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The physical processes governing the transition from purely mechanical ejection to electromechanical ejection to electrospraying are investigated through complementary scaling analysis and optical visualization. A new dimensionless parameter, the Fenn number, is introduced to define a transition between the spray regimes, in terms of its dependence on the characteristic Strouhal number for the ejection process.

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This page is a summary of: Regime transition in electromechanical fluid atomization and implications to analyte ionization for mass spectrometric analysis, Journal of the American Society for Mass Spectrometry, July 2010, American Chemical Society (ACS),
DOI: 10.1016/j.jasms.2010.07.007.
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