All Stories

  1. Heteroleptic lead(II)-halide complexes supported by a bulky iminoanilide ligand

    Article • Main Group Metal Chemistry, January 2017, De Gruyter

    Dr Yann Sarazin

  2. Sequential Barium-Catalysed N−H/H−Si Dehydrogenative Cross-Couplings: Cyclodisilazanes versus Linear Oligosilazanes

    Article • Chemistry - A European Journal, September 2016, Wiley

    Dr Yann Sarazin

  3. Calcium, Strontium and Barium Homogeneous Catalysts for Fine Chemicals Synthesis

    Article • The Chemical Record, June 2016, Wiley

    Dr Yann Sarazin

  4. Alkaline Earth-Olefin Complexes with Secondary Interactions

    Article • Chemistry - A European Journal, March 2016, Wiley

    Dr Yann Sarazin

  5. Alkali-Metal-Catalyzed Cross-Dehydrogenative Couplings of Hydrosilanes with Amines

    Article • ChemCatChem, February 2016, Wiley

    Dr Yann Sarazin

  6. Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N−H/H−Si Dehydrocoupling Reactions

    Article • Angewandte Chemie International Edition, February 2016, Wiley

    Dr Yann Sarazin

  7. Alkaline-Earth-Catalysed Cross-Dehydrocoupling of Amines and Hydrosilanes: Reactivity Trends, Scope and Mechanism

    Article • Chemistry - A European Journal, February 2016, Wiley

    Dr Yann Sarazin

  8. Aluminium, gallium and indium complexes supported by a chiral phenolato-prolinolato dianionic ligand

    Article • Main Group Metal Chemistry, January 2016, De Gruyter

    jean-francois carpentier, Dr Yann Sarazin

  9. Calcium complexes with imino-phosphinanilido chalcogenide ligands for heterofunctionalisation catalysis

    Article • RSC Advances, January 2016, Royal Society of Chemistry

    Dr Yann Sarazin

  10. Structure vs119Sn NMR Chemical Shift in Three-Coordinated Tin(II) Complexes: Experimental Data and Predictive DFT Computations

    Article • Organometallics, June 2015, American Chemical Society (ACS)

    Dr Yann Sarazin

  11. Barium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines: A Theoretical and Experimental Approach

    Article • Angewandte Chemie International Edition, May 2015, Wiley

    Dr Yann Sarazin

  12. Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides

    Article • Chemical Reviews, May 2015, American Chemical Society (ACS)

    Dr Yann Sarazin

  13. Structurally Characterized Lead(II) Alkoxides as Potent Ring-Opening Polymerization Catalysts

    Article • Organometallics, April 2015, American Chemical Society (ACS)

    Dr Yann Sarazin

  14. Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters

    Article • Chemistry - A European Journal, April 2015, Wiley

    Dr Yann Sarazin

  15. Highly Active, Chemo- and Regioselective YbIIand SmIICatalysts for the Hydrophosphination of Styrene with Phenylphosphine

    Article • Chemistry - A European Journal, March 2015, Wiley

    Dr Yann Sarazin

  16. Highly Fluorinated Tris(indazolyl)borate Silylamido Complexes of the Heavier Alkaline Earth Metals: Synthesis, Characterization, and Efficient Catalytic Intramolecular Hydroamination

    Article • Chemistry - A European Journal, January 2015, Wiley

    Dr Yann Sarazin

  17. Aluminum, Indium, and Mixed Yttrium–Lithium Complexes Supported by a Chiral Binap-Based Fluorinated Dialkoxide: Structural Features and Heteroselective ROP of Lactide

    Article • Organometallics, October 2014, American Chemical Society (ACS)

    Dr Yann Sarazin

  18. Potassium and Well-Defined Neutral and Cationic Calcium Fluoroalkoxide Complexes: Structural Features and Reactivity

    Article • Organometallics, October 2014, American Chemical Society (ACS)

    Dr Yann Sarazin

  19. C sp 3H Bond Activation with Triel Metals: Indium and Gallium Zwitterions through Internal Hydride Abstraction in Rigid Salan Ligands

    Article • Chemistry - A European Journal, May 2014, Wiley

    Dr Yann Sarazin

  20. Chiral (1,2)-Diphenylethylene-Salen Complexes of Triel Metals: Coordination Patterns and Mechanistic Considerations in the Isoselective ROP of Lactide

    Article • Chemistry - A European Journal, April 2014, Wiley

    Dr Yann Sarazin

  21. Kinetic Analysis of the Immortal Ring-Opening Polymerization of Cyclic Esters: A Case Study with Tin(II) Catalysts

    Article • Macromolecules, April 2014, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin

  22. Divalent Heteroleptic Ytterbium Complexes – Effective Catalysts for Intermolecular Styrene Hydrophosphination and Hydroamination

    Article • Inorganic Chemistry, February 2014, American Chemical Society (ACS)

    Dr Yann Sarazin

  23. Stable divalent germanium, tin and lead amino(ether)-phenolate monomeric complexes: structural features, inclusion heterobimetallic complexes, and ROP catalysis

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Dr Yann Sarazin

  24. On the coordination chemistry of organochalcogenolates RNMe2^E− and RNMe2^E^O− (E = S, Se) onto lead(ii) and lighter divalent tetrel elements

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Dr Yann Sarazin

  25. Kinetic Analysis of the Living Ring‐Opening Polymerisation of L‐Lactide with Tin(II) Initiators

    Article • European Journal of Inorganic Chemistry, October 2013, Wiley

    Professor Manfred Bochmann, Dr Yann Sarazin

  26. Charge-Neutral and Cationic Complexes of Large Alkaline Earths for Ring-Opening Polymerization and Fine Chemicals Catalysis

    Article • October 2013, Wiley

    Dr Yann Sarazin

  27. Heteroleptic Alkyl and Amide Iminoanilide Alkaline Earth and Divalent Rare Earth Complexes for the Catalysis of Hydrophosphination and (Cyclo)Hydroamination Reactions

    Article • Chemistry - A European Journal, August 2013, Wiley

    Dr Yann Sarazin

  28. Heteroleptic Tin(II) Initiators for the Ring-Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations

    Article • Chemistry - A European Journal, August 2013, Wiley

    Dr Yann Sarazin

  29. Diamido-Ether Actinide Complexes as Initiators for Lactide Ring-Opening Polymerization

    Article • Organometallics, March 2013, American Chemical Society (ACS)

    Dr Yann Sarazin

  30. Discrete Divalent Rare-Earth Cationic ROP Catalysts: Ligand-Dependent Redox Behavior and Discrepancies with Alkaline-Earth Analogues in a Ligand-Assisted Activated Monomer Mechanism

    Article • Chemistry - A European Journal, February 2013, Wiley

    Dr Yann Sarazin

  31. Cyclohydroamination of Aminoalkenes Catalyzed by Disilazide Alkaline-Earth Metal Complexes: Reactivity Patterns and Deactivation Pathways

    Article • Chemistry - A European Journal, January 2013, Wiley

    Dr Yann Sarazin

  32. Alkali aminoether-phenolate complexes: synthesis, structural characterization and evidence for an activated monomer ROP mechanism

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Francesca M Kerton, Dr Yann Sarazin

  33. Alkaline-Earth Metal Complexes in Homogeneous Polymerization Catalysis

    Article • January 2013, Springer Science + Business Media

    Dr Yann Sarazin

  34. Aluminum, calcium and zinc complexes supported by potentially tridentate iminophenolate ligands: synthesis and use in the ring-opening polymerization of lactide

    Article • Applied Organometallic Chemistry, October 2012, Wiley

    Dr Yann Sarazin

  35. Highly Effective Alkaline Earth Catalysts for the Sterically Governed Hydrophosphonylation of Aldehydes and Nonactivated Ketones

    Article • Chemistry - A European Journal, September 2012, Wiley

    Dr Yann Sarazin

  36. Metal Phenolates as Polymerization Catalysts

    Article • June 2012, Wiley

    Dr Yann Sarazin

  37. β-Diketiminato-Alkaline Earth Cationic Complexes: Synthesis, Structures, Lactide Polymerization and Unusual Oxidative Reactivity of the Ancillary Ligand

    Article • European Journal of Inorganic Chemistry, May 2012, Wiley

    Dr Yann Sarazin

  38. When Bigger Is Better: Intermolecular Hydrofunctionalizations of Activated Alkenes Catalyzed by Heteroleptic Alkaline Earth Complexes

    Article • Angewandte Chemie International Edition, April 2012, Wiley

    Dr Yann Sarazin

  39. Heteroleptic Silylamido Phenolate Complexes of Calcium and the Larger Alkaline Earth Metals: β-Agostic Ae⋅⋅⋅SiH Stabilization and Activity in the Ring-Opening Polymerization ofL-Lactide

    Article • Chemistry - A European Journal, April 2012, Wiley

    Dr Yann Sarazin

  40. Synthetic and Mechanistic Aspects of the Immortal Ring‐Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo‐ and Heteroleptic Tin(II)‐Phenolate Catalysts

    Article • Chemistry - A European Journal, January 2012, Wiley

    Professor Manfred Bochmann, Dr Yann Sarazin

  41. Allyl strontium compounds: synthesis, molecular structure and properties

    Article • Dalton Transactions, January 2012, Royal Society of Chemistry

    Dr Yann Sarazin

  42. Well-defined, solvent-free cationic barium complexes: Synthetic strategies and catalytic activity in the ring-opening polymerization of lactide

    Article • Inorganica Chimica Acta, January 2012, Elsevier

    Dr Yann Sarazin

  43. Discrete, Solvent-Free Alkaline-Earth Metal Cations: Metal···Fluorine Interactions and ROP Catalytic Activity

    Article • Journal of the American Chemical Society, June 2011, American Chemical Society (ACS)

    Dr Yann Sarazin

  44. Isoselective Styrene Polymerization Catalyzed byansa-Bis(indenyl) Allyl Rare Earth Complexes. Stereochemical and Mechanistic Aspects

    Article • Macromolecules, May 2011, American Chemical Society (ACS)

    Dr Lionel PERRIN, Dr Yann Sarazin

  45. Syndio- and Isoselective Coordinative Chain Transfer Polymerization of Styrene Promoted by ansa-Lanthanidocene/ Dialkylmagnesium Systems

    Article • Advanced Synthesis & Catalysis, May 2011, Wiley

    Dr Yann Sarazin

  46. Well-defined Syndiotactic Polystyrene-b -Atactic Polystyrene Stereoblock Polymers

    Article • Macromolecular Rapid Communications, March 2011, Wiley

    Dr Yann Sarazin

  47. Zinc and magnesium complexes supported by bulky multidentate amino-ether phenolate ligands: potent pre-catalysts for the immortalring-opening polymerisation of cyclic esters

    Article • Dalton Transactions, January 2011, Royal Society of Chemistry

    Dr Yann Sarazin

  48. Bis(dimethylsilyl)amide Complexes of the Alkaline-Earth Metals Stabilized by β-Si−H Agostic Interactions: Synthesis, Characterization, and Catalytic Activity

    Article • Organometallics, December 2010, American Chemical Society (ACS)

    Dr Yann Sarazin

  49. Discrete, Base-Free, Cationic Alkaline-Earth Complexes - Access and Catalytic Activity in the Polymerization of Lactide

    Article • European Journal of Inorganic Chemistry, June 2010, Wiley

    Dr Yann Sarazin

  50. Discrete allyl complexes of group 3 metals and lanthanides

    Article • Comptes Rendus Chimie, June 2010, Cellule MathDoc/CEDRAM

    Sophie Guillaume, Dr Yann Sarazin

  51. Water-tolerant catalyst systems for the bulk cationic polymerization of para-methylstyrene and indene

    Article • European Polymer Journal, May 2010, Elsevier

    Dr Yann Sarazin

  52. One-Pot Synthesis of Lactide-Styrene Diblock Copolymers via Catalytic Immortal Ring-Opening Polymerization of Lactide and Nitroxide-Mediated Polymerization of Styrene

    Article • ChemSusChem, April 2010, Wiley

    Dr Yann Sarazin

  53. Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Sophie Guillaume, Dr Yann Sarazin

  54. On the Initiation Mechanism of Syndiospecific Styrene Polymerization Catalyzed by Single-Componentansa-Lanthanidocenes

    Article • Chemistry - A European Journal, February 2009, Wiley

    Dr Lionel PERRIN, Dr Yann Sarazin

  55. Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Dr Yann Sarazin

  56. Synthesis and structures of new binuclear zinc alkyl, aryl and aryloxo complexes

    Article • Journal of Organometallic Chemistry, April 2008, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin

  57. Mixed-ligand iminopyrrolato-salicylaldiminato group 4 metal complexes: Optimising catalyst structure for ethylene/propylene copolymerisations

    Article • Journal of Organometallic Chemistry, October 2007, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin, William Clegg

  58. Mono(arene) Complexes of Thallium(I) Supported by a Weakly Coordinating Anion

    Article • Organometallics, February 2007, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin

  59. Thallium(I) Sandwich, Multidecker, and Ether Complexes Stabilized by Weakly-Coordinating Anions:  A Spectroscopic, Structural, and Theoretical Investigation

    Article • Journal of the American Chemical Society, January 2007, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin

  60. Synthesis and crystal structure of [C6H5Hg(H2NSiMe3)][H2N{B(C6F5)3}2], a phenyl–mercury(II) cation stabilised by a non-coordinating counter-anion

    Article • Journal of Organometallic Chemistry, December 2006, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin

  61. Cationic Brønsted Acids for the Preparation of SnIV Salts: Synthesis and Characterisation of [Ph3Sn(OEt2)][H2N{B(C6F5)3}2],[Sn(NMe2)3(HNMe

    Article • European Journal of Inorganic Chemistry, August 2006, Wiley

    Dr Simon J Coles, Professor Manfred Bochmann, Dr Yann Sarazin

  62. Titanium, zinc and alkaline-earth metal complexes supported by bulky O,N,N,O-multidentate ligands: syntheses, characterisation and activity in cyclic esterpolymerisation

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor Manfred Bochmann, Dr Yann Sarazin

  63. Binary cerium(IV) tert-butoxides-dialkylmagnesium systems: Radical versus coordinative polymerization of styrene

    Article • Journal of Molecular Catalysis A Chemical, September 2005, Elsevier

    Dr Yann Sarazin

  64. Copolymerization of Propene and 5‐Vinyl‐2‐Norbornene: A Simple Route to Polar Poly(propylene)s

    Article • Macromolecular Rapid Communications, July 2005, Wiley

    Professor Manfred Bochmann, Dr Yann Sarazin

  65. Chromium allyl and alkyl catalysts for the vinyl polymerization of norbornene and ethylene–norbornene copolymerizations

    Article • Journal of Molecular Catalysis A Chemical, July 2005, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin

  66. Heterogenized “Ligand-Free” Lanthanide Catalysts for the Homo- and Copolymerization of Ethylene and 1,3-Butadiene

    Article • Macromolecules, March 2005, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin

  67. Synthesis and structure of [Cp2Zr(OPri)(HOPri)]+ and its activity in the polymerisation of propene oxide

    Article • Journal of Organometallic Chemistry, November 2004, Elsevier

    Professor Manfred Bochmann, Dr Yann Sarazin

  68. Novel Zinc and Magnesium Alkyl and Amido Cations for Ring-Opening Polymerization Reactions

    Article • Organometallics, May 2004, American Chemical Society (ACS)

    Professor Manfred Bochmann, Dr Yann Sarazin