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New Porous Coordination Polymers (PCPs) were achieved based on the coordination capabilities of first-row transition metal ions such as Co2+, Ni2+, and Zn2+. The obtained composite PCPs containing a [Zn2M2O]6+ (M = Co or Ni) bimetallic cluster core with open metal sites (OMSs) exhibited distinct isosteric heats of adsorption and surface areas due to the difference in their open metal Lewis acidic sites of solvent-free state. Additionally, these composite PCPs exhibit remarkable superhydrophobic properties with contact angles of 159.3° and 160.8° respectively for Zn–Co and Zn–Ni analogs. This superhydrophobic surface survives even at a high temperature for longer time periods.

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To create artificial lotus leaves

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This is a very hard working the problem from groups

Prabhakara Rao Koya
Vignan Educational Foundation

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This page is a summary of: Temperature-Stable Compelled Composite Superhydrophobic Porous Coordination Polymers Achieved via an Unattainable de Novo Synthetic Method, Journal of the American Chemical Society, September 2018, American Chemical Society (ACS),
DOI: 10.1021/jacs.8b07577.
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