Linear and nonlinear optical properties of gold nanoparticles doped borate glasses

What is it about?

Gold nanoparticles (NPs) embedded in sodium antimony borate glass system were fabricated and their optical, physical, structural, ultrafast nonlinear optical properties were studied and analyzed. Metallic gold NPs were synthesized using thermal reducing agent Sb2O3 and demonstrated the reduction mechanism of Au3+/ Au+→Au0 by using reduction potentials of corresponding redox system. UV–Visible spectroscopy measurements have revealed the characteristic surface plasmon resonance (SPR) of Au NPs at ~565 nm, attributed due to interband transition. The micrographs of High-Resolution Transmission Electron Microscopy (HR-TEM) confirmed the existence of uniformly distributed spherical shaped Au NPs with particle sizes in the 8–45 nm range with an average particle size of 25 nm. The ultrafast nonlinear optical properties of gold doped glasses were investigated using the Z-scan technique at a non-resonant wavelength (λ =800 nm, 80 MHz repetition rate) with femtosecond (fs) Ti:sapphire laser pulses. Z-scan measurements of undoped glass depicted a reverse saturable absorption (RSA) type of nonlinearity whereas the gold-doped glass demonstrated saturable absorption (SA) kind of nonlinearity due to intraband (sp→sp) transitions. The Z-scan data demonstrated that the investigated glasses are potential materials for the applications in nonlinear optics devices, particularly in optical switching devices.

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Why is it important?

Novel functional glasses are required for photonic applications.