All Stories

  1. Heteroleptic lead(II)-halide complexes supported by a bulky iminoanilide ligand

    Article • Main Group Metal Chemistry, January 2017, De Gruyter

    Dr Yann Sarazin

  2. Sequential Barium-Catalysed N−H/H−Si Dehydrogenative Cross-Couplings: Cyclodisilazanes versus Linear Oligosilazanes

    Article • Chemistry - A European Journal, September 2016, Wiley

    Dr Yann Sarazin

  3. Calcium, Strontium and Barium Homogeneous Catalysts for Fine Chemicals Synthesis

    Article • The Chemical Record, June 2016, Wiley

    Dr Yann Sarazin

  4. Alkaline Earth-Olefin Complexes with Secondary Interactions

    Article • Chemistry - A European Journal, March 2016, Wiley

    Dr Yann Sarazin

  5. Alkali-Metal-Catalyzed Cross-Dehydrogenative Couplings of Hydrosilanes with Amines

    Article • ChemCatChem, February 2016, Wiley

    Dr Yann Sarazin

  6. Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N−H/H−Si Dehydrocoupling Reactions

    Article • Angewandte Chemie International Edition, February 2016, Wiley

    Dr Yann Sarazin

  7. Alkaline-Earth-Catalysed Cross-Dehydrocoupling of Amines and Hydrosilanes: Reactivity Trends, Scope and Mechanism

    Article • Chemistry - A European Journal, February 2016, Wiley

    Dr Yann Sarazin

  8. Aluminium, gallium and indium complexes supported by a chiral phenolato-prolinolato dianionic ligand

    Article • Main Group Metal Chemistry, January 2016, De Gruyter

    jean-francois carpentier, Dr Yann Sarazin

  9. Calcium complexes with imino-phosphinanilido chalcogenide ligands for heterofunctionalisation catalysis

    Article • RSC Advances, January 2016, Royal Society of Chemistry

    Dr Yann Sarazin

  10. Structure vs119Sn NMR Chemical Shift in Three-Coordinated Tin(II) Complexes: Experimental Data and Predictive DFT Computations

    Article • Organometallics, June 2015, American Chemical Society (ACS)

    Dr Yann Sarazin

  11. Barium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines: A Theoretical and Experimental Approach

    Article • Angewandte Chemie International Edition, May 2015, Wiley

    Dr Yann Sarazin

  12. Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides

    Article • Chemical Reviews, May 2015, American Chemical Society (ACS)

    Dr Yann Sarazin

  13. Structurally Characterized Lead(II) Alkoxides as Potent Ring-Opening Polymerization Catalysts

    Article • Organometallics, April 2015, American Chemical Society (ACS)

    Dr Yann Sarazin

  14. Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters

    Article • Chemistry - A European Journal, April 2015, Wiley

    Dr Yann Sarazin

  15. Highly Active, Chemo- and Regioselective YbIIand SmIICatalysts for the Hydrophosphination of Styrene with Phenylphosphine

    Article • Chemistry - A European Journal, March 2015, Wiley

    Dr Yann Sarazin

  16. Highly Fluorinated Tris(indazolyl)borate Silylamido Complexes of the Heavier Alkaline Earth Metals: Synthesis, Characterization, and Efficient Catalytic Intramolecular Hydroamination

    Article • Chemistry - A European Journal, January 2015, Wiley

    Dr Yann Sarazin

  17. Aluminum, Indium, and Mixed Yttrium–Lithium Complexes Supported by a Chiral Binap-Based Fluorinated Dialkoxide: Structural Features and Heteroselective ROP of Lactide

    Article • Organometallics, October 2014, American Chemical Society (ACS)

    Dr Yann Sarazin

  18. Potassium and Well-Defined Neutral and Cationic Calcium Fluoroalkoxide Complexes: Structural Features and Reactivity

    Article • Organometallics, October 2014, American Chemical Society (ACS)

    Dr Yann Sarazin

  19. C sp 3H Bond Activation with Triel Metals: Indium and Gallium Zwitterions through Internal Hydride Abstraction in Rigid Salan Ligands

    Article • Chemistry - A European Journal, May 2014, Wiley

    Dr Yann Sarazin

  20. Kinetic Analysis of the Immortal Ring-Opening Polymerization of Cyclic Esters: A Case Study with Tin(II) Catalysts

    Article • Macromolecules, April 2014, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin

  21. Chiral (1,2)-Diphenylethylene-Salen Complexes of Triel Metals: Coordination Patterns and Mechanistic Considerations in the Isoselective ROP of Lactide

    Article • Chemistry - A European Journal, April 2014, Wiley

    Dr Yann Sarazin

  22. Divalent Heteroleptic Ytterbium Complexes – Effective Catalysts for Intermolecular Styrene Hydrophosphination and Hydroamination

    Article • Inorganic Chemistry, February 2014, American Chemical Society (ACS)

    Dr Yann Sarazin

  23. Stable divalent germanium, tin and lead amino(ether)-phenolate monomeric complexes: structural features, inclusion heterobimetallic complexes, and ROP catalysis

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Dr Yann Sarazin

  24. On the coordination chemistry of organochalcogenolates RNMe2^E− and RNMe2^E^O− (E = S, Se) onto lead(ii) and lighter divalent tetrel elements

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Dr Yann Sarazin

  25. Kinetic Analysis of the Living Ring-Opening Polymerisation ofL-Lactide with Tin(II) Initiators

    Article • European Journal of Inorganic Chemistry, October 2013, Wiley

    Professor Manfred Bochmann, Dr Yann Sarazin

  26. Charge-Neutral and Cationic Complexes of Large Alkaline Earths for Ring-Opening Polymerization and Fine Chemicals Catalysis

    Article • October 2013, Wiley

    Dr Yann Sarazin

  27. Heteroleptic Alkyl and Amide Iminoanilide Alkaline Earth and Divalent Rare Earth Complexes for the Catalysis of Hydrophosphination and (Cyclo)Hydroamination Reactions

    Article • Chemistry - A European Journal, August 2013, Wiley

    Dr Yann Sarazin

  28. Heteroleptic Tin(II) Initiators for the Ring-Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations

    Article • Chemistry - A European Journal, August 2013, Wiley

    Dr Yann Sarazin

  29. Diamido-Ether Actinide Complexes as Initiators for Lactide Ring-Opening Polymerization

    Article • Organometallics, March 2013, American Chemical Society (ACS)

    Dr Yann Sarazin

  30. Discrete Divalent Rare-Earth Cationic ROP Catalysts: Ligand-Dependent Redox Behavior and Discrepancies with Alkaline-Earth Analogues in a Ligand-Assisted Activated Monomer Mechanism

    Article • Chemistry - A European Journal, February 2013, Wiley

    Dr Yann Sarazin

  31. Cyclohydroamination of Aminoalkenes Catalyzed by Disilazide Alkaline-Earth Metal Complexes: Reactivity Patterns and Deactivation Pathways

    Article • Chemistry - A European Journal, January 2013, Wiley

    Dr Yann Sarazin

  32. Alkali aminoether-phenolate complexes: synthesis, structural characterization and evidence for an activated monomer ROP mechanism

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Francesca M Kerton, Dr Yann Sarazin

  33. Alkaline-Earth Metal Complexes in Homogeneous Polymerization Catalysis

    Article • January 2013, Springer Science + Business Media

    Dr Yann Sarazin

  34. Aluminum, calcium and zinc complexes supported by potentially tridentate iminophenolate ligands: synthesis and use in the ring-opening polymerization of lactide

    Article • Applied Organometallic Chemistry, October 2012, Wiley

    Dr Yann Sarazin

  35. Highly Effective Alkaline Earth Catalysts for the Sterically Governed Hydrophosphonylation of Aldehydes and Nonactivated Ketones

    Article • Chemistry - A European Journal, September 2012, Wiley

    Dr Yann Sarazin

  36. Metal Phenolates as Polymerization Catalysts

    Article • June 2012, Wiley

    Dr Yann Sarazin

  37. β-Diketiminato-Alkaline Earth Cationic Complexes: Synthesis, Structures, Lactide Polymerization and Unusual Oxidative Reactivity of the Ancillary Ligand

    Article • European Journal of Inorganic Chemistry, May 2012, Wiley

    Dr Yann Sarazin

  38. When Bigger Is Better: Intermolecular Hydrofunctionalizations of Activated Alkenes Catalyzed by Heteroleptic Alkaline Earth Complexes

    Article • Angewandte Chemie International Edition, April 2012, Wiley

    Dr Yann Sarazin

  39. Heteroleptic Silylamido Phenolate Complexes of Calcium and the Larger Alkaline Earth Metals: β-Agostic Ae⋅⋅⋅SiH Stabilization and Activity in the Ring-Opening Polymerization ofL-Lactide

    Article • Chemistry - A European Journal, April 2012, Wiley

    Dr Yann Sarazin

  40. Synthetic and Mechanistic Aspects of the Immortal Ring-Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo- and Heteroleptic Tin(II)-Phenolate Catalysts

    Article • Chemistry - A European Journal, January 2012, Wiley

    Professor Manfred Bochmann, Dr Yann Sarazin

  41. Allyl strontium compounds: synthesis, molecular structure and properties

    Article • Dalton Transactions, January 2012, Royal Society of Chemistry

    Dr Yann Sarazin

  42. Well-defined, solvent-free cationic barium complexes: Synthetic strategies and catalytic activity in the ring-opening polymerization of lactide

    Article • Inorganica Chimica Acta, January 2012, Elsevier

    Dr Yann Sarazin

  43. Discrete, Solvent-Free Alkaline-Earth Metal Cations: Metal···Fluorine Interactions and ROP Catalytic Activity

    Article • Journal of the American Chemical Society, June 2011, American Chemical Society (ACS)

    Dr Yann Sarazin

  44. Isoselective Styrene Polymerization Catalyzed byansa-Bis(indenyl) Allyl Rare Earth Complexes. Stereochemical and Mechanistic Aspects

    Article • Macromolecules, May 2011, American Chemical Society (ACS)

    Dr Lionel PERRIN, Dr Yann Sarazin

  45. Syndio- and Isoselective Coordinative Chain Transfer Polymerization of Styrene Promoted by ansa-Lanthanidocene/ Dialkylmagnesium Systems

    Article • Advanced Synthesis & Catalysis, May 2011, Wiley

    Dr Yann Sarazin

  46. Well-defined Syndiotactic Polystyrene-b -Atactic Polystyrene Stereoblock Polymers

    Article • Macromolecular Rapid Communications, March 2011, Wiley

    Dr Yann Sarazin

  47. Zinc and magnesium complexes supported by bulky multidentate amino-ether phenolate ligands: potent pre-catalysts for the immortalring-opening polymerisation of cyclic esters

    Article • Dalton Transactions, January 2011, Royal Society of Chemistry

    Dr Yann Sarazin

  48. Bis(dimethylsilyl)amide Complexes of the Alkaline-Earth Metals Stabilized by β-Si−H Agostic Interactions: Synthesis, Characterization, and Catalytic Activity

    Article • Organometallics, December 2010, American Chemical Society (ACS)

    Dr Yann Sarazin

  49. Discrete, Base-Free, Cationic Alkaline-Earth Complexes - Access and Catalytic Activity in the Polymerization of Lactide

    Article • European Journal of Inorganic Chemistry, June 2010, Wiley

    Dr Yann Sarazin

  50. Discrete allyl complexes of group 3 metals and lanthanides

    Article • Comptes Rendus Chimie, June 2010, Cellule MathDoc/CEDRAM

    Sophie Guillaume, Dr Yann Sarazin

  51. Water-tolerant catalyst systems for the bulk cationic polymerization of para-methylstyrene and indene

    Article • European Polymer Journal, May 2010, Elsevier

    Dr Yann Sarazin

  52. One-Pot Synthesis of Lactide-Styrene Diblock Copolymers via Catalytic Immortal Ring-Opening Polymerization of Lactide and Nitroxide-Mediated Polymerization of Styrene

    Article • ChemSusChem, April 2010, Wiley

    Dr Yann Sarazin

  53. Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Sophie Guillaume, Dr Yann Sarazin

  54. On the Initiation Mechanism of Syndiospecific Styrene Polymerization Catalyzed by Single-Componentansa-Lanthanidocenes

    Article • Chemistry - A European Journal, February 2009, Wiley

    Dr Lionel PERRIN, Dr Yann Sarazin

  55. Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Dr Yann Sarazin

  56. Synthesis and structures of new binuclear zinc alkyl, aryl and aryloxo complexes

    Article • Journal of Organometallic Chemistry, April 2008, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin

  57. Mixed-ligand iminopyrrolato-salicylaldiminato group 4 metal complexes: Optimising catalyst structure for ethylene/propylene copolymerisations

    Article • Journal of Organometallic Chemistry, October 2007, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin, William Clegg

  58. Mono(arene) Complexes of Thallium(I) Supported by a Weakly Coordinating Anion

    Article • Organometallics, March 2007, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin

  59. Thallium(I) Sandwich, Multidecker, and Ether Complexes Stabilized by Weakly-Coordinating Anions:  A Spectroscopic, Structural, and Theoretical Investigation

    Article • Journal of the American Chemical Society, January 2007, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin

  60. Synthesis and crystal structure of [C6H5Hg(H2NSiMe3)][H2N{B(C6F5)3}2], a phenyl–mercury(II) cation stabilised by a non-coordinating counter-anion

    Article • Journal of Organometallic Chemistry, December 2006, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin

  61. Cationic Brønsted Acids for the Preparation of SnIV Salts: Synthesis and Characterisation of [Ph3Sn(OEt2)][H2N{B(C6F5)3}2],[Sn(NMe2)3(HNMe

    Article • European Journal of Inorganic Chemistry, August 2006, Wiley

    Dr Simon J Coles, Professor Manfred Bochmann, Dr Yann Sarazin

  62. Titanium, zinc and alkaline-earth metal complexes supported by bulky O,N,N,O-multidentate ligands: syntheses, characterisation and activity in cyclic esterpolymerisation

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor Manfred Bochmann, Dr Yann Sarazin

  63. Binary cerium(IV) tert-butoxides-dialkylmagnesium systems: Radical versus coordinative polymerization of styrene

    Article • Journal of Molecular Catalysis A Chemical, September 2005, Elsevier

    Dr Yann Sarazin

  64. Copolymerization of Propene and 5-Vinyl-2-Norbornene: A Simple Route to Polar Poly(propylene)s

    Article • Macromolecular Rapid Communications, August 2005, Wiley

    Professor Manfred Bochmann, Dr Yann Sarazin

  65. Chromium allyl and alkyl catalysts for the vinyl polymerization of norbornene and ethylene–norbornene copolymerizations

    Article • Journal of Molecular Catalysis A Chemical, July 2005, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin

  66. Heterogenized “Ligand-Free” Lanthanide Catalysts for the Homo- and Copolymerization of Ethylene and 1,3-Butadiene

    Article • Macromolecules, April 2005, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin

  67. Synthesis and structure of [Cp2Zr(OPri)(HOPri)]+ and its activity in the polymerisation of propene oxide

    Article • Journal of Organometallic Chemistry, November 2004, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin

  68. Novel Zinc and Magnesium Alkyl and Amido Cations for Ring-Opening Polymerization Reactions

    Article • Organometallics, June 2004, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin