All Stories

  1. Phosphazenylphosphonium Frameworks: A Novel Main Group Mitochondrial Delivery Vector with Enhanced Properties
  2. Mechanosynthesis and Photophysics of Colour-tunable Photoluminescent Group 13 Metal Complexes with Sterically Demanding 3,5-di-tert-butyl Substituted Salen and Salophen Ligands
  3. Mechanochemistry
  4. Pre-arranged building block approach for the orthogonal synthesis of an unfolded tetrameric organic–inorganic phosphazane macrocycle
  5. Single- and double-bridged PNP ligands in chromium-catalysed ethylene oligomerisation
  6. Mechanochemical transformation of planar polyarenes to curved fused-ring systems
  7. Mechanochemical Rearrangements
  8. Mechanosynthesis of Higher‐Order Cocrystals: Tuning Order, Functionality and Size in Cocrystal Design**
  9. Upscaling Mechanochemistry: Challenges and Opportunities for Sustainable Industry
  10. Alkyl vs Aryl Modifications: A Comparative Study on Modular Modifications of Triphenylphosphonium Mitochondrial Vectors
  11. Alkyl vs Aryl Modifications: A Comparative Study on Modular Modifications of Triphenylphosphonium Mitochondrial Vectors
  12. Rhenium Carbonyl Complexes Conjugated with Methylated Triphenylphosphonium Cations as Sensitive Mitochondria Trackers for X-Ray Fluorescence Imaging
  13. Rhenium Carbonyl Complexes Conjugated with Methylated Triphenylphosphonium Cations as Sensitive Mitochondria Trackers for X-Ray Fluorescence Imaging
  14. Robust Cobalt Catalyst for Nitrile/Alkyne [2+2+2] Cycloaddition: Synthesis of Polyarylpyridines and Their Mechanochemical Cyclodehydrogenation to Nitrogen‐Containing Polyaromatics**
  15. Robust Cobalt Catalyst for Nitrile/Alkyne [2+2+2] Cycloaddition: Synthesis of Polyarylpyridines and Their Mechanochemical Cyclodehydrogenation to Nitrogen‐Containing Polyaromatics**
  16. Mechanochemical Synthesis of Tripodal Tris[4-(1,2,3-triazol-5-ylidene)methyl]amine Mesoionic Carbene Ligands and Their Complexation with Silver(I)
  17. Size-control in the synthesis of oxo-bridged phosphazane macrocycles via a modular addition approach
  18. Synergic Topological- and Size-Control on Phosphazane Chemistry: First Unfolded Hybrid Tetrameric Macrocycle
  19. Synergic Topological- and Size-Control on Phosphazane Chemistry: First Unfolded Hybrid Tetrameric Macrocycle
  20. Multigram Mechanochemical synthesis of a Salophen Complex: A Comparative Analysis
  21. Mechanochemical Transformation of Planar Polyarene to Curved Fused-Ring System: Solid-Phase Synthesis of Corannulene
  22. Mechanochemical Transformation of Planar Polyarene to Curved Fused-Ring System: Solid-Phase Synthesis of Corannulene
  23. Alkyl vs. aryl modifications: a comparative study on modular modifications of triphenylphosphonium mitochondrial vectors
  24. Rhenium carbonyl complexes bearing methylated triphenylphosphonium cations as antibody-free mitochondria trackers for X-ray fluorescence imaging
  25. Cobalt-Catalyzed Intermolecular [2+2+2] Cycloaddition of Nitriles and Alkynes: Facile Synthesis of Polyarylpyridines and Their Mechanochemical Cyclodehydrogenation to Nitrogen-Containing Polyaromatics
  26. Cobalt-Catalyzed Intermolecular [2+2+2] Cycloaddition of Nitriles and Alkynes: Facile Synthesis of Polyarylpyridines and Their Mechanochemical Cyclodehydrogenation to Nitrogen-Containing Polyaromatics
  27. A Facile Modular Addition Approach to Size Control in the Synthesis of Oxo Bridged Phosphazane Macrocycles
  28. Multi-gram Mechanosynthesis of Salophen-Complex: A Comparative Analysis
  29. N‐Bridged Acyclic Trimeric Poly‐Cyclodiphosphazanes: Highly Tuneable Cyclodiphosphazane Building Blocks
  30. Mechanochemical Synthesis of Corannulene‐Based Curved Nanographenes
  31. Mechanochemical Synthesis of Corannulene‐Based Curved Nanographenes
  32. Understanding the Solid-State Assembly of Pharmaceutically-Relevant N,N-Dimethyl-O-Thiocarbamates in the Absence of Labile Hydrogen Bonds
  33. Synthesis, properties, and catalysis of p-block complexes supported by bis(arylimino)acenaphthene ligands
  34. European Research in Focus: Mechanochemistry for Sustainable Industry (COST Action MechSustInd )
  35. Investigating the solid-state assembly of pharmaceutically-relevant N,N-dimethyl-O-thiocarbamates in the absence of labile hydrogen bonds
  36. Site-selective aromatic C–H λ3-iodanation with a cyclic iodine(iii) electrophile in solution and solid phases
  37. Enabling Mitochondrial Uptake of Lipophilic Dications Using Methylated Triphenylphosphonium Moieties
  38. Completely Solvent-free Protocols to Access Phase-Pure, Metastable Metal Halide Perovskites and Functional Photodetectors from the Precursor Salts
  39. Main group mechanochemistry: from curiosity to established protocols
  40. Synthesis of Unique Phosphazane Macrocycles via Steric Activation of C–N Bonds
  41. cis-Cyclodiphosph(v/v)azanes as highly stable and robust main group supramolecular building blocks
  42. Orthogonality in main group compounds: a direct one-step synthesis of air- and moisture-stable cyclophosphazanes by mechanochemistry
  43. Bay-Region Functionalisation of Ar-BIAN Ligands and Their Use Within Highly Absorptive Cationic Iridium(III) Dyes
  44. Main group mechanochemistry
  45. Inside Back Cover: Mechanochemical Synthesis of Phosphazane-Based Frameworks (Chem. Eur. J. 47/2017)
  46. Mechanochemical Synthesis of Phosphazane-Based Frameworks
  47. Synthesis and the Optical and Electrochemical Properties of Indium(III) Bis(arylimino)acenaphthene Complexes
  48. Unique Triphenylphosphonium Derivatives for Enhanced Mitochondrial Uptake and Photodynamic Therapy
  49. Aryl-NHC-group 13 trimethyl complexes: structural, stability and bonding insights
  50. The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P 4 (N t Bu) 6 : Enabled by Mechanochemi...
  51. The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P 4 (N t Bu) 6 : Enabled by Mechanochemi...
  52. A multi-step solvent-free mechanochemical route to indium(iii) complexes
  53. Synthesis and Hydrolytic Studies on the Air-Stable [(4-CN-PhO)(E)P(μ-NtBu)]2 (E = O, S, and Se) Cyclodiphosphazanes
  54. Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes
  55. Steric C–N bond activation on the dimeric macrocycle [{P(μ-NR)}2(μ-NR)]2
  56. Switching between halogen- and hydrogen-bonding in stoichiometric variations of a cocrystal of a phosphine oxide
  57. Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity
  58. Syntheses and structures of [Me2Si{As(PtBu)3}2] and [(CyP)3SiMe2] (Cy=cyclohexyl, C6H11)
  59. Mixed Alkylamido Aluminate as a Kinetically Controlled Base
  60. Suppressing the Anionic Fries Rearrangement of Aryl Dialkylcarbamates; the Isolation of a Crystallineortho-Deprotonated Carbamate
  61. Direct synthesis of the 1,2,3-[C6H4PPP]− anion, isoelectronic with the indenyl anion [C6H4CHCHCH]−
  62. π-Bonding versus oligomerisation in the aromatic anions [C6H4N2E]−: formation of the cyclic tetrameric tetraanion [C6H4N2Sb]44−
  63. Synthesis and structure of the Li13 cage [{[OP(μ-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(μ-NtBu)]22− dianion
  64. Effective Visible Light-Activated B-Doped and B,N-Codoped TiO2 Photocatalysts
  65. Formation and Structure of the [(1,2-C6H4P2Sb)2]4− Ion: Implications for an Extended Family of Isoelectronic Main-Group Radicals
  66. Trapping of Oligomeric Cyclopentadienyllithium Cationic and Anionic Fragments by a VV-Bonded Ligand
  67. An Unexpected Pathway in the Cage Opening and Aggregation of P4
  68. Syntheses and structures of the heterometallic complexes [{MeIn(μ-PCy)}2(μ-PCy)]2(Li·Et2O)4, [Me2In(PhMes)2]−[Li(TMEDA)2]+ and [Me2(PHMes)2In]−[K(PMDETA)2]+ [Cy=cyclohexyl, Mes=2,4,6-Me3C6H2, TMEDA=(Me2NCH2)2, PMDETA=(Me2NCH2CH2)2NMe]
  69. Group 2 (Be-Ba) and Group 12 (Zn-Hg)
  70. Reactions of Sn(NMe2)2 with MPHCy: The Effects of Alkali Metal Phosphide Coupling (Cy=Cyclohexyl; M=Li, Na, K, Rb)
  71. Structural, Solid-State NMR and Theoretical Studies of the Inverse-Coordination of Lithium Chloride Using Group 13 Phosphide Hosts
  72. Ansa-tris(allyl) complexes of alkali metals: tripodal analogues of cyclopentadienyl and ansa-metallocene ligands
  73. Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2and the unusual manganate cage [LiMn(hpp)3]2(hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2,a]pyrimidine)
  74. Pyridyl ‘ring-flipping’ in the dimers [Me2E(2-py)]2(E = B, Al, Ga; 2-py = 2-pyridyl)
  75. Efficient synthesis of brominated tetrathiafulvalene (TTF) derivatives: solid-state structure and electrochemical behaviour
  76. Reactions of Sn(NMe2)2 with Alkali-Metal tert-Butylphosphides tBuPHM (M = Li, Na, K):  Evidence for Metal-Induced Modification of the Tin(II) Phosphinidene Anions
  77. Syntheses and Structure of Heterometallic Complexes Containing Tripodal Group 13 Ligands [RE(2-py)3]- (E = Al, In)
  78. Adventures in Tin(II) phosphinidene chemistry; insights into the mechanism of P–P and Sn–Sn bond formation
  79. The cationic cluster Grignard [{MgCl(thf)2}3(μ3-C3H5)2]+
  80. Encapsulation of hydride by molecular main group metal clusters: manipulating the source and coordination sphere of the interstitial ion
  81. Efficient visible light-active N-doped TiO2photocatalysts by a reproducible and controllable synthetic route
  82. Targeting large phosp(iii)azane macrocyles [{P(μ-NR)}2(LL)]n(n ≥ 2)
  83. The first complex of the pentameric phosphazane macrocycle [{P(μ-NtBu)}2(μ-NH)]5 with a neutral molecular guest: Synthesis and structure of [{P(μ-NtBu)}2(μ-NH)]5(CH2Cl2)2
  84. Inverse Coordination of an Ionic Lattice by a Metal Host
  85. Quadruple Deprotonation of 2-Aminophenylphosphane with a p-Block-Metal/Alkali-Metal Base
  86. Reactions of Sn(NMe2)2 with Primary Aryl Phosphides, ArPH-:  Synthesis and Structures of the Heteroleptic Cages [{(PhP−PPh)Sn(μ-PPh)}2(Na·PMDETA)4 and [{Sn(μ3-Ppy)}3{Sn(μ...
  87. Synthesis and structure of the calixarene-like phosph(iii)azane macrocycle [{P(µ-NtBu)}2{1,5-(NH)2C10H6}]3
  88. Selection of the cis and trans phosph(iii)azane macrocycles [{P(µ-NtBu)}2(1-Y-2-NH-C6H4)]2(Y = O, S)
  89. Highly selective epoxidation of styrene using a transition metal–aluminium(iii) complex containing the [MeAl(2-py)3]−anion (2-py = 2-pyridyl)
  90. Triphosph(iii)azanes to diphosph(iii)azanes; a cracking transformation
  91. The folded, tetrameric phosph(iii)azane macrocycle [{P(µ-NtBu)}2{1,4-(NH)2C6H4}]4
  92. Selection of a Pentameric Host in the Host-Guest Complexes {[{[P(μ-NtBu)]2(μ-NH)}5]⋅I}−[Li(thf)4]+and [{[P(μ-NtBu)]2(μ-NH)}5]⋅HBr⋅THF
  93. Synthesis and Structure of [{Sn2(μ-PMes)3}K2·3THF]∞, Exhibiting Multifunctional Coordination of [Sn2(μ-PMes)3]2- Anions to K+
  94. Synthesis of the [MeAl(2-py)3]- Anion and Its Application as a Stable and Mild Pyridyl-Transfer Reagent (2-py = 2-Pyridyl)
  95. Thermodynamic/Kinetic Control in the Isomerization of the[{tBuNP(μ-NtBu)}2]2− Ion
  96. Steric control in the oligomerisation of phosphazane dimers; towards new phosphorus–nitrogen macrocycles
  97. The formation of dimeric phosph(iii)azane macrocycles [{P(µ-NtBu)}2·LL]2[LL = organic spacer]
  98. Selective formation of the [PhP(H)–PPh]−anion in the reaction of PhPHLi with MeAlCl2; synthesis and structure of the unusual tetramer [{PhP(H)–PPh}Li·thf]4
  99. A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42−
  100. The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX] (X = 0.2Br, 0.8Cl)
  101. Reductive-elimination of phosphide units; the basis of a general approach to a range of alloys and materials
  102. Primary amido and phosphido complexes of zinc: potential precursors to heterometallic arrangements
  103. Reactions of metallated cyclohexyl phosphine (CyPHM) with As(NMe2)3; synthesis of [(CyP)4As]– anions (M = Li or Na, Cy = cyclohexyl)
  104. Exo-metal coordination by a tricyclic [{P(µ-N-2-NC5H4)}2(µ-O)]2dimer in [{P(µ-N-2-NC5H4)}2(µ-O)]2{CuCl·(C5H5N)2}4{2-NC
  105. Synthesis and structure of [{MeAl(μ-PMes)(PMes)}2Li4]2·7thf, containing a [MeAl(μ-PMes)(PMes)]24−tetraanion (Mes = 2,4,6-Me3C6H2)
  106. Suggestion of a “Twist” Mechanism in the Oligomerisation of a Dimeric Phospha(III)zane: Insights into the Selection of Adamantoid and Macrocyclic Alternatives
  107. Formation and decomposition of the Sb(III)/Li cage [{Sb(P-t-Bu)3}2Li6·6THF]
  108. Templating and Selection in the Formation of Macrocycles Containing [{P(μ-NtBu)2}(μ-NH)]n Frameworks: Observation of Halide Ion Coordination
  109. Synthesis of a deca-lithium cage containing an [(RN)2As(µ-NR)As(NR)2]4– tetraanion; a homologue of group 15 trianions of the type [E(NR)3]3–Electronic supplementary information (ESI) available: synthesis and spectroscopic details for 1 and 2. See http:...
  110. Synthesis and structure of [{Sb(µ-NCy)}2(µ-N)]3(Li·THF)3(LiNNH), containing a macrocyclic [{Sb(µ-NCy)}2N]33– trianion
  111. Syntheses and structures of the cubanes [PhOSb(µ3-NCy)]4and [pyOBi(µ3-NCy)]4(Cy = cyclohexyl, py = 2-pyridyl)
  112. Group 2 (Be–Ba) and Group 12 (Zn–Hg)
  113. Group 2 (Be–Ba) and Group 12 (Zn–Hg)