive catalytic electrophilic fluorination/amination of β-keto esters: toward α-fluoro-α-amino acids?

    Article • Tetrahedron Asymmetry, February 2006, Elsevier

    Professor Antonio Togni

  78. Chiral Ru/PNNP complexes in catalytic and stoichiometric electrophilic O- and F-atom transfer to 1,3-dicarbonyl compounds

    Article • Pure and Applied Chemistry, January 2006, De Gruyter

    Professor Antonio Togni

  79. A Novel Chiral Ferrocene-Based Amidine/Amidinato Ligand and Its Rhodium Complexes

    Article • Organometallics, January 2006, American Chemical Society (ACS)

    Professor Antonio Togni

  80. PdII Complexes of Tridentate PCP N-Heterocyclic Carbene Ligands: Structural Aspects and Application in Asymmetric Hydroamination of Cyano Olefins

    Article • European Journal of Inorganic Chemistry, December 2005, Wiley

    Professor Antonio Togni

  81. Enantioselective Addition of Secondary Phosphines to Methacrylonitrile:  Catalysis and Mechanism

    Article • Journal of the American Chemical Society, December 2005, American Chemical Society (ACS)

    Professor Antonio Togni

  82. Titanium(IV)-Catalyzed Enantioselective Sulfenylation of β-Ketoesters

    Article • Organic Letters, September 2005, American Chemical Society (ACS)

    Professor Antonio Togni

  83. N-Ferrocenyl-Substituted Planar-Chiral N-Heterocyclic Carbenes and Their PdII Complexes

    Article • European Journal of Inorganic Chemistry, January 2005, Wiley

    Professor Antonio Togni

  84. A Dinuclear Copper(I) Complex Containing a Bridging Chiral Tridentate Carbene Ligand

    Article • Organometallics, January 2005, American Chemical Society (ACS)

    Professor Antonio Togni

  85. Nickel(II)-Catalyzed Highly Enantioselective Hydrophosphination of Methacrylonitrile

    Article • Journal of the American Chemical Society, November 2004, American Chemical Society (ACS)

    Professor Antonio Togni

  86. Relative Electrophilic Fluorinating Power as Assayed by Competitive Catalytic Halogenation Reactions

    Article • Helvetica Chimica Acta, October 2004, Wiley

    Professor Antonio Togni

  87. Iridium-Imine and -Amine Complexes Relevant to the (S)-Metolachlor Process: Structures, Exchange Kinetics, and C?H Activation by IrI Causing Racemization

    Article • Chemistry - A European Journal, September 2004, Wiley

    Professor Antonio Togni

  88. Novel silica gel supported chiral biaryl-diphosphine ligands for enantioselective hydrogenation

    Article • Tetrahedron Asymmetry, July 2004, Elsevier

    Professor Antonio Togni

  89. Enantioselective Palladium-Catalyzed Hydrosilylation of Styrene:  Detailed Reaction Mechanism from First-Principles and Hybrid QM/MM Molecular Dynamics Simulations

    Article • Organometallics, June 2004, American Chemical Society (ACS)

    Professor Antonio Togni

  90. Synthesis and Coordination Chemistry of a New Chiral Tridentate PCP N -Heterocyclic Carbene Ligand Based on a Ferrocene Backbone

    Article • Organometallics, May 2004, American Chemical Society (ACS)

    Professor Antonio Togni

  91. Expanding the scope of asymmetric electrophilic atom-transfer reactions: Titanium- and ruthenium-catalyzed hydroxylation of β-ketoesters

    Article • Proceedings of the National Academy of Sciences, April 2004, Proceedings of the National Academy of Sciences

    Professor Antonio Togni

  92. Catalytic Asymmetric Chlorination of β‐Keto Esters with Hypervalent Iodine Compounds

    Article • Helvetica Chimica Acta, March 2004, Wiley

    Dr Hasim Ibrahim, Professor Antonio Togni

  93. Chiral Xyliphos Complexes for the Catalytic Imine Hydrogenation Leading to the Metolachlor Herbicide: Isolation of Catalyst–Substrate Adducts

    Article • Chemistry - A European Journal, January 2004, Wiley

    Professor Antonio Togni

  94. Novel chiral ferrocenyl-imino phosphine ligands and their use in palladium catalyzed allylic alkylations

    Article • Tetrahedron Letters, November 2003, Elsevier

    Dr Pierluigi Barbaro, Professor Antonio Togni, Dr Giuliano Giambastiani

  95. Titanium-Catalyzed Stereoselective Geminal Heterodihalogenation of β-Ketoesters

    Article • Organic Letters, May 2003, American Chemical Society (ACS)

    Professor Antonio Togni

  96. Ni(ii) Complexes containing chiral tridentate phosphines as new catalysts for the hydroamination of activated olefins

    Article • Chemical Communications, November 2002, Royal Society of Chemistry

    Professor Antonio Togni

  97. Synthesis and Structure of an Enantiomerically Pure C2 Symmetric Ferrocenyl Carbene

    Article • Helvetica Chimica Acta, August 2002, Wiley

    Professor Antonio Togni

  98. TitaniumLewis Acids for Asymmetric Catalysis: Synthesis and Structural Characterization of Dichloro[diolato(2−)-κO,κO′]bis(solvent)titanium ([TiCl2(diolato)(solvent)2]) Complexes

    Article • Helvetica Chimica Acta, June 2002, Wiley

    Professor Antonio Togni

  99. The Mechanism of Catalytic Enantioselective Fluorination: Computational and Experimental Studies

    Article • Angewandte Chemie, March 2002, Wiley

    Professor Antonio Togni

  100. Article • Topics in Catalysis, January 2002, Springer Science + Business Media

    Professor Antonio Togni

  101. Structural Aspects of Palladium and Platinum Complexes With Chiral Diphosphinoferrocenes Relevant to the Regio- and Stereoselective Copolymerization of CO with Propene

    Article • Helvetica Chimica Acta, October 2001, Wiley

    Professor Antonio Togni

  102. Catalytic Fluorination by Halide Exchange with 16-Electron Ruthenium(II) Complexes. X-ray Structure of [Tl(μ-F) 2 Ru(dppe) 2 ]PF 6

    Article • Organometallics, August 2001, American Chemical Society (ACS)

    Professor Antonio Togni

  103. Synthesis, characterization, and application in asymmetric catalysis of dendrimers containing chiral ferrocenyl diphosphines

    Article • Canadian Journal of Chemistry, January 2001, Canadian Science Publishing

    Professor Antonio Togni

  104. Catalytic Enantioselective Fluorination ofβ-Ketoesters

    Article • Angewandte Chemie, December 2000, Wiley

    Professor Antonio Togni

  105. Catalytic Enantioselective Chlorination and Bromination of β-Keto Esters

    Article • Helvetica Chimica Acta, September 2000, Wiley

    Professor Antonio Togni

  106. Ligand Electronic Effect in Enantioselective Palladium-Catalyzed Copolymerization of Carbon Monoxide and Propene

    Article • Angewandte Chemie, July 2000, Wiley

    Professor Antonio Togni

  107. Toward Metal-Mediated C−F Bond Formation. Synthesis and Reactivity of the 16-Electron Fluoro Complex [RuF(dppp) 2 ]PF 6 (dppp = 1,3-Bis(diphenylphosphino)propane)

    Article • Organometallics, July 2000, American Chemical Society (ACS)

    Professor Antonio Togni

  108. Phosphane lone-pair energies as a measure of ligand donor strengths and relation to activation energies

    Article • Journal of Molecular Structure THEOCHEM, July 2000, Elsevier

    Professor Antonio Togni

  109. Toward an Alkene Hydroamination Catalyst:  Static and Dynamic ab Initio DFT Studies

    Article • Journal of the American Chemical Society, May 2000, American Chemical Society (ACS)

    Professor Antonio Togni

  110. Synthesis and Characterization of Chiral Bis(aminato)iridate(I) and Aminato-Bridged Iridium(I) Complexes

    Article • Helvetica Chimica Acta, January 2000, Wiley

    Professor Antonio Togni

  111. Carbon−Fluorine Bond Formationvia a Five-Coordinate Fluoro Complex of Ruthenium(II), Preliminary Communication

    Article • Helvetica Chimica Acta, December 1999, Wiley

    Professor Antonio Togni

  112. Charge-Transfer Salts of Ferrocene Derivatives with Bis(maleonitriledithiolato)metallate(III) Complexes ([M(mnt)2]−, M=Ni, Pt): A Ground-State High-Spin [(Ni(mnt)2)2]2− Dimer

    Article • Helvetica Chimica Acta, September 1999, Wiley

    Professor Antonio Togni

  113. Synthesis and characterization of chiral bis-ferrocenyl triphosphine Ni(II) and Rh(III) complexes and their use as catalyst precursors for acetalization reactions

    Article • Journal of Molecular Catalysis A Chemical, September 1999, Elsevier

    Dr Pierluigi Barbaro, Professor Antonio Togni

  114. Dendrimers Containing Chiral Ferrocenyl Diphosphine Ligands for Asymmetric Catalysis

    Article • Journal of the American Chemical Society, October 1998, American Chemical Society (ACS)

    Professor Antonio Togni

  115. The [IrCl(Diphosphine)] 2 /Fluoride System. Developing Catalytic Asymmetric Olefin Hydroamination

    Article • Journal of the American Chemical Society, November 1997, American Chemical Society (ACS)

    Professor Antonio Togni

  116. A remarkable anion effect on the enantioselectivity of the Pd-catalyzed allylic amination using ferrocenyl ligands

    Article • Tetrahedron Asymmetry, January 1997, Elsevier

    Professor Antonio Togni

  117. Synthesis of P,S,O-ligands incorporating a planar chiral ferrocenyl motif

    Article • Tetrahedron Asymmetry, January 1996, Elsevier

    Professor Antonio Togni

  118. Palladium-Catalyzed Asymmetric Allylic Amination Using Ferrocenyl Pyrazole Ligands:  Steric Control of η 3 -Allyl Configuration and Site-Selective Nucleophilic Attack

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor Antonio Togni

  119. Synthesis and structure of new chiral ferrocenylphosphines for asymmetric catalysis

    Article • Inorganica Chimica Acta, July 1994, Elsevier

    Professor Antonio Togni

  120. Asymmetric allylic alkylation with palladium coordinated to a new optically active pyrazolylmethane ligand

    Article • Journal of Organometallic Chemistry, June 1993, Elsevier

    Professor Antonio Togni

  121. The gold(I)-catalyzed aldol reaction utilizing chiral ferrocenylamine ligands: Synthesis of N-benzyl-substituted ligands

    Article • Journal of Organometallic Chemistry, May 1992, Elsevier

    Professor Antonio Togni

  122. Cooperativity of chirality in homogeneous catalysis: The gold(I)-catalyzed aldol reaction and the vanadium(IV)-catalyzed hetero Diels-Alder cycloaddition

    Article • Chirality, January 1991, Wiley

    Professor Antonio Togni

  123. Asymmetric allylic alkylation catalyzed by palladium-sparteine complexes

    Article • Tetrahedron Asymmetry, January 1991, Elsevier

    Professor Antonio Togni

  124. Enantioselective synthesis: Catalysis of the aldol reaction by neutral gold(I)-chiral ferrocenylphosphine complexes. Crystal structure of the complex [{(η5-C5H4PPh2)(η5-C5H3(PPh2)CH(Me)N(Me)CH2CH2NMe2)Fe}2(AuCl)3] · Et2O

    Article • Journal of Organometallic Chemistry, January 1990, Elsevier

    Professor Antonio Togni

  125. Asymmetric synthesis: Modification of chiral ferrocenylamine ligands for the gold(I)-catalyzed aldol reaction

    Article • Tetrahedron Letters, January 1990, Elsevier

    Professor Antonio Togni

  126. Sterically congested ligands: Synthesis and spectral characterization of the first Pd(II) and Pt(II) complexes of tetra-t-butyl-substituted biaryloxybis(1,3,2-oxazaphospholidines)

    Article • Inorganica Chimica Acta, May 1989, Elsevier

    Professor Antonio Togni

  127. Enantioselective synthesis of β-hydroxy-α-aminophosphonic acid precursors

    Article • Tetrahedron Letters, January 1989, Elsevier

    Professor Antonio Togni

  128. Mono- and di-hydrido-bridged platinum(II)-tungsten(IV) complexes. Synthesis and X-ray crystal structure of [Cp2W(μ-H)2PtPh(PEt3)][BPh4] and [Cp2(H)W(μ-H)PtPh(PEt3)2][BPh4]

    Article • Journal of Organometallic Chemistry, August 1987, Elsevier

    Professor Antonio Togni

  129. Hydrido-1,5-cyclooctadieneiridium(III) complexes stabilized by trichlorostannate ligands and the structure of [IrH2(SnCl3)(PPh3)3]

    Article • Journal of Organometallic Chemistry, February 1985, Elsevier

    Professor Antonio Togni

  130. Planar-Chiral Ferrocenest Synthetic Methods and Applications

    Article • Wiley

    Professor Antonio Togni

  131. Chiral 1,2-Disubstituted Ferrocene Diphosphines for Asymmetric Catalysis

    Article • Wiley

    Professor Antonio Togni