What is it about?
Dehydrative condensation between aromatic carboxylic acids and amines gave amide bonds in good to excellent yields. The admiration was promoted by catalytic tris(o-phenylenedioxy)cyclotriphosphazene.
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Why is it important?
Catalytic amidation of aromatic carboxylic acids is not trivial but using catalytic P(V) species, the reaction proceeded. To the best of our knowledge, this would be the first example of catalytic P(V)-promoted dehydrate amidation between carboxylic acids and amines.
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This page is a summary of: Tris(o-phenylenedioxy)cyclotriphosphazene as a Promoter for the Formation of Amide Bonds Between Aromatic Acids and Amines, Synthesis, July 2020, Thieme Publishing Group,
DOI: 10.1055/s-0040-1707174.
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