All Stories

  1. Symmetry is the key to the design of reticular frameworks
  2. MOCOFs: Crystalline porous frameworks based on double extension of metal–organic and covalent organic linkages
  3. A redox active rod coordination polymer from tetrakis(4-carboxylic acid biphenyl)tetrathiafulvalene
  4. Three in one: engineering MOF channels via coordinated water arrays for regulated separation of alkanes and alkenes
  5. An Octacarboxylate-Linked Sodium Metal–Organic Framework with High Porosity
  6. Unlocking New Topologies in Zr-Based Metal–Organic Frameworks by Combining Linker Flexibility and Building Block Disorder
  7. Three-periodic nets, tilings and surfaces. A short review and new results
  8. Net-clipping as a top-down approach for the prediction of topologies of MOFs built from reduced-symmetry linkers
  9. Chiral Motifs in Highly Interpenetrated Metal–Organic Frameworks Formed from Achiral Tetrahedral Ligands**
  10. The Microscopic Diamond Anvil Cell: Stabilization of Superhard, Superconducting Carbon Allotropes at Ambient Pressure
  11. The Microscopic Diamond Anvil Cell: Stabilization of Superhard, Superconducting Carbon Allotropes at Ambient Pressure
  12. Customized Synthesis: Solvent- and Acid-Assisted Topology Evolution in Zirconium-Tetracarboxylate Frameworks
  13. Vibrational properties of graphdiynes as 2D carbon materials beyond graphene
  14. Visualization and Quantification of Geometric Diversity in Metal–Organic Frameworks
  15. Design of MOFs with Absolute Structures: A Case Study
  16. Designing All Graphdiyne Materials as Graphene Derivatives: Topologically Driven Modulation of Electronic Properties
  17. The Different Story of π Bonds
  18. High‐Throughput Electron Diffraction Reveals a Hidden Novel Metal–Organic Framework for Electrocatalysis
  19. High‐Throughput Electron Diffraction Reveals a Hidden Novel Metal–Organic Framework for Electrocatalysis
  20. CrystalGrower: a generic computer program for Monte Carlo modelling of crystal growth
  21. Size-Selective Urea-Containing Metal–Organic Frameworks as Receptors for Anions
  22. A New Group of Edge-transitive 3-Periodic Nets and Their Derived Nets for Reticular Chemistry
  23. Record Complexity in the Polycatenation of Three Porous Hydrogen-Bonded Organic Frameworks with Stepwise Adsorption Behaviors
  24. Isotopy classes for 3-periodic net embeddings
  25. New Quasicrystal Approximant in the Sc–Pd System: From Topological Data Mining to the Bench
  26. A Porous Covalent Organic Framework with Voided Square Grid Topology for Atmospheric Water Harvesting
  27. Combined DFT and geometrical–topological analysis of Li-ion conductivity in complex hydrides
  28. Breathing Metal–Organic Framework Based on Flexible Inorganic Building Units
  29. Diversifying molecular and topological space via a supramolecular solid-state synthesis: a purely organic mok net sustained by hydrogen bonds
  30. Predicting superhard materials via a machine learning informed evolutionary structure search
  31. Topochemical Synthesis of Single-Crystalline Hydrogen-Bonded Cross-Linked Organic Frameworks and Their Guest-Induced Elastic Expansion
  32. Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks
  33. Three Cationic, Nonporous CuI-Coordination Polymers: Structural Investigation and Vapor Iodine Capture
  34. Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF
  35. Toward Engineering Chiral Rodlike Metal–Organic Frameworks with Rare Topologies
  36. Generating carbon schwarzites via zeolite-templating
  37. Deconstruction of Crystalline Networks into Underlying Nets: Relevance for Terminology Guidelines and Crystallographic Databases
  38. Lu5Pd4Ge8 and Lu3Pd4Ge4: Two More Germanides among Polar Intermetallics
  39. Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
  40. Distinguishing Metal–Organic Frameworks
  41. Data-driven learning and prediction of inorganic crystal structures
  42. Water-stable fluorinated metal–organic frameworks (F-MOFs) with hydrophobic properties as efficient and highly active heterogeneous catalysts in aqueous solution
  43. Topology of Intermetallic Structures: From Statistics to Rational Design
  44. Packing topology in crystals of proteins and small molecules: a comparison
  45. Two Exceptional Patterns of Helical Secondary Building Units Found in Metal–Organic Framework Structures
  46. Self-Catenated Coordination Polymers Involving Bis-pyridyl-bis-amide
  47. Extracting Crystal Chemistry from Amorphous Carbon Structures
  48. Urea Metal–Organic Frameworks for Nitro-Substituted Compounds Sensing
  49. How 2-periodic coordination networks are interweaved: entanglement isomerism and polymorphism
  50. Capture of volatile iodine by newly prepared and characterized non-porous [CuI]n-based coordination polymers
  51. A new glance on R2MGe6(R = rare earth metal, M = another metal) compounds. An experimental and theoretical study of R2PdGe6germanides
  52. The R2Pd3Ge5 (R = La–Nd, Sm) germanides: synthesis, crystal structure and symmetry reduction
  53. Homo Citans and Carbon Allotropes: For an Ethics of Citation
  54. Homo Citansund Kohlenstoffallotrope: Für eine Ethik des Zitierens
  55. Searching New Crystalline Substrates for OMBE: Topological and Energetic Aspects of Cleavable Organic Crystals
  56. Crystal structures of the new ternary stannides La3Mg4−xSn2+x and LaMg3−xSn2
  57. Metal–organic frameworks assembled from flexible alicyclic carboxylate and bipyridyl ligands for sensing of nitroaromatic explosives
  58. Spinel type twins of the new cubic Er6Zn23Ge compound
  59. Li-Filled, B-Substituted Carbon Clathrates
  60. Diorganotin(IV) complexes with 2-furancarboxylic acid hydrazone derivative of benzoylacetone: Synthesis, X-ray structure, antibacterial activity, DNA cleavage and molecular docking
  61. A Collection of Topological Types of Nanoclusters and Its Application to Icosahedron-Based Intermetallics
  62. Vacancy Ordering as a Driving Factor for Structural Changes in Ternary Germanides: The New R2Zn1–xGe6Series of Polar Intermetallics (R = Rare-Earth Metal)
  63. From zeolite nets to sp3carbon allotropes: a topology-based multiscale theoretical study
  64. Structural directing roles of isomeric phenylenediacetate ligands in the formation of coordination networks based on flexible N,N′-di(3-pyridyl)suberoamide
  65. Interpenetration of three-periodic networks in crystal structures: Description and classification methods, geometrical-topological conditions of implementation
  66. Phase equilibria in the La–Mg–Ge system at 500°C and crystal structure of the new ternary compounds La11Mg2Ge7 and LaMg3−xGe2
  67. Entangled Two-Dimensional Coordination Networks: A General Survey
  68. Applied Topological Analysis of Crystal Structures with the Program Package ToposPro
  69. Influence of the counter anion and steric hindrance of pyrazolyl and imidazolyl flexible ligands on the structure of zinc-based coordination polymers
  70. Textural properties of a large collection of computationally constructed MOFs and zeolites
  71. Stepwise formation of heteronuclear coordination networks based on quadruple-bonded dimolybdenum units containing formamidinate ligands
  72. γ-Brass Polyhedral Core in Intermetallics: The Nanocluster Model
  73. Nets with collisions (unstable nets) and crystal chemistry
  74. Influence of the counter ion on the structure of two new copper(I) coordination polymers: Synthesis, structural characterization and thermal analysis
  75. The Zeolite Conundrum: Why Are There so Many Hypothetical Zeolites and so Few Observed? A Possible Answer from the Zeolite-Type Frameworks Perceived As Packings of Tiles
  76. The asc Trinodal Platform: Two‐Step Assembly of Triangular, Tetrahedral, and Trigonal‐Prismatic Molecular Building Blocks
  77. Construction of N,N′-di(3-pyridyl)adipoamide-based Zn(ii) and Cd(ii) coordination networks by tuning the isomeric effect of polycarboxylate ligands
  78. Two C28 Clathrates
  79. A Database of Topological Representations of Polynuclear Nickel Compounds
  80. A topological method for the classification of entanglements in crystal networksA preliminary account of this work was presented at the workshop `Topological dynamics in physics and biology' held in Pisa, 12–13 July 2011.
  81. High-nuclearity cobalt coordination clusters: Synthetic, topological and magnetic aspects
  82. Insight into the SBU Condensation in Mg Coordination and Supramolecular Frameworks: A Combined Experimental and Theoretical Study
  83. Totally unimodular nets
  84. A method for topological analysis of high nuclearity coordination clusters and its application to Mn coordination compounds
  85. Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands
  86. New Ternary Germanides La4Mg5Ge6 and La4Mg7Ge6: Crystal Structure and Chemical Bonding
  87. Synthesis and characterization of new oligomeric and polymeric complexes based on the [CuII(bpca)]+ unit [Hbpca=bis(2-pyridylcarbonyl)amine]
  88. Super Flexibility of a 2D Cu-Based Porous Coordination Framework on Gas Adsorption in Comparison with a 3D Framework of Identical Composition: Framework Dimensionality-Dependent Gas Adsorptivities
  89. New Types of Multishell Nanoclusters with a Frank–Kasper Polyhedral Core in Intermetallics
  90. Interpenetrated metal–organic frameworks of self-catenated four-connected mok nets
  91. Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database
  92. The novel metalloligand [Fe(bppd)3] (bppd = 1,3-bis(4-pyridyl)-1,3-propanedionate) for the crystal engineering of heterometallic coordination networks with different silver salts. Anionic control of the structures
  93. Periodic-Graph Approaches in Crystal Structure Prediction
  94. Halogen-bonded and interpenetrated networks through the self-assembly of diiodoperfluoroarene and tetrapyridyl tectons
  95. Heterometallic Modular Metal–Organic 3D Frameworks Assembled via New Tris‐β‐Diketonate Metalloligands: Nanoporous Materials for Anion Exchange and Scaffolding of Selected Anionic Guests
  96. Synthesis and characterization of new tetra-substituted porphyrins with exo-donor carboxylic groups as building blocks for supramolecular architectures: Catalytic and structural studies of their metalated derivatives
  97. Natural Tilings for Zeolite-Type Frameworks
  98. Polycatenation weaves a 3D web
  99. New Metal−Organic Framework with Uninodal 4-Connected Topology Displaying Interpenetration, Self-Catenation, and Second-Order Nonlinear Optical Response
  100. Nanocluster Model of Intermetallic Compounds with Giant Unit Cells: β, β′-Mg 2 Al 3 Polymorphs
  101. Vertex-, face-, point-, Schläfli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology
  102. Ligand dependent topology changes in six zinc coordination polymers
  103. Crystallization Behavior of Coordination Polymers. 1. Kinetic and Thermodynamic Features of 1,3-Bis(4-pyridyl)propane/MCl 2 Systems
  104. Three Lanthanum MOF Polymorphs: Insights into Kinetically and Thermodynamically Controlled Phases
  105. Topological relations between three-periodic nets. II. Binodal nets
  106. Controlling the Structure of Arenedisulfonates toward Catalytically Active Materials
  107. Ligand isomerism-controlled structural diversity of cadmium(II) perchlorate coordination polymers containing dipyridyladipoamide ligands
  108. A Short History of an Elusive Yet Ubiquitous Structure in Chemistry, Materials, and Mathematics
  109. Interpenetrated Three-Dimensional Networks of Hydrogen-Bonded Organic Species: A Systematic Analysis of the Cambridge Structural Database
  110. Dendrimeric Tectons in Halogen Bonding-Based Crystal Engineering
  111. A Rare-Earth MOF Series: Fascinating Structure, Efficient Light Emitters, and Promising Catalysts
  112. Generation of a 4-crossing [2]-catenane motif by the 2D→2D parallel interpenetration of pairs of (4,4) sheets
  113. Interpenetrated three-dimensional hydrogen-bonded networks from metal–organic molecular and one- or two-dimensional polymeric motifs
  114. Metal–organic coordination frameworks assembled with the long flexible ligand 4,4′-bis(imidazol-1-ylmethyl)biphenyl
  115. A New Polycatenated 3D Array of Interlaced 2D Brickwall Layers and 1D Molecular Ladders in [Mn 2 (bix) 3 (NO 3 ) 4 ]·2CHCl 3 [bix = 1,4-bis(imidazol-1-ylmethyl)benzene] That Undergoes Supramolecular Isomerization upon Guest Removal
  116. An Indium Layered MOF as Recyclable Lewis Acid Catalyst
  117. Double−Step Gas Sorption of a Two−Dimensional Metal−Organic Framework
  118. Three-periodic nets and tilings: natural tilings for nets
  119. Highly Interpenetrated Supramolecular Networks Supported by N⋅⋅⋅I Halogen Bonding
  120. Preparation and electrochemical behaviour of {[Ru(bipy)4Cl2Ag]NO3(CHCl3)·6H2O}n obtained from the self-assembly of trans-Ru(bipy)4Cl2 and AgNO3
  121. New metal–organic frameworks and supramolecular arrays assembled with the bent ditopic ligand 4,4-diaminodiphenylmethane
  122. What do we know about three-periodic nets?
  123. Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part II [1]. Analysis of the Inorganic Crystal Structure Database (ICSD)
  124. Four new 2D porous polymeric frames from the self-assembly of silver triflate and silver tosylate with free-base and Zn-metallated 5,10,15,20-tetra(4-pyridyl)porphyrin
  125. Parallel and Inclined (1D → 2D) Interlacing Modes in New Polyrotaxane Frameworks [M2(bix)3(SO4)2] [M = Zn(II), Cd(II); Bix = 1,4-Bis(imidazol-1-ylmethyl)benzene]
  126. The Cation as a Tool to Get Spin-Canted Three-Dimensional Iron(III) Networks
  127. Main Group Element Nets to a T
  128. Non‐Natural Eight‐Connected Solid‐State Materials: A New Coordination Chemistry
  129. A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4)·7H2O [bix = 1,4-bis(imidazol-1-yl...
  130. Interpenetrating metal–organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database
  131. Supramolecular isomers in the same crystal: a new case involving two different types of layers polycatenated in the 3D architecture of [Cu(bix)2(SO4)]·7.5H2O [bix = 1,4-bis(imidazol-1-ylmethyl)benzene]
  132. An Unusual Three-Dimensional Coordination Network Formed by Parallel Polycatenation of Two-Fold Interpenetrated (6,3) Layers Based on a Novel Three-Connecting Ligand
  133. Polycatenation, polythreading and polyknotting in coordination network chemistry
  134. Design, Synthesis, and Structural Characterization of Molecular and Supramolecular Heterobimetallic Metallamacrocycles Based on the 1,1‘-Bis(4-pyridyl)ferrocene (Fe(η 5 -C 5 H 4 -1-C 5 H 4 N) 2 ) Ligand
  135. Silver(i) polymeric coordination frameworks assembled with the new multimodal ligand 2,2′-azobispyrazine
  136. Open Network Architectures from the Self-Assembly of AgNO3 and 5,10,15,20-Tetra(4-pyridyl)porphyrin (H2tpyp) Building Blocks: The Exceptional Self-Penetrating Topology of the 3D Network of [Ag8(ZnIItpyp)7(H2O)2](NO3)8
  137. Borromean links and other non-conventional links in ‘polycatenated’ coordination polymers: re-examination of some puzzling networks
  138. New architectures from the self-assembly of MIISO4 salts with bis(4-pyridyl) ligands. The first case of polycatenation involving three distinct sets of 2D polymeric (4,4)-layers parallel to a common axis
  139. Crystal Engineering of Mixed-Metal Ru–Ag Coordination Networks by Using the trans-[RuCl2(pyz)4] (pyz=pyrazine) Building Block This work was supported by MURST within the project “Solid Supermolecules” 2000–2001 and by CSMTBO-CNR Center.
  140. Using long bis(4-pyridyl) ligands designed for the self-assembly of coordination frameworks and architectures
  141. A three-dimensional nanoporous flexible network of ‘square-planar’ copper(ii) centres with an unusual topologyElectronic supplementary information (ESI) available: XRPD spectra. See http://www.rsc.org/suppdata/cc/b2/b202588d/
  142. Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](Agi)22+/(Cuii)24+/(Znii)24+
  143. Three Novel Interpenetrating Diamondoid Networks from Self-Assembly of 1,12-Dodecanedinitrile with Silver(I) Salts
  144. Coordination networks from the self-assembly of silver salts and the linear chain dinitriles NC(CH2)nCN (n = 2 to 7): a systematic investigation of the role of counterions and of the increasing length of the spacers
  145. Monitoring the Crystal Growth and Interconversion of New Coordination Networks in the Self-assembly of MCl 2 Salts (M = Co, Ni, Cu, Cd) and 1,3-Bis(4-pyridyl)propane
  146. Synthesis, Structural Analysis, and Superconductivity of Ba x V 6 S 8
  147. Discrete molecular and extended polymeric copper(I) halide complexes of tetradentate thioether macrocycles
  148. Interlinked molecular squares with [Cu(2,2′-bipy)]2+ corners generating a three-dimensional network of unprecedented topological type
  149. Structural Properties and Topological Diversity of Polymeric Ag(I)-hexamethylenetetramine Complexes: Self-Assembly of Three Novel Two-Dimensional Coordination Networks and Their Supramolecular Interactions
  150. Polymeric Layers Catenated by Ribbons of Rings in a Three-Dimensional Self-Assembled Architecture: A Nanoporous Network with Spongelike Behavior
  151. Hydrothermal Synthesis and Structural Characterization of a Novel Hydroxo Stannate: Sr2Sn(OH)8
  152. New examples of self-catenation in two three-dimensional polymeric co-ordination networks †
  153. Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co5(bpe)9(H2O)8(SO4)4](SO4)·14H2O [bpe = 1,2-bis(4-pyridyl)ethane]
  154. Crystal engineering of coordination polymers and architectures using the [Cu(2,2′-bipy)]2+ molecular corner as building block (bipy = 2,2′-bipyridyl)
  155. 1,2- eq,eq -[Re 2 (CO) 8 (THF) 2 ]:  A Reactive Re 2 (CO) 8 Fragment That Easily Activates H−H and C−H Bonds
  156. Complex Interwoven Polymeric Frames from the Self-Assembly of Silver(I) Cations and Sebaconitrile
  157. A new type of supramolecular entanglement in the silver(I) coordination polymer [Ag2(bpethy)5](BF4)2 [bpethy = 1,2-bis(4-pyridyl)ethyne]
  158. Exploring Tellurides: Synthesis and Characterization of New Binary, Ternary, and Quaternary Compounds
  159. Stepwise electron-induced demolition of the Ni-I ?-bond in complexes with tetradentate tripodal ligands: A theoretical rationalization of structural and electrochemical results
  160. MO theory made visible
  161. Aromaticity and Agostic Interactions as Stabilizing Factors in Trinuclear Rhenium Clusters with Low Electron Count
  162. Stabilisation of trivalent nickel through 1 : 2 co-ordination by cyclic terdentate ligands CH2CH2NH(CH2)2NH(CH2)2X (X = NH, O, or S)
  163. Networks, Topologies, and Entanglements