All Stories

  1. A high-entropy coordination cage featuring an Au-porphyrin metalloligand for the photodynamic therapy of liver cancer
  2. Thiazole Functionalization of Thiosemicarbazone for Cu(II) Complexation: Moving toward Highly Efficient Anticancer Drugs with Promising Oral Bioavailability
  3. Chirality Sensing of Amino Acid Esters by S-2-Methylbutanamido-Substituted m-Phthalic Diamide-Linked Zinc Bisporphyrinate
  4. Thiazole Functionalization of Thiosemicarbazone for Cu(II) Complexation: Toward Highly Efficient Anticancer Drugs with Promising Oral Bioavailability
  5. [FeIIICl(TMPPH2)][FeIIICl4]2: A Stand-Alone Molecular Nanomedicine That Induces High Cytotoxicity by Ferroptosis
  6. [Fe<sup>III</sup>Cl(TMPPH<sub>2</sub>)][Fe<sup>III</sup>Cl<sub>4</sub>]<sub>2</sub>: A Stand-Alone Molecular Nanomedicine that Induces High Cytotoxicity by Ferroptosis
  7. A Porphyrin‐Based 3D Metal‐Organic Framework Featuring [Cu8Cl6]10+ Cluster Secondary Building Units: Synthesis, Structure Elucidation, Anion Exchange, and Peroxidase‐Like Activity
  8. Bioorthogonal Activation of RCA-Based Amplifiable DNAzymes in Bimetallic NMOF for Precise Gene/Chemo-Dynamic Combination Therapy
  9. Immunogenic Radiation Therapy for Enhanced Antitumor Immunity via a Core–Shell Nanosensitizer-Mediated Immunosuppressive Tumor Microenvironment Modulation
  10. An NIR-II light-responsive nanoplatform for photothermal and enhanced photodynamic synergistic therapy toward drug-resistant bacterial infection and hypoxia relief in subcutaneous wound healing
  11. Nanoscale Two-Dimensional FeII- and CoII-Based Metal–Organic Frameworks of Porphyrin Ligand for the Photodynamic Therapy of Breast Cancer
  12. Remodeling the Tumor Microenvironment with Core–Shell Nanosensitizer Featuring Dual-Modal Imaging and Multimodal Therapy for Breast Cancer
  13. trans-[Ni(pdm)2]2+ (pdm = 2-pyridinemethanol) as a reliable synthon for isoreticular metal–organic frameworks of linear dicarboxylates
  14. Biotin-decorated hollow gold nanoshells for dual-modal imaging-guided NIR-II photothermal and radiosensitizing therapy toward breast cancer
  15. GSH-activatable camptothecin prodrug-loaded gold nanostars coated with hyaluronic acid for targeted breast cancer therapy via multiple radiosensitization strategies
  16. Reprogramming of the tumor microenvironment using a PCN-224@IrNCs/d-Arg nanoplatform for the synergistic PDT, NO, and radiosensitization therapy of breast cancer and improving anti-tumor immunity
  17. Two-dimensional Cd3-based metal–organic frameworks with halogen bonding sites for the uptake of I2
  18. Vacuum-Induced Guest N,N′-Diethylformamide Binding in a Metastable Cd5-Based Metal–Organic Framework
  19. NIR-PTT/ROS-Scavenging/Oxygen-Enriched Synergetic Therapy for Rheumatoid Arthritis by a pH-Responsive Hybrid CeO2-ZIF-8 Coated with Polydopamine
  20. ZIF-8 with cationic defects toward efficient125I2uptake forin vitroradiotherapy of colon cancer
  21. Connectivity Replication of Neutral Eu3+- and Tb3+-Based Metal–Organic Frameworks (MOFs) from Anionic Cd2+-Based MOF Crystallites
  22. Structural Insights into the Host–Guest Complexation between β-Cyclodextrin and Bio-Conjugatable Adamantane Derivatives
  23. Enhancing the Physiochemical Properties of Puerarin via L-Proline Co-Crystallization: Synthesis, Characterization, and Dissolution Studies of Two Phases of Pharmaceutical Co-Crystals
  24. Metal–organic frameworks of linear trinuclear cluster secondary building units: structures and applications
  25. On the Single-Crystal Structure of Tenofovir Alafenamide Mono-Fumarate: A Metastable Phase Featuring a Mixture of Co-Crystal and Salt
  26. A Heterometallic Three-Dimensional Metal−Organic Framework Bearing an Unprecedented One-Dimensional Branched-Chain Secondary Building Unit
  27. Zinc and Cadmium Complexes of Pyridinemethanol Carboxylates: Metal Carboxylate Zwitterions and Metal–Organic Frameworks
  28. Sequential Ag+/biothiol and synchronous Ag+/Hg2+biosensing with zwitterionic Cu2+-based metal–organic frameworks
  29. An N,N′-diethylformamide solvent-induced conversion cascade within a metal–organic framework single crystal
  30. Similarities and differences between Mn(ii) and Zn(ii) coordination polymers supported by porphyrin-based ligands: synthesis, structures and nonlinear optical properties
  31. Ultralow Lattice Thermal Conductivity in SnTe by Manipulating the Electron–Phonon Coupling
  32. A Single-Crystal to Single-Crystal Conversion Scheme for a Two-Dimensional Metal–Organic Framework Bearing Linear Cd3 Secondary Building Units
  33. Synchronous sensing of three conserved sequences of Zika virus using a DNAs@MOF hybrid: experimental and molecular simulation studies
  34. Effective loading of cisplatin into a nanoscale UiO-66 metal–organic framework with preformed defects
  35. Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal–organic framework with a porphyrinic skeleton
  36. Isoreticular Tp*–W–Cu–S cluster-based one-dimensional coordination polymers with an uncommon [Tp*WS3Cu2] + [Cu] combination and their third-order nonlinear optical properties
  37. A cationic [Ag12S12] cluster-based 2D coordination polymer and its dye composite with enhanced photocurrent and dielectric responses
  38. Piperazine-Based Functional Materials as Draw Solutes for Desalination via Forward Osmosis
  39. Guest-Induced Switchable Breathing Behavior in a Flexible Metal–Organic Framework with Pronounced Negative Gas Pressure
  40. Successive and Specific Detection of Hg2+ and I– by a DNA@MOF Biosensor: Experimental and Simulation Studies
  41. Co2 and Co3 Mixed Cluster Secondary Building Unit Approach toward a Three-Dimensional Metal-Organic Framework with Permanent Porosity
  42. Evaluating the component contribution to nonlinear optical performances using stable [Ni4O4] cuboidal clusters as models
  43. Preparation of carbon-based AuAg alloy nanoparticles by using the heterometallic [Au4Ag4] cluster for efficient oxidative coupling of anilines
  44. Rectangle and [2]catenane from cluster modular construction
  45. Smoothing the single-crystal to single-crystal conversions of a two-dimensional metal–organic framework via the hetero-metal doping of the linear trimetallic secondary building unit
  46. Deciphering the Structural Relationships of Five Cd-Based Metal–Organic Frameworks
  47. Tungsten(VI)–Copper(I)–Sulfur Cluster-Supported Metal–Organic Frameworks Bridged by in Situ Click-Formed Tetrazolate Ligands
  48. A crystalline zinc(ii) complex showing hollow hexagonal tubular morphology evolution, selective dye absorption and unique response to UV irradiation
  49. A cuboidal [Ni4O4] cluster as a precursor for recyclable, carbon-supported nickel nanoparticle reduction catalysts
  50. Efficient ring-opening polymerization (ROP) of ε-caprolactone catalysed by isomeric pyridyl β-diketonate iron(iii) complexes
  51. Counterintuitive Solid-State Syntheses of Indium-Thiolate-Phen Cations as Efficient and Selective Fluorescent Biosensors for HIV-1 ds-DNA and Sudan Ebolavirus RNA Sequences
  52. Assembly of [Tp*WS3Cu2]-Supported Coordination Polymers from Linkers with a Unique μ-Pyridyl Bridging Mode and Their Enhanced Third-Order Nonlinear Optical Performances
  53. Diverse Tp*-Capped W–Cu–S Clusters from One-Pot Assembly Involving in Situ Thiolation of Phosphines
  54. A unique cooperative catalytic system carrying metallic iron and 2-hydroxyethyl 2-bromoisobutyrate for the controlled/living ring-opening polymerization of ε-caprolactone
  55. A zwitterionic 1D/2D polymer co-crystal and its polymorphic sub-components: a highly selective sensing platform for HIV ds-DNA sequences
  56. Inorganic–organic hybrid sorbent for aromatic desulfurization of hydrocarbons: regenerative adsorption based on a charge-transfer complex
  57. Rational construction of functional molybdenum (tungsten)–copper–sulfur coordination oligomers and polymers from preformed cluster precursors
  58. Site-selective homo- and hetero-metallic doping of a 1D Zn-based coordination polymer to enhance the dimensionality and photocurrent responses
  59. Utilisation of gold nanoparticles on amine-functionalised UiO-66 (NH2-UiO-66) nanocrystals for selective tandem catalytic reactions
  60. Spacer-Directed Selective Assembly of Copper Square or Hexagon and Ring-Stacks or Coordination Nanotubes
  61. Metal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates
  62. Heterometallic transition metal clusters and cluster-supported coordination polymers derived from Tp- and Tp*-based Mo(W) sulfido precursors
  63. Unlocking Inter- to Non-Penetrating Frameworks Using Steric Influences on Spacers for CO2Adsorption
  64. Pyrididine-Carboxylate Ligands as Double-Bridge Spacers in CuIMetallacycles
  65. Construction of Zn(ii) and Cd(ii) metal–organic frameworks of diimidazole and dicarboxylate mixed ligands for the catalytic photodegradation of rhodamine B in water
  66. Dianthraceno[a,e]pentalenes: synthesis, crystallographic structures and applications in organic field-effect transistors
  67. Solvent effect-driven assembly of W/Cu/S cluster-based coordination polymers from the cluster precursor [Et4N][Tp*WS3(CuBr)3] and CuCN: isolation, structures and enhanced NLO responses
  68. Isolation of first row transition metal-carboxylate zwitterions
  69. A 1D anionic coordination polymer showing superior Congo Red sorption and its dye composite exhibiting remarkably enhanced photocurrent response
  70. A unique Zn(ii)-based MOF fluorescent probe for the dual detection of nitroaromatics and ketones in water
  71. Two Cluster-Based Coordination Polymers Derived from [Et4N][Tp*WS3(CuBr)3] and CuCN: Isolation, Structures and Amplified Third-Order Nonlinear Optical Responses
  72. Stable 7,14-Disubstituted-5,12-Dithiapentacenes with Quinoidal Conjugation
  73. Nickel(II) thiolates derived from transmetallation reaction of [Zn(Tab)4](PF6)2 with Ni(II) ions and their catalytic activity toward the CN coupling reactions
  74. para-Quinodimethane-Bridged Perylene Dimers and Pericondensed Quaterrylenes: The Effect of the Fusion Mode on the Ground States and Physical Properties
  75. Transmetalation of a Dodecahedral Na 9 Aggregate-Based Polymer: A Facile Route to Water Stable Cu(II) Coordination Networks
  76. Stitching 2D Polymeric Layers into Flexible Interpenetrated Metal-Organic Frameworks within Single Crystals
  77. Construction of Cd(ii) coordination polymers used as catalysts for the photodegradation of organic dyes in polluted water
  78. Distinct optical and kinetic responses from E/Z isomers of caspase probes with aggregation-induced emission characteristics
  79. Bent tritopic carboxylates for coordination networks: clues to the origin of self-penetration
  80. Antiaromatic bisindeno-[n]thienoacenes with small singlet biradical characters: syntheses, structures and chain length dependent physical properties
  81. Dibenzoheptazethrene Isomers with Different Biradical Characters: An Exercise of Clar’s Aromatic Sextet Rule in Singlet Biradicaloids
  82. NATURALLY EFFICIENT EMITTERS: LUMINESCENT ORGANOMETALLIC COMPLEXES DERIVED FROM NATURAL PRODUCTS
  83. Enhanced Emission and Analyte Sensing by Cinchonine Iridium(III) Cyclometalated Complexes Bearing Bent Diphosphine Chelators
  84. Spacer length-directed construction of two-dimensional [MoS3Cu3]-based coordination polymers from a precursor cluster [PPh4][Cp∗MoS3(CuNCS)3] (Cp∗=η5-C5Me5) and 4-pyridyl-based ditopic ligands
  85. Trans [OReV–OH] core stabilised by chelating N-heterocyclic dicarbene ligands
  86. Soluble Phosphorescent Iridium(III) Complexes from Cinchonine-Derived Ligands
  87. One-step entry to olefin-tethered N,S-heterocyclic carbene complexes of ruthenium with mixed ligands
  88. Recent advances in metal catalysts with hybrid ligands
  89. Phosphorescent Emitters from Natural Products: Cinchonine-Derived Iridium(III) Complexes
  90. Complexation of 1,1′-bis(diphenylphosphino)ferrocene dioxide (dppfO2) with 3d metals and revisit of its coordination to Pd(ii)
  91. Nuclearity growth towards Ni(ii) cubane in self-assembly with 2-hydroxymethyl pyridine (hmpH) and 5-ethoxycarbonyl-2-hydroxymethyl pyridine (5-ehmpH)
  92. How Does a Non- C 3 -Symmetry Guest Molecule Fit into a C 3 -Symmetry Host Cavity?
  93. Cluster-Based Supramolecular Compounds from Mo(W)/Cu/S Cluster Precursors
  94. Formation of Four Different [MoOS3Cu3]-Based Coordination Polymers from the Same Components via Four Synthetic Routes
  95. Construction of Symmetric and Asymmetric Mo/S/Cu Clusters from a Cluster Precursor [Et 4 N] 2 [(edt) 2 Mo 2 S 2 (μ-S) 2 ] (edt = Ethanedithiolate)
  96. Assembly of [(η 5 -C 5 Me 5 )MoS 3 Cu 3 ]-Supported One-Dimensional Chains with Single, Double, Triple, and Quadruple Strands
  97. Constructions of a set of novel hydrogen-bonded supramolecules from reactions of cobalt(II) salt with bis(3,5-dimethylpyrazolyl)methane and different carboxylic acids
  98. Solvothermal syntheses, crystal structures, and luminescent properties of two novel silver(I) coordination polymers containing 5-aryl-substituted tetrazolate ligands
  99. Stepwise Guest Exchange in a Cluster-Supported Three-Dimensional Host
  100. CS2 elimination and C–S bond cleavage in [Zn(dmpzdtc)2] – Leading to formation of a cyclic octanuclear complex [Zn4(μ-dmpz)5(μ-OH)(μ3-S)(py)]2·py(dmpzdtc=3,5-dimethylpyrazole-1-dithiocarboxylate, dmpz=3,5-dimethylpyrazolate)
  101. Binuclear Cluster-to-Cluster-Based Supramolecular Compounds: Design, Assembly, and Enhanced Third-Order Nonlinear Optical Performances of {[Et 4 N] 2 [MoOS 3 Cu 2 (μ-CN)] 2 ·2aniline} n and {[Et 4 N] 4 [MoOS 3 Cu 3 CN(μ′-CN)] 2 (μ-CN) 2 } n
  102. Reactions of a Tungsten Trisulfido Complex of Hydridotris(3,5-dimethylpyrazol-1-yl)borate (Tp*) [Et 4 N][Tp*WS 3 ] with CuX (X = Cl, NCS, or CN):  Isolation, Structures, and Third-Order NLO Properties
  103. Solvothermal synthesis and crystal structure of a luminescent 2D copper(I) coordination polymer with a (3,4)-connected net
  104. Formation of a 1D water chain into the channel of a unique 3D hydrogen-bound coordination polymer {[Cd(μ-Cl)(4-pya)(H2O)]2·4H2O}∞ (4-pya=trans-4-pyridylacrylate)
  105. Construction of [(η 5 -C 5 Me 5 )MoS 3 Cu 3 ]-Based Supramolecular Assemblies from the [(η 5 -C 5 Me 5 )MoS 3 (CuNCS) 3 ] - Cluster Anion and Multitopic Ligands with Different Symmetries
  106. Excited State Absorption Dynamics in Metal Cluster Polymer [WS 4 Cu 3 I(4-bpy) 3 ] n Solution
  107. Synthesis, structure and luminescent properties of a unique [WS4Cu4]-based supramolecular compound [WS4Cu4(dmpzm)2(dca)2]∞
  108. Protonolysis Reactions of [(Me3Si)2N]3Ln(μ-Cl)Li(thf)3 withtBuSH or EtSH: Isolation, Structures and Catalytic Properties of Dinuclear Complexes [{(Me3Si)2N}2Ln(μ-StBu)]2 and Tetranuclear Complexes [Li(thf)4][{(Me3Si)2N}4Ln4(μ4-SEt)(μ-SEt)8] (Ln = Pr, Sm)
  109. Synthesis and structural characterization of a unique 3D coordination polymer [Pb(4-pya)2]n(4-pya=trans-4-pyridylacrylate)
  110. Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [WOS3Cu2(4-tBuPy)2]2 (4-tBuPy=4-tert-butylpyridine)
  111. Unique formation of two high-nuclearity metallamacrocycles from a mononuclear complex [Zn(dmpzdtc)2] (dmpzdtc = 3,5-dimethylpyrazole-1-dithiocarboxylate) via CS2 elimination
  112. Mo(W)/Cu/S Cluster-Based Supramolecular Arrays Assembled from Preformed Clusters [Et 4 N] 4 [WS 4 Cu 4 I 6 ] and [( n -Bu) 4 N] 2 [MoOS 3 Cu 3 X 3 ] (X = I, SCN) with Flexible Ditopic Ligands
  113. Construction of a Novel 2D Polymer [Co(dmpzm)(dca)2]∞ from Reaction of a Mononuclear Complex [Co(dmpzm)Cl2] with Sodium Dicyanamide (dca) [dmpzm=bis(3,5-dimethylpyrazolyl)methane]
  114. Toward Rational Construction of Gold, Gold−Silver, and Gold−Mercury String Complexes:  Syntheses, Structures, and Properties of [Au(Tab) 2 ] 2 L 2 (L = I and PF 6 ), {[(Tab) 2 M][Au(CN) 2 ]} 2 (M = Au and Ag), and {[Hg(Tab) 2 ][Au(CN) 2 ] 2 } [Tab = 4...
  115. Synthesis of Two Heterobimetallic Cluster Isomers [(η 5 -C 5 Me 5 ) 2 Mo 2 (μ 3 -S) 3 S(CuI) 2 ] and [(η 5 -C 5 Me 5 ) 2 Mo 2 (μ 3 -S) 4 (CuI) 2 ] from trans -[(η 5 -C 5 Me 5 ) 2 Mo 2 (μ-S) 2 S 2 ] and Their trans -to- cis Isomerization, Structures, a...
  116. Reactions of the pentamethylcyclopentadienyl trisulfido tungsten with M′Cl2 (M′=Zn, Cd, Hg): Isolation and structural characterization of [PPh4][(η5-C5Me5)WS3(ZnCl2)] and [{(η5-C5Me5)WS3}2Hg]
  117. Synthesis and Structural Characterization of Two Lead(II) Complexes of Bis(3,5-dimethylpyrazolyl)methane
  118. Construction of [(η 5 -C 5 Me 5 )WS 3 Cu 3 ]-Based Supramolecular Compounds from Preformed Incomplete Cubane-Like Clusters [PPh 4 ][(η 5 -C 5 Me 5 )WS 3 (CuX) 3 ] (X = CN, Br)
  119. Unique Formation of a Pentanuclear Lanthanum(III) Thiolate Oxide Cluster via Control of Hydrolysis
  120. Assembly of a New Family of Mercury(II) Zwitterionic Thiolate Complexes from a Preformed Compound [Hg(Tab) 2 ](PF 6 ) 2 [Tab = 4-(Trimethylammonio)benzenethiolate]
  121. Syntheses, crystal structures and luminescent properties of two one-dimensional coordination polymers [CuX(dmpzm)]n (X=CN, NCS; dmpzm=bis(3,5-dimethylpyrazolyl)methane)
  122. catena-Poly[[[diaqua[trans-3-(4-pyridyl)acrylato]samarium(III)]-di-μ-trans-3-(4-pyridyl)acrylato] dihydrate]
  123. Formation of new organometallic W/Cu/S clusters from reactions of [{(η5-C5Me5)WS3}3Cu7(MeCN)9](PF6)4 with donor ligands. Crystal structures and optical limiting properties of [(η5-C5Me5)WS3Cu3(Py)6](PF6)2, [(η5-C5Me5)WS3Cu3Br(PPh3)3](PF6), and [(η5-C5M...
  124. Syntheses, crystal structures and luminescent properties of two novel lanthanide/4-pya complexes: [Ln(4-pya)3(H2O)2]2 (Ln=Eu, La; 4-pya=trans-4-pyridylacrylate)
  125. Acetic Acid Induced Self-Assembly of Supramolecular Compounds [Et 4 N] 3 [(WS 4 Cu 2 ) 2 (μ-CN) 3 ]·2MeCN and [PPh 4 ][WS 4 Cu 3 (μ-CN) 2 ]·MeCN from Preformed Clusters [A] 2 [WS 4 (CuCN) 2 ] (A = Et 4 N, PPh 4 )
  126. Construction of Polymeric and Oligomeric Lanthanide(III) Thiolates from Preformed Complexes [(TMS) 2 N] 3 Ln(μ-Cl)Li(THF) 3 (Ln = Pr, Nd, Sm; (TMS) 2 N = Bis(trimethylsilyl)amide)
  127. Syntheses, crystal structures, and third-order nonlinear optical properties of two novel Mo/Cu/S clusters: [MoS4Cu4(α-MePy)5Br2]·2(α-MePy)0.5 and {[MoS4Cu4(α-MePy)3Br](μ-Br)·(α-MePy)}n (α-MePy=α-methylpyridine)
  128. Di-μ-iodo-bis{[1,1′-methylenebis(3,5-dimethyl-1H-pyrazole-κN2)]copper(I)}
  129. Bis[4-(trimethylammonio)phenyl] disulfide tetraiodomercurate(II)
  130. catena-Poly[[bis(pentane-2,4-dionato-κ2O,O′)cobalt(II)]-μ-4,4′-methylenedianiline-κ2N:N′]
  131. Syntheses, crystal structures and catalytic properties of a series of lanthanide(III) bis(trimethylsilyl)amide chloride complexes: [{((Me3Si)2N)2Nd(μ′-Cl)Li(THF)3}(μ-Cl)]2, [{((Me3Si)2N)2Ln(μ′-Cl)Li(THF)2}(μ3-Cl)]2 (Ln=Eu, Ho), and [{(Me3Si)2NLn(μ′-Cl)...
  132. Poly[[silver(I)-μ-4,4′-bipyridine-μ-formato] monohydrate formic acid solvate]