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How does the MnIII=O and MnIV=O activates C-H bond and how are there oxidation potential varies is been answered in this paper.

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This page is a summary of: Theoretical studies on concerted versus two steps hydrogen atom transfer reaction by non-heme MnIV/IIIO complexes: how important is the oxo ligand basicity in the C–H activation step?, Dalton Transactions, January 2013, Royal Society of Chemistry,
DOI: 10.1039/c3dt52290c.
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