All Stories

  1. Synthesis of cyclic monothiocarbonates via the coupling reaction of carbonyl sulfide (COS) with epoxides

    Article • Catalysis Science & Technology, January 2016, Royal Society of Chemistry

    Professor Donald J Darensbourg

  2. Terpolymerization of propylene oxide and vinyl oxides with CO2: copolymer cross-linking and surface modification via thiol–ene click chemistry

    Article • Polymer Chemistry, January 2015, Royal Society of Chemistry

    Professor Donald J Darensbourg

  3. Highly regioselective and alternating copolymerization of carbonyl sulfide with phenyl glycidyl ether

    Article • Polymer Chemistry, January 2015, Royal Society of Chemistry

    Professor Donald J Darensbourg

  4. Copolymerization and Cycloaddition Products Derived from Coupling Reactions of 1,2-Epoxy-4-cyclohexene and Carbon Dioxide. Postpolymerization Functionalization via Thiol–Ene Click Reactions

    Article • Macromolecules, November 2014, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  5. Availability of Other Aliphatic Polycarbonates Derived from Geometric Isomers of Butene Oxide and Carbon Dioxide Coupling Reactions

    Article • Macromolecules, August 2014, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  6. Postpolymerization Functionalization of Copolymers Produced from Carbon Dioxide and 2-Vinyloxirane: Amphiphilic/Water-Soluble CO 2 -Based Polycarbonates

    Article • Macromolecules, June 2014, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  7. Sequestering CO 2 for Short-Term Storage in MOFs: Copolymer Synthesis with Oxiranes

    Article • ACS Catalysis, May 2014, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  8. Thermal and Photochemical Reactivity of Manganese Tricarbonyl and Tetracarbonyl Complexes with a Bulky Diazabutadiene Ligand

    Article • Inorganic Chemistry, April 2014, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  9. A concise review of computational studies of the carbon dioxide–epoxide copolymerization reactions

    Article • Polymer Chemistry, January 2014, Royal Society of Chemistry

    Professor Donald J Darensbourg

  10. Kinetics and thermodynamics of the decarboxylation of 1,2-glycerol carbonate to produce glycidol: computational insights

    Article • Green Chemistry, January 2014, Royal Society of Chemistry

    Professor Donald J Darensbourg

  11. Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes

    Article • Chemical Science, January 2014, Royal Society of Chemistry

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  12. Personal Adventures in the Synthesis of Copolymers from Carbon Dioxide and Cyclic Ethers

    Article • January 2014, Elsevier

    Professor Donald J Darensbourg

  13. Iron Complexes Containing Electrochemically Active Diazocycle-bis(di- tert -butyl-phenol) Ligands

    Article • Journal of the Brazilian Chemical Society, January 2014, GN1 Genesis Network

    Professor Donald J Darensbourg

  14. Catalytic Coupling of Cyclopentene Oxide and CO 2 Utilizing Bifunctional (salen)Co(III) and (salen)Cr(III) Catalysts: Comparative Processes Involving Binary (salen)Cr(III) Analogs

    Article • ACS Catalysis, December 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  15. Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination

    Article • Journal of the American Chemical Society, November 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  16. Light-Enhanced Displacement of Methyl Acrylate from Iron Carbonyl: Investigation of the Reactive Intermediate via Rapid-Scan Fourier Transform Infrared and Computational Studies

    Article • Inorganic Chemistry, November 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  17. Oxygen/Sulfur Scrambling During the Copolymerization of Cyclopentene Oxide and Carbon Disulfide: Selectivity for Copolymer vs Cyclic [Thio]carbonates

    Article • Macromolecules, October 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  18. A One-Pot Synthesis of a Triblock Copolymer from Propylene Oxide/Carbon Dioxide and Lactide: Intermediacy of Polyol Initiators

    Article • Angewandte Chemie, August 2013, Wiley

    Professor Donald J Darensbourg

  19. A One-Pot Synthesis of a Triblock Copolymer from Propylene Oxide/Carbon Dioxide and Lactide: Intermediacy of Polyol Initiators

    Article • Angewandte Chemie International Edition, August 2013, Wiley

    Professor Donald J Darensbourg

  20. An Efficient Method of Depolymerization of Poly(cyclopentene carbonate) to Its Comonomers: Cyclopentene Oxide and Carbon Dioxide

    Article • Macromolecules, August 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  21. Synthesis of CO 2 -Derived Poly(indene carbonate) from Indene Oxide Utilizing Bifunctional Cobalt(III) Catalysts

    Article • Macromolecules, August 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  22. Relative basicities of cyclic ethers and esters. Chemistry of importance to ring-opening co- and terpolymerization reactions

    Article • Polyhedron, July 2013, Elsevier

    Professor Donald J Darensbourg

  23. Kinetic and Thermodynamic Investigations of CO2Insertion Reactions into Ru-Me and Ru-H Bonds - An Experimental and Computational Study

    Article • European Journal of Inorganic Chemistry, June 2013, Wiley

    Professor Donald J Darensbourg

  24. Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)/ Thiolate Dinitrosyl Iron Complex (DNIC)

    Article • Journal of the American Chemical Society, June 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  25. Depolymerization of Poly(indene carbonate). A Unique Degradation Pathway

    Article • Macromolecules, May 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  26. Acrylic Acid Derivatives of Group 8 Metal Carbonyls: A Structural and Kinetic Study

    Article • Inorganic Chemistry, May 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  27. Crystalline CO 2 Copolymer from Epichlorohydrin via Co(III)-Complex-Mediated Stereospecific Polymerization

    Article • Macromolecules, March 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  28. Thermodynamics of the Carbon Dioxide–Epoxide Copolymerization and Kinetics of the Metal-Free Degradation: A Computational Study

    Article • Macromolecules, January 2013, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  29. Estimating the strength of the M–H–B interaction: a kinetic approach

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Donald J Darensbourg

  30. Base initiated depolymerization of polycarbonates to epoxide and carbon dioxide co-monomers: a computational study

    Article • Green Chemistry, January 2013, Royal Society of Chemistry

    Professor Donald J Darensbourg

  31. Mechanism of CO Displacement from an Unusually Labile Rhenium Complex: An Experimental and Theoretical Investigation

    Article • Inorganic Chemistry, December 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  32. Tandem Metal-Coordination Copolymerization and Organocatalytic Ring-Opening Polymerization via Water To Synthesize Diblock Copolymers of Styrene Oxide/CO 2 and Lactide

    Article • Journal of the American Chemical Society, October 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  33. Formation of Cyclic Carbonates from Carbon Dioxide and Epoxides Coupling Reactions Efficiently Catalyzed by Robust, Recyclable One-Component Aluminum-Salen Complexes

    Article • ACS Catalysis, September 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  34. Depolymerization of Polycarbonates Derived from Carbon Dioxide and Epoxides to Provide Cyclic Carbonates. A Kinetic Study

    Article • Macromolecules, August 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  35. Time Resolved Infrared Spectroscopy: Kinetic Studies of Weakly Binding Ligands in an Iron–Iron Hydrogenase Model Compound

    Article • Inorganic Chemistry, July 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  36. Time-Resolved Infrared Spectroscopy Studies of Olefin Binding in Photogenerated CpRu(CO)X (X = Cl, I) Transients

    Article • Organometallics, May 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  37. ChemInform Abstract: Cobalt Catalysts for the Coupling of CO2and Epoxides to Provide Polycarbonates and Cyclic Carbonates

    Article • ChemInform, April 2012, Wiley

    Professor Donald J Darensbourg

  38. Photochemically Generated Transients from κ 2 - and κ 3 -Triphos Derivatives of Group 6 Metal Carbonyls and Their Reactivity with Olefins

    Article • Organometallics, April 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  39. Kinetic Studies of the Alternating Copolymerization of Cyclic Acid Anhydrides and Epoxides, and the Terpolymerization of Cyclic Acid Anhydrides, Epoxides, and CO 2 Catalyzed by (salen)Cr III Cl

    Article • Macromolecules, March 2012, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  40. Cobalt catalysts for the coupling of CO2and epoxides to provide polycarbonates and cyclic carbonates

    Article • Chemical Society Reviews, January 2012, Royal Society of Chemistry

    Professor Donald J Darensbourg

  41. Synthesis of Poly(indene carbonate) from Indene Oxide and Carbon Dioxide—A Polycarbonate with a Rigid Backbone

    Article • Journal of the American Chemical Society, November 2011, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  42. (Salan)CrCl, an effective catalyst for the copolymerization and terpolymerization of epoxides and carbon dioxide

    Article • Journal of Polymer Science Part A Polymer Chemistry, September 2011, Wiley

    Professor Donald J Darensbourg

  43. Perfectly Alternating Copolymerization of CO 2 and Epichlorohydrin Using Cobalt(III)-Based Catalyst Systems

    Article • Journal of the American Chemical Society, September 2011, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  44. Ring-Opening Polymerization of Cyclic Esters and Trimethylene Carbonate Catalyzed by Aluminum Half-Salen Complexes

    Article • Inorganic Chemistry, July 2011, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  45. Ligand Displacement from TpMn(CO) 2 L Complexes: A Large Rate Enhancement in Comparison to the CpMn(CO) 2 L Analogues

    Article • Organometallics, June 2011, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  46. Book Review of Poly(Lactic Acid): Synthesis, Structures, Properties, Processing, and Applications Poly(Lactic Acid): Synthesis, Structures, Properties, Processing, and Applications . Edited by Rafael A. Auras (Michigan State University, East Lansing, M...

    Article • Journal of the American Chemical Society, May 2011, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  47. Aliphatic Polycarbonates Produced from the Coupling of Carbon Dioxide and Oxetanes and Their Depolymerization via Cyclic Carbonate Formation

    Article • Macromolecules, April 2011, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  48. Ring-Opening Polymerization of Renewable Six-Membered Cyclic Carbonates. Monomer Synthesis and Catalysis

    Article • March 2011, Wiley

    Professor Donald J Darensbourg

  49. Alternating copolymerization of CO2 and styrene oxide with Co(iii)-based catalyst systems: differences between styrene oxide and propylene oxide

    Article • Energy & Environmental Science, January 2011, Royal Society of Chemistry

    Professor Donald J Darensbourg

  50. Salen Metal Complexes as Catalysts for the Synthesis of Polycarbonates from Cyclic Ethers and Carbon Dioxide

    Article • January 2011, Springer Science + Business Media

    Professor Donald J Darensbourg

  51. Chemistry of Carbon Dioxide Relevant to Its Utilization: A Personal Perspective

    Article • Inorganic Chemistry, December 2010, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  52. Ring-Opening Polymerization of l -Lactide and ε-Caprolactone Utilizing Biocompatible Zinc Catalysts. Random Copolymerization of l -Lactide and ε-Caprolactone

    Article • Macromolecules, November 2010, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  53. Highly Selective Synthesis of CO 2 Copolymer from Styrene Oxide

    Article • Macromolecules, November 2010, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  54. Stereoselective Ring-Opening Polymerization of rac -Lactides Catalyzed by Chiral and Achiral Aluminum Half-Salen Complexes †

    Article • Organometallics, November 2010, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  55. ChemInform Abstract: The Organometallic Chemistry of Carbon Dioxide Pertinent to Catalysis

    Article • ChemInform, August 2010, Wiley

    Professor Donald J Darensbourg

  56. ChemInform Abstract: Uses of Metal Clusters in Homogeneous and Heterogeneous Catalysis

    Article • ChemInform, August 2010, Wiley

    Professor Donald J Darensbourg

  57. Ligand Substitution from the (η 5 -DMP)Mn(CO) 2 (Solv) [DMP = 2,5-dimethylpyrrole, Solv = solvent] Complexes: To Ring Slip or Not to Ring Slip?

    Article • Inorganic Chemistry, August 2010, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  58. ChemInform Abstract: Catalysts for the Reactions of Epoxides and Carbon Dioxide

    Article • ChemInform, August 2010, Wiley

    Professor Donald J Darensbourg

  59. Tuning the Selectivity of the Oxetane and CO 2 Coupling Process Catalyzed by (Salen)CrCl/ n -Bu 4 NX: Cyclic Carbonate Formation vs Aliphatic Polycarbonate Production

    Article • Macromolecules, July 2010, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  60. Ring-Opening Polymerization of Lactides Catalyzed by Natural Amino-Acid Based Zinc Catalysts

    Article • Inorganic Chemistry, March 2010, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  61. A facile catalytic synthesis of trimethylene carbonate from trimethylene oxide and carbon dioxide

    Article • Green Chemistry, January 2010, Royal Society of Chemistry

    Professor Donald J Darensbourg

  62. Highly Selective and Reactive (salan)CrCl Catalyst for the Copolymerization and Block Copolymerization of Epoxides with Carbon Dioxide

    Article • Macromolecules, September 2009, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  63. Copolymerization of Epoxides and Carbon Dioxide. Evidence Supporting the Lack of Dual Catalysis at a Single Metal Site

    Article • Inorganic Chemistry, September 2009, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  64. Displacement Kinetics of η 2 -Bound Furan and 2,3-Dihydrofuran from Mn and Cr Centers: Evidence for the Partial Dearomatization of the Furan Ligand

    Article • Inorganic Chemistry, August 2009, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  65. (Salen)Co(II)/ n -Bu 4 NX Catalysts for the Coupling of CO 2 and Oxetane: Selectivity for Cyclic Carbonate Formation in the Production of Poly-(trimethylene carbonate)

    Article • Macromolecules, June 2009, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  66. Investigations into the coupling of cyclohexene oxide and carbon disulfide catalyzed by (salen)CrCl. Selectivity for the production of copolymers vs. cyclic thiocarbonates

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Professor Donald J Darensbourg

  67. An Exploration of the Coupling Reactions of Epoxides and Carbon Dioxide Catalyzed by Tetramethyltetraazaannulene Chromium(III) Derivatives: Formation of Copolymers versus Cyclic Carbonates

    Article • Inorganic Chemistry, December 2008, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  68. Mechanistic Insight into the Initiation Step of the Coupling Reaction of Oxetane or Epoxides and CO 2 Catalyzed by (salen)CrX Complexes

    Article • Inorganic Chemistry, November 2008, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  69. Carbon Dioxide

    Article • September 2008, Wiley

    Professor Donald J Darensbourg

  70. Studies of the Carbon Dioxide and Epoxide Coupling Reaction in the Presence of Fluorinated Manganese(III) Acacen Complexes: Kinetics of Epoxide Ring-Opening

    Article • Inorganic Chemistry, June 2008, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  71. Ring-Opening Polymerization of Cyclic Monomers by Complexes Derived from Biocompatible Metals. Production of Poly(lactide), Poly(trimethylene carbonate), and Their Copolymers

    Article • Macromolecules, May 2008, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  72. Mechanistic Studies of the Copolymerization Reaction of Oxetane and Carbon Dioxide to Provide Aliphatic Polycarbonates Catalyzed by (Salen)CrX Complexes

    Article • Journal of the American Chemical Society, May 2008, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  73. A phase separable polycarbonate polymerization catalyst

    Article • Chemical Communications, January 2008, Royal Society of Chemistry

    Professor David E Bergbreiter, Professor Donald J Darensbourg

  74. X-Ray crystal structures of five-coordinate (salen)MnN3 derivatives and their binding abilities towards epoxides: chemistry relevant to the epoxide–CO2 copolymerization process

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Professor Donald J Darensbourg

  75. Switchable-Polarity Solvents Prepared with a Single Liquid Component

    Article • The Journal of Organic Chemistry, January 2008, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  76. What is the Real Steric Impact of Triphenylphosphite? Solid-State and Solution Structural Studies of cis - and trans -Isomers of M(CO) 4 [P(OPh) 3 ] 2 (M = Mo and W)

    Article • Organometallics, December 2007, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  77. Inquiry into the Formation of Cyclic Carbonates during the (Salen)CrX Catalyzed CO 2 /Cyclohexene Oxide Copolymerization Process in the Presence of Ionic Initiators

    Article • Macromolecules, October 2007, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  78. Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO2

    Article • ChemInform, September 2007, Wiley

    Professor Donald J Darensbourg

  79. (Tetramethyltetraazaannulene)chromium Chloride:  A Highly Active Catalyst for the Alternating Copolymerization of Epoxides and Carbon Dioxide

    Article • Inorganic Chemistry, July 2007, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  80. Manganese(III) Schiff Base Complexes:  Chemistry Relevant to the Copolymerization of Epoxides and Carbon Dioxide

    Article • Inorganic Chemistry, July 2007, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  81. Making Plastics from Carbon Dioxide:  Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO 2

    Article • Chemical Reviews, June 2007, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  82. Biomimetic study of a polymeric composite material for joint repair applications

    Article • Journal of Materials Research, June 2007, Cambridge University Press

    Professor Donald J Darensbourg

  83. Ring-Opening Polymerization of Cyclic Monomers by Biocompatible Metal Complexes. Production of Poly(lactide), Polycarbonates, and Their Copolymers

    Article • Macromolecules, May 2007, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  84. Further studies related to the copolymerization of cyclohexene oxide and carbon dioxide catalyzed by chromium Schiff base complexes. Crystal structures of two μ-hydroxo-bridged Schiff base dimers of chromium(III)

    Article • Inorganica Chimica Acta, February 2007, Elsevier

    Professor Donald J Darensbourg

  85. Labile Copper (I) Chloride Complexes: Preparation and Handling

    Article • January 2007, Wiley

    Professor Donald J Darensbourg

  86. Tricarbonyl(Hydrido) [1,2-Bis (Diphenyl-phosphino)Ethane]Manganese as Precursor to Labile Site Derivatives

    Article • January 2007, Wiley

    Professor Donald J Darensbourg

  87. Group 6 Pentacarbonyl Acetates as their μ-Nitrido-Bis(Triphenylphosphorus)(1+) Salts

    Article • January 2007, Wiley

    Professor Donald J Darensbourg

  88. (Meta - Sulfonatophenyl) Diphenylphosphine, Sodium Salt and its Complexes with Rhodium(I), Ruthenium(II), Iridium(I)

    Article • January 2007, Wiley

    Professor Donald J Darensbourg

  89. Potassium μ-Hydrido-Bis[Pentacarbonylchromate(0)] and Potassium μ-Hydrido-Bis[Pentacarbonyltungstate(0)]

    Article • January 2007, Wiley

    Professor Donald J Darensbourg

  90. Biometal Derivatives as Catalysts for the Ring-Opening Polymerization of Trimethylene Carbonate. Optimization of the Ca(II) Salen Catalyst System

    Article • Macromolecules, June 2006, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  91. Metal Salen Derivatives as Catalysts for the Alternating Copolymerization of Oxetanes and Carbon Dioxide To Afford Polycarbonates

    Article • Inorganic Chemistry, May 2006, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  92. Ring-Opening Polymerization of Trimethylene Carbonate Using Aluminum(III) and Tin(IV) Salen Chloride Catalysts. Volume 38, Number 13, June 28, 2005, pp 5406−5410.

    Article • Macromolecules, April 2006, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  93. A Kinetic Study of the Ring-Opening Process in Tungsten Carbonyl Complexes Containing Hemilabile Metallodithiolate Ligands

    Article • Inorganic Chemistry, January 2006, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  94. Characterization of Steric and Electronic Properties of NiN 2 S 2 Complexes as S-Donor Metallodithiolate Ligands

    Article • Journal of the American Chemical Society, December 2005, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  95. Role of the Cocatalyst in the Copolymerization of CO 2 and Cyclohexene Oxide Utilizing Chromium Salen Complexes [ J. Am. Chem. Soc. 2005 , 127 , 14026−14038].

    Article • Journal of the American Chemical Society, December 2005, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  96. Role of the Cocatalyst in the Copolymerization of CO 2 and Cyclohexene Oxide Utilizing Chromium Salen Complexes

    Article • Journal of the American Chemical Society, October 2005, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  97. The synthesis and characterization of iron cyanide building blocks: [K]2[CpFe(CN)3] and its pentamethylcyclopentadienyl (Cp*) analog

    Article • Inorganica Chimica Acta, September 2005, Elsevier

    Professor Donald J Darensbourg

  98. Transition Metals

    Article • ChemInform, August 2005, Wiley

    Professor Donald J Darensbourg

  99. Ring-Opening Polymerization of Trimethylene Carbonate Using Aluminum(III) and Tin(IV) Salen Chloride Catalysts

    Article • Macromolecules, June 2005, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  100. Aluminum Salen Complexes and Tetrabutylammonium Salts:  A Binary Catalytic System for Production of Polycarbonates from CO 2 and Cyclohexene Oxide

    Article • Inorganic Chemistry, March 2005, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  101. Copolymerization of CO2 and Epoxides Catalyzed by Metal Salen Complexes

    Article • ChemInform, February 2005, Wiley

    Professor Donald J Darensbourg

  102. N2S2Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic Reactivity

    Article • Angewandte Chemie, February 2005, Wiley

    Professor Donald J Darensbourg

  103. N2S2Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic Reactivity

    Article • Angewandte Chemie International Edition, February 2005, Wiley

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  104. Catalysts for an Aqueous Catalysis: Section 3.1

    Article • January 2005, Wiley

    Professor Donald J Darensbourg

  105. Pressure Dependence of the Carbon Dioxide/Cyclohexene Oxide Coupling Reaction Catalyzed by Chromium Salen Complexes. Optimization of the Comonomer-Alternating Enchainment Pathway

    Article • Organometallics, January 2005, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  106. Bio-mimetic study of novel materials for joint replacements

    Article • MRS Proceedings, January 2005, Cambridge University Press

    Professor Donald J Darensbourg

  107. Structural Characterization of Several (CO) 3 (dppp)MnX Derivatives, dppp = 1,3-Bis(diphenylphosphino)propane and X = H, OTs, OC 2 H 5 , Cl, Br, or N 3 . An Assessment of Their Efficacy for Catalyzing the Coupling of Carbon Dioxide and Epoxides

    Article • Organometallics, December 2004, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  108. Probing the mechanistic aspects of the chromium salen catalyzed carbon dioxide/epoxide copolymerization process using in situ ATR/FTIR

    Article • Catalysis Today, December 2004, Elsevier

    Professor Donald J Darensbourg

  109. Copolymerization of CO 2 and Epoxides Catalyzed by Metal Salen Complexes

    Article • Accounts of Chemical Research, November 2004, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  110. 113 Cd NMR Determination of the Binding Parameters of Alicyclic Epoxides to [Hydrotris(3-phenylpyrazol-1-yl)borate]Cd(II) Acetate

    Article • Organometallics, October 2004, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  111. Mechanistic Studies of the Copolymerization Reaction of Aziridines and Carbon Monoxide to Produce Poly-β-peptoids

    Article • Journal of the American Chemical Society, October 2004, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  112. Cyclohexene Oxide/CO 2 Copolymerization Catalyzed by Chromium(III) Salen Complexes and N -Methylimidazole:  Effects of Varying Salen Ligand Substituents and Relative Cocatalyst Loading

    Article • Inorganic Chemistry, September 2004, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  113. Five-coordinate Schiff base complexes of gallium. Potential catalysts for the copolymerization of carbon dioxide and epoxides

    Article • Comptes Rendus Chimie, August 2004, Elsevier

    Professor Donald J Darensbourg

  114. Synthesis and structural characterization of iron(III) salen complexes possessing appended anionic oxygen donor ligands

    Article • Inorganica Chimica Acta, May 2004, Elsevier

    Professor Donald J Darensbourg

  115. cis-Perhydro-1,4-benzodioxin-2,3-dione

    Article • Acta Crystallographica Section E Structure Reports Online, April 2004, International Union of Crystallography

    Professor Donald J Darensbourg

  116. A New Water-Soluble Phosphine Derived from 1,3,5-Triaza-7-phosphaadamantane (PTA), † 3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane. Structural, Bonding, and Solubility Properties

    Article • Organometallics, April 2004, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  117. (Salen)Cr III X Catalysts for the Copolymerization of Carbon Dioxide and Epoxides:  Role of the Initiator and Cocatalyst

    Article • Inorganic Chemistry, March 2004, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  118. Mixed metal cyanide complexes derived from the CpCo(CN)3− anion

    Article • Inorganica Chimica Acta, March 2004, Elsevier

    Professor Donald J Darensbourg

  119. Catalytic Coupling of Carbon Dioxide and 2,3-Epoxy-1,2,3,4-tetrahydronaphthalene in the Presence of a (Salen)CrIIICl Derivative

    Article • Organometallics, February 2004, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  120. Kinetic Study of the Insertion and Deinsertion of Carbon Dioxide intofac-(CO)3(dppe)MnOR Derivatives

    Article • Organometallics, December 2003, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  121. Synthesis and Structural Characterization of Double Metal Cyanides of Iron and Zinc:  Catalyst Precursors for the Copolymerization of Carbon Dioxide and Epoxides

    Article • Inorganic Chemistry, December 2003, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  122. Synthesis and Structures of Nickel and Palladium Salicylaldiminato 1,3,5-Triaza-7-phosphaadamantane (PTA) Complexes

    Article • Inorganic Chemistry, October 2003, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  123. Synthesis and Structural Characterization of Potassium Salts of Phosphane-Substituted (Cyclopentadienyl)iron Dicyanides, and Their Use as Bridging Ligands for Copper(I) Phosphane Derivatives

    Article • European Journal of Inorganic Chemistry, October 2003, Wiley

    Professor Donald J Darensbourg

  124. The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO 2 Soluble Polycarbonate

    Article • Inorganic Chemistry, July 2003, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  125. Comparative Kinetic Studies of the Copolymerization of Cyclohexene Oxide and Propylene Oxide with Carbon Dioxide in the Presence of Chromium Salen Derivatives. In Situ FTIR Measurements of Copolymer vs Cyclic Carbonate Production

    Article • Journal of the American Chemical Society, June 2003, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  126. 2-Thia-1,3,5-triaza-7-phosphaadamantane 2,2-Dioxide (PASO 2 ). Comparative Structural and Reactivity Investigation with the Water-Soluble Phosphine Ligand 1,3,5-triaza-7-phosphaadamantane (PTA)

    Article • Organometallics, May 2003, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  127. Intermolecular hydrogen-bonding in the solid-state structure of CpFe(CN)2(PTAH)

    Article • Journal of Organometallic Chemistry, January 2003, Elsevier

    Professor Donald J Darensbourg

  128. Carbon Dioxide/Epoxide Coupling Reactions Utilizing Lewis Base Adducts of Zinc Halides as Catalysts. Cyclic Carbonate versus Polycarbonate Production

    Article • Inorganic Chemistry, January 2003, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  129. Mechanistic Aspects of the Copolymerization Reaction of Carbon Dioxide and Epoxides, Using a Chiral Salen Chromium Chloride Catalyst

    Article • Journal of the American Chemical Society, June 2002, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  130. Solution and Solid-State Structural Studies of Epoxide Adducts of Cadmium Phenoxides. Chemistry Relevant to Epoxide Activation for Ring-Opening Reactions

    Article • Journal of the American Chemical Society, June 2002, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  131. Solid-State Structures of Zinc(II) Benzoate Complexes. Catalyst Precursors for the Coupling of Carbon Dioxide and Epoxides

    Article • Inorganic Chemistry, February 2002, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  132. Synthesis, characterization and crystal structure of a zinc bis-dithiocarboxylate derivative

    Article • Inorganic Chemistry Communications, January 2002, Elsevier

    Professor Donald J Darensbourg

  133. Toward the Design of Double Metal Cyanides for the Copolymerization of CO 2 and Epoxides

    Article • Inorganic Chemistry, December 2001, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  134. Synthesis and Characterization of a Monocyanide-Bridged Bimetallic Iron(II) and Copper(I) Complex

    Article • Inorganic Chemistry, December 2001, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  135. Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups Containing Monodentate or Bidentate Phosphanes Bound to Copper(I), Including an Alternative Structure Based on the Nature of the Bidentate Phosphane Ligand

    Article • European Journal of Inorganic Chemistry, November 2001, Wiley

    Professor Donald J Darensbourg

  136. Synthesis and Structures of (Dialkylamino)ethylcyclopentadienyl Derivatives of Zinc

    Article • Organometallics, October 2001, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  137. Tricyclohexylphosphine Derivatives of Bis(2,6-difluorophenoxide)cadmium:  A Solution and Solid-State NMR Study

    Article • Inorganic Chemistry, July 2001, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  138. An Experimental and Theoretical Investigation of the Carbon Dioxide Insertion Process into the Tungsten−Nitrogen Bond of an Anionic W(0) Complex

    Article • Inorganic Chemistry, April 2001, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  139. Bis-Salicylaldiminato Complexes of Zinc. Examination of the Catalyzed Epoxide/CO 2 Copolymerization

    Article • Inorganic Chemistry, February 2001, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  140. Synthesis and crystal structure of [H2B(3-Phpz)2]2Zn

    Article • Journal of Organometallic Chemistry, December 2000, Elsevier

    Professor Donald J Darensbourg

  141. Organometallic Complexes of Uracil and Orotic Acid Derivatives: Coordination Mode, Structure, and Reactivity

    Article • European Journal of Inorganic Chemistry, December 2000, Wiley

    Professor Donald J Darensbourg

  142. Bis 2,6-difluorophenoxide Dimeric Complexes of Zinc and Cadmium and Their Phosphine Adducts:  Lessons Learned Relative to Carbon Dioxide/Cyclohexene Oxide Alternating Copolymerization Processes Catalyzed by Zinc Phenoxides

    Article • Journal of the American Chemical Society, December 2000, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  143. Water-Soluble Organometallic Compounds. 9. 1 Catalytic Hydrogenation and Selective Isomerization of Olefins by Water-Soluble Analogues of Vaska's Complex

    Article • Organometallics, September 2000, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  144. Solution and Solid-State Structures of Phosphine Adducts of Monomeric Zinc Bisphenoxide Complexes. Importance of These Derivatives in CO 2 /Epoxide Copolymerization Processes †

    Article • Inorganic Chemistry, April 2000, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  145. Solution 31 P and 113 Cd NMR Studies of Phosphine Adducts of Monomeric Cadmium (Bisphenoxide) Complexes and the Solid-State Structures of (2,6-Di- tert -butylphenoxide) 2 Cd(PCy 3 ) and (2,6-Di- tert -butylphenoxide) 2 Cd(PMe 3 ) 2 †

    Article • Inorganic Chemistry, February 2000, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  146. Coordination Chemistry, Structure, and Reactivity of Thiouracil Derivatives of Tungsten(0) Hexacarbonyl:  A Theoretical and Experimental Investigation into the Chelation/Dechelation of Thiouracil via CO Loss and Addition

    Article • Inorganic Chemistry, October 1999, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  147. Structural and Spectroscopic Studies of 16-Electron, Unsaturated Derivatives of Low-Valent, Group 6 Carbonyl Complexes Containing π-Donor Ligands

    Article • Inorganic Chemistry, October 1999, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  148. Water-Soluble Organometallic Compounds. 7. Further Studies of 1,3,5-Triaza-7-Phosphaadamantane Derivatives of Group 10 Metals, Including Metal Carbonyls and Hydrides

    Article • Inorganic Chemistry, August 1999, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  149. Water-Soluble Organometallic Compounds. 7. 1 Further Studies of 1,3,5-Triaza-7-Phosphaadamantane Derivatives of Group 10 Metals, Including Metal Carbonyls and Hydrides

    Article • Inorganic Chemistry, May 1999, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  150. Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups

    Article • Inorganic Chemistry, April 1999, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  151. Copolymerization and Terpolymerization of CO 2 and Epoxides Using a Soluble Zinc Crotonate Catalyst Precursor

    Article • Macromolecules, April 1999, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  152. Trigonal-Planar Zinc(II) and Cadmium(II) Tris(phenoxide) Complexes

    Article • Inorganic Chemistry, March 1999, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  153. Catalytic Activity of a Series of Zn(II) Phenoxides for the Copolymerization of Epoxides and Carbon Dioxide

    Article • Journal of the American Chemical Society, January 1999, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  154. Bis(triphenylphosphine)copper(I) Complexes of Orotate and l -Dihydroorotate

    Article • Inorganic Chemistry, November 1998, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  155. Responses of the Fe(CN) 2 (CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase

    Article • Journal of the American Chemical Society, October 1998, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  156. Binucleating Coordination of N , N ‘-Ethylenebis(salicylideneamine) (H 2 salen) to Low-Valent Group 6 Carbonyl Complexes

    Article • Inorganic Chemistry, October 1998, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  157. Crystal structures of aryloxide complexes of zinc embracing sodium aryl group interactions: Na[Zn(2,6-diphenylphenoxide)3(H2O)] and Na[Zn2(2,6-diisopropylphenoxide)4Cl]·3THF

    Article • Inorganica Chimica Acta, June 1998, Elsevier

    Professor Donald J Darensbourg

  158. Phosphine Adducts of Monomeric Zinc(bis-phenoxides):  Solution and Solid-State Structures of (2,6-Di- tert -butylphenoxide)ZnL Complexes (L = PMePh 2 and PCy 3 )

    Article • Inorganic Chemistry, June 1998, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  159. Organometallic Derivatives of Orotic Acid. CO−Labilizing Ability of the Amido Group in Chromium and Tungsten Carbonyl Complexes

    Article • Inorganic Chemistry, May 1998, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  160. The propensity of alkoxide and aryloxide derivatives of tungsten carbonyls to aggregate in solution. Synthesis and X-ray structures of dinuclear, trinuclear and tetranuclear complexes derived from the MeOW(CO)5− anion

    Article • Inorganica Chimica Acta, April 1998, Elsevier

    Professor Donald J Darensbourg

  161. Structural Diversity in Monomeric Cadmium Phenoxides

    Article • Inorganic Chemistry, December 1997, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  162. Water-Soluble Organometallic Compounds. 6. 1 Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals

    Article • Inorganic Chemistry, September 1997, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  163. Analysis of an Organometallic Iron Site Model for the Heterodimetallic Unit of [NiFe]Hydrogenase

    Article • Journal of the American Chemical Society, August 1997, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  164. Amino Acid Complexes of Metal Carbonyls:  Mechanistic Aspects of the CO-Labilizing Ability of Glycinate Ligands in Zero-Valent Chromium and Tungsten Derivatives †

    Article • Inorganic Chemistry, August 1997, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  165. Syntheses, Structures, and Binding Constants of Cyclic Ether and Thioether Adducts of Soluble Cadmium(II) Carboxylates. Intermediates in the Homopolymerization of Oxiranes and Thiiranes and in Carbon Dioxide Coupling Processes

    Article • Inorganic Chemistry, May 1997, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  166. Aryloxide and Alkoxide Derivatives of Metal Clusters. Syntheses, Structures, and Reactivities of the μ-Oxo-Bridged Triuthenium Clusters Ru 3 (CO) 8 (μ-η 2 -OC 6 H 4 Cl) 2 and Ru 3 (CO) 8 (μ-η 2 -OCH 2 C 6 H 4 N) 2

    Article • Inorganic Chemistry, January 1997, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  167. Structural characterizations of coordination complexes of bis-triphenylphosphine copper(I) dicarboxylates

    Article • Polyhedron, July 1996, Elsevier

    Professor Donald J Darensbourg

  168. Aqueous organometallic chemistry: the mechanism of catalytic hydrogenations with chlorotris(1,3,5-triaza-7-phosphaadamantane) rhodium(I)

    Article • Journal of Organometallic Chemistry, April 1996, Elsevier

    Professor Donald J Darensbourg

  169. Coordinatively and Electronically Unsaturated Tungsten(0) Carbonyl Complexes Stabilized by π-Donating Amido Ligands

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  170. The Reversible Insertion Reaction of Carbon Dioxide with the W(CO) 5 OH - Anion. Isolation and Characterization of the Resulting Bicarbonate Complex [PPN][W(CO) 5 O 2 COH]

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  171. Synthesis and X-ray Structure of the Novel Aluminum Complex [{η 3 -HB(3-Phpz) 2 (5-Phpz)} 2 Al][AlCl 4 ]. Catalysis of CO 2 /Propylene Oxide to Propylene Carbonate by the AlCl 4 - Anion

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  172. Cyanide-Bridged Heterobimetallic Complexes of the Group 6 Metal Carbonyls and Copper(I). X-ray Structures of (CO) 5 MCNCu(PPh 3 ) 3 (M = Cr, W) Derivatives

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  173. Supercritical carbon dioxide as solvent for the copolymerization of carbon dioxide and propylene oxide using a heterogeneous zinc carboxylate catalyst

    Article • Journal of Molecular Catalysis A Chemical, December 1995, Elsevier

    Professor Donald J Darensbourg

  174. 113Cd Shielding Tensors of Monomeric Cadmium Compounds Containing Nitrogen Donor Atoms. 3. Syntheses, Crystal Structure, and 113Cd NMR Spectroscopy of the Six-Coordinate Complexes [HB(pz)3]2Cd, [HB(3-Phpz)3]2Cd, and [B(pz)4]Cd[HB(3-Phpz)3] (pz = pyrazo...

    Article • Journal of the American Chemical Society, November 1995, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  175. Coordination Complexes of Bis(triphenylphosphine) Copper(I) Carbonate and Bicarbonate

    Article • Inorganic Chemistry, October 1995, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  176. Catalytic Activity of Zinc(II) Phenoxides Which Possess Readily Accessible Coordination Sites. Copolymerization and Terpolymerization of Epoxides and Carbon Dioxide

    Article • Macromolecules, October 1995, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  177. CO-Labilizing Ability of the Fluoride Ligand in Tungsten(0) Carbonyl Fluorides. X-ray Structure of [Et4N]3[W2(CO)6F3]

    Article • Inorganic Chemistry, September 1995, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  178. Chromium Tricarbonyl Catecholate Derivatives. Structural and Reactivity Studies of "16-Electron" Complexes

    Article • Inorganic Chemistry, August 1995, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  179. A More Intimate Examination of the Role of Copper(I) in the Decarboxylation of Derivatives of Malonic Acid. Comparisons with Zinc(II) Analogs

    Article • Inorganic Chemistry, April 1995, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  180. Water-soluble organometallic compounds. 5. The regio-selective catalytic hydrogenation of unsaturated aldehydes to saturated aldehydes in an aqueous two-phase solvent system using 1,3,5-triaza-7-phosphaadamantane complexes of rhodium

    Article • Journal of Organometallic Chemistry, February 1995, Elsevier

    Professor Donald J Darensbourg

  181. The Use of 1,3,5-Triaza-7-Phosphaadamantane (PTA), A Water-Soluble , Air Stable Ligand, in Organometallic Chemistry and Catalysis

    Article • January 1995, Springer Science + Business Media

    Professor Donald J Darensbourg

  182. Syntheses and Structures of Epoxide Adducts of Soluble Cadmium(II) Carboxylates. Models for the Initiation Process in Epoxide/CO2 Coupling Reactions

    Article • Journal of the American Chemical Society, January 1995, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  183. Role of the Metal Center in the Homogeneous Catalytic Decarboxylation of Select Carboxylic Acids. Copper(I) and Zinc(II) Derivatives of Cyanoacetate

    Article • Journal of the American Chemical Society, January 1995, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  184. Structural characterization of bidentate carboxylate derivatives of copper(I) bistriphenylphosphine

    Article • Inorganica Chimica Acta, December 1994, Elsevier

    Professor Donald J Darensbourg

  185. Amino Acid Derivatives of Tungsten Carbonyl. Structure and Reactivity Investigations of Zerovalent Tungsten Glycine Derivatives

    Article • Inorganic Chemistry, November 1994, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  186. Homogeneous catalytic synthesis of formaldehyde using the tungsten carbonyl complex [(CO)5WCl]− in the presence of sodium methoxide

    Article • Journal of Molecular Catalysis, October 1994, Elsevier

    Professor Donald J Darensbourg

  187. Aryloxide and Alkoxide Derivatives of Metal Clusters. Syntheses, Structures, and Reactivities of the .mu.-Oxo-Bridged Triruthenium Clusters Ru3(CO)8(.mu.-.eta.2-OC6H4Cl)2 and Ru3(CO)8(.mu.-.eta.2-OCH2C5H4N)2

    Article • Inorganic Chemistry, August 1994, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  188. SYNTHESIS AND STRUCTURE OF 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE COMPLEXES OF COPPER(I) ACETATE. CATALYSTS FOR THE DECARBOXYLATION OF CARBOXYLIC ACIDS

    Article • Journal of Coordination Chemistry, June 1994, Taylor & Francis

    Professor Donald J Darensbourg

  189. Rational Synthesis of Dinuclear Mixed-Valence Cu(I)/Cu(II)Carboxylate Derivatives. Steric Influence of Phosphine Ligands on the Structures of the Complexes

    Article • Inorganic Chemistry, April 1994, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  190. Intramolecular and intermolecular hydrogen bonding in triphenylphosphine derivatives of copper(I) carboxylates, (Ph3P)2CuO2C(CH2)nCOOH. Role of copper(I) in the decarboxylation of malonic acid and its derivatives

    Article • Inorganic Chemistry, February 1994, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  191. Water-soluble organometallic compounds. 4. Catalytic hydrogenation of aldehydes in an aqueous two-phase solvent system using a 1,3,5-triaza-7-phosphaadamantane complex of ruthenium

    Article • Inorganic Chemistry, January 1994, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  192. Nucleophilic addition of a water-soluble phosphine to aldehydes. Isolation of (1-hydroxyalkyl)phosphonium salts and the crystal structure of the (1-methoxy-1-benzyl)(m-sulfonatophenyl)diphenylphosphonium salt

    Article • Inorganic Chemistry, January 1994, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  193. Synthesis and reactivity of tungsten pentacarbonyl hydroxo and bicarbonato complexes. Molecular structure of [PPN][W(CO)5HCO3], an organometallic analog for carbonic anhydrase

    Article • Inorganic Chemistry, October 1993, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  194. Reversible decarboxylation of phosphine derivatives of Cu(I) cyanoacetate. Mechanistic aspects germane to catalytic decarboxylation of carboxylic acids

    Article • Journal of the American Chemical Society, September 1993, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  195. The catalytic decarboxylation of cyanoacetic acid: anionic tungsten carboxylates as homogeneous catalysts

    Article • Journal of the American Chemical Society, June 1993, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  196. The synthesis and X-ray structure of a phenoxide-bridged heterobimetallic anion, W(CO)5OPh(Cr(CO)3) −, and its reactivity with carbon dioxide and carbonyl sulfide

    Article • Journal of Organometallic Chemistry, June 1993, Elsevier

    Professor Donald J Darensbourg

  197. Water-soluble organometallic compounds. 3. Kinetic investigations of dissociative phosphine substitution processes involving water-soluble Group 6 metal derivatives in miscible aqueous/organic media

    Article • Inorganic Chemistry, January 1993, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  198. Cateholates asσ- andπ-Donationg Ligands: The Synthesis and Structure of(Et4N)2[W(CO)4(O2C6H4)] and the“Sixteen Electron” Analogue Resulting from CO Dissociation

    Article • Angewandte Chemie International Edition in English, November 1992, Wiley

    Professor Donald J Darensbourg

  199. Catecholate als σ- und π-Donor-Liganden: (Et4N)2[W(CO)4(O2C6H4)] und das durch CO-Abspaltung entstehende 16-Valenzelektronen-Analogon

    Article • Angewandte Chemie, November 1992, Wiley

    Professor Donald J Darensbourg

  200. Structural and reactivity studies of a cyanoacetic acid derivative of tungsten pentacarbonyl. X-ray structure of W(CO)5NCCH2COOH

    Article • Inorganic Chemistry, October 1992, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  201. A linear, monomeric copper(I) acetate derivative, bis[bis(phenanthroline)copper] bis(acetato)cuprate(1-) hydrogen bis(acetate). An effective catalyst for the decarboxylation of carboxylic acids

    Article • Inorganic Chemistry, September 1992, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  202. Anionic Group 6 metal carbonyl oxalate complexes. X-ray structures of [Et4N]2[W(CO)4C2O4] and [PPN]2[W2(CO)8C2O4].cntdot.1/2(CH3CH2)2O

    Article • Inorganic Chemistry, August 1992, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  203. Water-soluble organometallic compounds. 2. Catalytic hydrogenation of aldehydes and olefins by new water-soluble 1,3,5-triaza-7-phosphaadamantane complexes of ruthenium and rhodium

    Article • Organometallics, June 1992, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  204. Carbon dioxide insertion and deinsertion processes involving metal-carbon bonds: solid-state structure of [PPN][W(CO)5CH2CN]

    Article • Organometallics, September 1991, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  205. Investigations into the steric influences on the reaction mechanism of carbon dioxide insertion into metal-oxygen bonds. Carbonyl sulfide activation as a model for CO2

    Article • Inorganic Chemistry, May 1991, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  206. Water-soluble organometallic compounds. 1. The synthesis, characterization, and x-ray structure of (kryptofix-221)sodium pentacarbonyl[tris(m-sulfonatophenyl)phosphine]tungstate(3-)

    Article • Inorganic Chemistry, March 1991, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  207. Further studies on the role of neighboring group participation in carbonyl substitution reactions of group 6 metal carboxylates

    Article • Inorganic Chemistry, March 1991, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  208. Preparation and solid-state structure of a novel carboxylate derivative of copper(I), (Ph3P)2Cu(O2CCH2CN)2H

    Article • Inorganic Chemistry, February 1991, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  209. Photochemically enhanced carbon-carbon bond-forming reaction between carbon disulfide and methylpentacarbonyltungstate. X-ray structure of [PPN][W(CO)4(.eta.2-S2CCH3)]

    Article • Organometallics, January 1991, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  210. Mechanistic studies of carbon dioxide insertion into metal hydrides and extrusion from the corresponding metal formates utilizing Group 6 metal carbonyl derivatives as reaction probes

    Article • Journal of the American Chemical Society, December 1990, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  211. Solid-state and solution structure of (2,2'-bipyridine)(tetracarbonylcobalt)copper

    Article • Inorganic Chemistry, November 1990, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  212. Mechanistic aspects of decarboxylation reactions of Group 10 metal formato hydrido tricyclohexylphosphine [(PCy3)2M(H)O2CH] derivatives

    Article • Journal of the American Chemical Society, July 1990, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  213. Chemistry of zerovalent tungsten alkoxides. Synthesis, x-ray structure and reactivity toward carbon dioxide

    Article • Inorganic Chemistry, May 1990, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  214. Crystal structure and reactivity of bis[bis(1,2-dimethylphosphino)ethane]copper(2+) bis(tetracarbonylcobalt)curprate(2-): staggered and eclipsed conformations of [(CO)4CoCuCo(CO)4]- anions

    Article • Inorganic Chemistry, May 1990, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  215. Carbon monoxide ligand substitutional processes involving anionic Group 6 metal carboxylates and their relevance to decarboxylation mechanisms

    Article • Inorganic Chemistry, February 1990, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  216. The Organometallic Chemistry of Carbon Dioxide Pertinent to Catalysis

    Article • January 1990, Springer Science + Business Media

    Professor Donald J Darensbourg

  217. Uses of Metal Clusters in Homogeneous and Heterogeneous Catalysis

    Article • January 1990, Springer Science + Business Media

    Professor Donald J Darensbourg

  218. Multinuclear Metal Carbonyl Alkoxide and Aryloxide Derivatives as Models for Metal Carbonyls Adsorbed on Metal Oxide Supports

    Article • Israel Journal of Chemistry, January 1990, Wiley

    Professor Donald J Darensbourg

  219. Isolation of pentamethylcyclopentadienylchromium tricarbonyl dimer by two methods. X-Ray crystal structural study of two polymorphs

    Article • Journal of Organometallic Chemistry, January 1990, Elsevier

    Professor Donald J Darensbourg

  220. Synthesis, structure, and reactivity of zerovalent group 6 metal pentacarbonyl aryl oxide complexes. Reactions with carbon dioxide

    Article • Journal of the American Chemical Society, August 1989, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  221. Metal-Induced Transformations of Carbon Dioxide

    Article • December 1988, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  222. Comparative reactivities of anionic group 6 alkyl, silyl, and stannyl pentacarbonyl metalates toward carbon dioxide and sulfur dioxide. Crystal structure of bis(triphenylphosphine)nitrogen(1+) pentacarbonyl(trimethylsilyl)tungstate(1-)

    Article • Inorganic Chemistry, November 1988, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  223. Synthesis and characterization of carbonyl thiolato [Et4N][M(CO)5SR] and [Et4N]2[M2(CO)8(SR)2] complexes (M = chromium, molybdenum, tungsten). Ligand substitution reactions and x-ray crystal structure of [Et4N]2[W2(CO)8(SPh)2]

    Article • Inorganic Chemistry, October 1988, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  224. Synthesis and x-ray crystal structure of zerovalent tungsten aryloxide dimers

    Article • Inorganic Chemistry, September 1988, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  225. Cluster synthesis via aggregation: synthesis and solution and solid-state characterization of sulfur-capped group 6 metal carbonyl clusters

    Article • Inorganic Chemistry, March 1988, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  226. New Methods for Acquiring IR Spectral Data in Organometallic Chemistry and Catalysis

    Article • November 1987, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  227. Reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of an hydridonickel formate complex, HNi(O2CH)(Cy3P)2

    Article • Journal of the American Chemical Society, November 1987, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  228. Insertion reactions of carbon dioxide with square-planar rhodium alkyl and aryl complexes

    Article • Inorganic Chemistry, November 1987, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  229. Synthesis, reactivity, and x-ray structure of fac-(acetonitrile)tricarbonyl[bis(diphenylphosphino)methane]tungsten. Stereoselective preparation of fac-W(CO)3(13CO)(dppm) and subsequent intramolecular rearrangement processes

    Article • Inorganic Chemistry, November 1987, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  230. Selective homogeneous production of alkyl formate from CO and alcohol using metal carbonyl/alkoxide catalyst systems

    Article • Journal of Molecular Catalysis, August 1987, Elsevier

    Professor Donald J Darensbourg

  231. FT-IR, photoacoustic and micro-Raman spectra of the dodecacarbonyltriruthenium (O) complexes Ru3(13CO)12and Ru3(CO)12

    Article • Journal of Raman Spectroscopy, August 1987, Wiley

    Professor Donald J Darensbourg

  232. Homogeneous catalytic synthesis of alkyl formates from the reaction of alkyl halides, carbon dioxide, and hydrogen in the presence of anionic Group 6 carbonyl catalysts and sodium salts

    Article • Journal of the American Chemical Society, May 1987, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  233. Carbon dioxide insertion processes involving metal-carbon bonds: solid-state and solution structure of (18-crown-6) sodium pentacarbonylmethyltungstate(1-)

    Article • Inorganic Chemistry, April 1987, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  234. Anionic group 6 hydrides and carboxylates as homogeneous catalysts for reduction of aldehydes and ketones

    Article • Journal of the American Chemical Society, September 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  235. Chemical and structural characterization of W(CO)5OPPh2NPPh3. A novel tungsten carbonyl complex containing a phosphine oxide ligand derived from the bis(triphenylphosphine)nitrogen(1+) cation

    Article • Inorganic Chemistry, September 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  236. Ligand substitution processes in tetranuclear carbonyl clusters. 10. X-ray structural characterization of products resulting from reactions of nonacarbonyl[tris(diphenylphosphino)methane]tetracobalt with phosphine ligands

    Article • Inorganic Chemistry, August 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  237. Catalytic carbon dioxide methanation by alumina-supported mono- and polynuclear ruthenium carbonyls

    Article • Inorganic Chemistry, May 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  238. The Chemistry of the Metal-Carbon Bond. Volume 2. The Nature and Cleavage of Metal-Carbon Bonds.

    Article • Organometallics, April 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  239. Intramolecular ligand rearrangements in anionic group 6 metal pentacarbonyl hydride derivatives

    Article • Inorganic Chemistry, March 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  240. Preparation and structure of W(CO)5OPPh2NPPh3, a novel complex containing a ligand derived from the bis(triphenylphosphine)nitrogen(1+) cation

    Article • Inorganic Chemistry, January 1986, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  241. Stereochemical studies of the carbon dioxide insertion reactions into the tungsten-alkyl bond

    Article • Journal of the American Chemical Society, December 1985, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  242. A kinetic investigation of carbon dioxide insertion processes involving anionic tungsten-alkyl and -aryl derivatives: effects of carbon dioxide pressure, counterions, and ancillary ligands. Comparisons with migratory carbon monoxide insertion processes

    Article • Journal of the American Chemical Society, December 1985, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  243. MECHANISTIC ASPECTS OF CATALYTIC CARBON DIOXIDE METHANATION

    Article • Reviews in Inorganic Chemistry, October 1985, De Gruyter

    Professor Donald J Darensbourg

  244. Synthesis and characterization of polynuclear chromium carbonyl tetraanions

    Article • Inorganic Chemistry, October 1985, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  245. Cation-anion interaction in the [Na-kryptofix-221][W(CO)5O2CH] derivative and its relevance in carbon dioxide reduction processes

    Article • Journal of the American Chemical Society, October 1985, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  246. Aspects of homogeneous catalysis. Volume 5

    Article • Journal of Molecular Catalysis, August 1985, Elsevier

    Professor Donald J Darensbourg

  247. Synthesis and x-ray structure of anionic chelating phosphine-acyl derivative of tungsten, [cyclic] [PPh4][W(CO)4C(O)CH2CH2CH2PPh2], and the reactivity of its decarbonylated analog with carbon dioxide

    Article • Organometallics, June 1985, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  248. The X-ray structural characterization of a tetrameric binuclear bis(μ-oxo) molybdenum(V) compound bridged by methoxide ligands

    Article • Inorganica Chimica Acta, March 1985, Elsevier

    Professor Donald J Darensbourg

  249. Homogeneous catalysis of methyl formate production from carbon monoxide and methanol in the presence of metal carbonyl catalysts

    Article • Journal of Molecular Catalysis, March 1985, Elsevier

    Professor Donald J Darensbourg

  250. Ligand substitution processes in tetranuclear carbonyl clusters. 9. Reactions of Co4(CO)9(tripod), tripod = HC(PPh2)3, and its derivatives

    Article • Organometallics, January 1985, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  251. A convenient route to carbon-13-enriched triruthenium dodecacarbonyl. Chemistry relevant to methyl formate production from carbon monoxide and methanol

    Article • Organometallics, December 1984, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  252. Ligand additivity in the valence photoelectron spectroscopy of phosphine-substituted molybdenum carbonyls

    Article • Inorganic Chemistry, December 1984, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  253. Ligand substitution processes in tetranuclear carbonyl clusters. 8. Reactions of dodecacarbonyltetracobalt (Co4(12CO)12/Co4(13CO)12) with phosphorus donor ligands. Further evidence for cluster integrity during ligand substitution processes

    Article • Inorganic Chemistry, December 1984, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  254. Synthesis and characterization of sulfur-capped trinuclear group 6B metal clusters

    Article • Organometallics, October 1984, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  255. Stereochemical nonrigidity in six-coordinate Group VIB metal carbonyl derivatives via a nondissociative pathway

    Article • Inorganic Chemistry, September 1984, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  256. Ligand substitution processes in tetranuclear carbonyl clusters. 7. Molecular structure and carbon monoxide exchange processes of Co4(CO)9(tripod), tripod = 1,1,1-tris(diphenylphosphino)methane or HC(PPh2)3

    Article • Organometallics, August 1984, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  257. Anionic Group 6B metal carbonyls as homogeneous catalysts for carbon dioxide/hydrogen activation. The production of alkyl formates

    Article • Journal of the American Chemical Society, June 1984, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  258. Metal-induced transformations of carbon dioxide. Carbon-carbon bond-forming processes involving anionic Group VIB metal derivatives, and the x-ray structure of [PNP][cis-MeW(CO)4PMe3]

    Article • Journal of the American Chemical Society, June 1984, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  259. Potential intermediates in carbon dioxide reduction processes. Synthesis and structure of (.mu.-formato)decacarbonyltriruthenium and (.mu.-acetato)decacarbonyltriruthenium anions

    Article • Organometallics, October 1983, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  260. Homogeneous catalysts for carbon dioxide/hydrogen activation. Alkyl formate production using anionic ruthenium carbonyl clusters as catalysts

    Article • Journal of the American Chemical Society, September 1983, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  261. The Activation of Carbon Dioxide by Metai Complexes

    Article • January 1983, Elsevier

    Professor Donald J Darensbourg

  262. Anionic Group 6B metal carbonyl hydrides and formates. Chemistry relevant to catalysis of the water-gas shift reaction by Group 6B metal hexacarbonyls

    Article • Organometallics, December 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  263. Reactions of cryptand-solubilized sodium sulfide (NaSH) in aprotic solvents with the Group 6B metal hexacarbonyls. X-ray structural analysis and ligand lability studies of the isolated M(CO)5SH- anions

    Article • Organometallics, September 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  264. X-ray structural studies of cis-Mo(CO)4(PR3)2 (R = Me, Et, n-Bu) derivatives and their relationship to solution isomerization processes in these octahedral species

    Article • Inorganic Chemistry, July 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  265. Ligand substitution processes in tetranuclear carbonyl clusters. 6. Steric contribution to ligand dissociation in multisubstituted tetrairidium dodecacarbonyl derivatives

    Article • Journal of the American Chemical Society, July 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  266. Intermediates in the reaction of trans-Cr(CO)4(PPh3)2 with carbon-13 monoxide and fluxionality in octahedral Group VIB metal carbonyls via a nondissociative mechanism

    Article • Inorganic Chemistry, June 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  267. Solid-state and solution structures of [PNP][W(CO)5O2CCH3] and [PNP][W(CO)4(PEt3)O2CCH3] and the carbonyl-labilizing ability of the acetato ligand in these anionic derivatives

    Article • Inorganic Chemistry, April 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  268. Structural characterizations of cis-Mo(CO)4(PPhMe2)(NHC5H10) and cis-Mo(CO)4(PPhMe2)(PPh3) and their solution reactivities toward carbon monoxide

    Article • Inorganic Chemistry, April 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  269. Facile Reduction of Carbon Dioxide by Anionic Group 6B Metal Hydrides. Chemistry Relevant to Catalysis of the Water-Gas Shift Reaction - Correction

    Article • Journal of the American Chemical Society, February 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  270. Ligand-substitution processes in tetranuclear carbonyl clusters. 5. A kinetic and infrared investigation of carbon-13 monoxide incorporation into tri-.mu.-carbonyl-nonacarbonyltetracobalt and its monosubstituted derivatives

    Article • Organometallics, February 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  271. Mechanistic Pathways for Ligand Substitution Processes in Metal Carbonyls

    Article • January 1982, Elsevier

    Professor Donald J Darensbourg

  272. Reduction of carbon dioxide and carbonyl sulfide by anionic Group VIB metal hydrides and alkyls. Carbon-hydrogen and carbon-carbon bond formation processes and the structure of [PNP][Cr(CO)5SC(O)H]

    Article • Journal of the American Chemical Society, January 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  273. Steric contributions to the solid-state structures of bis(phosphine) derivatives of molybdenum carbonyl. X-ray structural studies of cis-Mo(CO)4[PPh3-nMen]2 (n = 0, 1, 2)

    Article • Inorganic Chemistry, January 1982, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  274. Chromium, molybdenum, and tungsten

    Article • Journal of Organometallic Chemistry, December 1981, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  275. Length of a tungsten-phosphine bond free of excessive steric interactions: crystal structure of pentacarbonyl(trimethylphosphine)tungsten

    Article • Inorganic Chemistry, December 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  276. Kinetic studies of ligand substitution reactions and general-base catalysis in amine-ligand exchange processes for Group 6B metal carbonyl amine derivatives. Kinetic and spectroscopic evidence for hydrogen-bonded intermediates

    Article • Inorganic Chemistry, December 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  277. Molecular and electronic structures of three pyridine- and piperidine-substituted chromium carbonyl compounds: Cr(CO)5(C5H5N), Cr(CO)5(C5H10NH) and cis-Cr(CO)4(C5H10NH)[P(OMe)3]

    Article • Inorganic Chemistry, December 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  278. Ligand substitution processes in tetranuclear carbonyl clusters. 4. Molecular structure and reactivity of octacarbonyltetrakis(trimethylphosphine)tetrairidium

    Article • Inorganic Chemistry, November 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  279. Crystal and molecular structure of dicarbonyl(.eta.5-cyclopentadienyl)(formato)iron(II)

    Article • Inorganic Chemistry, October 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  280. Reactions of M2Cl4(PR3)4 (M  Mo and W) with carbon monoxide

    Article • Journal of Organometallic Chemistry, September 1981, Elsevier

    Professor Donald J Darensbourg

  281. Studies using tributylphosphine oxide as a carbon monoxide labilizing ligand in the synthesis of metal carbonyl complexes highly enriched in carbon-13 monoxide

    Article • Inorganic Chemistry, June 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  282. Facile reduction of carbon dioxide by anionic Group 6b metal hydrides. Chemistry relevant to catalysis of the water-gas shift reaction

    Article • Journal of the American Chemical Society, June 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  283. Ligand substitution processes in tetranuclear carbonyl clusters. 3. Molecular structures of Co4(CO)8(.mu.-CO)3[P(C6H5)3] and Co4(CO)7(.mu.-CO)3[P(OCH3)3]2

    Article • Inorganic Chemistry, June 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  284. Further studies of the unusual nature of tris(.beta.-cyanoethyl)phosphine: structures of the phosphine and the phosphine oxide

    Article • Inorganic Chemistry, June 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  285. The Importance of Reactions of Oxygen Bases with Metal Carbonyl Derivatives in Catalysis

    Article • May 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  286. X-ray molecular structures of Mn(CO)5(O2CCF3) and Mn(CO)3(C5H5N)2(O2CCF3)

    Article • Inorganic Chemistry, April 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  287. On the use of 13C13C coupling in establishing intramolecular versus intermolecular CO ligand reaarangement processes in metal carbonyl derivatives

    Article • Journal of Organometallic Chemistry, April 1981, Elsevier

    Professor Donald J Darensbourg

  288. Formate ion as a monodentate ligand. Synthesis, structure, and decarboxylation of (.eta.5-cyclopentadienyl)dicarbonyl(formato)iron

    Article • Journal of the American Chemical Society, March 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  289. .pi. Acidity of tris(2-cyanoethyl)phosphine. X-ray structural studies of M(CO)5P(CH2CH2CN)3 (M = chromium, molybdenum) and Mo(CO)5P(C6H5)3

    Article • Inorganic Chemistry, February 1981, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  290. Photochemistry of piperidine pentacarbonyl complexes of the Group 6B metals isolated in an argon matrix at 10 K

    Article • Inorganic Chemistry, November 1980, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  291. Ligand substitution processes in tetranuclear metal carbonyl clusters. 2. Tris(.mu.-carbonyl)-nonacarbonyltetracobalt derivatives

    Article • Inorganic Chemistry, September 1980, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  292. Phase-transfer-catalyzed nucleophilic reactions of hydroxide ions at metal-bound carbon monoxide centers

    Article • Journal of the American Chemical Society, July 1980, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  293. Synthesis of metal carbonyl complexes highly enriched in carbon-13: utilization of the carbon monoxide-labilizing ability of (n-Bu)3P:O

    Article • Journal of the American Chemical Society, January 1980, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  294. Intramolecular hydrogen-bonding implications on the lability of the molybdenum-piperidine bond. Kinetic and mechanistic studies of the reaction of cis-Mo(CO)4[P(OCH3)3]NHC5H10 with carbon monoxide

    Article • Inorganic Chemistry, October 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  295. Intramolecular rearrangement of carbonyl ligands in the octahedral complex pentacarbonyl(trimethyl phosphite) tungsten by a nondissociative process: an example of the utility of the oxygen-18 isotope shift on the carbon-13 NMR of the carbonyl ligand

    Article • Journal of the American Chemical Society, October 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  296. Correction. Steric Contributions to the Solution Dynamics Involving Phosphorus Ligand Dissociation in Substituted Derivatives of Molybdenum Hexacarbonyl

    Article • Inorganic Chemistry, August 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  297. Oxygen-18 isotope shifts on the 13C nuclear magnetic resonance of metal carbonyl derivatives

    Article • Journal of Organometallic Chemistry, August 1979, Elsevier

    Professor Donald J Darensbourg

  298. Oxygen-Exchange and Ligand Substitution Reactions in Cr(CO) 6 and μ-H[Cr(CO) 5 ] 2 - , and the Water Gas Shift Reaction

    Article • May 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  299. Ligand substitution process in tetranuclear metal carbonyl clusters

    Article • Journal of Organometallic Chemistry, May 1979, Elsevier

    Professor Donald J Darensbourg

  300. Steric contributions to the solution dynamics involving phosphorus ligand dissociation in substituted derivatives of molybdenum hexacarbonyl

    Article • Inorganic Chemistry, May 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  301. Reaction of iron pentacarbonyl with oxygen-18-enriched hydroxide. Decarboxylation vs. oxygen exchange in the [Fe(COOH)] intermediate

    Article • Inorganic Chemistry, May 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  302. Concomitant bond formation and bond fission in the mass spectral fragmentation of an organometallic molecule

    Article • Journal of the Chemical Society Chemical Communications, January 1979, Royal Society of Chemistry

    Professor Donald J Darensbourg

  303. Intramolecular isomerization of an octahedral complex: bis(tri-n-butylphosphine)molybdenum tetracarbonyl

    Article • Inorganic Chemistry, January 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  304. Solution photochemistry of anionic metal carbonyl hydride derivatives. Substitution and dimer disruption processes in .mu.-H[M(CO)5]2- (M = chromium and tungsten)

    Article • Inorganic Chemistry, January 1979, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  305. A mass spectral study of intramolecular rearrangements in cis-M(CO)4(13CO)piperidine (M = Cr, W) derivatives

    Article • Journal of Organometallic Chemistry, November 1978, Elsevier

    Professor Donald J Darensbourg

  306. Preparation of oxygen-18-labeled derivatives of [Mn(CO)3(diphos)H] via reaction of [Mn(CO)4(diphos)][PF6] with water (oxygen-18) in the presence of triethylamine. Decarboxylation of a [Mn(COOH)] intermediate

    Article • Inorganic Chemistry, November 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  307. Preparation of a stereospecifically carbon-13 monoxide-labeled [(.mu.-H)[Mo(CO)5]2]- species and analysis of its carbonyl stretching vibrational modes

    Article • Inorganic Chemistry, September 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  308. A convenient synthesis of cis-Mo(CO)4L2 derivatives (L = Group 5a ligand) and a qualitative study of their thermal reactivity toward ligand dissociation

    Article • Inorganic Chemistry, September 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  309. The solution behavior of unsaturated molybdenum carbonyl species as evidenced via stereospecific carbon-13 monoxide labeling studies

    Article • Journal of the American Chemical Society, June 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  310. Solution photosubstitution chemistry of amine pentacarbonyl derivatives of the Group 6B metals in the presence of carbon-13 monoxide. An example of stereospecific incorporation of carbon-13 monoxide

    Article • Inorganic Chemistry, April 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  311. Solution structure and reactivity of hydridoiron tetracarbonyl anion, [HFe(CO)4]-

    Article • Inorganic Chemistry, February 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  312. Phase-transfer catalyzed oxygen-18 labeling studies of carbonyl ligands in neutral metal carbonyl derivatives

    Article • Journal of the American Chemical Society, January 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  313. The solution photosubstitution chemistry of triphenylphosphine derivatives of molybdenum hexacarbonyl

    Article • Journal of the American Chemical Society, January 1978, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  314. A thermal route to stereospecifically 13CO labelled group VIB metal pentacarbonyl amine derivatives

    Article • Journal of Organometallic Chemistry, November 1977, Elsevier

    Professor Donald J Darensbourg

  315. Chemical and infrared spectral details of reactions involving stereospecific incorporation of oxygen-18 into substituted manganese and rhenium carbonyl derivatives via exchange reactions with water (oxygen-18)

    Article • Journal of the American Chemical Society, August 1977, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  316. Oxygen exchange reactions of water (oxygen-18) with hexacarbonyl cations of manganese and rhenium

    Article • Journal of the American Chemical Society, June 1977, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  317. Photochemical substitution reactions of Group 6B metal tetracarbonyl norbornadiene complexes with carbon-13 monoxide, kinetics of subsequent thermal rearrangements in the stereospecifically labeled species, and relation of these results to the photoind...

    Article • Journal of the American Chemical Society, February 1977, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  318. Chromium, molybdenum and tungsten

    Article • Journal of Organometallic Chemistry, September 1976, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  319. Stereospecific incorporation of 13CO into olefinic substituted metal carbonyl compounds

    Article • Journal of Organometallic Chemistry, September 1976, Elsevier

    Professor Donald J Darensbourg

  320. Evidence for the fluxionality and structure in solution of intermediates of the type W(CO)4(L) (L = lewis base)

    Article • Journal of Organometallic Chemistry, August 1976, Elsevier

    Professor Donald J Darensbourg

  321. Infrared, conductance, and kinetic evidence for alkali metal ion interactions with derivatives of manganese carbonylates

    Article • Journal of the American Chemical Society, May 1976, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  322. Oxygen Exchange Reactions of Cationic Carbonyl Derivatives of Manganese and Rhenium with H218O and Related Processes

    Article • Israel Journal of Chemistry, January 1976, Wiley

    Professor Donald J Darensbourg

  323. Stereospecific incorporation of oxygen-18 into manganese and rhenium pentacarbonyl derivatives via exchange reactions with water (oxygen-18)

    Article • Journal of the American Chemical Society, January 1976, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  324. Metal Carbonyl Spectra

    Article • Journal of Organometallic Chemistry, October 1975, Elsevier

    Professor Donald J Darensbourg

  325. Synthesis, spectral properties, and reactions of manganese and rhenium pentacarbonyl phosphine and phosphite cation derivatives and related complexes

    Article • Inorganic Chemistry, July 1975, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  326. The stereochemical course of reactions leading to formation of mono-ligated (phenylacetyl)manganese tetracarbonyl compounds

    Article • Journal of Organometallic Chemistry, January 1975, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  327. Chromium, molybdenum and tungsten

    Article • Journal of Organometallic Chemistry, December 1974, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  328. Chromium, molybdenum and tungsten annual servey covering the year 1973

    Article • Journal of Organometallic Chemistry, December 1974, Elsevier

    Professor Donald J Darensbourg

  329. Infrared determination of stereochemistry in metal complexes. The determination of symmetry coordinates

    Article • Journal of Chemical Education, December 1974, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  330. The synthesis and spectral properties of manganese pentacarbonyl phosphine and phosphite cation derivatives and related complexes

    Article • Journal of Organometallic Chemistry, July 1974, Elsevier

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  331. Reactions of phenylacetymanganesepentacarbonyl with phosphine and phosphite ligands

    Article • Journal of Organometallic Chemistry, July 1974, Elsevier

    Professor Donald J Darensbourg

  332. Preparation of dinitrogen-rhenium complexes with tertiary arsines as coligands. Interaction of indium trichloride with rhenium(I)-dinitrogen species

    Article • Inorganic Chemistry, June 1974, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  333. Chromium, molybdenum and tungsten

    Article • Journal of Organometallic Chemistry, December 1973, Elsevier

    Professor Donald J Darensbourg

  334. Electronic and steric control of reactions of benzylmagnesium chloride with substituted metal carbonyls

    Article • Journal of the American Chemical Society, September 1973, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  335. Encounters in experimental chemistry (Jolly, William L.)

    Article • Journal of Chemical Education, July 1973, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  336. Kinetic studies of thermal decomposition and substitution reactions of cis-Mo(CO)4[P(C6H5)3](amine) compounds. Competitive study of Lewis bases for the intermediate [Mo(CO)4P(C6H5)3]

    Article • Inorganic Chemistry, June 1973, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  337. Infrared intensities and calculation of infrared band shapes of the carbon monoxide stretching vibrations in substituted tungsten carbonyl derivatives

    Article • Inorganic Chemistry, May 1973, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  338. Chromium, molybdenum and tungsten annual survey covering the year 1971

    Article • Journal of Organometallic Chemistry, November 1972, Elsevier

    Professor Donald J Darensbourg

  339. Photochemical substitution reactions of substituted Group VI metal carbonyls

    Article • Inorganic Chemistry, August 1972, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  340. Infrared intensities of the carbonyl stretching vibrations in cyclopentadienyliron dicarbonyl derivatives

    Article • Inorganic Chemistry, July 1972, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  341. Photochemical reactions of transition-metal dinitrogen compounds in the presence of carbon monoxide

    Article • Inorganic and Nuclear Chemistry Letters, June 1972, Elsevier

    Professor Donald J Darensbourg

  342. Correlation between the stretching frequency and the absolute infrared intensity of the dinitrogen ligand in isoelectronic transition metal compounds

    Article • Inorganic Chemistry, June 1972, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  343. The nature of binuclear dinitrogen complexes of rhenium(I) and rhenium(V) in solution

    Article • Inorganica Chimica Acta, January 1972, Elsevier

    Professor Donald J Darensbourg

  344. Infrared and kinetic studies of Group VI metal pentacarbonyl amine compounds

    Article • Inorganic Chemistry, January 1972, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  345. Relative importance of .sigma. and .pi. bonding of molecular nitrogen and carbonyl in osmium(II) complexes as determined by infrared intensities of the molecular nitrogen and carbonyl stretching vibrations

    Article • Inorganic Chemistry, November 1971, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  346. Nature of the intermediate procreated in substitution reactions of Group VI metal carbonyls

    Article • Journal of the American Chemical Society, June 1971, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  347. Reactions of transition metal carbonyls with nucleophilic reagents: reactivity and bonding

    Article • Inorganica Chimica Acta, March 1971, Elsevier

    Professor Donald J Darensbourg

  348. Infrared intensities of the molecular nitrogen and carbonyl stretching vibrations in iridium(I) complexes

    Article • Inorganic Chemistry, February 1971, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  349. Reactions of transition metal carbonyls with organolithium compounds. II. Prediction of nucleophilic attack at carbon and resultant stereochemistry

    Article • Inorganic Chemistry, July 1970, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  350. Infrared determination of stereochemistry in metal complexes: An application of group theory

    Article • Journal of Chemical Education, January 1970, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  351. Spectroscopic studies of some carbene pentacarbonyl complexes of chromium(0) and tungsten(0)

    Article • Inorganic Chemistry, January 1970, American Chemical Society (ACS)

    Professor Donald J Darensbourg, Professor Marcetta Y Darensbourg

  352. Infrared intesities of the carbonyl stretching modes in bipyramidal cobalt and iron tetracarbonyl compounds

    Article • Inorganica Chimica Acta, January 1970, Elsevier

    Professor Donald J Darensbourg

  353. Infrared intensities of the carbonyl stretching modes and electronic spectra of substituted molybdenum carbonyls

    Article • Inorganic Chemistry, May 1968, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  354. Intensities of CO stretching modes in the infrared spectra of adsorbed CO and metal carbonyls

    Article • Inorganic Chemistry, May 1967, American Chemical Society (ACS)

    Professor Donald J Darensbourg

  355. 1,3,5-Triaz-7-Phosphatricyclo[3.3.1.13,7]Decane and Derivatives

    Article • Wiley

    Professor Donald J Darensbourg

  356. Polymers from Carbon Dioxide: Polycarbonates, Polythiocarbonates, and Polyurethanes

    Article • Wiley

    Professor Donald J Darensbourg

  357. Greig, Professor Donald Westlake

    Article • Brill

    Professor Donald J Darensbourg