What is it about?
We synthesized, characterized, and tested a novel precursor for the fabrication of copper and copper oxide materials via Chemical Vapor Deposition. Our joint experimental and theoretical analyses predicted and explained the first fragmentation steps of the precursor in terms of the effects of temperature on the Cu(II)-ligands bonds.
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Why is it important?
The main novelty of this work is that we highlighted for the first time how temperature affects the molecular structure of a precursor for CVD experiments. We showed that temperature greatly enhances the oscillations of the metal-ligand bonds in the complex, and that this effect is greater for the weakest metal-ligand bond. This behaviour preludes to bond breaking and plays a key role in the decomposition of the precursor.
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This page is a summary of: An integrated experimental and theoretical investigation on Cu(hfa)2·TMEDA: structure, bonding and reactivity, Physical Chemistry Chemical Physics, January 2009, Royal Society of Chemistry,
DOI: 10.1039/b904145a.
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