What is it about?
Two molybdenum(VI) tris(dithiolene) complexes with a three dimensional structure substituents synthesized and their two-photon absorption properties were determined. Both of these complexes exhibited significant two-photon cross sections around the wavelength of 1300 nm, with the naphthyl substituted complex showing a two-photon cross section of 660 10^-50 cm4 s^-1 photon^-1, suggesting a new class of three-dimensional
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Why is it important?
These molecules show sizable two-photon absorption at 1300 nm and may be useful for two-photon based optical switching for telecommunications.
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This page is a summary of: Molybdenum(vi) tris(dithiolene) complexes as a new class of three-dimensional two-photon absorption chromophores at telecommunications wavelengths, Journal of Materials Chemistry C, January 2014, Royal Society of Chemistry,
DOI: 10.1039/c3tc31058b.
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