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  1. Photoredox-Catalyzed Transfer Thiobenzoyloxylation of Styrenes Using Oxime-Based Surrogates
  2. Regio- and stereoselective tert -butylthiolation of internal alkynes with thioethers initiated and maintained by silylium-ion catalysis
  3. Epimerization-Free Synthesis of Azo-Substituted Di- and Tripeptides by Cross-Coupling of O-Triflated Derivatives and Diazenyl Anion Equivalents
  4. Kinetics and Mechanism of Enantioselective Cu-Catalyzed Alcohol Silylation
  5. Photoinduced Deoxygenative Boration of Unactivated Alcohols Involving In-Situ-Formed Alkyl Iodides
  6. Photoredox-Catalyzed Transfer Thio(poly)fluoroacyloxylation of Alkenes Using Oxime-Based Surrogates
  7. Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
  8. Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
  9. Analysis of Cyclohexa-1,4-dienes with an Asymmetrically Substituted, 3° Carbon Atom as Chiral Dihydrogen Surrogates in Reagent-Controlled Transfer Hydrogenation of Alkenes
  10. Directing Effects of Silyl and Germyl Groups in Transition‐Metal‐Catalyzed Allylic Substitution
  11. Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles
  12. Isolation of halogen-substituted silylium ions
  13. Silylium-Ion-Promoted Formation of Methylenecyclobutenes by Formal (2 + 2) Cycloaddition of Allenylsilanes and Internal Alkynes
  14. Kinetic Resolution of BINAMs by Stereoselective Copper-Catalyzed Dehydrogenative Si–N Coupling with Prochiral Dihydrosilanes
  15. Nickel-Catalyzed Enantioconvergent C(sp3)–C(sp3) Cross-Coupling between α-Iodogermanes and Alkylzinc Reagents
  16. Dynamic Kinetic C(sp2)–Si Cross-Coupling with Si–B Reagents for the Atroposelective Construction of Unsymmetrical Heterobiaryls
  17. Kinetic Resolution of Acyclic 1,3-Diols by Copper-Catalyzed Regioselective Dehydrogenative Si–O-Coupling
  18. Photoredox-Catalyzed Transfer Aminochlorination of Unactivated Alkenes Using Oxime-Based Surrogates
  19. One-Pot Sequential Alcohol Activation and Nickel-Catalyzed Cross-Electrophile Coupling with Chlorosilanes
  20. Ionic Remote α-C–H Allenylation of Silyl Ethers Involving a [1,5]-Hydride Shift Promoted by Silylium-Ion Regeneration
  21. Silylium-Ion-Promoted (3 + 2) Annulation of Allenylsilanes with Internal Alkynes Involving a Pentadienyl-to-Allyl Cation Electrocyclization
  22. Enantio‐ and Diastereoselective Desymmetrization of 1,1’‐Biaryl‐2,6‐Dicarbaldehydes by Copper‐Catalyzed 1,2‐Addition of Silicon Nucleophiles
  23. Enantio‐ und Diastereoselektive Desymmetrisierung von 1,1’‐Biaryl‐2,6‐Dicarbaldehyden durch kupferkatalysierte 1,2‐Addition von Siliciumnukleophilen
  24. Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes
  25. Enantio‐ and Regioconvergent Nickel‐Catalyzed Etherification of Phenols by Allylation to Access Chiral C(sp3)−O Allyl Aryl Ethers
  26. Enantio‐ und regiokonvergente, nickelkatalysierte Veretherung von Phenolen durch Allylierung zur Darstellung chiraler C(sp3)−O‐Allylarylether
  27. From Process Chemistry to Methodology Development in Metal-Mediated Chemistry and Catalysis
  28. Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines
  29. Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines
  30. Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides
  31. Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides
  32. Ni–H-Catalyzed Chemo- and Regioselective Hydroarylation of Vinylsilanes
  33. Synthesis of a Cationic Cobalt–Selenolate Complex for Cooperative Sn–H Bond Activation: Solvent-Dependent Stereoselectivity in Alkyne Hydrostannylation
  34. Silylium-Ion-Initiated Twofold Halodealkylation of Fully Alkylated Silanes
  35. Enantioselective Dearomatization of Pyridinium Salts by Copper‐Catalyzed C4‐Selective Addition of Silicon Nucleophiles
  36. Enantioselektive Dearomatisierung von Pyridiniumsalzen durch kupferkatalysierte C4‐selektive Addition von Siliciumnukleophilen
  37. Functional group transfer strategies unlock new synthetic avenues
  38. Electrophilic Activation of S−Si Reagents by Silylium Ions for Their Regio‐ and Diastereoselective Addition Across C−C Multiple Bonds
  39. Elektrophile Aktivierung von S−Si‐Reagenzien mit Silyliumionen für deren regio‐ und diastereoselektive Addition an C−C‐Mehrfachbindungen
  40. Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
  41. Chiral Carborane Acids Decorated with Binol-Based Phosphonates: Synthesis, Characterization, and Application
  42. Desymmetrization of Cyclohexadienones Containing a Quaternary γ-Carbon Atom by Conjugate Addition of Boron Nucleophiles
  43. Ligand-Controlled On–Off Switch of a Silicon-Tethered Directing Group Enabling the Regiodivergent Hydroalkylation of Vinylsilanes under Ni–H Catalysis
  44. Bond-Forming Processes Enabled by Silicon-Masked Aryl- and Alkyl-Substituted Diazenes
  45. Arenium-ion-catalysed halodealkylation of fully alkylated silanes
  46. Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions
  47. Fluoride-Catalyzed Arylation of α-(Trifluoromethyl)styrene Derivatives with Silicon-Masked, Functionalized Aryl Pronucleophiles
  48. Generation of Silicon-Centered Stereogenicity by Chiral Counteranion-Directed Desymmetrization of Silanediols
  49. Dehydrative Coupling of 1,1-Diarylalkenes and Cyclohexa-2,5-diene-1-carbaldehyde Derivatives Induced by a B(C6F5)3-Initiated [1,2]-Alkyl Migration
  50. Regioselective Hydroalkylation of Vinyl- and Allylsilanes as Well as Vinylgermanes under Ni–H Catalysis
  51. Discrimination of the Enantiotopic Faces of Structurally Unbiased Carbenium Ions Employing a Cyclohexadiene‐Based Chiral Hydride Source
  52. Unterscheidung der enantiotopen Seiten von strukturell unvoreingenommenen Carbeniumionen unter Verwendung einer cyclohexadienbasierten, chiralen Hydridquelle
  53. The Two Faces of Carbenium Ions: Intermolecular Trapping of Prochiral Carbocations with Stereocontrol
  54. Atroposelective Silylation of 1,1′‐Biaryl‐2,6‐diols by a Chiral Counteranion Directed Desymmetrization Enhanced by a Subsequent Kinetic Resolution
  55. Atropselektive Silylierung von 1,1′‐Biaryl‐2,6‐diolen mittels chiraler gegenaniondirigierter Desymmetrisierung und anschließender Verbesserung durch kinetische Racematspaltung
  56. Enantio- and Regioconvergent Synthesis of γ-Stereogenic Vinyl Germanes and Their Use as Masked Vinyl Halides
  57. Intramolecular 7-endo-dig-Selective Carbosilylation of Internal Alkynes Involving Silylium-Ion Regeneration
  58. Photoinduced radical–ionic dihalogen transfer to carbon–carbon multiple bonds using oxime-based surrogates
  59. Catalytically Generated Meerwein’s Salt-Type Oxonium Ions for Friedel–Crafts C(sp2)–H Methylation with Methanol
  60. B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes
  61. Silylium Ion Initiated Intramolecular Friedel–Crafts-Type Cyclization of 1,1-Difluoroalkenes with Subsequent Hydrodefluorination of C(sp3)–F Bonds
  62. Copper‐Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3‐Substituted 2H‐Azirines Using an Si−B Reagent
  63. Kupferkatalysierte, hochgradig enantioselektive Addition eines Siliciumnukleophils an 3‐substituierte 2H‐Azirine unter Verwendung eines Si‐B‐Reagenzes
  64. The [3]Dendralene Motif as an Entry into Nazarov Cyclizations by Silylium-Ion Initiation
  65. Advances in Enantioconvergent Transition-Metal-Catalyzed Cross-Coupling Reactions of Racemic α-Silyl and α-Boryl Reagents
  66. Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis
  67. Experimental Mechanistic Analysis of Carbonyl Hydrosilylation Catalyzed by Abu-Omar’s Rhenium(V) Oxo Complex
  68. Synthesis of Benzhydryl-Substituted Amines by Silanolate-Mediated Aldimine Arylation with Functionalized Aryl Nucleophiles Released from Diazene-Based Reagents
  69. Palladium-Catalyzed Denitrogenative Cross-Coupling of Silicon-Masked, Aryl-Substituted Diazenes and Aryl Bromides
  70. Silylium-Ion-Promoted Skeletal Reorganization of β-Silylated Cyclopropanes Bearing an Allyl Group at the Silicon Atom Coupled with Intermolecular Formation of a Quaternary Carbon Atom
  71. Boosting the Enantioselectivity of Conjugate Borylation of α,β‐Disubstituted Cyclobutenones with Monooxides of ChiralC2‐Symmetric Bis(phosphine) Ligands
  72. Synthese von unsymmetrischen Azobenzolen durch palladiumkatalysierte Kreuzkupplung von siliciummaskierten Diazenylanionen und (Hetero)arylhalogeniden
  73. Synthesis of Non‐Symmetric Azoarenes by Palladium‐Catalyzed Cross‐Coupling of Silicon‐Masked Diazenyl Anions and (Hetero)Aryl Halides
  74. Photochemical, Nickel-Catalyzed C(sp3)–C(sp3) Reductive Cross-Coupling of α-Silylated Alkyl Electrophiles and Allylic Sulfones
  75. Enantio- and Regioconvergent Nickel-Catalyzed Allylic Substitution of Racemic α- or γ-Silylated Allylic Bromides with Benzylzinc Reagents
  76. Intermolecular Carbosilylation of α‐Olefins with C(sp3)−C(sp) Bond Formation Involving Silylium‐Ion Regeneration
  77. Intermolekulare Carbosilylierung von α‐Olefinen mit C(sp3)−C(sp)‐Bindungsknüpfung unter Neubildung von Silyliumionen
  78. B(C6F5)3-Catalyzed Reductive Denitrogenation of Benzonitrile Derivatives
  79. Decarbonylative Transfer Hydrochlorination of Alkenes and Alkynes Based on a B(C6F5)3‐Initiated Grob Fragmentation
  80. Decarbonylierende Transferhydrochlorierung von Alkenen und Alkinen auf Grundlage einer B(C6F5)3‐ausgelösten Grob‐Fragmentierung
  81. Cationic Cobalt–Thiolate Complexes for the Dehydrogenative Coupling of nBu3SnH
  82. Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis
  83. Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by Cyclization of the Allyl-Cation Intermediate
  84. Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion
  85. Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride
  86. One out of Four: Kinetic Resolution of Stereoisomeric Mixtures of Secondary Alcohols with a Quaternary Carbon Atom in the β-Position by Cu–H-Catalyzed Enantioselective Silylation
  87. Enantioselective, Copper-Catalyzed Addition of Nucleophilic Silicon to Alkenyl-Substituted Phosphine Oxides
  88. Synthesis of Silylated Cyclobutanone and Cyclobutene Derivatives Involving 1,4‐Addition of Zinc‐Based Silicon Nucleophiles
  89. Silylium-Ion Regeneration by Protodesilylation Enables Friedel–Crafts Alkylation with Less Isomerization and No Defunctionalization
  90. The Power of the Proton: From Superacidic Media to Superelectrophile Catalysis
  91. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  92. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  93. Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen
  94. Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
  95. Transition‐Metal‐Free Coupling of Polyfluorinated Arenes and Functionalized, Masked Aryl Nucleophiles
  96. B(C6F5)3-Catalyzed Diastereoselective Formal (4 + 1)-Cycloaddition of Vinylcyclopropanes and Et2SiH2
  97. Radical entry into Ni-catalyzed transfer hydrocyanation using cheap AIBN
  98. Metal‐Free Hydrosilylation of Ketenes with Silicon Electrophiles: Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers
  99. Enantio‐ and Regioconvergent Nickel‐Catalyzed C(sp3)−C(sp3) Cross‐Coupling of Allylic Electrophiles Steered by a Silyl Group
  100. Enantio‐ und regiokonvergente, nickelkatalysierte C(sp3)‐C(sp3)‐Kreuzkupplung von allylischen Elektrophilen gelenkt durch eine Silylgruppe
  101. Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts
  102. Chemoselective Deoxygenation of 2° Benzylic Alcohols through a Sequence of Formylation and B(C6F5)3‐Catalyzed Reduction
  103. Enantioconvergent and Regioselective Synthesis of Allenylsilanes by Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling Starting from Racemic α-Silylated Propargylic Bromides
  104. Development of a Radical Silylzincation of (Het)Aryl‐Substituted Alkynes and Computational Insights into the Origin of the trans‐Stereoselectivity
  105. Diastereotopic Group-Selective Intramolecular Aldol Reactions Initiated by Enantioselective Conjugate Silylation: Diastereodivergence Controlled by the Silicon Nucleophile
  106. The Trityl Cation Embedded into a [7]Helicene-Like Backbone: Preparation and Application as a Lewis Acid Catalyst
  107. Aufeinanderfolgende β,β′‐selektive C(sp3)‐H‐Silylierung von tertiären Aminen mit Dihydrosilanen katalysiert durch B(C6F5)3
  108. Consecutive β,β′‐Selective C(sp3)−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C6F5)3
  109. At Long Last: The Me3Si Group as a Masked Alcohol
  110. Zu guter Letzt: Die Me3Si‐Gruppe als ein getarnter Alkohol
  111. Activation of the Si–B interelement bond related to catalysis
  112. Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes
  113. Mild reductive rearrangement of oximes and oxime ethers to secondary amines with hydrosilanes catalyzed by B(C6F5)3
  114. Kinetic Resolution of Neopentylic Secondary Alcohols by Cu–H-Catalyzed Enantioselective Silylation with Hydrosilanes
  115. Cationic Ru–Se Complexes for Cooperative Si–H Bond Activation
  116. Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition‐Metal Catalysts
  117. Dynamische kinetische Racematspaltung von Alkoholen mittels enantioselektiver Silylierung ermöglicht durch zwei orthogonale Übergangsmetallkatalysatoren
  118. The Cyclohexa‐2,5‐dienyl Group as a Placeholder for Hydrogen: Organocatalytic Michael Addition of an Acetaldehyde Surrogate
  119. Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors
  120. B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes
  121. Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates
  122. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
  123. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
  124. Reductive Deamination with Hydrosilanes Catalyzed by B(C6F5)3
  125. Reduktive Desaminierung mit Hydrosilanen katalysiert durch B(C6F5)3
  126. Copper-Catalyzed Enantioselective and Exo-Selective Addition of Silicon Nucleophiles to 7-Oxa- and 7-Azabenzonorbornadiene Derivatives
  127. Synthese eines gegenanionstabilisierten Bis(silylium)ions
  128. Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion
  129. Kilian Muñiz (1970–2020)
  130. Seeds for the Future: Growing Chemistry Trends
  131. Autocatalytic Carbonyl Arylation through In Situ Release of Aryl Nucleophiles from N‐Aryl‐N′‐Silyldiazenes
  132. Autokatalytische Carbonylarylierung mittels lokaler Freisetzung von Arylnukleophilen ausgehend von N‐Aryl‐N′‐silyldiazenen
  133. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes
  134. Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C−F Coupling of Aryl Boronic Esters
  135. Übergangsmetallartige Katalyse mit einem Hauptgruppenelement: Bismutkatalysierte C‐F‐Kupplung von Arylboronsäureestern
  136. Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O2-Tolerant [NiFe] Hydrogenase
  137. Defunctionalisation catalysed by boron Lewis acids
  138. Emerging Strategies for C–H Silylation
  139. Outstanding Reviewers for Chemical Science in 2019
  140. Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates
  141. Stereospezifische und chemoselektive kupferkatalysierte, deaminierende Silylierung von Benzylammoniumtriflaten
  142. General Synthesis and Optical Properties of N-Aryl-N′-Silyldiazenes
  143. Cationic silicon Lewis acids in catalysis
  144. Chiral Modification of the Tetrakis(pentafluorophenyl)borate Anion with Myrtanyl Groups
  145. Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates
  146. Si-H Bond Activation with Bullock’s Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand
  147. Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions
  148. Katalytische Difunktionalisierung von nichtaktivierten Alkenen mit reaktionsträgem Hexamethyldisilan durch Neubildung von Silyliumionen
  149. Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes
  150. Lewis Säure‐katalysierte Transferhydromethallylierung für den Aufbau quartärer Kohlenstoffzentren
  151. Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers
  152. Characterization of hydrogen-substituted silylium ions in the condensed phase
  153. Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to Alkenes Activated by Azaaryl Groups
  154. Kupferkatalysierte regio‐ und enantioselektive Addition von Silicium‐Grignard‐Reagenzien an durch Azaarylgruppen aktivierte Alkene
  155. Metal-Free Transfer Hydrobromination of C–C Triple Bonds
  156. Bioinspired Metal‐Free Formal Decarbonylation of α‐Branched Aliphatic Aldehydes at Ambient Temperature
  157. Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes Initiated by Enantioselective Copper-Catalyzed Borylation
  158. Tertiäre α‐Silylalkohole mittels diastereoselektiver Kupplung von 1,3‐Dienen und Acylsilanen, eingeleitet durch enantioselektive kupferkatalysierte Borylierung
  159. Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups
  160. Regiodivergent and Stereospecific Aziridine Opening by Copper‐Catalyzed Addition of Silicon Grignard Reagents
  161. Mechanistic Dichotomy of Magnesium- and Zinc-Based Germanium Nucleophiles in the C(sp3 )−Ge Cross-Coupling with Alkyl Electrophiles
  162. Gegensätzliche Reaktionsweisen magnesium‐ und zinkbasierter Germaniumnukleophile in der C(sp 3 )‐Ge‐Kreuzkupplung mit Alkylelektrophilen
  163. Further Structural Modification of Sulfur-Stabilized Silicon Cations with Binaphthyl Backbones
  164. Enantioselective Construction of α-Chiral Silanes by Nickel-Catalyzed C(sp3 )−C(sp3 ) Cross-Coupling
  165. Enantioselektiver Aufbau von α‐chiralen Silanen durch nickelkatalysierte C(sp 3 )‐C(sp 3 )‐Kreuzkupplung
  166. Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and Reactivity in the Hydrosilylation of Ketones
  167. Bor-Lewis-Säure-katalysierte Transferhydrocyanierung α- und α,β-substituierter Styrole
  168. Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids
  169. Kinetic Resolution of Tertiary Propargylic Alcohols by Enantioselective Cu−H-Catalyzed Si−O Coupling
  170. Kinetische Racematspaltung tertiärer Propargylalkohole durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  171. Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones
  172. Using alcohols as simple H2-equivalents for copper-catalysed transfer semihydrogenations of alkynes
  173. Metal-Free Transfer Hydroiodination of C–C Multiple Bonds
  174. Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles
  175. Palladium-Catalyzed Three-Component Reaction of Dihydrosilanes and Vinyl Iodides in the Presence of Alcohols: Rapid Assembly of Silyl Ethers of Tertiary Silanes
  176. C(sp3)–Si Cross-Coupling
  177. Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels–Alder Reactions with Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  178. Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution
  179. Einelektronenübertragungsreaktionen in frustrierten und klassischen Silyliumion/Phosphan-Lewis-Paaren
  180. Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs
  181. Regioselective Transfer Hydrodeuteration of Alkenes with a Hydrogen Deuteride Surrogate Using B(C6F5)3 Catalysis
  182. Electrophilic Phosphonium Cations as Lewis Acid Catalysts in Diels–Alder Reactions and Nazarov Cyclizations
  183. Bioinspired Catalytic Generation of Main-group Electrophiles by Cooperative Bond Activation
  184. Bench-Stable Stock Solutions of Silicon Grignard Reagents: Application to Iron- and Cobalt-Catalyzed Radical C(sp3 )-Si Cross-Coupling Reactions
  185. Stabile Stammlösungen von Silicium-Grignard-Reagenzien: Anwendung in eisen- und cobaltkatalysierten radikalischen C(sp3 )-Si-Kreuzkupplungsreaktionen
  186. Copper-Catalyzed Double C(sp3)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Switch in the Reaction Mechanism
  187. Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral C6 F5 -Substituted Boron Lewis Acid
  188. Enantioselektive Nazarov-Cyclisierungen, die von einer axial-chiralen, C6 F5 -substituierten Bor-Lewis-Säure katalysiert werden
  189. Z-Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by the Trityl Cation
  190. Copper-Catalyzed Silylation of C(sp3)–H Bonds Adjacent to Amide Nitrogen Atoms
  191. Innenrücktitelbild: Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung (Angew. Chem. 33/2018)
  192. Inside Back Cover: Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling (Angew. Chem. Int. Ed. 33/2018)
  193. Cleavage of Unactivated Si−C(sp3 ) Bonds with Reed's Carborane Acids: Formation of Known and Unknown Silylium Ions
  194. Spaltung nicht aktivierter Si-C(sp3 )-Bindungen mit Reedschen Carboransäuren: Bildung bekannter und unbekannter Silyliumionen
  195. Custom Hydrosilane Synthesis Based on Monosilane
  196. Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide
  197. Elektrophile Formylierung von Aromaten durch silyliumionvermittelte Aktivierung von Kohlenmonoxid
  198. Direct Acetophenone-Acetophenone Crossed Aldol Reaction and Aldol Self-Reaction Promoted by a Tethered Ru-S Complex
  199. Refinement of the Catalyst Backbone of Chiral Intramolecular Silicon-Sulfur Lewis Pairs: Improved Enantioselectivity in the Diels-Alder Reaction of Cyclohexa-1,3-diene and Chalcone Derivatives
  200. Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling
  201. Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  202. A Neutral RuII Hydride Complex for the Regio- and Chemoselective Reduction of N -Silylpyridinium Ions
  203. The electrophilic aromatic substitution approach to C–H silylation and C–H borylation
  204. Catalytic Dehydrogenative Stannylation of C(sp)–H Bonds Involving Cooperative Sn–H Bond Activation of Hydrostannanes
  205. Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion
  206. Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration
  207. Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst
  208. Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation
  209. Cluster Preface: Silicon in Synthesis and Catalysis
  210. An Expedient Procedure for the Synthesis of Benzo[4,5]silolo[2,3-b]thiophenes and Related Systems
  211. Copper-Catalyzed Decarboxylative Radical Silylation of Redox-Active Aliphatic Carboxylic Acid Derivatives
  212. Kupferkatalysierte decarboxylierende radikalische Silylierung von redoxaktiven aliphatischen Carbonsäurederivaten
  213. B(C6F5)3-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes
  214. BArF3-Catalyzed Imine Hydroboration with Pinacolborane Not Requiring the Assistance of an Additional Lewis Base
  215. Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes
  216. Exhaustive Chemoselective Reduction of Nitriles by Catalytic Hydrosilylation Involving Cooperative Si–H Bond Activation
  217. Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study
  218. Photocatalysis Enabling Acceptorless Dehydrogenation of Benzofused Saturated Rings at Room Temperature
  219. Photokatalyse ermöglicht die akzeptorfreie Dehydrierung von benzanellierten gesättigten Ringen bei Raumtemperatur
  220. Synthesis of a Chiral Borate Counteranion, Its Trityl Salt, and Application Thereof in Lewis-Acid Catalysis
  221. Cooperative Catalysis at Metal–Sulfur Bonds
  222. Access to Fully Alkylated Germanes by B(C6F5)3-Catalyzed Transfer Hydrogermylation of Alkenes
  223. A Tethered Ru-S Complex with an Axial Chiral Thiolate Ligand for Cooperative Si-H Bond Activation: Application to Enantioselective Imine Reduction
  224. Katalytische Friedel-Crafts-C-H-Borylierung elektronenreicher Arene: starke Reaktionsbeschleunigung durch Versetzen mit Alkenen
  225. Catalytic Friedel-Crafts C−H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes
  226. Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand
  227. B(C6F5)3-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes
  228. B(C6F5)3-katalysierte chemoselektive Defunktionalisierung von etherhaltigen primären Alkyltosylaten mit Hydrosilanen
  229. Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application
  230. Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes
  231. Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes
  232. C H Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3)
  233. 4.4.7 Product Subclass 7: Silylboron Reagents
  234. Catalytic Access to Indole-Fused Benzosiloles by 2-Fold Electrophilic C–H Silylation with Dihydrosilanes
  235. Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C−H Silylation
  236. Elektrophile aromatische Substitution mit Siliciumelektrophilen: die katalytische Friedel-Crafts-C-H-Silylierung
  237. Teaching nature the unnatural
  238. Stereodivergent Synthesis of β-Heteroatom-Substituted Vinyl­silanes by Sequential Silylzincation–Copper(I)-Mediated Electrophilic­ Substitution
  239. 3-tert -Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 )3 -Catalyzed Transfer Hydro-tert -Butylation of Alkenes
  240. Copper-Catalyzed Cross-Coupling of Silicon Pronucleophiles with Unactivated Alkyl Electrophiles Coupled with Radical Cyclization
  241. Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF 3 Does What B(C6 F5 )3 Cannot Do!
  242. Enantioselective Diels–Alder Reactions of Cyclohexa-1,3-diene and Chalcones Catalyzed by Intramolecular Silicon–Sulfur Lewis Pairs as Chiral Lewis Acids
  243. Ausbalancieren von C=C-Funktionalisierung und C=O-Reduktion in der Cu-H-Katalyse
  244. Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis
  245. Merging Platinum-Catalyzed Alkene Hydrosilylation with SiH4 Surrogates: Salt-Free Preparation of Trihydrosilanes
  246. Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation
  247. B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes
  248. Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates
  249. The Asymmetric Piers Hydrosilylation
  250. Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,4-dienes as Dihydrogen Surrogates
  251. Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes
  252. Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations
  253. An Air-Stable Dimeric Ru–S Complex with an NHC as Ancillary Ligand for Cooperative Si–H Bond Activation
  254. Copper-Catalyzed Si–B Bond Activation in the Nucleophilic Substitution of Primary Aliphatic Triflates
  255. Planar Chiral, Ferrocene-Stabilized Silicon Cations
  256. Durch Nichtedelmetallsalze ausgelöste Friedel-Crafts-artige intermolekulare C-H-Silylierung von elektronenreichen Arenen
  257. Friedel-Crafts-Type Intermolecular C−H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts
  258. Transfer Hydrosilylation
  259. Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization
  260. Extending the Scope of the B(C6F5)3-Catalyzed CN Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones
  261. Phosphinic Amide as Directing Group Enabling Palladium(II)-CatalyzedorthoC−H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom
  262. B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another
  263. Formal SiH4 chemistry using stable and easy-to-handle surrogates
  264. The Cyclohexadienyl-Leaving-Group Approach toward Donor-Stabilized Silylium Ions
  265. A Catalytic SEAr Approach to Dibenzosiloles Functionalized at Both Benzene Cores
  266. Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels–Alder Reactions
  267. Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors
  268. Platinum(0)-Catalyzed Indolyne Insertion into Bis(pinacolato)diboron Followed by Site-Selective Suzuki–Miyaura Cross-Coupling
  269. Synthesis of 2,6-Dihalogenated Purine Nucleosides by Thermostable Nucleoside Phosphorylases
  270. A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination
  271. Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution
  272. Faszinierende Chemie des Wasserstoffatomtransfers auf Alkene inspiriert durch Probleme in Totalsynthesen
  273. Fascinating Hydrogen Atom Transfer Chemistry of Alkenes Inspired by Problems in Total Synthesis
  274. Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State
  275. Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study
  276. A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
  277. Mechanism of the cooperative Si–H bond activation at Ru–S bonds
  278. Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
  279. Asymmetric Addition of Boron and Silicon Nucleophiles
  280. B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa-1,4-dienes as a Dihydrogen Source
  281. B(C6F5)3-katalysierte Transferhydrierung von Iminen und verwandten Heteroaromaten mit Cyclohexa-1,4-dienen als Wasserstoffquelle
  282. Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C–H/C–H Arylation of Indolines at the C-7 Position under Air
  283. Chemoselective Tin–Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom
  284. B(C6F5)3-Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond
  285. B(C6F5)3-katalysierte Hydrierung von Oximethern ohne Spaltung der N-O-Bindung
  286. Trans-Selective Radical Silylzincation of Ynamides
  287. Trans-Selective Radical Silylzincation of Ynamides
  288. McQuade’s Six-Membered NHC–Copper(I) Complexes for Catalytic Asymmetric­ Silyl Transfer
  289. Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds
  290. New Frontiers and Challenges in Silicon Chemistry:ISOS XVII in Berlin
  291. Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  292. En Route to Stable All-Carbon-Substituted Silylenes: Synthesis and Reactivity of a Bis(α-spirocyclopropyl)silylene
  293. Martin Oestreich
  294. Martin Oestreich
  295. Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling
  296. Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex
  297. Enantioselektive Addition von Siliciumnukleophilen an Aldimine mit einem präformierten NHC-Kupfer(I)-Komplex als Katalysator
  298. Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Copper(I) Complex as the Catalyst
  299. Diastereotopic Group Selection in Hydroxy‐Directed Intramolecular CH Alkenylation of Indole under Oxidative Palladium(II) Catalysis
  300. Tris(5,6,7,8-tetrafluoronaphthalen-2-yl)borane, a Partially Fluorinated Boron Lewis Acid with Fluorination Distal to the Boron Atom
  301. Brandaktuelles von der enantioselektiven intermolekularen Heck-Reaktion
  302. Breaking News on the Enantioselective Intermolecular Heck Reaction
  303. Salt-Free Preparation of Trimethylsilyl Ethers by B(C6F5)3-Catalyzed Transfer Silylation by Using a Me3SiH Surrogate
  304. Metal-Catalyzed Cross-Coupling Reactions and More
  305. 7.21 Addition Reactions with Formation of CarbonHalogen Bonds
  306. Ferrocene-Stabilized Silicon Cations as Catalysts for Diels–Alder Reactions: Attempted Experimental Quantification of Lewis Acidity and ReactIR Kinetic Analysis
  307. Silylium Ion Promoted Reduction of Imines with Hydrosilanes
  308. Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism
  309. The Family of Ferrocene‐Stabilized Silylium Ions: Synthesis,29Si NMR Characterization, Lewis Acidity, Substituent Scrambling, and Quantum‐Chemical Analyses
  310. Oxidative Palladium(II)-Catalyzed C-7 Alkenylation of Indolines
  311. 3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes
  312. 3-Silylierte Cyclohexa-1,4-diene als Vorstufen für gasförmige Hydrosilane: die B(C6F5)3-katalysierte Transferhydrosilylierung von Alkenen
  313. Katalytische 1,4-selektive Hydrosilylierung von Pyridinverbindungen und benzanellierten Verwandten
  314. Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners
  315. Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane
  316. Main-Group Lewis Acids for C–F Bond Activation
  317. Oxidative Palladium(II)-Catalyzed Dehydrogenative CH/CH Cross-Coupling of 2,3-Substituted Indolines with Arenes at the C7 Position
  318. Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by a Silicon Nucleophile
  319. SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pincer Complex and B(C6F5)3
  320. Si-H-Bindungsaktivierung: Parallelen der Lewis-Säure-Katalyse mit Brookharts Iridium(III)-Pincerkomplex und B(C6F5)3
  321. Asymmetrische Synthese α-chiraler Allylsilane durch enantiokonvergente γ-selektive Kupfer(I)-katalysierte allylische Silylierung
  322. Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation
  323. C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle
  324. The Renaissance of Silicon-Stereogenic Silanes: A Personal Account
  325. Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis
  326. Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base
  327. Aerobic Palladium(II)-Catalyzed Dehydrogenation of Cyclohexene-1-carbonyl Indole Amides: An Indole-Directed Aromatization
  328. Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
  329. Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane
  330. 1,2,3,4-Tetrahydro-1-(1,1-dimethylethyl)-1-silanaphthalene
  331. 1,2,3,4-Tetrahydro-1-(1-methylethyl)-1-silanaphthalene
  332. Hemilabile BINAP(O) as a Chiral Ligand in Desymmetrizing Mizoroki-Heck Cyclizations
  333. Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophilic Silicon to Propargylic Chlorides and Phosphates
  334. Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes
  335. Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles
  336. Organic Reactions. Volume 75 (Diamond Volume). Herausgegeben von Scott E. Denmark.
  337. Organic Reactions. Volume 75 (Diamond Volume). Edited by Scott E. Denmark.
  338. Catalytic enantioselective dehydrogenative Si–O coupling of oxime ether-functionalized alcohols
  339. Silylium Ion-Catalyzed Challenging Diels–Alder Reactions: The Danger of Hidden Proton Catalysis with Strong Lewis Acids
  340. Ein neuer Weg der C-H-Alkenylierung: Silanol als helfende Hand
  341. A New Direction in CH Alkenylation: Silanol as a Helping Hand
  342. Aerobic Palladium(II)-Catalyzed 5-endo-trig Cyclization: An Entry into the Diastereoselective C-2 Alkenylation of Indoles with Tri- and Tetrasubstituted Double Bonds
  343. Aerobe Palladium(II)-katalysierte 5-endo-trig-Cyclisierung als ein Einstieg in die diastereoselektive C-2-Alkenylierung von Indolen mit tri- und tetrasubstituierten Doppelbindungen
  344. Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems
  345. BINAP versus BINAP(O) in Asymmetric Intermolecular Mizoroki-Heck Reactions: Substantial Effects on Selectivities
  346. Copper(I)-Catalyzed Regioselective Propargylic Substitution Involving Si–B Bond Activation
  347. A New Motif for Lewis Base Catalysis: Asymmetric Reduction of β-Enamino Esters
  348. A Unique Transition Metal-Stabilized Silicon Cation
  349. An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity
  350. Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines
  351. Shortened Synthesis of a Silicon-Stereogenic Cyclic Silane
  352. Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism
  353. Organische Chemie 2010
  354. All-Carbon-Substituted Quaternary Carbon Atoms in Oxindoles by an Aerobic Palladium(II)-Catalyzed Ring Closure onto Tri- and Tetrasubstituted Double Bonds
  355. Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles
  356. Self-regeneration of a silylium ion catalyst in carbonyl reduction
  357. Stereochemical Surprises in the Lewis Acid-Mediated Allylation of Isatins
  358. Kupferkatalysierte Si-B-Bindungsaktivierung in der verzweigtselektiven allylischen Substitution linearer Allylchloride
  359. Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides
  360. Base-Catalyzed Dehydrogenative Si-O Coupling of Dihydrosilanes: Silylene Protection of Diols
  361. Transition-Metal-Catalyzed C-P Cross-Coupling Reactions
  362. Der asymmetrische konjugierte Silyltransfer in iterativen katalytischen Sequenzen: Synthese des C7-C16-Fragments von (+)-Neopeltolid
  363. Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide
  364. Expeditious synthesis of TADDOL-derived phosphoramidite and phosphonite ligands
  365. Katalytische asymmetrische Si-O-Kupplung einfacher achiraler Silane und chiraler donorfunktionalisierter Alkohole
  366. Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols
  367. Organische Chemie 2009
  368. Enantioselektive konjugierte Borylierung
  369. Enantioselective Conjugate Borylation
  370. Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!
  371. Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides
  372. Asymmetric Si–O coupling of alcohols
  373. Silylium ions in catalysis
  374. Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes
  375. Ein gezähmtes Silyliumion für Diels-Alder-Reaktionen bei niedrigen Temperaturen
  376. Taming the Silylium Ion for Low-Temperature Diels-Alder Reactions
  377. B(C 6 F 5 ) 3 -Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding
  378. Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)–phosphine or Rh(I)–carbene complexes. Probing the mechanism with chirality at the silicon atom or the phosphorus atom of the Si–P reagent
  379. Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon
  380. Enantiospezifische Synthese und Allylierung ausschließlich Kohlenstoff-substituierter, α-chiraler Allylstannane
  381. Enantiospecific Synthesis and Allylation of All-Carbon-Substituted α-Chiral Allylic Stannanes
  382. Asymmetrische Ringschlussmetathese mit Pfiff
  383. Asymmetric Ring-Closing Metathesis with a Twist
  384. Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors
  385. Potassiumtert-Butoxide-Catalyzed Dehydrogenative SiO Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection
  386. Organische Chemie 2008
  387. The Mizoroki–Heck Reaction
  388. Facile preparation of CF3-substituted carbinols with an azine donor and subsequent kinetic resolution through stereoselective Si–O coupling
  389. Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes
  390. A Catalytic Asymmetric Fujiwara-Moritani Cyclization
  391. Schlüssiger Nachweis eines SN2-Si-Mechanismus in der B(C6F5)3- katalysierten Hydrosilylierung von Carbonylverbindungen: Einsichten in die verwandte Hydrierung
  392. Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation
  393. Transition-Metal-Free Conjugate Stannyl Transfer to α,β-Unsaturated Carbonyl and Carboxyl Compounds in Basic Aqueous Media
  394. Katalytische asymmetrische C-Si-Bindungsknüpfung an acyclischen α,β-ungesättigten Akzeptoren durch RhI-katalysierten konjugierten Silyltransfer mithilfe einer Si-B-Bindung
  395. Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage
  396. Enantio- and Diastereotopos Differentiation in the Palladium(II)-Catalyzed Hydrosilylation of Bicyclo[2.2.1]alkene Scaffolds with Silicon-Stereogenic Silanes
  397. Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane
  398. Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols
  399. Kinetische Racematspaltung und Desymmetrisierung durch stereoselektive Silylierung von Alkoholen
  400. Chirale Erkennung mit siliciumstereogenen Silanen: außergewöhnliche Selektivitätsfaktoren bei der kinetischen Racematspaltung von donorfunktionalisierten Alkoholen
  401. Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols
  402. Oxygen Donor-Mediated Equilibration of Diastereomeric Alkene−Palladium(II) Intermediates in Enantioselective Desymmetrizing Heck Cyclizations
  403. Silicon-Stereogenic Silanes in Asymmetric Catalysis
  404. Polishing a Diamond in the Rough: “Cu—H” Catalysis with Silanes
  405. Asymmetric Synthesis - The Essentials
  406. Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A comparative study
  407. Vom Schleifen eines “Rohdiamanten”: die “Cu-H”-Katalyse mit Silanen
  408. Polishing a Diamond in the Rough: “CuH” Catalysis with Silanes
  409. Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides
  410. Directed Mizoroki–Heck Reactions
  411. Synthesis by Hydration of Alkynes
  412. Synthesis by Direct Hydration
  413. Intermolecular Chirality Transfer from Silicon to Carbon:  Interrogation of the Two-Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Crossover
  414. Organische Chemie online… und gratis?
  415. Organic Chemistry Online … and for Free?
  416. An Enantioselective Access to an Anthracycline AB Synthon by a ­Desymmetrizing Heck Cyclization
  417. Rhodiumkatalysierter enantioselektiver konjugierter Silyltransfer: 1,4-Addition von Silylboronsäureestern an cyclische Enone und Lactone
  418. Rhodium-Catalyzed Enantioselective Conjugate Silyl Transfer: 1,4-Addition of Silyl Boronic Esters to Cyclic Enones and Lactones
  419. Preparation of a Privileged Silicon-Stereogenic Silane: Classicalversus Kinetic Resolution
  420. Copper-Free and Copper-Promoted Conjugate Addition Reactions of Bis(triorganosilyl) Zincs and Tris(triorganosilyl) Zincates
  421. Organische Chemie 2005
  422. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Herausgegeben von Jens Christoffers und Angelika Baro.
  423. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Edited by Jens Christoffers and Angelika Baro.
  424. Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes
  425. Silylzincation of carbon–carbon multiple bonds revisited
  426. Chirality Transfer from Silicon to Carbon
  427. Kinetische Racematspaltung von chiralen sekundären Alkoholen durch dehydrierende Kupplung mit zurückgewinnbaren, siliciumstereogenen Silanen
  428. Kinetic Resolution of Chiral Secondary Alcohols by Dehydrogenative Coupling with Recyclable Silicon-Stereogenic Silanes
  429. OMCOS 13
  430. Kaleidoskop der Katalyse: Heidelberger Forum für Molekulare Katalyse 2005
  431. Kaleidoscope of Catalysis: Heidelberg Forum of Molecular Catalysis 2005
  432. Schweizer Leckerli: Bürgenstock 2005
  433. Swiss Delight: Bürgenstock 2005
  434. Chemie-Nachwuchsgruppenleiter in Freiburg
  435. Strategien zur katalytischen asymmetrischen elektrophilen ?-Halogenierung von Carbonylverbindungen
  436. Strategies for Catalytic Asymmetric Electrophilic ? Halogenation of Carbonyl Compounds
  437. Practical Synthesis of Allylic Silanes from Allylic Esters and Carbamates by Stereoselective Copper-Catalyzed Allylic Substitution Reactions
  438. ?Echter? Chiralit�tstransfer von Silicium auf Kohlenstoff: asymmetrische Verst�rkung in einer reagenskontrollierten palladiumkatalysierten Hydrosilylierung
  439. ?True? Chirality Transfer from Silicon to Carbon: Asymmetric Amplification in a Reagent-Controlled Palladium-Catalyzed Hydrosilylation
  440. Neighbouring‐Group Effects in Heck Reactions
  441. Hypervalent Silicon as a Reactive Site in Selective Bond-Forming Processes
  442. Catalytic Desymmetrizing Intramolecular Heck Reaction: Evidence for an Unusual Hydroxy-Directed Migratory Insertion
  443. On the Mechanism of the Reductive Metallation of Asymmetrically Substituted Silyl Chlorides
  444. Katalytische desymmetrisierende intramolekulare Heck-Reaktion: Nachweis einer ungewöhnlichen hydroxydirigierten Alkeninsertion
  445. Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters
  446. 23. Regio-Symposium in Falkau/Schwarzwald
  447. Copper-Catalyzed Conjugate Addition of a Bis(triorganosilyl) Zinc and a Methyl(triorganosilyl) Magnesium
  448. Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions
  449. A Convergent Method for the Synthesis of Highly Enantiomerically Enriched Cyclic Silanes with Silicon-Centered Chirality
  450. Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion
  451. Thwartingβ-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction
  452. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  453. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  454. (−)-Sparteine-Mediated Asymmetric Intramolecular Carbolithiation of Alkenes: Synthesis of Enantiopure Cyclopentanes with Three Consecutive Stereogenic Centers
  455. (−)-Sparteine-Mediated Stereoselective Intramolecular Carbolithiation of 4-Substituted 5-Hexynyl Carbamates. Synthesis of Enantiopure 1,3-Difunctionalized Alkylidene Cyclopentanes
  456. Corrigendum
  457. (−)-Sparteine-mediated stereoselective intramolecular conjugate addition reactions of dienes and enynes
  458. (−)-Sparteine-mediated stereoselective intramolecular carbolithiation of alkynes
  459. Stereoselective Preparation and Reactions of Cycloalkylzinc Compounds
  460. Stereoselektive Herstellung und Reaktionen von Cycloalkylzinkverbindungen
  461. Formation of Carbocycles
  462. Palladium-Catalyzed Arylation Reactions of Alkenes (Mizoroki–Heck Reaction and Related Processes)
  463. Taming Super Lewis Acids for Catalysis: The Family of Ferrocene-Stabilized Silicon Cations
  464. Diverse Modes of Silane Activation for the Hydrosilylation of Carbonyl Compounds