What is it about?
Regioselective additions of nucleophilic radicals to perfluoroalkylethylenes (I) are achieved as described. Correlation of experimental with theoretical data, obtained by two quantum chemical methods, i.e. PM3 methods and ab initio calculations, shows that the more accurate level of ab initio calculations substantiate a greater reliability for predictions based on this method.
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Why is it important?
Regioselective additions of nucleophilic radicals to perfluoroalkylethylenes (I) are achieved as described. Correlation of experimental with theoretical data, obtained by two quantum chemical methods, i.e. PM3 methods and ab initio calculations, shows that the more accurate level of ab initio calculations substantiate a greater reliability for predictions based on this method.
Perspectives
Regioselective additions of nucleophilic radicals to perfluoroalkylethylenes (I) are achieved as described. Correlation of experimental with theoretical data, obtained by two quantum chemical methods, i.e. PM3 methods and ab initio calculations, shows that the more accurate level of ab initio calculations substantiate a greater reliability for predictions based on this method.
Dr Vladimír Církva
Institute of Chemical Process Fundamentals
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This page is a summary of: ChemInform Abstract: Radical Addition Reactions of Fluorinated Species. Part 8. Regioselectivity of Radical Additions to Perfluoroalkylethylenes and Quantum Chemical Calculations. Highly Selective Two‐Step Synthesis of 4‐(Perfluoroalkyl)butane‐1,2‐diols., ChemInform, July 2000, Wiley,
DOI: 10.1002/chin.200029041.
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