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The role of the localization of acid sites in macroporous sulfonic resin Amberlyst 15 in the synthesis of ethyl tert-butyl ether was investigated. By partial blockage of the acid sites by Na+ cations it was established that internal acid sites are primarily active in the reaction while a side reaction with the formation of tert-butanol takes place at the external acid sites.
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This page is a summary of: Effect of Acid Site Localization in Sulfonic Resin Amberlyst 15 on its Catalytic Properties in Ethyl tert-butyl Ether Synthesis, Theoretical and Experimental Chemistry, May 2017, Springer Science + Business Media,
DOI: 10.1007/s11237-017-9510-1.
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