Microwave Photochemistry and Photocatalysis. Part 1: Principles and Overview

What is it about?

The coupled activation of photochemical and photocatalytic reactions by using of two different types of radiation, microwave and UV/Vis, is covered by the new discipline called microwave photochemistry and photocatalysis. Such a connection might have a synergic effect on reaction efficiencies or, at least, enhance them by summing up the individual effects. The objective of this discipline is frequently, but not necessarily, connected to the electrodeless discharge lamp (EDL) as a novel light source which generates efficiently UV/Vis radiation when placed into a microwave field. This review article is focused on the general principles of microwave photochemistry and photocatalysis, i.e. generation of UV/Vis discharge in EDL (theory of the microwave discharges, construction of EDL, preparation of the thin titania films on EDL, spectral characteristics of EDL, and performance of EDL). Likewise, the various microwave photochemical and photocatalytic reactor types (batch with external or internal light source, flow-through with external light source, annular flow-through with internal EDL, and cylindrical flow-through surrounded with EDL) with different arrangement of the lamps are described. The concept of microwave photochemistry and photocatalysis as an important issue in synthetic chemistry and material science is presented in several tables.

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Why is it important?

The coupled activation of photochemical and photocatalytic reactions by using of two different types of radiation, microwave and UV/Vis, is covered by the new discipline called microwave photochemistry and photocatalysis. Such a connection might have a synergic effect on reaction efficiencies or, at least, enhance them by summing up the individual effects. The objective of this discipline is frequently, but not necessarily, connected to the electrodeless discharge lamp (EDL) as a novel light source which generates efficiently UV/Vis radiation when placed into a microwave field. This review article is focused on the general principles of microwave photochemistry and photocatalysis, i.e. generation of UV/Vis discharge in EDL (theory of the microwave discharges, construction of EDL, preparation of the thin titania films on EDL, spectral characteristics of EDL, and performance of EDL). Likewise, the various microwave photochemical and photocatalytic reactor types (batch with external or internal light source, flow-through with external light source, annular flow-through with internal EDL, and cylindrical flow-through surrounded with EDL) with different arrangement of the lamps are described. The concept of microwave photochemistry and photocatalysis as an important issue in synthetic chemistry and material science is presented in several tables.

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