What is it about?
Intramolecular folding indicated by C-H-pi interaction in solution by NMR further confirmed in solid by X-ray crystallography due to intramolecular pi-pi interaction.
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Why is it important?
To the best of our knowledge, this is the first example of a folded compound due to intramolecular arene interaction in the solid state.
Perspectives
Further studies will confirm the utility of intramolecular pi-pi interaction for control in conformation.
kamlakar avasthi
Central Drug Research Institute
Read the Original
This page is a summary of: 1,3-Bis[4,6-bis(methylthio)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]propane, Acta Crystallographica Section C Crystal Structure Communications, November 1995, International Union of Crystallography,
DOI: 10.1107/s0108270195006524.
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