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CO2 is an attractive solvent as it is safe and an ideal substitute for many hazardous and toxic solvents. We report on the use of SHB (supported by Hydrogen Bond) copper(I) catalysts in asymmetric cyclopropanations under flow condition by using CO2 as carrier. The catalytic system showed high stability and good recyclability without loss of activity for at least 24 h in CO2.
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This page is a summary of: Continuous flow asymmetric cyclopropanation reactions using Cu(i) complexes of Pc-L* ligands supported on silica as catalysts with carbon dioxide as a carrier, Green Chemistry, January 2014, Royal Society of Chemistry,
DOI: 10.1039/c4gc00119b.
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