What is it about?
The two-step synthesis of title compounds (IV) is based on the radical addition of dioxolane (II) to perfluoroalk-1-enes (I) with high yields for each step. The additions are completely chemoselective and almost completely regioselective. The factors influencing fluoroolefin and dioxolane regioselectivity are discussed.
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Why is it important?
The two-step synthesis of title compounds (IV) is based on the radical addition of dioxolane (II) to perfluoroalk-1-enes (I) with high yields for each step. The additions are completely chemoselective and almost completely regioselective. The factors influencing fluoroolefin and dioxolane regioselectivity are discussed.
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This page is a summary of: ChemInform Abstract: Radical Addition Reactions of Fluorinated Species. Part 7. Highly Selective Two‐Step Synthesis of 1‐(Polyfluoroalkyl)ethane‐1,2‐diols; Regioselectivity of the Additions of Methylated 1,3‐Dioxolanes to Perfluoroolefins., ChemInform, August 1999, Wiley,
DOI: 10.1002/chin.199935137.
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