What is it about?
The use of a non-equilibrium continuous flow reactor system enabled us to unravel the self-assembly formation mechanism of a metal-oxide based nanowheel containing 150 metal centres, by trapping the transient template, and this knowledge allows its accelerated synthesis with increased yield.
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Why is it important?
The crystallization of an intermediate structure showed a central {Mo36} cluster to template the assembly of the {Mo150} nano-wheel. The transient nature of the template is demonstrated by its ejection after the wheel is formed.
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This page is a summary of: Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel, Science, December 2009, American Association for the Advancement of Science,
DOI: 10.1126/science.1181735.
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