All Stories

  1. Chiral Rh phosphine–phosphite catalysts immobilized on ionic resins for the enantioselective hydrogenation of olefins in water

    Article • Green Chemistry, January 2015, Royal Society of Chemistry

    Dr Pierluigi Barbaro, Dr Antonio Pizzano

  2. A mild route to solid-supported rhodium nanoparticle catalysts and their application to the selective hydrogenation reaction of substituted arenes

    Article • Catalysis Science & Technology, January 2015, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  3. Green semi-hydrogenation of alkynes by Pd@borate monolith catalysts under continuous flow

    Article • Journal of Catalysis, March 2014, Elsevier

    Dr Pierluigi Barbaro

  4. Energy efficient continuous production of γ-valerolactone by bifunctional metal/acid catalysis in one pot

    Article • Green Chemistry, January 2014, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  5. Continuous flow synthesis of Rh and Pd nanoparticles onto ion-exchange borate monoliths: application to selective catalytic hydrogenation of unsaturated carbonyl compounds under flow conditions

    Article • Catalysis Science & Technology, January 2014, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  6. Strong Cation Exchange with Innocence: Synthesis and Characterization of Borate Containing Resins and Macroporous Monoliths

    Article • Macromolecules, July 2013, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  7. Partial hydrogenation reactions over Pd-containing hybrid inorganic/polymeric catalytic membranes

    Article • Applied Catalysis A General, May 2013, Elsevier

    Dr Pierluigi Barbaro

  8. Selective hydrogenation over Pd nanoparticles supported on a pore-flow-through silica monolith microreactor with hierarchical porosity

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  9. Continuous Partial Hydrogenation Reactions by Pd@unconventional Bimodal Porous Titania Monolith Catalysts

    Article • ACS Catalysis, September 2012, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  10. Heterogeneous Bifunctional Metal/Acid Catalysts for Selective Chemical Processes

    Article • European Journal of Inorganic Chemistry, July 2012, Wiley

    Dr Pierluigi Barbaro

  11. Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3‐Dihydride‐2‐iodidecyclotetraphosphane

    Article • Angewandte Chemie International Edition, July 2012, Wiley

    Dr Pierluigi Barbaro

  12. Green production of polymer-supported PdNPs: application to the environmentally benign catalyzed synthesis of cis-3-hexen-1-ol under flow conditions

    Article • Dalton Transactions, January 2012, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  13. Facile heterogeneous catalytic hydrogenations of CN and CO bonds in neat water: anchoring of water-soluble metal complexes onto ion-exchange resins

    Article • Green Chemistry, January 2012, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  14. In situ generation of resin-supported Pd nanoparticles under mild catalytic conditions: a green route to highly efficient, reusable hydrogenation catalysts

    Article • Catalysis Science & Technology, January 2012, Royal Society of Chemistry

    Dr Pierluigi Barbaro, Professor Debora Berti

  15. Enantioselective hydrogenation of prochiral substrates in catalytic membrane reactors

    Article • Catalysis Science & Technology, January 2011, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  16. Emerging strategies in sustainable fine-chemical synthesis: asymmetric catalysis by metal nanoparticles

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Dr Pierluigi Barbaro, Dr Vladimiro Dal Santo

  17. Heterogenized Homogeneous Catalysts for Fine Chemicals Production

    Article • January 2010

    Dr Pierluigi Barbaro

  18. Catalysis for Sustainable Energy Production

    Article • March 2009, Wiley

    Dr Pierluigi Barbaro

  19. Ion Exchange Resins: Catalyst Recovery and Recycle

    Article • Chemical Reviews, December 2008, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  20. NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus

    Article • Magnetic Resonance in Chemistry, October 2008, Wiley

    Dr Pierluigi Barbaro

  21. Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium‐Coordinated 1‐Hydroxytriphosphane by Hydrolysis of Doubly Metalated P4

    Article • Angewandte Chemie International Edition, May 2008, Wiley

    Dr Pierluigi Barbaro

  22. Benzene Hydrogenation by Silica-Supported Catalysts Made of Palladium Nanoparticles and Electrostatically Immobilized Rhodium Single Sites

    Article • Organometallics, May 2008, American Chemical Society (ACS)

    Dr Pierluigi Barbaro, Dr Vladimiro Dal Santo

  23. Heterobimetallic Cooperation Mediates the Transformation of White Phosphorus into Zwitterionic catena‐Phosphonium(+)diphosphenide(−) Ligands

    Article • Angewandte Chemie International Edition, April 2008, Wiley

    Dr Pierluigi Barbaro

  24. Dynamic Behaviour of the [(Triphos)Rh(η1:η2‐P4RR′)]n+ Complexes [Triphos = MeC(CH2PPh2)3; R = H, Alkyl, Aryl; R′ = Lone Pair, H, Me; n = 0, 1]: NMR and Computati...

    Article • European Journal of Inorganic Chemistry, March 2008, Wiley

    Dr Pierluigi Barbaro

  25. Recycling Asymmetric Hydrogenation Catalysts by Their Immobilization onto Ion‐Exchange Resins

    Article • Chemistry - A European Journal, July 2006, Wiley

    Dr Pierluigi Barbaro

  26. A Snapshot of P4 Tetrahedron Opening: Rh‐ and Ir‐Mediated Activation of White Phosphorus

    Article • Angewandte Chemie International Edition, June 2006, Wiley

    Dr Pierluigi Barbaro

  27. Hydrogenation of Arenes over Silica-Supported Catalysts That Combine a Grafted Rhodium Complex and Palladium Nanoparticles:  Evidence for Substrate Activation on Rhsingle-site−Pdmet...

    Article • Journal of the American Chemical Society, May 2006, American Chemical Society (ACS)

    Dr Pierluigi Barbaro, Dr Vladimiro Dal Santo

  28. Adducts of Cyclotriphosphorus Complexes with Cyclopentadienyl Ruthenium Fragments: Synthesis, Solid‐State Structure and Solution Behaviour

    Article • European Journal of Inorganic Chemistry, April 2005, Wiley

    Dr Pierluigi Barbaro

  29. Large-Scale Synthesis of Chiral Ferrocenyl Imino-Phosphines

    Article • Synthesis, January 2005, Thieme Publishing Group

    Dr Pierluigi Barbaro, Dr Giuliano Giambastiani

  30. Synthetic Approaches to New Diastereomerically Pure Ferrocenyl Triphosphine­s Combining Phosphorus, Planar, and Carbon Chirality

    Article • Synthesis, January 2004, Thieme Publishing Group

    Dr Pierluigi Barbaro

  31. Recycling asymmetric hydrogenation catalysts by their immobilisation onto ion-exchange resinsElectronic supplementary information (ESI) available: Experimental section, 31P{1H} HP NMR spectra, typical EDS surface area spectrum and ESEM images. See http...

    Article • Dalton Transactions, January 2004, Royal Society of Chemistry

    Dr Pierluigi Barbaro, Dr Vladimiro Dal Santo, Dr Giuliano Giambastiani

  32. Ruthenium(II) Complexes with Triphosphane Ligands Combining Planar, Phosphorus, and Carbon Chirality: Application to Asymmetric Reduction of Trifluoroacetophenone

    Article • European Journal of Inorganic Chemistry, November 2003, Wiley

    Dr Pierluigi Barbaro

  33. Novel chiral ferrocenyl-imino phosphine ligands and their use in palladium catalyzed allylic alkylations

    Article • Tetrahedron Letters, November 2003, Elsevier

    Dr Pierluigi Barbaro, Professor Antonio Togni, Dr Giuliano Giambastiani

  34. Complexes of Rhodium(I) and Iridium(I) with the Chiral Tridentate Phosphane Pigiphos: Structure and Reactivity Studies

    Article • European Journal of Inorganic Chemistry, January 2003, Wiley

    Dr Pierluigi Barbaro

  35. The first tridentate phosphine ligand combining planar, phosphorus and carbon chiralityElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b2/b208384a/

    Article • Chemical Communications, October 2002, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  36. Hydrogenation of Indole by Phosphine-Modified Rhodium and Ruthenium Catalysts

    Article • Organometallics, March 2002, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  37. Hydrogenation of Quinoline by Rhodium Catalysts Modified with the Tripodal Polyphosphine Ligand MeC(CH2PPh2)3

    Article • Helvetica Chimica Acta, October 2001, Wiley

    Dr Pierluigi Barbaro

  38. Hydrogenation of Quinoline by Rhodium Catalysts Modified with the Tripodal Polyphosphine Ligand MeC(CH2PPh2)3

    Article • Helvetica Chimica Acta, October 2001, Wiley

    Dr Pierluigi Barbaro

  39. Transition metal complexes with the C1-symmetric diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to enantioselective catalysis in different p...

    Article • Journal of Organometallic Chemistry, March 2001, Elsevier

    Dr Pierluigi Barbaro

  40. Immobilization of Optically Active Rhodium-Diphosphine Complexes on Porous Silica via Hydrogen Bonding

    Article • Advanced Synthesis & Catalysis, January 2001, Wiley

    Dr Pierluigi Barbaro, Dr Vladimiro Dal Santo

  41. Immobilization of Optically Active Rhodium-Diphosphine Complexes on Porous Silica via Hydrogen Bonding

    Article • Advanced Synthesis & Catalysis, January 2001, Wiley

    Dr Pierluigi Barbaro, Dr Vladimiro Dal Santo

  42. In Situ and Reactor Study of the Enantioselective Hydrogenation of Acetylacetone by Ruthenium Catalysis with the New Chiral Diphosphine Ligand (R)-(R)-3-Benzyl-2,4-bis(diphenylphosphino)pentane

    Article • Organometallics, May 2000, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  43. Synthesis and characterization of chiral bis-ferrocenyl triphosphine Ni(II) and Rh(III) complexes and their use as catalyst precursors for acetalization reactions

    Article • Journal of Molecular Catalysis A Chemical, September 1999, Elsevier

    Dr Pierluigi Barbaro, Professor Antonio Togni

  44. Styrene Cyclopropanation and Ethyl Diazoacetate Dimerization Catalyzed by Ruthenium Complexes Containing Chiral Tridentate Phosphine Ligands

    Article • Organometallics, April 1999, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  45. Enantioselective Hydrogenation of 2-Methylquinoxaline to (−)-(2S)-2-Methyl-1,2,3,4-tetrahydroquinoxaline by Iridium Catalysis

    Article • Organometallics, June 1998, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  46. Interaction of methylmercury(II) with the bifunctional ligand o-diphenylphosphinobenzoate, dpb. Synthesis and characterization of [(dpb)HgMe] and [(dpbo)HgMe], dpbo=o-diphenylphosphinoxidebenzoate

    Article • Journal of Organometallic Chemistry, March 1998, Elsevier

    Dr Pierluigi Barbaro

  47. Preparative, potentiometric and NMR studies of the interaction of beryllium(II) with oxalate and malonate. X-ray structure of K3[Be3(OH)3(O2C–CH2–CO2)3]·6H2O

    Article • Inorganica Chimica Acta, October 1997, Elsevier

    Dr Pierluigi Barbaro

  48. Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)−P3or −P2S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone

    Article • Organometallics, June 1997, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  49. Valence localization in [M(triphos)(3,5-di-tert-butyl-catecholate)]+ ions (M = Co, Rh or Ir) probed by resonance Raman spectroscopy

    Article • Inorganica Chimica Acta, November 1996, Elsevier

    Dr Franti Hartl, Dr Pierluigi Barbaro

  50. Chiral P,S-Ligands Based on β-d-Thioglucose Tetraacetate. Palladium(II) Complexes and Allylic Alkylation

    Article • Organometallics, April 1996, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  51. New enantiomerically pure aminoalcohols from (R)-α-methylbenzylamine and cyclohexene oxide

    Article • Tetrahedron Asymmetry, March 1996, Elsevier

    Dr Pierluigi Barbaro

  52. Dioxomolybdenum(VI) Complexes with New Enantiomerically Pure Amino Diol Ligands

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  53. Synthesis, properties and characterization of the trinuclear clusters [Co3(µ-SR)6(PEt3)3]X (R = Me or Et, X = BPh4–or PF6–)

    Article • Journal of the Chemical Society Dalton Transactions, January 1996, Royal Society of Chemistry

    Dr Pierluigi Barbaro

  54. 1,3-Diphenylallyl Complexes of Palladium(II): NMR, x-ray, and Catalytic Studies

    Article • Organometallics, November 1995, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  55. A New Chiral Tridentate Ferrocenyl Ligand. Synthesis and Characterization of Its Palladium(II) and Nickel(II) Complexes

    Article • Organometallics, July 1995, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  56. Metal Coordination and Hg-C Bond Protonolysis in Organomercury(II) Compounds. Synthesis, Characterization, and Reactivity of the Tetrahedral Complexes [(np3)HgR][(CF3)SO3] {np3 = N(CH2CH2PPh2)3; R = CH3, C2H5, C6H5}

    Article • Inorganic Chemistry, December 1994, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  57. Dioxomolybdenum(VI) Complexes Stabilized by Polydentate Ligands with NO3, N2O2, and NS2 Donor-Atom Sets

    Article • Inorganic Chemistry, July 1994, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  58. Regio- and stereoselective dimerization of 1-alkynes catalyzed by an Os(II) complex

    Article • Inorganica Chimica Acta, June 1994, Elsevier

    Dr Pierluigi Barbaro

  59. Dioxygen and Carbon Monoxide Uptake by Iridium(I) Complexes Stabilized by Mixed N,P-Donor Ligands

    Article • Inorganic Chemistry, April 1994, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  60. Thermal and photochemical carbon-hydrogen bond activation reactions at iridium. .pi.-Coordination vs. C-H cleavage of ethene, styrene, and phenylacetylene

    Article • Organometallics, July 1993, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  61. Dioxygen uptake and transfer by Co(III), Rh(III) and Ir(III) catecholate complexes

    Article • Inorganica Chimica Acta, August 1992, Elsevier

    Dr Pierluigi Barbaro

  62. Chemoselective oxidation of 3,5-di-tert-butylcatechol by molecular oxygen. Catalysis by an iridium(III) catecholate through its dioxygen adduct

    Article • Inorganic Chemistry, April 1992, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  63. Assembling ethylene, alkyl, hydride, and carbon monoxide ligands at iridium

    Article • Organometallics, July 1991, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  64. Synthetic models for catechol 1,2-dioxygenases. Interception of a metal catecholate-dioxygen adduct

    Article • Journal of the American Chemical Society, April 1991, American Chemical Society (ACS)

    Dr Pierluigi Barbaro

  65. The tetranuclear trianion [Fe4Te4(SC6H5)4]3-: crystal and molecular structure and magnetic properties

    Article • Journal of the American Chemical Society, September 1990, American Chemical Society (ACS)

    Dr Pierluigi Barbaro