What is it about?
In this work we discuss the influence of solvents on the stability of Cr and W complexes. It is observed that this stability depends on the metal as well as the path followed by the reaction so that the organic ligand is replaced by one or more solvent molecules.
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Why is it important?
The knowledge of these reaction trucks help to understand the behavior of for example organometallic catalysts that are very important to carry out a cleaner and friendly chemical with the environment, it is called green chemistry.
Perspectives
In-depth knowledge of elementary processes such as a ligand exchange can allow for better management of the catalysts and the design of more sustainable processes over time without endangering the environment.
Professor Alejandro M. Granados
INFIQC-UNC
Read the Original
This page is a summary of: Disconnection of the organic moiety in chromium and tungsten complexes [(dithiin)M(CO)5], Journal of Physical Organic Chemistry, December 2006, Wiley,
DOI: 10.1002/poc.1044.
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