What is it about?
In this work, we carride out a kinetic study of the aryl azide formation usimg functionalised imidazoilium ILs with azide anion as a nucleophile, under mild reaction conditions.
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Why is it important?
This is one of the few works analysing from a kinetic perspective, which structural parameters of the substrates favor the reactions and which, on the ohter hand disfavor it. Importantly this works offers also a mechanistic view of the azidation of aromatic compounds with functionalised ionic liquids.
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This page is a summary of: Aryl Azides Formation Under Mild Conditions: A Kinetic Study in Some Ionic Liquid Solutions, The Journal of Organic Chemistry, December 2009, American Chemical Society (ACS),
DOI: 10.1021/jo9022952.
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