All Stories

  1. Cooperative redox and spin activity from three redox congeners of sulfur-bridged iron nitrosyl and nickel dithiolene complexes

    Article • Proceedings of the National Academy of Sciences, June 2022, Proceedings of the National Academy of Sciences

    Professor Marcetta Y Darensbourg

  2. Connecting Main-Group Metals (Al, Ga, In) and Tungsten(0) Carbonyls via the N2S2 Metallo-Ligand Strategy

    Article • Inorganics, September 2019, MDPI AG

    Professor Marcetta Y Darensbourg

  3. A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen versus Sulfur-Gold Interactions

    Article • Angewandte Chemie, July 2015, Wiley

    Professor Marcetta Y Darensbourg

  4. A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen versus Sulfur-Gold Interactions

    Article • Angewandte Chemie, July 2015, Wiley

    Professor Marcetta Y Darensbourg

  5. Synthetic Advances Inspired by the Bioactive Dinitrosyl Iron Unit

    Article • Accounts of Chemical Research, July 2015, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  6. ChemInform Abstract: Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry

    Article • ChemInform, July 2015, Wiley

    Professor Marcetta Y Darensbourg

  7. Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry

    Article • Chemical Reviews, June 2015, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  8. Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties

    Article • Inorganic Chemistry, April 2015, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  9. The ligand unwrapping/rewrapping pathway that exchanges metals in S-acetylated, hexacoordinate N2S2O2complexes

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  10. Intramolecular Iron-Mediated C–H Bond Heterolysis with an Assist of Pendant Base in a [FeFe]-Hydrogenase Model

    Article • Journal of the American Chemical Society, December 2014, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  11. The Bioorganometallic Chemistry of Hydrogenase

    Article • November 2014, Wiley

    Professor Marcetta Y Darensbourg

  12. Conformational Mobility and Pendent Base Effects on Electrochemistry of Synthetic Analogues of the [FeFe]-Hydrogenase Active Site

    Article • Organometallics, September 2014, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  13. Metallodithiolates as Ligands to Dinitrosyl Iron Complexes: Toward the Understanding of Structures, Equilibria, and Spin Coupling

    Article • Inorganic Chemistry, September 2014, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  14. Electrocatalytic O2Reduction by [Fe-Fe]-Hydrogenase Active Site Models

    Article • Journal of the American Chemical Society, June 2014, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  15. Redox active iron nitrosyl units in proton reduction electrocatalysis

    Article • Nature Communications, May 2014, Springer Science + Business Media

    Professor Marcetta Y Darensbourg

  16. Heterogenization of a Water-Insoluble Molecular Complex for Catalysis of the Proton-Reduction Reaction in Highly Acidic Aqueous Solutions

    Article • Electrocatalysis, April 2014, Springer Science + Business Media

    Professor Marcetta Y Darensbourg

  17. N,N′-Bis(Mercaptoethyl)-1,4-Diazacycloheptane (H2BME-DACH) and its Nickel Complex: A Model for Bioinorganic Chemistry

    Article • April 2014, Wiley

    Professor Marcetta Y Darensbourg

  18. Molecular catalysis that transpires only when the complex is heterogenized: Studies of a hydrogenase complex surface-tethered on polycrystalline and (111)-faceted gold by EC, PM-FT-IRRAS, HREELS, XPS and STM

    Article • Journal of Electroanalytical Chemistry, March 2014, Elsevier

    Professor Marcetta Y Darensbourg

  19. Addendum to Immobilization-Enabled Proton-Reduction Catalysis by a Di-iron Hydrogenase Mimic

    Article • Electrocatalysis, February 2014, Springer Science + Business Media

    Professor Marcetta Y Darensbourg

  20. Versatile N2S2nickel-dithiolates as mono- and bridging bidentate, S-donor ligands to gold(i)

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  21. Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes

    Article • Chemical Science, January 2014, Royal Society of Chemistry

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  22. Immobilization-Enabled Proton Reduction Catalysis by a Di-iron Hydrogenase Mimic

    Article • Electrocatalysis, September 2013, Springer Science + Business Media

    Professor Marcetta Y Darensbourg

  23. Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M=Fe, Co) as metallodithiolate ligands

    Article • Polyhedron, July 2013, Elsevier

    Professor Marcetta Y Darensbourg

  24. Enzymes activated by synthetic components

    Article • Nature, June 2013, Springer Science + Business Media

    Professor Marcetta Y Darensbourg

  25. Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)/ Thiolate Dinitrosyl Iron Complex (DNIC)

    Article • Journal of the American Chemical Society, June 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  26. Hyperfine interactions and electron distribution in FeIIFeI and FeIFeI models for the active site of the [FeFe] hydrogenases: Mössbauer spectroscopy studies of low-spin FeI

    Article • JBIC Journal of Biological Inorganic Chemistry, May 2013, Springer Science + Business Media

    Professor Marcetta Y Darensbourg

  27. Ambidentate Thiocyanate and Cyanate Ligands in Dinitrosyl Iron Complexes

    Article • Inorganic Chemistry, February 2013, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  28. Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  29. A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion

    Article • Chemical Communications, January 2013, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  30. Structural and Spectroscopic Features of Mixed Valent Fe II Fe I Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase

    Article • Journal of the American Chemical Society, August 2012, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  31. Time Resolved Infrared Spectroscopy: Kinetic Studies of Weakly Binding Ligands in an Iron–Iron Hydrogenase Model Compound

    Article • Inorganic Chemistry, July 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  32. Comparisons of zinc with cadmium in N2S2coordination and as S-bonded adducts to tungsten carbonyls

    Article • Dalton Transactions, January 2012, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  33. Self-Assembly of Dinitrosyl Iron Units into Imidazolate-Edge-Bridged Molecular Squares: Characterization Including Mössbauer Spectroscopy

    Article • Journal of the American Chemical Society, December 2011, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  34. Merging the old with the new

    Article • Nature Chemistry, December 2011, Springer Science + Business Media

    Professor Marcetta Y Darensbourg

  35. N-Heterocyclic Carbene Ligands as Mimics of Imidazoles/Histidine for the Stabilization of Di- and Trinitrosyl Iron Complexes

    Article • Inorganic Chemistry, September 2011, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  36. Modeling Structures and Vibrational Frequencies for Dinitrosyl Iron Complexes (DNICs) with Density Functional Theory

    Article • Inorganic Chemistry, September 2011, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  37. Sulfonated Diiron Complexes as Water-Soluble Models of the [Fe–Fe]-Hydrogenase Enzyme Active Site

    Article • Inorganic Chemistry, June 2011, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  38. Tetradentate N 2 S 2 Vanadyl(IV) Coordination Complexes: Synthesis, Characterization, and Reactivity Studies

    Article • Inorganic Chemistry, March 2011, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  39. Article • European Journal of Inorganic Chemistry, March 2011, Wiley

    Professor Marcetta Y Darensbourg

  40. Hydrogenases (Eur. J. Inorg. Chem. 7/2011)

    Article • European Journal of Inorganic Chemistry, February 2011, Wiley

    Professor Marcetta Y Darensbourg

  41. Sulfoxygenation of Active Site Models of [NiFe] and [FeFe] Hydrogenases – A Commentary on Possible Chemical Models of Hydrogenase Enzyme Oxygen Sensitivity

    Article • European Journal of Inorganic Chemistry, February 2011, Wiley

    Professor Marcetta Y Darensbourg

  42. S K-Edge X-Ray Absorption Spectroscopy and Density Functional Theory Studies of High and Low Spin {FeNO} 7 Thiolate Complexes: Exchange Stabilization of Electron Delocalization in {FeNO} 7 and {FeO 2 } 8

    Article • Inorganic Chemistry, January 2011, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  43. cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(μ-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(μ-SR)4[Fe(NO)2]3

    Article • Dalton Transactions, January 2011, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  44. HYDROGENASE ACTIVE SITES: A NEW PARADIGM FOR NATURAL PRODUCT-INSPIRED SYNTHESIS BASED ON ORGANOMETALLIC CHEMISTRY

    Article • Comments on Inorganic Chemistry, November 2010, Taylor & Francis

    Professor Marcetta Y Darensbourg

  45. A {Fe(NO) 3 } 10 Trinitrosyliron Complex Stabilized by an N-Heterocyclic Carbene and the Cationic and Neutral {Fe(NO) 2 } 9/10 Products of Its NO Release

    Article • Journal of the American Chemical Society, October 2010, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  46. The Modular Assembly of Clusters Is the Natural Synthetic Strategy for the Active Site of [FeFe] Hydrogenase

    Article • Angewandte Chemie, September 2010, Wiley

    Professor Marcetta Y Darensbourg

  47. A Cyclodextrin Host/Guest Approach to a Hydrogenase Active Site Biomimetic Cavity

    Article • Journal of the American Chemical Society, July 2010, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  48. Orientation and Stereodynamic Paths of Planar Monodentate Ligands in Square Planar Nickel N 2 S Complexes

    Article • Inorganic Chemistry, June 2010, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  49. Analysis of a Pentacoordinate Iron Dicarbonyl as Synthetic Analogue of the Hmd or Mono-Iron Hydrogenase Active Site

    Article • Chemistry - A European Journal, March 2010, Wiley

    Professor Marcetta Y Darensbourg

  50. Mechanism of electrocatalytic hydrogen production by a di-iron model of iron–iron hydrogenase: A density functional theory study of proton dissociation constants and electrode reduction potentials

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  51. Synthesis and Mössbauer Characterization of Octahedral Iron(II) Carbonyl Complexes FeI 2 (CO) 3 L and FeI 2 (CO) 2 L 2 : Developing Models of the [Fe]-H 2 ase Active Site

    Article • Inorganic Chemistry, December 2009, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  52. Influence of Sulf-Oxygenation on CO/L Substitution and Fe(CO) 3 Rotation in Thiolate-Bridged Diiron Complexes

    Article • Inorganic Chemistry, September 2009, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  53. Imidazole-Containing (N 3 S)-Ni II Complexes Relating to Nickel Containing Biomolecules

    Article • Inorganic Chemistry, August 2009, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  54. Sulfur Oxygenates of Biomimetics of the Diiron Subsite of the [FeFe]-Hydrogenase Active Site: Properties and Oxygen Damage Repair Possibilities

    Article • Journal of the American Chemical Society, June 2009, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  55. Development of Five-Coordinate Zinc Mono- and Dithiolates as S-Donor Metalloligands: Formation of a Zn−W Coordination Polymer

    Article • Inorganic Chemistry, June 2009, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  56. Chemical Issues Addressing the Construction of the Distal Ni[Cysteine-Glycine-Cysteine] 2− Site of Acetyl CoA Synthase: Why Not Copper?

    Article • Inorganic Chemistry, April 2009, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  57. Reactions of palladium and gold complexes with zinc-thiolate chelates using electrospray mass spectrometry and X-ray diffraction: molecular identification of [Pd(bme-dach)], [Au(bme-dach]+ and [ZnCl(bme-dach)]2Pd

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  58. Zinc/Nickel exchange and ligand cannibalism in N2S2O1,2 donor ligand sets

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  59. Resin-bound models of the [FeFe]-hydrogenase enzyme active site and studies of their reactivity

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  60. Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models

    Article • Angewandte Chemie, November 2008, Wiley

    Professor Marcetta Y Darensbourg

  61. A paramagnetic trigonal paddlewheel complex with iron-dithiolato ligand paddles: {[(C9H18N2S2)Fe(NO)]3Ag2}(BF4)2

    Article • Journal of Molecular Structure, November 2008, Elsevier

    Professor Marcetta Y Darensbourg

  62. The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (μ-SCH2CR2CH2S)[Fe(CO)3][Fe(CO)2L] complexes

    Article • Comptes Rendus Chimie, August 2008, Elsevier

    Professor Marcetta Y Darensbourg

  63. Series of Mixed Valent Fe(II)Fe(I) Complexes That Model the H ox State of [FeFe]Hydrogenase: Redox Properties, Density-Functional Theory Investigation, and Reactivities with Extrinsic CO

    Article • Inorganic Chemistry, August 2008, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  64. CO-Migration in the Ligand Substitution Process of the Chelating Diphosphite Diiron Complex (μ-pdt)[Fe(CO) 3 ][Fe(CO){(EtO) 2 PN(Me)P(OEt) 2 }]

    Article • Inorganic Chemistry, August 2008, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  65. Thiolate Bridging and Metal Exchange in Adducts of a Zinc Finger Model and Pt II Complexes: Biomimetic Studies of Protein/Pt/DNA Interactions

    Article • Journal of the American Chemical Society, May 2008, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  66. Refining the Active Site Structure of Iron−Iron Hydrogenase Using Computational Infrared Spectroscopy

    Article • Inorganic Chemistry, April 2008, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  67. Electronic Effects of (N 2 S 2 )M(NO) Complexes (M = Fe, Co) as Metallodithiolate Ligands

    Article • Inorganic Chemistry, March 2008, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  68. Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the Hox state of [FeFe]-hydrogenase

    Article • Chemical Communications, January 2008, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  69. S K-Edge XAS and DFT Calculations on Square-Planar Ni II −Thiolate Complexes:  Effects of Active and Passive H-Bonding

    Article • Inorganic Chemistry, November 2007, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  70. Computational definition of a mixed valent Fe(II)Fe(I) model of the [FeFe]hydrogenase active site resting state

    Article • Journal of Inorganic Biochemistry, November 2007, Elsevier

    Professor Marcetta Y Darensbourg

  71. An Experimental and Computational Study of Sulfur-Modified Nucleophilicity in a Dianionic NiN 2 S 2 Complex

    Article • Inorganic Chemistry, September 2007, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  72. Synthesis of Carboxylic Acid-Modified [FeFe]-Hydrogenase Model Complexes Amenable to Surface Immobilization

    Article • Organometallics, July 2007, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  73. Sulfur K-Edge XAS and DFT Studies on Ni II Complexes with Oxidized Thiolate Ligands:  Implications for the Roles of Oxidized Thiolates in the Active Sites of Fe and Co Nitrile Hydratase

    Article • Inorganic Chemistry, June 2007, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  74. A Mixed-Valent, Fe(II)Fe(I), Diiron Complex Reproduces the Unique Rotated State of the [FeFe]Hydrogenase Active Site

    Article • Journal of the American Chemical Society, June 2007, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  75. The acetyl CoA synthase paradigm for hybrid bio-organometallics: Quantitative measures for resin-bound Ni–Rh complexes

    Article • Journal of Organometallic Chemistry, February 2007, Elsevier

    Professor Marcetta Y Darensbourg

  76. CO and Ethylene Migratory Insertion Reactions and Copolymerization Involving Palladium Complexes of a NiN 2 S 2 Metallodithiolate Ligand

    Article • Organometallics, February 2007, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  77. Control of S-Based Aggregation:  Designed Synthesis of NiM 2 and Ni 2 M Trinuclear Complexes

    Article • Inorganic Chemistry, January 2007, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  78. The reaction of electrophiles with models of iron–iron hydrogenase: A switch in regioselectivity

    Article • Journal of Molecular Structure THEOCHEM, October 2006, Elsevier

    Professor Marcetta Y Darensbourg

  79. A Nickel Tripeptide as a Metallodithiolate Ligand Anchor for Resin-Bound Organometallics

    Article • Journal of the American Chemical Society, May 2006, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  80. Iron nitrosyl complexes as models for biological nitric oxide transfer reagents

    Article • JBIC Journal of Biological Inorganic Chemistry, March 2006, Springer Science + Business Media

    Professor Marcetta Y Darensbourg

  81. De Novo Design of Synthetic Di-Iron(I) Complexes as Structural Models of the Reduced Form of Iron−Iron Hydrogenase

    Article • Inorganic Chemistry, February 2006, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  82. NiN2S2 complexes as metallodithiolate ligands to RhI, RhII and RhIII

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  83. A Kinetic Study of the Ring-Opening Process in Tungsten Carbonyl Complexes Containing Hemilabile Metallodithiolate Ligands

    Article • Inorganic Chemistry, January 2006, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  84. Correlation between computed gas-phase and experimentally determined solution-phase infrared spectra: Models of the iron–iron hydrogenase enzyme active site

    Article • Journal of Computational Chemistry, January 2006, Wiley

    Professor Marcetta Y Darensbourg

  85. Characterization of Steric and Electronic Properties of NiN 2 S 2 Complexes as S-Donor Metallodithiolate Ligands

    Article • Journal of the American Chemical Society, December 2005, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  86. Better than platinum? Fuel cells energized by enzymes

    Article • Proceedings of the National Academy of Sciences, November 2005, Proceedings of the National Academy of Sciences

    Professor Marcetta Y Darensbourg

  87. Synthesis and Molecular Structures of Mononitrosyl (N 2 S 2 )M(NO) Complexes (M = Fe, Co)

    Article • Inorganic Chemistry, November 2005, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  88. Dual Electron Uptake by Simultaneous Iron and Ligand Reduction in an N-Heterocyclic Carbene Substituted [FeFe] Hydrogenase Model Compound

    Article • Inorganic Chemistry, August 2005, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  89. Erratum to “Fundamental properties of small molecule models of Fe-only hydrogenase: computations relative to the definition of an entatic state in the active site” [Coord. Chem. Rev. 238/239 (2003) 255-266]

    Article • Coordination Chemistry Reviews, May 2005, Elsevier

    Professor Marcetta Y Darensbourg

  90. N2S2Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic Reactivity

    Article • Angewandte Chemie, February 2005, Wiley

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  91. Synthetic chemistry: Making a natural fuel cell

    Article • February 2005, Nature

    Professor Marcetta Y Darensbourg

  92. N 2 S 2 Ni Metallodithiolate Complexes as Ligands:  Structural and Aqueous Solution Quantitative Studies of the Ability of Metal Ions to Form M−S−Ni Bridges to Mercapto Groups Coordinated to Nickel(II). Implications for Acetyl Coenzyme A Synthase

    Article • Inorganic Chemistry, February 2005, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  93. Thiolate-bridged heterodinuclear platinum–zinc chelates as models for ternary platinum–DNA–protein complexes and zinc ejection from zinc fingers. Evidence from studies using ESI-mass spectrometry

    Article • Chemical Communications, January 2005, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  94. Metallodithiolato ligands as bridges in multiply bonded dimolybdenum complexes

    Article • Chemical Communications, January 2005, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  95. The Vapochromic Behavior, Desulfoxidation and Structural Characterization of the SO2 Adducts of Ni(BME-DACH) from Powder Data

    Article • Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, January 2005, Taylor & Francis

    Professor Marcetta Y Darensbourg

  96. The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H 2 Production Electrocatalysts:  Iron Hydrogenase Model Complexes

    Article • Journal of the American Chemical Society, September 2004, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  97. Bismercaptoethanediazacyclooctane as a N 2 S 2 Chelating Agent and Cys−X−Cys Mimic for Fe(NO) and Fe(NO) 2

    Article • Journal of the American Chemical Society, September 2004, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  98. Accommodation of the Irregular Coordination Geometry of Lead(II) by a Square Planar N 2 S 2 Ligand and Its Preference for Zinc(II)

    Article • Inorganic Chemistry, September 2004, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  99. Sensing of Sulfur Dioxide by Base Metal Thiolates:  Structures and Properties of Molecular NiN 2 S 2 /SO 2 Adducts

    Article • Inorganic Chemistry, July 2004, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  100. Structures and Energetics of Models for the Active Site of Acetyl-Coenzyme A Synthase:  Role of Distal and Proximal Metals in Catalysis

    Article • Journal of the American Chemical Society, March 2004, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  101. The Construction of (N2S2)Ni−Pd Clusters: A Slant-Chair, a Basket and a C4-Paddlewheel Structure

    Article • European Journal of Inorganic Chemistry, January 2004, Wiley

    Professor Marcetta Y Darensbourg

  102. SYNERGY BETWEEN THEORY AND EXPERIMENT AS APPLIED TO H/D EXCHANGE ACTIVITY ASSAYS IN [Fe]H2ase ACTIVE SITE MODELS

    Article • January 2004, Elsevier

    Professor Marcetta Y Darensbourg

  103. Adamantane-like Cluster Complexes of Mixed-Valent Copper−Copper and Nickel−Copper Thiolates

    Article • Inorganic Chemistry, May 2003, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  104. The organometallic active site of [Fe]hydrogenase: Models and entatic states

    Article • Proceedings of the National Academy of Sciences, March 2003, Proceedings of the National Academy of Sciences

    Professor Marcetta Y Darensbourg

  105. Fundamental properties of small molecule models of Fe-only hydrogenase: computations relative to the definition of an entatic state in the active site

    Article • Coordination Chemistry Reviews, March 2003, Elsevier

    Professor Marcetta Y Darensbourg

  106. Requirements for Functional Models of the Iron Hydrogenase Active Site:  D2/H2O Exchange Activity in {(μ-SMe)(μ-pdt)[Fe(CO)2(PMe3)]2+}[BF4-]

    Article • Inorganic Chemistry, February 2003, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  107. Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships

    Article • Dalton Transactions, January 2003, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  108. Capture of NiII, CuIand ZnIIby thiolate sulfurs of an N2S2Ni complex: A role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site

    Article • Chemical Communications, January 2003, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  109. Activation of Alkenes and H 2 by [Fe]-H 2 ase Model Complexes

    Article • Journal of the American Chemical Society, January 2003, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  110. X-ray structure of [Nb(η5-C5H5)2(SCH2CH2CH2S].

    Article • Polyhedron, October 2002, Elsevier

    Professor Marcetta Y Darensbourg

  111. Catalysis of H 2 /D 2 Scrambling and Other H/D Exchange Processes by [Fe]-Hydrogenase Model Complexes

    Article • Inorganic Chemistry, July 2002, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  112. Unique Reactivity of a Tetradentate N 2 S 2 Complex of Nickel:  Intermediates in the Production of Sulfur Oxygenates

    Article • Inorganic Chemistry, April 2002, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  113. Oxidative Addition of Phosphine-Tethered Thiols to Iron Carbonyl:  Binuclear Phosphinothiolate Complexes, (μ-SCH 2 CH 2 PPh 2 ) 2 Fe 2 (CO) 4 , and Hydride Derivatives

    Article • Inorganic Chemistry, February 2002, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  114. H/D Exchange Reactions in Dinuclear Iron Thiolates as Activity Assay Models of Fe−H 2 ase

    Article • Journal of the American Chemical Society, October 2001, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  115. Subtle Bite-Angle Influences on N 2 S 2 Ni Complexes

    Article • Inorganic Chemistry, July 2001, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  116. Coordination Sphere Flexibility of Active-Site Models for Fe-Only Hydrogenase:  Studies in Intra- and Intermolecular Diatomic Ligand Exchange

    Article • Journal of the American Chemical Society, April 2001, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  117. The bio-organometallic chemistry of active site iron in hydrogenases

    Article • Coordination Chemistry Reviews, September 2000, Elsevier

    Professor Marcetta Y Darensbourg

  118. Correlation of electrochemistry, nucleophilicity and density functional calculations of the cis-dithiolate (bme*-daco)Ni

    Article • Inorganica Chimica Acta, April 2000, Elsevier

    Professor Marcetta Y Darensbourg

  119. Heterobimetallics of Nickel−Iron Dinitrosyl:  Electronic Control by Chelate and Diatomic Ligands

    Article • Inorganic Chemistry, February 2000, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  120. Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase

    Article • Angewandte Chemie, November 1999, Wiley

    Professor Marcetta Y Darensbourg

  121. Synthesis and Dimer Cleavage Reactions of the N 2 S Thiolate Bridged Dimer [(mmp-dach) 2 Ni 2 ]Cl 2

    Article • Inorganic Chemistry, August 1999, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  122. Nickel mediated sulfur–selenium and sulfur–sulfur bond formation

    Article • Chemical Communications, January 1999, Royal Society of Chemistry

    Professor Marcetta Y Darensbourg

  123. Sulfur Site Iodine Adduct of a Nickel Thiolate Complex

    Article • Inorganic Chemistry, December 1998, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  124. Alkylation-Induced O-Atom Rearrangement in Nickel S-Oxygenates.

    Article • Organometallics, November 1998, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  125. Responses of the Fe(CN) 2 (CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase

    Article • Journal of the American Chemical Society, October 1998, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  126. Alkylation-Induced O-Atom Rearrangement in Nickel S-Oxygenates

    Article • Organometallics, October 1998, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  127. Pentacoordinate (μ-Oxo)diiron(III) Thiolate Complexes and Dimeric Iron(II) Precursors

    Article • Inorganic Chemistry, August 1998, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  128. Oxygen Capture by Sulfur in Nickel Thiolates

    Article • Accounts of Chemical Research, August 1998, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  129. Methylation of Tethered Thiolates in [(bme-daco)Zn] 2 and [(bme-daco)Cd] 2 as a Model of Zinc Sulfur-Methylation Proteins

    Article • Inorganic Chemistry, August 1998, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  130. Synthesis, Structures, and Electrochemical Properties of Nickel Complexes of Macrocyclic N 2 S 2 Aminothioethers

    Article • Inorganic Chemistry, January 1998, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  131. Inorganic Syntheses

    Article • January 1998

    Professor Marcetta Y Darensbourg

  132. Cyano[tri(cyclohexyl)phosphino]gold(I), [Au(CN){(C6H11)3P}]

    Article • Acta Crystallographica Section C Crystal Structure Communications, November 1997, International Union of Crystallography

    Professor Marcetta Y Darensbourg

  133. Analysis of an Organometallic Iron Site Model for the Heterodimetallic Unit of [NiFe]Hydrogenase

    Article • Journal of the American Chemical Society, August 1997, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  134. A New Macrocyclic N 3 S 2 Ligand and Its Nickel(II), Cobalt(II), Rhodium(III)-103, and Rhodium(III)-105 Complexes

    Article • Journal of the American Chemical Society, May 1997, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  135. Singlet Oxygen and the Production of Sulfur Oxygenates of Nickel(II) and Palladium(II) Thiolates

    Article • Inorganic Chemistry, April 1997, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  136. Thiolate Bridged Nickel–Iron Complexes Containing both Iron(0) and Iron(II) Carbonyls

    Article • Angewandte Chemie International Edition in English, November 1996, Wiley

    Professor Marcetta Y Darensbourg

  137. Lightinduced sulfur-dealkylation of phosphino-thioether nickel(0) complexes

    Article • Inorganica Chimica Acta, September 1996, Elsevier

    Professor Marcetta Y Darensbourg

  138. Structural and Electrochemical Comparison of NiII in an N2S2 Plane with Two, One and No Axial Ligands: Isolation and Characterization of a Five-Coordinate Nickel(II) Complex

    Article • Chemische Berichte, July 1996, Wiley

    Professor Marcetta Y Darensbourg

  139. Template Effect for O 2 Addition across cis -Sulfur Sites in Nickel Dithiolates

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  140. Polydentate N 2 S 2 O and N 2 S 2 O 2 Ligands as Alcoholic Derivatives of ( N , N ‘-Bis(2-mercaptoethyl)-1,5-diazacyclooctane)nickel(II) and ( N , N ‘-Bis(2-mercapto-2-methylpropane)-1,5-diazacyclooctane)nickel(II)

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  141. Influence of Sulfur Metalation on the Accessibility of the Ni II/I Couple in [ N , N‘ -Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II):  Insight into the Redox Properties of [NiFe]-Hydrogenase

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  142. Characteristics of Nickel(0), Nickel(I), and Nickel(II) in Phosphino Thioether Complexes:  Molecular Structure and S -Dealkylation of (Ph 2 P( o -C 6 H 4 )SCH 3 ) 2 Ni 0

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  143. A Coordination Polymer of Nickel(II) Based on a Pentadentate N, S, and O Donor Ligand

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  144. Structure/Function Relationships in Ligand-Based SO2/O2 Conversion to Sulfate As Promoted by Nickel and Palladium Thiolates

    Article • Inorganic Chemistry, December 1995, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  145. Metallosulfoxides and -sulfones: Sulfur Oxygenates of [1,5-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]palladium(II)

    Article • Inorganic Chemistry, December 1995, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  146. Study of Sulfinate and Sulfenate Complexes Derived from the Oxygenation of Thiolate Sulfur in [1,5-Bis(2-mercapto-2-methylpropyl)-1,5-diazacyclooctanato(2-)]nickel(II). [Erratum to document cited in CA122:70603]

    Article • Journal of the American Chemical Society, May 1995, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  147. Study of Sulfinate and Sulfenate Complexes Derived from the Oxygenation of Thiolate Sulfur in [1,5-Bis(2-mercapto-2-methylpropyl)-1,5-diazacyclooctanato(2-)]nickel(II)

    Article • Journal of the American Chemical Society, January 1995, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  148. Crystal structure of tetrakis[μ3-methoxo-2,4-pentanedionatomethanolnickel(II)],C28H56Ni4O16

    Article • Zeitschrift für Kristallographie, January 1995, De Gruyter

    Professor Marcetta Y Darensbourg

  149. Crystal structure of mercaptoethylene-1,4-diazacycloheptanenickel(II)-μ-S-1,4-bis(mercaptoethylene)-1,4-diazacycloheptanenickel(II) chloride methanol solvate, C16.8H36.6Cl1.1N4Ni2OS2.9

    Article • Zeitschrift für Kristallographie, January 1995, De Gruyter

    Professor Marcetta Y Darensbourg

  150. Reduction-Promoted Sulfur-Oxygen Bond Cleavage in a Nickel Sulfenate as a Model for the Activation of [NiFe] Hydrogenase

    Article • Journal of the American Chemical Society, October 1994, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  151. SYNTHETIC STRATEGIES FOR N2S2O-PENTACOORDINATE NICKEL(II) BASED ON THE HIGHLY STERICALLY ENCUMBERED LIGAND N,N′-BIS(2-MERCAPTO-2-METHYLPROPANE)-1,5-DIAZACYCLOOCTANE

    Article • Journal of Coordination Chemistry, June 1994, Taylor & Francis

    Professor Marcetta Y Darensbourg

  152. Synthesis and Characterization of a Stable Iron(II) Hydride-Thiolate Complex: (PhS)Fe(H)(CO)2(P(OPh)3)2

    Article • Inorganic Chemistry, March 1994, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  153. Sulfur site adducts of sulfur dioxide in nickel-bound thiolates and their conversion to sulfate

    Article • Inorganic Chemistry, February 1994, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  154. Variable oxygenation levels of sulfur in sterically hindered thiolates: molecular structure of [N-(2-mercapto-2-methylpropyl)-N'-(2-sulfeno-2-methylpropyl)-1,5-diazacyclooctanato]nickel(II)

    Article • Inorganic Chemistry, December 1993, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  155. Divergent pathways for the addition of dioxygen to sulfur in nickel cis-dithiolates: an isotopomeric analysis

    Article • Inorganic Chemistry, September 1993, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  156. X-ray structure and solution characterization of tetracarbonylmolybdenumbis(.mu.-diphenylphosphinoethanethiolato)nickel (Ni(.mu.-SCH2CH2PPh2)2Mo(CO)4)

    Article • Inorganic Chemistry, August 1993, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  157. Effects of sulfur site modification on the redox potentials of derivatives of [N,N'-bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II)

    Article • Journal of the American Chemical Society, June 1993, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  158. Organometallic chemistry of sulfur/phosphorus donor ligand complexes of nickel(II) and nickel(0)

    Article • Organometallics, March 1993, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  159. Axial Ligation of Diazacyclooctanenickel and -Zinc Complexes

    Article • Angewandte Chemie International Edition in English, January 1993, Wiley

    Professor Marcetta Y Darensbourg

  160. Variable modes of nickel(II) coordination with macrocyclic ligands based on 1,5-bis(2-mercaptoethyl)-1,5-diazacyclooctane (BME-DACO)

    Article • Inorganic Chemistry, November 1992, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  161. Synthesis and characterization of the electron-rich iron hydride HFe(CO)2(P(OPh)3)2- and its ligand-based redox substitution with thiolates

    Article • Organometallics, October 1992, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  162. Preparations and structures of a zinc(II) dimer and zinc(II)/nickel(II) pentanuclear derivatives of N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane: [(BME-DACO)Zn]2 and {[(BME-DACO)Ni]3[ZnCl]2}{BF4}2

    Article • Inorganic Chemistry, August 1992, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  163. Complexation of organotin halides with ambidentate, S, N, and O donor ligands

    Article • Inorganic Chemistry, July 1992, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  164. Isotopic labeling investigation of the oxygenation of nickel-bound thiolates by molecular oxygen

    Article • Journal of the American Chemical Society, June 1992, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  165. Stereochemical nonrigidity in heterobimetallic complexes containing the bent metallocene-thiolate fragment

    Article • Inorganic Chemistry, April 1992, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  166. Applications of the N2S2 ligand, N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane (BME-DACO), toward the formation of bi- and heterometallics: [(BME-DACO)Fe]2 and [(BME-DACO)NiFeCl2]2

    Article • Journal of the American Chemical Society, February 1991, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  167. Direct synthesis of mixed metal sulfide catalysts and their hydrodenitrogenation activity

    Article • Applied Catalysis, January 1991, Elsevier

    Professor Marcetta Y Darensbourg

  168. Sterically protected nickel(II) in a N2S2 donor environment: 1,5-bis(mercaptoethyl)-1,5-diazacyclooctane and its methylated derivative

    Article • Inorganic Chemistry, October 1990, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  169. Conformations of (.eta.5-C5H5)2Nb(S-p-C6H4X)2n(n=0,1): responsiveness to para substituents on aryl groups and to d-electron count

    Article • Journal of the American Chemical Society, September 1990, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  170. The synthesis and molecular structure of (Ph3PAu)2Fe(CO)3P(OEt)3: a triangular Au2Fe cluster

    Article • Journal of Organometallic Chemistry, August 1990, Elsevier

    Professor Marcetta Y Darensbourg

  171. Isolation of chromium(0) thiols: molecular structure of (tert-butylmercaptan)pentacarbonylchromium

    Article • Inorganic Chemistry, July 1990, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  172. Electron paramagnetic resonance and electrochemical study of the oxidation chemistry of mononuclear and binuclear chromium carbonyl thiolates

    Article • Journal of the American Chemical Society, July 1990, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  173. Reactions of anionic transition metal carbonyl hydrides with electrophilic metal carbonyls: Nucleophilic addition (hydride transfer) vs. electron transfer mechanisms

    Article • Journal of Organometallic Chemistry, February 1990, Elsevier

    Professor Marcetta Y Darensbourg

  174. Protonation sites in thiolato iron carbonylates: evidence for an arrested Fe(RS-H) oxidative addition

    Article • Journal of the American Chemical Society, September 1989, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  175. Thiolate, thioether, and thiol derivatives of iron(0) carbonyls

    Article • Journal of the American Chemical Society, May 1989, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  176. Structural studies of thiophenoxide niobium complexes (.eta.5-C5H5)2Nb(SC6H5)2, [(.eta.5-C5H5)2Nb(SC6H5)2+], and [(.eta.5-C5H5)2Nb(.mu.-SC6H5)2)Mo(CO)4+]

    Article • Organometallics, May 1989, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  177. Spectroscopic and chemical studies of nickel(II) hydrides

    Article • Inorganic Chemistry, May 1989, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  178. Addition of acrylonitrile to anionic transition metal hydrides. An ionic model for homogeneous olefin processes

    Article • Tetrahedron Letters, January 1989, Elsevier

    Professor Marcetta Y Darensbourg

  179. EPR spectrum of the ion pair [CR(CO)5−]2 in irradiated crystals of PPh4+ HCr(CO)5−

    Article • Magnetic Resonance in Chemistry, September 1988, Wiley

    Professor Marcetta Y Darensbourg

  180. Binuclear reductive elimination of water: new route to the (triphenylstannyl)pentacarbonyltungsten anion, Ph3SnW(CO)5-

    Article • Inorganic Chemistry, July 1988, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  181. Promotion of methyl/carbonyl migratory insertion by transition-metal Lewis acids. Synthesis and reactivity of a transition-metal heterobimetallic carbonyl alkyl anion, MeFeW(CO)9-

    Article • Organometallics, June 1988, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  182. Mechanisms of group transfer in anionic transition metal hydrides and alkyls

    Article • Pure and Applied Chemistry, January 1988, De Gruyter

    Professor Marcetta Y Darensbourg

  183. Reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of an hydridonickel formate complex, HNi(O2CH)(Cy3P)2

    Article • Journal of the American Chemical Society, November 1987, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  184. Temperature and solvent dependence of scalar coupling constants in salts of trans-HFe(CO)3PR3-

    Article • Journal of the American Chemical Society, July 1987, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  185. Properties and x-ray structure of bis(triphenylphosphine)nitrogen(1+) cis-tricarbonylhydridotris(triphenyl phosphite)ferrate(1-), an unexpected structural isomer

    Article • Inorganic Chemistry, May 1987, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  186. Competing nucleophilic displacement and radical-chain reduction in reactions of transition-metal hydride anions with alkyl bromides

    Article • Journal of the American Chemical Society, May 1987, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  187. Anionic Transition Metal Hydrides

    Article • January 1987, Elsevier

    Professor Marcetta Y Darensbourg

  188. Anionic group 6 hydrides and carboxylates as homogeneous catalysts for reduction of aldehydes and ketones

    Article • Journal of the American Chemical Society, September 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  189. Deprotonation of molybdenum carbonyl hydrido diphosphine [HMo(CO)2(PP)2]BF4 complexes: hard anions as proton carriers

    Article • Inorganic Chemistry, July 1986, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  190. Metal donor to metal acceptor complexes. Fe(CO)42-, HFe(CO)4-, and trans-HFe(CO)3P(OMe)3- as anionic ligands to M(CO)50, M = Cr, W

    Article • Journal of the American Chemical Society, May 1986, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  191. Intramolecular ligand rearrangements in anionic group 6 metal pentacarbonyl hydride derivatives

    Article • Inorganic Chemistry, March 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  192. Solution and solid-state structures of salts of trans-HFe(CO)3PR3- including a study of alkali cation contact ion pairing

    Article • Organometallics, January 1986, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  193. Comparisons of the heterobimetallic and heterotrimetallic anions HFeW(CO)9- and Ph3PAuFeW(CO)9-

    Article • Journal of the American Chemical Society, November 1985, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  194. Olefin isomerization catalysis by heterobimetallic hydrides, HFeM(CO)8L- (M = Cr, Mo, W; L = CO, PR3)

    Article • Journal of the American Chemical Society, April 1985, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  195. Anionic group 6 transition-metal carbonyl hydrides as reducing agents. ketones, aldehydes, and epoxides

    Article • Journal of the American Chemical Society, April 1985, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  196. Relative reactivity and mechanistic studies of the hydride-transfer reagents HM(CO)4L-(M = Cr, W; L = CO, PR3)

    Article • Organometallics, January 1985, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  197. Selective reduction of acyl chlorides to aldehydes by anionic Group VIB transition metal hydrides

    Article • Organometallics, October 1984, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  198. Hydrogen-deuterium exchange of the anionic Group VIB transition-metal hydrides. Convenient, in situ deuterium transfer reagents

    Article • Journal of the American Chemical Society, August 1984, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  199. The nature of alkali cation contact ion pairs with anionic transition-metal hydrides HM(CO)4L- (M = Cr, W; L = CO, PR3)

    Article • Organometallics, June 1984, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  200. Binuclear molybdenum carbonyls bridged both by hydride and bidentate phosphine ligands. Crystal and molecular structures of salts of hydridomolybdenum carbonyls with bidentate phosphine ligands (.mu.-H)(.mu.-Ph2P(CH2)nPPh2)Mo2(CO)8- (n = 1-4) and their...

    Article • Journal of the American Chemical Society, May 1984, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  201. Relative reactivities of anionic transition metal hydrides. Reduction of alkyl halides

    Article • Organometallics, April 1984, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  202. Chemistry of new heteronuclear bridging hydrides: (.mu.-H)[Fe(CO)4M(CO)5]- (M = chromium, molybdenum, or tungsten)

    Article • Journal of the American Chemical Society, January 1984, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  203. The anion assisted transfer of a sterically constrained proton: molecular structure of bis[1,2-ethanediylbis(diphenylphosphine)]dicarbonylhydridomolybdenum tetrachloroaluminate [HMo(CO)2(Ph2PCH2CH2PPh2)2+ AlCl4-]

    Article • Journal of the American Chemical Society, November 1983, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  204. Structural characterizations of salts of HCr(CO) 5 - and (μ-H) 2 BH 2 Cr(CO) 4 - and studies of their interconversions

    Article • Journal of the American Chemical Society, December 1982, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  205. Chemistry of hydrido carbonyl VIB metalates substituted by P-donor ligands: HW(CO)4PR3- (R = Me, OMe, Ph) and .mu.-H[WM(CO)10-x(P(OMe)3)x] (M = Cr, W; x = 1, 2)

    Article • Organometallics, December 1982, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  206. Interactions of CpM'(CO)3- (M' = chromium, molybdenum, or tungsten) with cations: effects on CO exchange and RX addition reactions

    Article • Journal of the American Chemical Society, March 1982, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  207. Site-specific ion pairing of monosubstituted vanadium carbonylates, LV(CO)5-

    Article • Organometallics, January 1982, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  208. Chromium, molybdenum, and tungsten

    Article • Journal of Organometallic Chemistry, December 1981, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  209. The use of ion-pairing phenomena in the assignment of v(co) ir bands of pv(co)5-

    Article • Journal of Organometallic Chemistry, September 1981, Elsevier

    Professor Marcetta Y Darensbourg

  210. Alternate synthetic routes to the pentacarbonylhydrides of chromium, molybdenum, and tungsten

    Article • Journal of the American Chemical Society, September 1981, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  211. Studies using tributylphosphine oxide as a carbon monoxide labilizing ligand in the synthesis of metal carbonyl complexes highly enriched in carbon-13 monoxide

    Article • Inorganic Chemistry, June 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  212. Facile reduction of carbon dioxide by anionic Group 6b metal hydrides. Chemistry relevant to catalysis of the water-gas shift reaction

    Article • Journal of the American Chemical Society, June 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  213. The pentacarbonylhydridochromium (1-) anion

    Article • Inorganic Chemistry, June 1981, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  214. A reactivity study of addition of organic halides to CpMo(CO)3−: counterion and RX dependences

    Article • Journal of Organometallic Chemistry, December 1980, Elsevier

    Professor Marcetta Y Darensbourg

  215. The .mu.-hydrobis[tetracarbonyl(methyldiphenylphosphine)molybdenum](2-) anion: an example of phosphine enhancement of metal-metal interaction

    Article • Journal of the American Chemical Society, April 1980, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  216. Synthesis of metal carbonyl complexes highly enriched in carbon-13: utilization of the carbon monoxide-labilizing ability of (n-Bu)3P:O

    Article • Journal of the American Chemical Society, January 1980, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  217. Cation interaction with transition metal carbonylates and cyanocarbonylates

    Article • Inorganic Chemistry, November 1979, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  218. Reaction of iron pentacarbonyl with oxygen-18-enriched hydroxide. Decarboxylation vs. oxygen exchange in the [Fe(COOH)] intermediate

    Article • Inorganic Chemistry, May 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  219. Structural and chemical characterization of a phosphine bound M-H-M bridged carbonylate: Et4N+(.mu.-H)[Mo2(CO)9PPh3]-

    Article • Journal of the American Chemical Society, May 1979, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  220. Arene-transition metal chemistry. 2. Hydrogenation of metal-arene and allylmetal-arene complexes

    Article • Inorganic Chemistry, March 1979, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  221. Arene-transition metal complexes. 1. Site exchange and chemical characteristics of .eta.6-C6(CH3)6Ru-.eta.4-C6(CH3)6

    Article • Journal of the American Chemical Society, November 1978, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  222. Preparation of a stereospecifically carbon-13 monoxide-labeled [(.mu.-H)[Mo(CO)5]2]- species and analysis of its carbonyl stretching vibrational modes

    Article • Inorganic Chemistry, September 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  223. Solution structure and reactivity of hydridoiron tetracarbonyl anion, [HFe(CO)4]-

    Article • Inorganic Chemistry, February 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  224. Ligand lability studies in bridging hydride complexes of Group 6B metal carbonylates

    Article • Inorganic Chemistry, January 1978, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  225. The extent of association of the bis(triphenylphosphine)iminium cation with organometallic anions in tetrahydrofuran solution

    Article • Journal of the American Chemical Society, March 1977, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  226. Conductivity studies of ion pairing in transition metal organics

    Article • Inorganic Chemistry, December 1976, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  227. Chromium, molybdenum and tungsten

    Article • Journal of Organometallic Chemistry, September 1976, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  228. Carbonyl Ligand Lability in the μ-H[Cr(CO)5]2− Anion

    Article • Journal of Organometallic Chemistry, September 1976, Elsevier

    Professor Marcetta Y Darensbourg

  229. Infrared, conductance, and kinetic evidence for alkali metal ion interactions with derivatives of manganese carbonylates

    Article • Journal of the American Chemical Society, May 1976, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  230. Molecular structure and spectral properties of phosphatriazaadamantanemolybdenum pentacarbonyl complex

    Article • Inorganic Chemistry, April 1976, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  231. Synthesis, spectral properties, and reactions of manganese and rhenium pentacarbonyl phosphine and phosphite cation derivatives and related complexes

    Article • Inorganic Chemistry, July 1975, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  232. Synthesis and spectral properties of metal carbonyl derivatives of the tetrabasic, nonchelating phosphatriazaadamantane ligand

    Article • Inorganic Chemistry, May 1975, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  233. The stereochemical course of reactions leading to formation of mono-ligated (phenylacetyl)manganese tetracarbonyl compounds

    Article • Journal of Organometallic Chemistry, January 1975, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  234. Chromium, molybdenum and tungsten

    Article • Journal of Organometallic Chemistry, December 1974, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  235. Solvent effects on the solution structure and chemical properties of lithium and magnesium salts of trans-phenylacyltricarbonyl(triphenylphosphine)iron(1-)

    Article • Inorganic Chemistry, December 1974, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  236. The synthesis and spectral properties of manganese pentacarbonyl phosphine and phosphite cation derivatives and related complexes

    Article • Journal of Organometallic Chemistry, July 1974, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  237. Alkylation and substitution reactions of metal carbonyl acylate and carbene complexes

    Article • Inorganic Chemistry, March 1974, American Chemical Society (ACS)

    Professor Marcetta Y Darensbourg

  238. The synthesis of group V substituted derivatives of iron pentacarbonyl in high yield

    Article • Journal of Organometallic Chemistry, January 1974, Elsevier

    Professor Marcetta Y Darensbourg

  239. Electronic and steric control of reactions of benzylmagnesium chloride with substituted metal carbonyls

    Article • Journal of the American Chemical Society, September 1973, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  240. Photochemical substitution reactions of substituted Group VI metal carbonyls

    Article • Inorganic Chemistry, August 1972, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  241. Reactions of organolithium and grignard reagents with the cyclopentadienyliron tricarbonyl cation and its derivatives

    Article • Journal of Organometallic Chemistry, May 1972, Elsevier

    Professor Marcetta Y Darensbourg

  242. Nature of the intermediate procreated in substitution reactions of Group VI metal carbonyls

    Article • Journal of the American Chemical Society, June 1971, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  243. Reactions of transition metal carbonyls with organolithium compounds. II. Prediction of nucleophilic attack at carbon and resultant stereochemistry

    Article • Inorganic Chemistry, July 1970, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  244. Spectroscopic studies of some carbene pentacarbonyl complexes of chromium(0) and tungsten(0)

    Article • Inorganic Chemistry, January 1970, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  245. Tetracarbonyliron(0) Complexes Containing Group V Donor Ligands

    Article • Wiley

    Professor Neil John Coville, Professor Marcetta Y Darensbourg

  246. Tetracarbonyl{[2-(Diphenylphosphino)Phenyl]Hydroxymethyl-C, P}Manganese

    Article • Wiley

    Professor Marcetta Y Darensbourg

  247. Heterobinuclear Nonacarbonyl Complexes and Hydride Complexes of Iron—Chromium, Iron—Molybdenum, and Iron—Tungsten

    Article • Wiley

    Professor Marcetta Y Darensbourg