All Stories

  1. Cooperative redox and spin activity from three redox congeners of sulfur-bridged iron nitrosyl and nickel dithiolene complexes
  2. Connecting Main-Group Metals (Al, Ga, In) and Tungsten(0) Carbonyls via the N2S2 Metallo-Ligand Strategy
  3. A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen versus Sulfur-Gold Interactions
  4. A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen versus Sulfur-Gold Interactions
  5. Synthetic Advances Inspired by the Bioactive Dinitrosyl Iron Unit
  6. ChemInform Abstract: Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry
  7. Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry
  8. Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties
  9. The ligand unwrapping/rewrapping pathway that exchanges metals in S-acetylated, hexacoordinate N2S2O2complexes
  10. Intramolecular Iron-Mediated C–H Bond Heterolysis with an Assist of Pendant Base in a [FeFe]-Hydrogenase Model
  11. The Bioorganometallic Chemistry of Hydrogenase
  12. Conformational Mobility and Pendent Base Effects on Electrochemistry of Synthetic Analogues of the [FeFe]-Hydrogenase Active Site
  13. Metallodithiolates as Ligands to Dinitrosyl Iron Complexes: Toward the Understanding of Structures, Equilibria, and Spin Coupling
  14. Electrocatalytic O2Reduction by [Fe-Fe]-Hydrogenase Active Site Models
  15. Redox active iron nitrosyl units in proton reduction electrocatalysis
  16. Heterogenization of a Water-Insoluble Molecular Complex for Catalysis of the Proton-Reduction Reaction in Highly Acidic Aqueous Solutions
  17. N,N′-Bis(Mercaptoethyl)-1,4-Diazacycloheptane (H2BME-DACH) and its Nickel Complex: A Model for Bioinorganic Chemistry
  18. Molecular catalysis that transpires only when the complex is heterogenized: Studies of a hydrogenase complex surface-tethered on polycrystalline and (111)-faceted gold by EC, PM-FT-IRRAS, HREELS, XPS and STM
  19. Addendum to Immobilization-Enabled Proton-Reduction Catalysis by a Di-iron Hydrogenase Mimic
  20. Versatile N2S2nickel-dithiolates as mono- and bridging bidentate, S-donor ligands to gold(i)
  21. Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes
  22. Immobilization-Enabled Proton Reduction Catalysis by a Di-iron Hydrogenase Mimic
  23. Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M=Fe, Co) as metallodithiolate ligands
  24. Enzymes activated by synthetic components
  25. Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)/ Thiolate Dinitrosyl Iron Complex (DNIC)
  26. Hyperfine interactions and electron distribution in FeIIFeI and FeIFeI models for the active site of the [FeFe] hydrogenases: Mössbauer spectroscopy studies of low-spin FeI
  27. Ambidentate Thiocyanate and Cyanate Ligands in Dinitrosyl Iron Complexes
  28. Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT
  29. A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion
  30. Structural and Spectroscopic Features of Mixed Valent Fe II Fe I Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase
  31. Time Resolved Infrared Spectroscopy: Kinetic Studies of Weakly Binding Ligands in an Iron–Iron Hydrogenase Model Compound
  32. Comparisons of zinc with cadmium in N2S2coordination and as S-bonded adducts to tungsten carbonyls
  33. Self-Assembly of Dinitrosyl Iron Units into Imidazolate-Edge-Bridged Molecular Squares: Characterization Including Mössbauer Spectroscopy
  34. Merging the old with the new
  35. N-Heterocyclic Carbene Ligands as Mimics of Imidazoles/Histidine for the Stabilization of Di- and Trinitrosyl Iron Complexes
  36. Modeling Structures and Vibrational Frequencies for Dinitrosyl Iron Complexes (DNICs) with Density Functional Theory
  37. Sulfonated Diiron Complexes as Water-Soluble Models of the [Fe–Fe]-Hydrogenase Enzyme Active Site
  38. Tetradentate N 2 S 2 Vanadyl(IV) Coordination Complexes: Synthesis, Characterization, and Reactivity Studies
  39. Hydrogenases (Eur. J. Inorg. Chem. 7/2011)
  40. Sulfoxygenation of Active Site Models of [NiFe] and [FeFe] Hydrogenases – A Commentary on Possible Chemical Models of Hydrogenase Enzyme Oxygen Sensitivity
  41. S K-Edge X-Ray Absorption Spectroscopy and Density Functional Theory Studies of High and Low Spin {FeNO} 7 Thiolate Complexes: Exchange Stabilization of Electron Delocalization in {FeNO} 7 and {FeO 2 } 8
  42. cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(μ-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(μ-SR)4[Fe(NO)2]3
  43. HYDROGENASE ACTIVE SITES: A NEW PARADIGM FOR NATURAL PRODUCT-INSPIRED SYNTHESIS BASED ON ORGANOMETALLIC CHEMISTRY
  44. A {Fe(NO) 3 } 10 Trinitrosyliron Complex Stabilized by an N-Heterocyclic Carbene and the Cationic and Neutral {Fe(NO) 2 } 9/10 Products of Its NO Release
  45. The Modular Assembly of Clusters Is the Natural Synthetic Strategy for the Active Site of [FeFe] Hydrogenase
  46. A Cyclodextrin Host/Guest Approach to a Hydrogenase Active Site Biomimetic Cavity
  47. Orientation and Stereodynamic Paths of Planar Monodentate Ligands in Square Planar Nickel N 2 S Complexes
  48. Analysis of a Pentacoordinate Iron Dicarbonyl as Synthetic Analogue of the Hmd or Mono-Iron Hydrogenase Active Site
  49. Mechanism of electrocatalytic hydrogen production by a di-iron model of iron–iron hydrogenase: A density functional theory study of proton dissociation constants and electrode reduction potentials
  50. Synthesis and Mössbauer Characterization of Octahedral Iron(II) Carbonyl Complexes FeI 2 (CO) 3 L and FeI 2 (CO) 2 L 2 : Developing Models of the [Fe]-H 2 ase Active Site
  51. Influence of Sulf-Oxygenation on CO/L Substitution and Fe(CO) 3 Rotation in Thiolate-Bridged Diiron Complexes
  52. Imidazole-Containing (N 3 S)-Ni II Complexes Relating to Nickel Containing Biomolecules
  53. Sulfur Oxygenates of Biomimetics of the Diiron Subsite of the [FeFe]-Hydrogenase Active Site: Properties and Oxygen Damage Repair Possibilities
  54. Development of Five-Coordinate Zinc Mono- and Dithiolates as S-Donor Metalloligands: Formation of a Zn−W Coordination Polymer
  55. Chemical Issues Addressing the Construction of the Distal Ni[Cysteine-Glycine-Cysteine] 2− Site of Acetyl CoA Synthase: Why Not Copper?
  56. Reactions of palladium and gold complexes with zinc-thiolate chelates using electrospray mass spectrometry and X-ray diffraction: molecular identification of [Pd(bme-dach)], [Au(bme-dach]+ and [ZnCl(bme-dach)]2Pd
  57. Zinc/Nickel exchange and ligand cannibalism in N2S2O1,2 donor ligand sets
  58. Resin-bound models of the [FeFe]-hydrogenase enzyme active site and studies of their reactivity
  59. Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models
  60. A paramagnetic trigonal paddlewheel complex with iron-dithiolato ligand paddles: {[(C9H18N2S2)Fe(NO)]3Ag2}(BF4)2
  61. The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (μ-SCH2CR2CH2S)[Fe(CO)3][Fe(CO)2L] complexes
  62. Series of Mixed Valent Fe(II)Fe(I) Complexes That Model the H ox State of [FeFe]Hydrogenase: Redox Properties, Density-Functional Theory Investigation, and Reactivities with Extrinsic CO
  63. CO-Migration in the Ligand Substitution Process of the Chelating Diphosphite Diiron Complex (μ-pdt)[Fe(CO) 3 ][Fe(CO){(EtO) 2 PN(Me)P(OEt) 2 }]
  64. Thiolate Bridging and Metal Exchange in Adducts of a Zinc Finger Model and Pt II Complexes: Biomimetic Studies of Protein/Pt/DNA Interactions
  65. Refining the Active Site Structure of Iron−Iron Hydrogenase Using Computational Infrared Spectroscopy
  66. Electronic Effects of (N 2 S 2 )M(NO) Complexes (M = Fe, Co) as Metallodithiolate Ligands
  67. Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the Hox state of [FeFe]-hydrogenase
  68. S K-Edge XAS and DFT Calculations on Square-Planar Ni II −Thiolate Complexes:  Effects of Active and Passive H-Bonding
  69. Computational definition of a mixed valent Fe(II)Fe(I) model of the [FeFe]hydrogenase active site resting state
  70. An Experimental and Computational Study of Sulfur-Modified Nucleophilicity in a Dianionic NiN 2 S 2 Complex
  71. Synthesis of Carboxylic Acid-Modified [FeFe]-Hydrogenase Model Complexes Amenable to Surface Immobilization
  72. Sulfur K-Edge XAS and DFT Studies on Ni II Complexes with Oxidized Thiolate Ligands:  Implications for the Roles of Oxidized Thiolates in the Active Sites of Fe and Co Nitrile Hydratase
  73. A Mixed-Valent, Fe(II)Fe(I), Diiron Complex Reproduces the Unique Rotated State of the [FeFe]Hydrogenase Active Site
  74. The acetyl CoA synthase paradigm for hybrid bio-organometallics: Quantitative measures for resin-bound Ni–Rh complexes
  75. CO and Ethylene Migratory Insertion Reactions and Copolymerization Involving Palladium Complexes of a NiN 2 S 2 Metallodithiolate Ligand
  76. Control of S-Based Aggregation:  Designed Synthesis of NiM 2 and Ni 2 M Trinuclear Complexes
  77. The reaction of electrophiles with models of iron–iron hydrogenase: A switch in regioselectivity
  78. A Nickel Tripeptide as a Metallodithiolate Ligand Anchor for Resin-Bound Organometallics
  79. Iron nitrosyl complexes as models for biological nitric oxide transfer reagents
  80. De Novo Design of Synthetic Di-Iron(I) Complexes as Structural Models of the Reduced Form of Iron−Iron Hydrogenase
  81. NiN2S2 complexes as metallodithiolate ligands to RhI, RhII and RhIII
  82. A Kinetic Study of the Ring-Opening Process in Tungsten Carbonyl Complexes Containing Hemilabile Metallodithiolate Ligands
  83. Correlation between computed gas-phase and experimentally determined solution-phase infrared spectra: Models of the iron–iron hydrogenase enzyme active site
  84. Characterization of Steric and Electronic Properties of NiN 2 S 2 Complexes as S-Donor Metallodithiolate Ligands
  85. Better than platinum? Fuel cells energized by enzymes
  86. Synthesis and Molecular Structures of Mononitrosyl (N 2 S 2 )M(NO) Complexes (M = Fe, Co)
  87. Dual Electron Uptake by Simultaneous Iron and Ligand Reduction in an N-Heterocyclic Carbene Substituted [FeFe] Hydrogenase Model Compound
  88. Erratum to “Fundamental properties of small molecule models of Fe-only hydrogenase: computations relative to the definition of an entatic state in the active site” [Coord. Chem. Rev. 238/239 (2003) 255-266]
  89. N2S2Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic Reactivity
  90. Synthetic chemistry: Making a natural fuel cell
  91. N 2 S 2 Ni Metallodithiolate Complexes as Ligands:  Structural and Aqueous Solution Quantitative Studies of the Ability of Metal Ions to Form M−S−Ni Bridges to Mercapto Groups Coordinated to Nickel(II). Implications for Acetyl Coenzyme A Synthase
  92. Thiolate-bridged heterodinuclear platinum–zinc chelates as models for ternary platinum–DNA–protein complexes and zinc ejection from zinc fingers. Evidence from studies using ESI-mass spectrometry
  93. Metallodithiolato ligands as bridges in multiply bonded dimolybdenum complexes
  94. The Vapochromic Behavior, Desulfoxidation and Structural Characterization of the SO2 Adducts of Ni(BME-DACH) from Powder Data
  95. The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H 2 Production Electrocatalysts:  Iron Hydrogenase Model Complexes
  96. Bismercaptoethanediazacyclooctane as a N 2 S 2 Chelating Agent and Cys−X−Cys Mimic for Fe(NO) and Fe(NO) 2
  97. Accommodation of the Irregular Coordination Geometry of Lead(II) by a Square Planar N 2 S 2 Ligand and Its Preference for Zinc(II)
  98. Sensing of Sulfur Dioxide by Base Metal Thiolates:  Structures and Properties of Molecular NiN 2 S 2 /SO 2 Adducts
  99. Structures and Energetics of Models for the Active Site of Acetyl-Coenzyme A Synthase:  Role of Distal and Proximal Metals in Catalysis
  100. The Construction of (N2S2)Ni−Pd Clusters: A Slant-Chair, a Basket and a C4-Paddlewheel Structure
  101. SYNERGY BETWEEN THEORY AND EXPERIMENT AS APPLIED TO H/D EXCHANGE ACTIVITY ASSAYS IN [Fe]H2ase ACTIVE SITE MODELS
  102. Adamantane-like Cluster Complexes of Mixed-Valent Copper−Copper and Nickel−Copper Thiolates
  103. The organometallic active site of [Fe]hydrogenase: Models and entatic states
  104. Fundamental properties of small molecule models of Fe-only hydrogenase: computations relative to the definition of an entatic state in the active site
  105. Requirements for Functional Models of the Iron Hydrogenase Active Site:  D2/H2O Exchange Activity in {(μ-SMe)(μ-pdt)[Fe(CO)2(PMe3)]2+}[BF4-]
  106. Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships
  107. Capture of NiII, CuIand ZnIIby thiolate sulfurs of an N2S2Ni complex: A role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site
  108. Activation of Alkenes and H 2 by [Fe]-H 2 ase Model Complexes
  109. X-ray structure of [Nb(η5-C5H5)2(SCH2CH2CH2S].
  110. Catalysis of H 2 /D 2 Scrambling and Other H/D Exchange Processes by [Fe]-Hydrogenase Model Complexes
  111. Unique Reactivity of a Tetradentate N 2 S 2 Complex of Nickel:  Intermediates in the Production of Sulfur Oxygenates
  112. Oxidative Addition of Phosphine-Tethered Thiols to Iron Carbonyl:  Binuclear Phosphinothiolate Complexes, (μ-SCH 2 CH 2 PPh 2 ) 2 Fe 2 (CO) 4 , and Hydride Derivatives
  113. H/D Exchange Reactions in Dinuclear Iron Thiolates as Activity Assay Models of Fe−H 2 ase
  114. Subtle Bite-Angle Influences on N 2 S 2 Ni Complexes
  115. Coordination Sphere Flexibility of Active-Site Models for Fe-Only Hydrogenase:  Studies in Intra- and Intermolecular Diatomic Ligand Exchange
  116. The bio-organometallic chemistry of active site iron in hydrogenases
  117. Correlation of electrochemistry, nucleophilicity and density functional calculations of the cis-dithiolate (bme*-daco)Ni
  118. Heterobimetallics of Nickel−Iron Dinitrosyl:  Electronic Control by Chelate and Diatomic Ligands
  119. Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase
  120. Synthesis and Dimer Cleavage Reactions of the N 2 S Thiolate Bridged Dimer [(mmp-dach) 2 Ni 2 ]Cl 2
  121. Nickel mediated sulfur–selenium and sulfur–sulfur bond formation
  122. Sulfur Site Iodine Adduct of a Nickel Thiolate Complex
  123. Alkylation-Induced O-Atom Rearrangement in Nickel S-Oxygenates.
  124. Responses of the Fe(CN) 2 (CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase
  125. Alkylation-Induced O-Atom Rearrangement in Nickel S-Oxygenates
  126. Pentacoordinate (μ-Oxo)diiron(III) Thiolate Complexes and Dimeric Iron(II) Precursors
  127. Oxygen Capture by Sulfur in Nickel Thiolates
  128. Methylation of Tethered Thiolates in [(bme-daco)Zn] 2 and [(bme-daco)Cd] 2 as a Model of Zinc Sulfur-Methylation Proteins
  129. Synthesis, Structures, and Electrochemical Properties of Nickel Complexes of Macrocyclic N 2 S 2 Aminothioethers
  130. Inorganic Syntheses
  131. Cyano[tri(cyclohexyl)phosphino]gold(I), [Au(CN){(C6H11)3P}]
  132. Analysis of an Organometallic Iron Site Model for the Heterodimetallic Unit of [NiFe]Hydrogenase
  133. A New Macrocyclic N 3 S 2 Ligand and Its Nickel(II), Cobalt(II), Rhodium(III)-103, and Rhodium(III)-105 Complexes
  134. Singlet Oxygen and the Production of Sulfur Oxygenates of Nickel(II) and Palladium(II) Thiolates
  135. Thiolate Bridged Nickel–Iron Complexes Containing both Iron(0) and Iron(II) Carbonyls
  136. Lightinduced sulfur-dealkylation of phosphino-thioether nickel(0) complexes
  137. Structural and Electrochemical Comparison of NiII in an N2S2 Plane with Two, One and No Axial Ligands: Isolation and Characterization of a Five-Coordinate Nickel(II) Complex
  138. Template Effect for O 2 Addition across cis -Sulfur Sites in Nickel Dithiolates
  139. Polydentate N 2 S 2 O and N 2 S 2 O 2 Ligands as Alcoholic Derivatives of ( N , N ‘-Bis(2-mercaptoethyl)-1,5-diazacyclooctane)nickel(II) and ( N , N ‘-Bis(2-mercapto-2-methylpropane)-1,5-diazacyclooctane)nickel(II)
  140. Influence of Sulfur Metalation on the Accessibility of the Ni II/I Couple in [ N , N‘ -Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II):  Insight into the Redox Properties of [NiFe]-Hydrogenase
  141. Characteristics of Nickel(0), Nickel(I), and Nickel(II) in Phosphino Thioether Complexes:  Molecular Structure and S -Dealkylation of (Ph 2 P( o -C 6 H 4 )SCH 3 ) 2 Ni 0
  142. A Coordination Polymer of Nickel(II) Based on a Pentadentate N, S, and O Donor Ligand
  143. Structure/Function Relationships in Ligand-Based SO2/O2 Conversion to Sulfate As Promoted by Nickel and Palladium Thiolates
  144. Metallosulfoxides and -sulfones: Sulfur Oxygenates of [1,5-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]palladium(II)
  145. Study of Sulfinate and Sulfenate Complexes Derived from the Oxygenation of Thiolate Sulfur in [1,5-Bis(2-mercapto-2-methylpropyl)-1,5-diazacyclooctanato(2-)]nickel(II). [Erratum to document cited in CA122:70603]
  146. Study of Sulfinate and Sulfenate Complexes Derived from the Oxygenation of Thiolate Sulfur in [1,5-Bis(2-mercapto-2-methylpropyl)-1,5-diazacyclooctanato(2-)]nickel(II)
  147. Crystal structure of tetrakis[μ3-methoxo-2,4-pentanedionatomethanolnickel(II)],C28H56Ni4O16
  148. Crystal structure of mercaptoethylene-1,4-diazacycloheptanenickel(II)-μ-S-1,4-bis(mercaptoethylene)-1,4-diazacycloheptanenickel(II) chloride methanol solvate, C16.8H36.6Cl1.1N4Ni2OS2.9
  149. Reduction-Promoted Sulfur-Oxygen Bond Cleavage in a Nickel Sulfenate as a Model for the Activation of [NiFe] Hydrogenase
  150. SYNTHETIC STRATEGIES FOR N2S2O-PENTACOORDINATE NICKEL(II) BASED ON THE HIGHLY STERICALLY ENCUMBERED LIGAND N,N′-BIS(2-MERCAPTO-2-METHYLPROPANE)-1,5-DIAZACYCLOOCTANE
  151. Synthesis and Characterization of a Stable Iron(II) Hydride-Thiolate Complex: (PhS)Fe(H)(CO)2(P(OPh)3)2
  152. Sulfur site adducts of sulfur dioxide in nickel-bound thiolates and their conversion to sulfate
  153. Variable oxygenation levels of sulfur in sterically hindered thiolates: molecular structure of [N-(2-mercapto-2-methylpropyl)-N'-(2-sulfeno-2-methylpropyl)-1,5-diazacyclooctanato]nickel(II)
  154. Divergent pathways for the addition of dioxygen to sulfur in nickel cis-dithiolates: an isotopomeric analysis
  155. X-ray structure and solution characterization of tetracarbonylmolybdenumbis(.mu.-diphenylphosphinoethanethiolato)nickel (Ni(.mu.-SCH2CH2PPh2)2Mo(CO)4)
  156. Effects of sulfur site modification on the redox potentials of derivatives of [N,N'-bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II)
  157. Organometallic chemistry of sulfur/phosphorus donor ligand complexes of nickel(II) and nickel(0)
  158. Axial Ligation of Diazacyclooctanenickel and -Zinc Complexes
  159. Variable modes of nickel(II) coordination with macrocyclic ligands based on 1,5-bis(2-mercaptoethyl)-1,5-diazacyclooctane (BME-DACO)
  160. Synthesis and characterization of the electron-rich iron hydride HFe(CO)2(P(OPh)3)2- and its ligand-based redox substitution with thiolates
  161. Preparations and structures of a zinc(II) dimer and zinc(II)/nickel(II) pentanuclear derivatives of N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane: [(BME-DACO)Zn]2 and {[(BME-DACO)Ni]3[ZnCl]2}{BF4}2
  162. Complexation of organotin halides with ambidentate, S, N, and O donor ligands
  163. Isotopic labeling investigation of the oxygenation of nickel-bound thiolates by molecular oxygen
  164. Stereochemical nonrigidity in heterobimetallic complexes containing the bent metallocene-thiolate fragment
  165. Applications of the N2S2 ligand, N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane (BME-DACO), toward the formation of bi- and heterometallics: [(BME-DACO)Fe]2 and [(BME-DACO)NiFeCl2]2
  166. Direct synthesis of mixed metal sulfide catalysts and their hydrodenitrogenation activity
  167. Sterically protected nickel(II) in a N2S2 donor environment: 1,5-bis(mercaptoethyl)-1,5-diazacyclooctane and its methylated derivative
  168. Conformations of (.eta.5-C5H5)2Nb(S-p-C6H4X)2n(n=0,1): responsiveness to para substituents on aryl groups and to d-electron count
  169. The synthesis and molecular structure of (Ph3PAu)2Fe(CO)3P(OEt)3: a triangular Au2Fe cluster
  170. Isolation of chromium(0) thiols: molecular structure of (tert-butylmercaptan)pentacarbonylchromium
  171. Electron paramagnetic resonance and electrochemical study of the oxidation chemistry of mononuclear and binuclear chromium carbonyl thiolates
  172. Reactions of anionic transition metal carbonyl hydrides with electrophilic metal carbonyls: Nucleophilic addition (hydride transfer) vs. electron transfer mechanisms
  173. Protonation sites in thiolato iron carbonylates: evidence for an arrested Fe(RS-H) oxidative addition
  174. Thiolate, thioether, and thiol derivatives of iron(0) carbonyls
  175. Structural studies of thiophenoxide niobium complexes (.eta.5-C5H5)2Nb(SC6H5)2, [(.eta.5-C5H5)2Nb(SC6H5)2+], and [(.eta.5-C5H5)2Nb(.mu.-SC6H5)2)Mo(CO)4+]
  176. Spectroscopic and chemical studies of nickel(II) hydrides
  177. Addition of acrylonitrile to anionic transition metal hydrides. An ionic model for homogeneous olefin processes
  178. EPR spectrum of the ion pair [CR(CO)5−]2 in irradiated crystals of PPh4+ HCr(CO)5−
  179. Binuclear reductive elimination of water: new route to the (triphenylstannyl)pentacarbonyltungsten anion, Ph3SnW(CO)5-
  180. Promotion of methyl/carbonyl migratory insertion by transition-metal Lewis acids. Synthesis and reactivity of a transition-metal heterobimetallic carbonyl alkyl anion, MeFeW(CO)9-
  181. Mechanisms of group transfer in anionic transition metal hydrides and alkyls
  182. Reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of an hydridonickel formate complex, HNi(O2CH)(Cy3P)2
  183. Temperature and solvent dependence of scalar coupling constants in salts of trans-HFe(CO)3PR3-
  184. Properties and x-ray structure of bis(triphenylphosphine)nitrogen(1+) cis-tricarbonylhydridotris(triphenyl phosphite)ferrate(1-), an unexpected structural isomer
  185. Competing nucleophilic displacement and radical-chain reduction in reactions of transition-metal hydride anions with alkyl bromides
  186. Anionic Transition Metal Hydrides
  187. Anionic group 6 hydrides and carboxylates as homogeneous catalysts for reduction of aldehydes and ketones
  188. Deprotonation of molybdenum carbonyl hydrido diphosphine [HMo(CO)2(PP)2]BF4 complexes: hard anions as proton carriers
  189. Metal donor to metal acceptor complexes. Fe(CO)42-, HFe(CO)4-, and trans-HFe(CO)3P(OMe)3- as anionic ligands to M(CO)50, M = Cr, W
  190. Intramolecular ligand rearrangements in anionic group 6 metal pentacarbonyl hydride derivatives
  191. Solution and solid-state structures of salts of trans-HFe(CO)3PR3- including a study of alkali cation contact ion pairing
  192. Comparisons of the heterobimetallic and heterotrimetallic anions HFeW(CO)9- and Ph3PAuFeW(CO)9-
  193. Olefin isomerization catalysis by heterobimetallic hydrides, HFeM(CO)8L- (M = Cr, Mo, W; L = CO, PR3)
  194. Anionic group 6 transition-metal carbonyl hydrides as reducing agents. ketones, aldehydes, and epoxides
  195. Relative reactivity and mechanistic studies of the hydride-transfer reagents HM(CO)4L-(M = Cr, W; L = CO, PR3)
  196. Selective reduction of acyl chlorides to aldehydes by anionic Group VIB transition metal hydrides
  197. Hydrogen-deuterium exchange of the anionic Group VIB transition-metal hydrides. Convenient, in situ deuterium transfer reagents
  198. The nature of alkali cation contact ion pairs with anionic transition-metal hydrides HM(CO)4L- (M = Cr, W; L = CO, PR3)
  199. Binuclear molybdenum carbonyls bridged both by hydride and bidentate phosphine ligands. Crystal and molecular structures of salts of hydridomolybdenum carbonyls with bidentate phosphine ligands (.mu.-H)(.mu.-Ph2P(CH2)nPPh2)Mo2(CO)8- (n = 1-4) and their...
  200. Relative reactivities of anionic transition metal hydrides. Reduction of alkyl halides
  201. Chemistry of new heteronuclear bridging hydrides: (.mu.-H)[Fe(CO)4M(CO)5]- (M = chromium, molybdenum, or tungsten)
  202. The anion assisted transfer of a sterically constrained proton: molecular structure of bis[1,2-ethanediylbis(diphenylphosphine)]dicarbonylhydridomolybdenum tetrachloroaluminate [HMo(CO)2(Ph2PCH2CH2PPh2)2+ AlCl4-]
  203. Structural characterizations of salts of HCr(CO) 5 - and (μ-H) 2 BH 2 Cr(CO) 4 - and studies of their interconversions
  204. Chemistry of hydrido carbonyl VIB metalates substituted by P-donor ligands: HW(CO)4PR3- (R = Me, OMe, Ph) and .mu.-H[WM(CO)10-x(P(OMe)3)x] (M = Cr, W; x = 1, 2)
  205. Interactions of CpM'(CO)3- (M' = chromium, molybdenum, or tungsten) with cations: effects on CO exchange and RX addition reactions
  206. Site-specific ion pairing of monosubstituted vanadium carbonylates, LV(CO)5-
  207. Chromium, molybdenum, and tungsten
  208. The use of ion-pairing phenomena in the assignment of v(co) ir bands of pv(co)5-
  209. Alternate synthetic routes to the pentacarbonylhydrides of chromium, molybdenum, and tungsten
  210. Studies using tributylphosphine oxide as a carbon monoxide labilizing ligand in the synthesis of metal carbonyl complexes highly enriched in carbon-13 monoxide
  211. Facile reduction of carbon dioxide by anionic Group 6b metal hydrides. Chemistry relevant to catalysis of the water-gas shift reaction
  212. The pentacarbonylhydridochromium (1-) anion
  213. A reactivity study of addition of organic halides to CpMo(CO)3−: counterion and RX dependences
  214. The .mu.-hydrobis[tetracarbonyl(methyldiphenylphosphine)molybdenum](2-) anion: an example of phosphine enhancement of metal-metal interaction
  215. Synthesis of metal carbonyl complexes highly enriched in carbon-13: utilization of the carbon monoxide-labilizing ability of (n-Bu)3P:O
  216. Cation interaction with transition metal carbonylates and cyanocarbonylates
  217. Reaction of iron pentacarbonyl with oxygen-18-enriched hydroxide. Decarboxylation vs. oxygen exchange in the [Fe(COOH)] intermediate
  218. Structural and chemical characterization of a phosphine bound M-H-M bridged carbonylate: Et4N+(.mu.-H)[Mo2(CO)9PPh3]-
  219. Arene-transition metal chemistry. 2. Hydrogenation of metal-arene and allylmetal-arene complexes
  220. Arene-transition metal complexes. 1. Site exchange and chemical characteristics of .eta.6-C6(CH3)6Ru-.eta.4-C6(CH3)6
  221. Preparation of a stereospecifically carbon-13 monoxide-labeled [(.mu.-H)[Mo(CO)5]2]- species and analysis of its carbonyl stretching vibrational modes
  222. Solution structure and reactivity of hydridoiron tetracarbonyl anion, [HFe(CO)4]-
  223. Ligand lability studies in bridging hydride complexes of Group 6B metal carbonylates
  224. The extent of association of the bis(triphenylphosphine)iminium cation with organometallic anions in tetrahydrofuran solution
  225. Conductivity studies of ion pairing in transition metal organics
  226. Chromium, molybdenum and tungsten
  227. Carbonyl Ligand Lability in the μ-H[Cr(CO)5]2− Anion
  228. Infrared, conductance, and kinetic evidence for alkali metal ion interactions with derivatives of manganese carbonylates
  229. Molecular structure and spectral properties of phosphatriazaadamantanemolybdenum pentacarbonyl complex
  230. Synthesis, spectral properties, and reactions of manganese and rhenium pentacarbonyl phosphine and phosphite cation derivatives and related complexes
  231. Synthesis and spectral properties of metal carbonyl derivatives of the tetrabasic, nonchelating phosphatriazaadamantane ligand
  232. The stereochemical course of reactions leading to formation of mono-ligated (phenylacetyl)manganese tetracarbonyl compounds
  233. Chromium, molybdenum and tungsten
  234. Solvent effects on the solution structure and chemical properties of lithium and magnesium salts of trans-phenylacyltricarbonyl(triphenylphosphine)iron(1-)
  235. The synthesis and spectral properties of manganese pentacarbonyl phosphine and phosphite cation derivatives and related complexes
  236. Alkylation and substitution reactions of metal carbonyl acylate and carbene complexes
  237. The synthesis of group V substituted derivatives of iron pentacarbonyl in high yield
  238. Electronic and steric control of reactions of benzylmagnesium chloride with substituted metal carbonyls
  239. Photochemical substitution reactions of substituted Group VI metal carbonyls
  240. Reactions of organolithium and grignard reagents with the cyclopentadienyliron tricarbonyl cation and its derivatives
  241. Nature of the intermediate procreated in substitution reactions of Group VI metal carbonyls
  242. Reactions of transition metal carbonyls with organolithium compounds. II. Prediction of nucleophilic attack at carbon and resultant stereochemistry
  243. Spectroscopic studies of some carbene pentacarbonyl complexes of chromium(0) and tungsten(0)
  244. Tetracarbonyliron(0) Complexes Containing Group V Donor Ligands
  245. Tetracarbonyl{[2-(Diphenylphosphino)Phenyl]Hydroxymethyl-C, P}Manganese
  246. Heterobinuclear Nonacarbonyl Complexes and Hydride Complexes of Iron—Chromium, Iron—Molybdenum, and Iron—Tungsten