What is it about?
We find that in the IC phase, because static displacements of chemically unlike atoms n a modulated state differ in amplitude while having the same wavelength. As a result, the bond tilts in the direction perpedicular to the polarization plane increase. From this standpoint, it appears natural to expect observation of the invar properties in the direction perpendicular to the polarization plane, as this indeed occurs in the many cases.
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Why is it important?
It would apparently be useful to proceed the TEC measurements to find exact modulation region.
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This page is a summary of: The invar effect and phase transitions in Cs2ZnI4 crystals, Physics of the Solid State, January 1999, Pleiades Publishing Ltd,
DOI: 10.1134/1.1130742.
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