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The presence or absence of internal folding in molecules can be used to tailor intramolecular electron transfer. Upon excitation to triplet, intramolecular electron transfer will depend on whether folding allows (or not) atomic sites involved in electron transfer to be close or far to each other.
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This page is a summary of: Configuration-Dependent Photoinduced Electron Transfer in Diastereomeric Naphthalene-Amino-Naphthalene Triads, Chemistry - A European Journal, July 2015, Wiley,
DOI: 10.1002/chem.201501008.
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