What is it about?
Fluoroalkylation of aliphatic diols, tetrahydrofuran and 1,3-dioxolanes with perfluoroolefins under photochemical initiation was studied. The aim of the study was the preparation of fluoroalkylated diols as intermediates for special fluorinated monomers. Fluoroalkylation was only partly successful in the case of 1,4-butanediol and quite successful with tetrahydrofuran and 2,2-dimethyl-1,3-dioxolane. The fluoroalkyl diols obtained were converted to monomethacrylates that are amphiphilic monomers.
Featured Image
Why is it important?
Fluoroalkylation of aliphatic diols, tetrahydrofuran and 1,3-dioxolanes with perfluoroolefins under photochemical initiation was studied. The aim of the study was the preparation of fluoroalkylated diols as intermediates for special fluorinated monomers. Fluoroalkylation was only partly successful in the case of 1,4-butanediol and quite successful with tetrahydrofuran and 2,2-dimethyl-1,3-dioxolane. The fluoroalkyl diols obtained were converted to monomethacrylates that are amphiphilic monomers.
Perspectives
Read the Original
This page is a summary of: Photoaddition reactions of fluoroolefins with diols and cyclic ethers, Macromolecular Symposia, May 1994, Wiley,
DOI: 10.1002/masy.19940820113.
You can read the full text:
Contributors
The following have contributed to this page