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The catalytic activity of ZrO2-SiO2 systems in the gas-phase carboxylation of methanol was studied. The formation of dimethyl carbonate proceeds on the catalysts with predominantly strong base sites. The concentration and strength of these sites is a function of the phase composition of the catalysts.
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This page is a summary of: Effect of the Component Ratio in ZrO2-SiO2 Catalysts on the Selectivity of Dimethyl Carbonate Formation from Methanol and Carbon Dioxide, Theoretical and Experimental Chemistry, November 2014, Springer Science + Business Media,
DOI: 10.1007/s11237-014-9382-6.
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