What is it about?

Liquids are intriguing and open up possibilities. To a large extent living matter is liquid. What happens when metal-oxides form liquid and that too at room temperature? Lot of possibilities open up. Starting from observation of fascinating architecture at billionth of a meter that can render chemical reactions faster to controlled patterning of surfaces. All such and myriads of other possibilities from conversion of CO2 to fuel with concomitant oxidation of water to produce oxygen with light can take place. Courtesy: Liquid oxometalates or Soft-oxometalates. In this review we visit Soft-oxometalates (SOMs) that are essentially liquids with myriads of possibilities and show what they are and what they can do.

Featured Image

Why is it important?

SOMs are not new. They have been around since the times of Berzelius and Scheele. In this work we put a structure to the prevalent body of literature that can qualify as SOMs. Defining the SOMs as a soft (liquid) state of oxometalates (charged metal-oxides) enables us to understand: 1. Crystallization of large beautiful molecules known as polyoxometalates, 2. Apply such knowledge in patterning surfaces and making them move 3. Control the architecture of SOMs and engineer better catalysts with more active sites.

Perspectives

Writing this article was a great pleasure. With this article I wanted to put structure on an existing body of very rich literature, but in course of writing this article I realized that this article has shaped my thoughts and crystallized my concepts on SOMs which influenced and still influences our research directions with extremely gifted students, co-workers and colleagues with whom I work together today on SOMs.

Professor Soumyajit Roy
Indian Institute of Science Education & Research Kolkata

Read the Original

This page is a summary of: Soft-oxometalates beyond crystalline polyoxometalates: formation, structure and properties, CrystEngComm, January 2014, Royal Society of Chemistry,
DOI: 10.1039/c4ce00115j.
You can read the full text:

Read

Resources

Contributors

The following have contributed to this page