What is it about?
The ligand properties of a series of aryl oligogermanes for the synthesis of transition metal carbonyl complexes such as R3Ge‐GeAr2(R′C6H4‐η6)M(CO)3 (M = Cr, Mo, W) were investigated. A comparative analysis of donor and acceptor properties of aryl oligogermanes as ligands for transition metal carbonyl complexes is reported.
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Why is it important?
New class of organogermanium compounds is obtained. The most effective way of their synthesis is found. It was established that oligogermyl group is a donor for arene metal carbonyl complexes.
Perspectives
Results obtained are important for targeted synthesis of useful compounds with determined properties (chemistry of materials, catalysis).
Kirill Zaitsev
Moscow State University
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This page is a summary of: Aryl Oligogermanes as Ligands for Transition Metal Complexes, European Journal of Inorganic Chemistry, November 2018, Wiley,
DOI: 10.1002/ejic.201801095.
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