What is it about?
This work explores how rechargeable battery materials change during operation by using laboratory-based X-ray absorption measurements, a technique also known as X-ray absorption fine structure (XAFS). Typically, such studies require large synchrotron facilities, but we show that it is possible to track chemical changes in battery materials in real time in a regular lab. Using a specially designed battery cell and two advanced X-ray spectrometers, we followed how iron atoms in lithium-ion and sodium-ion electrodes change during charging and discharging. This approach provides a flexible and faster way to study battery chemistry, helping researchers improve battery performance and develop new, more sustainable materials.
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Why is it important?
Monitoring battery materials during operation is crucial for designing better, longer-lasting, and more sustainable batteries. This study demonstrates that laboratory-based X-ray absorption measurements (XAFS) can complement large-scale synchrotron experiments, offering rapid, accessible insights into the electronic structure and chemistry of battery electrodes. By enabling operando studies in the lab, researchers can optimize new materials more efficiently, reduce costs, and accelerate the development of advanced battery technologies.
Perspectives
For me, the most exciting aspect of this work is showing that high-quality operando X-ray absorption measurements can be done outside of synchrotrons. Being able to track chemical changes in real time in the lab opens new possibilities for faster material testing and optimization. I hope this approach encourages others to explore lab-based XAFS for sustainable battery research and helps accelerate innovation in energy storage technologies.
Sebastian Praetz
Technische Universitat Berlin
Read the Original
This page is a summary of: Operando laboratory XAS on battery materials using the DANOISE cell in a von Hámos spectrometer, Journal of Analytical Atomic Spectrometry, January 2025, Royal Society of Chemistry,
DOI: 10.1039/d5ja00155b.
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