All Stories

  1. Operando XAFS of supported Pd nanoparticles in flowing ethanol/water mixtures: implications for catalysis
  2. Chemo‐ and Diastereoselectivities in the Electrochemical Reduction of Maleimides
  3. Electronic structures of cyclometalated palladium complexes in the higher oxidation states
  4. Structure and bonding of [(SIPr)AgX] (X = Cl, Br, I and OTf)
  5. Atropisomeric [(diphosphine)Au2Cl2] Complexes and their Catalytic Activity Towards Asymmetric Cycloisomerisation of 1,6‐Enynes
  6. (1R,5R,6R)-Spiro[4.4]nonane-1,6-diyl Diphenylphosphinous Acid Ester
  7. Catalysis in flow: Operando study of Pd catalyst speciation and leaching
  8. ChemInform Abstract: Silver‐Catalyzed Intramolecular Hydroamination of Alkynes with Trichloroacetimidates.
  9. ChemInform Abstract: Methylene‐Bridged Bis(imidazoline)‐Derived 2‐Oxopyrimidinium Salts as Catalysts for Asymmetric Michael Reactions.
  10. ChemInform Abstract: Levonantradol: Asymmetric Synthesis and Structural Analysis.
  11. ChemInform Abstract: Coinage Metal Catalysts for the Addition of O—H to C=C Bonds.
  12. Methylene‐Bridged Bis(imidazoline)‐Derived 2‐Oxopyrimidinium Salts as Catalysts for Asymmetric Michael Reactions
  13. Methylene‐Bridged Bis(imidazoline)‐Derived 2‐Oxopyrimidinium Salts as Catalysts for Asymmetric Michael Reactions
  14. New Chiral Zwitterionic Phosphorus Heterocycles: Synthesis, Structure, Properties and Application as Chiral Solvating Agents
  15. Coinage Metal Catalysts for the Addition of O–H to C=C Bonds
  16. Levonantradol: asymmetric synthesis and structural analysis
  17. Silver-catalysed intramolecular hydroamination of alkynes with trichloroacetimidates
  18. ChemInform Abstract: Asymmetric Synthesis of 2‐Alkyl‐substituted Tetrahydroquinolines by an Enantioselective Aza‐Michael Reaction.
  19. PhanePhos and Related Derivatives
  20. Preparation of dicationic palladium catalysts for asymmetric catalytic reactions
  21. Silver‐Catalysed Enantioselective Addition of OH and NH Bonds to Allenes: A New Model for Stereoselectivity Based on Noncovalent Interactions
  22. Gold(I) Complexes of Conformationally Constricted Chiral Ferrocenyl Phosphines
  23. Deconvolution of the Mechanism of Homogeneous Gold-Catalyzed Reactions
  24. ChemInform Abstract: Palladium‐Catalyzed Heterofunctionalization of C—H, C:C, and CC Bonds
  25. Asymmetric synthesis of 2-alkyl-substituted tetrahydroquinolines by an enantioselective aza-Michael reaction
  26. Speciation of Pd(OAc)2in ligandless Suzuki–Miyaura reactions
  27. Catalysis in flow: Au-catalysed alkylation of amines by alcohols
  28. Palladium-Catalyzed Heterofunctionalization of C-H, C=C and C≡ C Bonds
  29. Alternative to Benzoquinone for Room-Temperature Fujiwara–Moritani Reactions
  30. ChemInform Abstract: Transition Metal Catalyzed Enantioselective α‐Heterofunctionalization of Carbonyl Compounds
  31. ChemInform Abstract: Catalysis in Flow: The Practical and Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones.
  32. An Expedient Synthesis of Olfactory Lactones by Intramolecular Hydroacylalkoxylation Reactions
  33. ChemInform Abstract: Oxidative Amidation of Activated Alkenes Using Pd(OAc)2 as a Catalyst Precursor.
  34. Transition Metal Catalyzed Enantioselective α-Heterofunctionalization of Carbonyl Compounds
  35. Oxidative Amidation of Activated Alkenes Using Pd(OAc)2 as a Catalyst Precursor
  36. ChemInform Abstract: Hydroamination Reactions by Metal Triflates: Broensted Acid versus Metal Catalysis?
  37. ChemInform Abstract: Palladium-Catalyzed Addition of R2NH to Double Bonds. Synthesis of α-Amino Tetrahydrofuran and Pyran Rings.
  38. ChemInform Abstract: Advances in the Heck Chemistry of Aryl Bromides and Chlorides
  39. Delineating Origins of Stereocontrol in Asymmetric Pd-Catalyzed α-Hydroxylation of 1,3-Ketoesters
  40. ChemInform Abstract: Copper‐Catalyzed Intramolecular O—H Addition to Unactivated Alkenes.
  41. ChemInform Abstract: Unusual Regiodivergence in Metal‐Catalyzed Intramolecular Cyclization of γ‐Allenols.
  42. ChemInform Abstract: Synthesis of Terphenyls
  43. Hydroamination reactions by metal triflates: Brønsted acid vs. metal catalysis?
  44. Catalysis in flow: the practical and selective aerobic oxidation of alcohols to aldehydes and ketones
  45. Copper-catalysed intramolecular O–H addition to unactivated alkenes
  46. ChemInform Abstract: Palladium‐Catalyzed Enantioselective α‐Hydroxylation of β‐Ketoesters.
  47. Synthesis of Terphenyls
  48. [Pd{2-CH2-5-MeC6H3C(H)NNC(S)NHEt}]3: An unprecedented trinuclear cyclometallated palladium(II) cluster through induced flexibility in the metallated ring
  49. Unusual regiodivergence in metal-catalysed intramolecular cyclisation of γ-allenols
  50. Palladium-catalysed enantioselective α-hydroxylation of β-ketoesters
  51. Delineating ligand effects in intramolecular aryl amidation reactions: formation of a novel spiro-heterocycle by a tandem cyclisation process
  52. ChemInform Abstract: A Recyclable Copper(II) Catalyst for the Annulation of Phenols with 1,3-Dienes.
  53. A recyclable copper(ii) catalyst for the annulation of phenols with 1,3-dienes
  54. Preparation of Macrocyclon Analogues: Calix[8]arenes with Extended Polyethylene Glycol Chains.
  55. A Concise Asymmetric Synthesis of Torcetrapib (I).
  56. Preparation of macrocyclon analogues: calix[8]arenes with extended polyethylene glycol chains
  57. A Practical and General Synthesis of Unsymmetrical Terphenyls
  58. A Concise Asymmetric Synthesis of Torcetrapib
  59. Enabling Ligand Screening for Palladium‐Catalysed Enantioselective Aza‐Michael Addition Reactions
  60. Applications of Phosphine‐Functionalized Polymers in Organic Synthesis
  61. Elucidating the Mechanism of the Asymmetric Aza-Michael Reaction
  62. Applications of phosphine-functionalised polymers in organic synthesis
  63. Copper‐Catalyzed Intermolecular Hydroamination of Alkenes.
  64. Development of Palladium Catalysts for Asymmetric Hydroamination Reactions
  65. Practical Synthesis of Chiral Vinylphosphine Oxides by Direct Nucleophilic Substitution. Stereodivergent Synthesis of Aminophosphine Ligands.
  66. Copper-Catalyzed Intermolecular Hydroamination of Alkenes
  67. Enabling Ligand Screening for Palladium‐Catalyzed Enantioselective aza‐Michael Addition Reactions.
  68. Ligand Effects in the Synthesis of N‐Heterocycles by Intramolecular Heck Reactions.
  69. Enabling Ligand Screening for Palladium‐Catalysed Enantioselective Aza‐Michael Addition Reactions
  70. Practical Synthesis of Chiral Vinylphosphine Oxides by Direct Nucleophilic Substitution. Stereodivergent Synthesis of Aminophosphine Ligands
  71. Synthesis of P‐Chirogenic Diarylphosphinoacetic Acids and Their Proline Derivatives for Palladium‐Catalyzed Allylic Alkylation Reactions.
  72. Copper(II)‐Catalyzed Addition of O—H Bonds to Norbornene.
  73. Mechanisms That Interchange Axial and Equatorial Atoms in Fluxional Processes: Illustration of the Berry Pseudorotation, the Turnstile, and the Lever Mechanisms via Animation of Transition State Normal Vibrational Modes
  74. Ligand Effects in the Synthesis of N-Heterocycles by Intramolecular Heck Reactions
  75. In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS
  76. Development of palladium catalysts for asymmetric hydroamination reactions
  77. Recyclable Polymer‐Supported Pd Catalysts for Aryl Amination Reactions.
  78. Reversal of Aryl Bromide Reactivity in Pd‐Catalyzed Aryl Amination Reactions Promoted by a Hemilabile Aminophosphine Ligand.
  79. Palladium‐Catalysed Enantioselective Conjugate Addition of Aromatic Amines to α,β‐Unsaturated N‐Imides. Effect of the Chelating Moiety
  80. Synthesis of P-chirogenic diarylphosphinoacetic acids and their proline derivatives for palladium-catalysed allylic alkylation reactions
  81. Enantioselective Addition of Amines to Alkenoyl‐N‐oxazolidinones.
  82. Recyclable polymer-supported Pd catalysts for aryl amination reactions
  83. Phosphine-functionalised polymer resins as Pd scavengers
  84. Reversal of aryl bromide reactivity in Pd-catalysed aryl amination reactions promoted by a hemilabile aminophosphine ligand
  85. Enantioselective addition of amines to alkenoyl-N-oxazolidinones
  86. Conformation Analyses, Dynamic Behavior and Amide Bond Distortions of Medium‐Sized Heterocycles. Part 1. Partially and Fully Reduced 1‐Benzazepines.
  87. Conformation Analyses, Dynamic Behavior, and Amide Bond Distortions of Medium‐Sized Heterocycles. Part 2. Partially and Fully Reduced 1‐Benzazocines, Benzazonines, and Benzazecines.
  88. Conformation Analyses, Dynamic Behavior and Amide Bond Distortions of Medium-sized Heterocycles. 1. Partially and Fully Reduced 1-Benzazepines
  89. Conformation Analyses, Dynamic Behavior, and Amide Bond Distortions of Medium-sized Heterocycles. 2. Partially and Fully Reduced 1-Benzazocines, Benzazonines, and Benzazecines
  90. Polymer-supported manganese porphyrin catalysts—peptide-linker promoted chemoselectivity
  91. Copper(ii)-catalysed addition of O–H bonds to norbornene
  92. Wang-aldehyde resin as a recyclable support for the synthesis of α,α-disubstituted amino acid derivatives
  93. Aminohydroxy Phosphine Oxide Ligands in Ruthenium‐Catalyzed Asymmetric Transfer Hydrogenation Reactions.
  94. Mixed Donor Aminophosphine Oxide Ligands in Ruthenium‐Catalyzed Asymmetric Transfer Hydrogenation Reactions.
  95. Chemoselective Epoxidation of Dienes Using Polymer‐Supported Manganese Porphyrin Catalysts.
  96. Chemoselective epoxidation of dienes using polymer-supported manganese porphyrin catalysts
  97. Aminohydroxy phosphine oxide ligands in ruthenium-catalysed asymmetric transfer hydrogenation reactions
  98. Conformationally Restricted Arene Intermediates in the Intermolecular Heck Arylation of Vinylarenes
  99. Asymmetric Synthesis of β‐Amino Acid and Amide Derivatives by Catalytic Conjugate Addition of Aromatic Amines to N‐Alkenoylcarbamates.
  100. Phosphorus—Nitrogen—Phosphorus Ligands: Cooperative Effects Between Nitrogen and Phosphorus Substituents on Catalytic Activity.
  101. Mixed donor aminophosphine oxide ligands in ruthenium-catalysed asymmetric transfer hydrogenation reactions
  102. Asymmetric Synthesis ofβ-Amino Acid and Amide Derivatives by Catalytic Conjugate Addition of Aromatic Amines toN-Alkenoylcarbamates
  103. Multigram Synthesis of Well-Defined Extended Bifunctional Polyethylene Glycol (PEG) Chains
  104. Phosphorus–nitrogen–phosphorus ligands: cooperative effects between nitrogen and phosphorus substituents on catalytic activity
  105. Unsymmetrical Terdentate Phosphorus‐Nitrogen‐Nitrogen (PNN) Ligands: Effect of the M/L Ratio and the Pendant Group on Stereoselectivity.
  106. Dicationic [(BINAP)Pd(solvent)2]2+[TfO-]2: Enantioselective Hydroamination Catalyst for Alkenoyl-N-oxazolidinones.
  107. Hydridopalladium Complexes
  108. Mild reduction of chlorophosphine boranes to secondary phosphine boranes
  109. Unsymmetrical terdentate phosphorus-nitrogen-nitrogen (PNN) ligands: effect of the M/L ratio and the pendant group on stereoselectivity
  110. Dicationic [(BINAP)Pd(solvent)2]2+[TfO–]2: enantioselective hydroamination catalyst for alkenoyl-N-oxazolidinones
  111. Air- and moisture-stable cationic (diphosphine)palladium(II) complexes as hydroamination catalysts
  112. Coordination Chemistry and Catalytic Activity of Ruthenium Complexes of Terdentate Phosphorus−Nitrogen−Phosphorus (PNP) and Bidentate Phosphorus−Nitrogen (PNH) Ligands
  113. Examining the effect of hemilabile donor groups in non-C2 symmetrical terdentate ligands
  114. Profound Steric Control of Reactivity in Aryl Halide Addition to Bisphosphane Palladium(0) Complexes
  115. Profound Steric Control of Reactivity in Aryl Halide Addition to Bisphosphane Palladium(0) Complexes
  116. Advances in the Heck chemistry of aryl bromides and chlorides
  117. Palladium-catalyzed addition of R 2 NH to double bonds. Synthesis of α-amino tetrahydrofuran and pyran rings
  118. The Chatt-Dewar-Duncanson Model Revisited: X-ray, DFT and NMR Studies of Rhodium-Alkene Binding—Deviations from Structural Ideality
  119. Corrigendum to “Examination of Ligand Effects in the Heck Arylation Reaction”
  120. ChemInform Abstract: Scope and Limitations of the Preparation of Aminophosphines R‐NH(CH2CH2PPh2) and Aminodiphosphines R‐N(CH2CH2PPh2)2 via Michael Addition of Amines to Viny...
  121. Examination of Ligand Effects in the Heck Arylation Reaction
  122. Scope and Limitations of the Preparation of Aminophosphines R-NH(CH2CH2PPh2) and Aminodiphosphines R-N(CH2CH2PPh2)2 via Michael Addition of Amines to Vinylphosphines
  123. Factors Affecting the Oxidative Addition of Aryl Electrophiles to 1,1‘-Bis(diphenylphosphino)ferrocenepalladium(η2-methyl acrylate), an Isolable Pd[0] Alkene Complex
  124. Syntheses and Properties of Palladium Complexes Containing Phosphorus−Nitrogen−Phosphorus Ligands with a Tunable Hemilabile Site
  125. Models for the Carbonyl-ene Cyclization Reaction: Open and Closed Transition States
  126. Modelle für die Carbonyl-En-Cyclisierung: offene und geschlossene Übergangszustände
  127. Modelle für die Carbonyl-En-Cyclisierung: offene und geschlossene Übergangszustände
  128. The Heck olefination reaction; A DFT study of the elimination pathway
  129. Intermediates in the Intermolecular, Asymmetric Heck Arylation of Dihydrofurans
  130. Conformational diastereoisomerism in tris-(2-alkylimino) triphenylphosphines
  131. Characterization of Reactive Intermediates in Palladium‐Catalyzed Arylation of Methyl Acrylate (Heck Reaction)
  132. Die Charakterisierung reaktiver Zwischenstufen in der Palladium‐katalysierten Arylierung von Methylacrylat (Heck‐Reaktion)
  133. Terdentate (P,N,N) complexes of a new pyridyl azine phosphine Z,E-PPh2CH2(But)CN–NC(Me)C5H4N and its deprotonated derivative (an azo phosphine) with transition metals
  134. Terdentate (P–N–O) complexes formed from Z,E-PPh2CH2C-(But)N–NCH(C6H4OH-2) or Z,E-PPh2CH2C(But)N–NCH-[C6H2(OH-2)(OMe)2-4,6] and...
  135. Complexes of the bidentate ligands PPh2CH2C(But)NNR2(R = H or Me) and PPh2CH2C(But)N–NCHPh with palladium and platinum. X-Ray crystal structure of cis-[Pt{PPh2CH...
  136. New bidentate ligands PPh2CH2C(But)NNR2(R = H or Me) and PPh2CH2C(But)NNCHPh and their complexes with Group 6 metal carbonyls
  137. Hydridopalladium Complexes
  138. 1. Catalysis in flow
  139. Application of phosphine ligands in organic synthesis