All Stories

  1. Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy2 derivative

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor vincent Louis Pecoraro

  2. Sculpting Metal-binding Environments inDe NovoDesigned Three-helix Bundles

    Article • Israel Journal of Chemistry, January 2015, Wiley

    Professor vincent Louis Pecoraro

  3. Correction: Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy2 derivative

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor vincent Louis Pecoraro

  4. Variable primary coordination environments of Cd(ii) binding to three helix bundles provide a pathway for rapid metal exchange

    Article • Metallomics, January 2015, Oxford University Press (OUP)

    Professor vincent Louis Pecoraro

  5. A De Novo Designed Metalloenzyme for the Hydration of CO 2

    Article • Angewandte Chemie International Edition, June 2014, Wiley

    Professor vincent Louis Pecoraro

  6. A De Novo Designed Metalloenzyme for the Hydration of CO2

    Article • Angewandte Chemie International Edition, June 2014, Wiley

    Professor vincent Louis Pecoraro

  7. Understanding Spin Structure in Metallacrown Single-Molecule Magnets using Magnetic Compton Scattering

    Article • Journal of the American Chemical Society, April 2014, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  8. Highly Emitting Near-Infrared Lanthanide “Encapsulated Sandwich” Metallacrown Complexes with Excitation Shifted Toward Lower Energy

    Article • Journal of the American Chemical Society, January 2014, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  9. Controllable Formation of Heterotrimetallic Coordination Compounds: Systematically Incorporating Lanthanide and Alkali Metal Ions into the Manganese 12-Metallacrown-4 Framework

    Article • Inorganic Chemistry, January 2014, American Chemical Society (ACS)

    Arunpatcha Nimthong, Professor vincent Louis Pecoraro

  10. Isolation of Elusive Tetranuclear and Pentanuclear M(II)–Hydroximate Intermediates in the Assembly of Lanthanide [15-Metallacrown-5] Complexes

    Article • Inorganic Chemistry, May 2013, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  11. Influence of Active Site Location on Catalytic Activity in de Novo -Designed Zinc Metalloenzymes

    Article • Journal of the American Chemical Society, April 2013, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  12. Insight into the structural versatility of the Ln(III)[15-metallacrown-5] platform by comparing analogs with Ni(II), Cu(II), and Zn(II) ring ions

    Article • Polyhedron, March 2013, Elsevier

    Professor vincent Louis Pecoraro

  13. Selective anion encapsulation in solid-state Ln(iii)[15-metallacrown-5]3+ compartments through secondary sphere interactions

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor vincent Louis Pecoraro

  14. Enhanced Guest Affinity and Enantioselectivity through Variation of the Gd 3+ [15-Metallacrown-5] Side Chain

    Article • Inorganic Chemistry, August 2012, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  15. Influencing the Size and Anion Selectivity of Dimeric Ln 3+ [15-Metallacrown-5] Compartments through Systematic Variation of the Host Side Chains and Central Metal

    Article • Inorganic Chemistry, April 2012, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  16. Single Molecule Magnet Behavior of a Pentanuclear Mn-Based Metallacrown Complex: Solid State and Solution Magnetic Studies

    Article • Inorganic Chemistry, November 2011, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  17. Assembly of Near-Infrared Luminescent Lanthanide Host(Host-Guest) Complexes With a Metallacrown Sandwich Motif

    Article • Angewandte Chemie, September 2011, Wiley

    Professor vincent Louis Pecoraro

  18. Assembly of Near-Infrared Luminescent Lanthanide Host(Host-Guest) Complexes With a Metallacrown Sandwich Motif

    Article • Angewandte Chemie International Edition, September 2011, Wiley

    Professor vincent Louis Pecoraro

  19. Gd(III)[15-Metallacrown-5] Recognition of Chiral α-Amino Acid Analogues

    Article • Inorganic Chemistry, June 2011, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  20. A Mixed 3d−4f 14-Metallacrown-5 Complex That Displays Slow Magnetic Relaxation through Geometric Control of Magnetoanisotropy

    Article • Inorganic Chemistry, October 2010, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  21. Cover Picture: Voltammetric Characterization of Redox-Inactive Guest Binding to LnIII[15-Metallacrown-5] Hosts Based on Competition with a Redox Probe (Chem. Eur. J. 23/2010)

    Article • Chemistry - A European Journal, June 2010, Wiley

    Professor vincent Louis Pecoraro

  22. Thermodynamics of Core Metal Replacement and Self-Assembly of Ca 2+ 15-Metallacrown-5 †

    Article • Inorganic Chemistry, June 2010, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  23. Voltammetric Characterization of Redox-Inactive Guest Binding to LnIII[15-Metallacrown-5] Hosts Based on Competition with a Redox Probe

    Article • Chemistry - A European Journal, May 2010, Wiley

    Professor vincent Louis Pecoraro

  24. Disruption of the La(III)[15-Metallacrown-5] Cavity through Bithiophene Dicarboxylate Inclusion

    Article • Zeitschrift für Naturforschung B, March 2010, De Gruyter

    Professor vincent Louis Pecoraro

  25. Chiral Metallacrown Supramolecular Compartments that Template Nanochannels: Self-Assembly and Guest Absorption

    Article • Chemistry - An Asian Journal, January 2010, Wiley

    Professor vincent Louis Pecoraro

  26. Cover Picture: Chiral Metallacrown Supramolecular Compartments that Template Nanochannels: Self-Assembly and Guest Absorption (Chem. Asian J. 1/2010)

    Article • Chemistry - An Asian Journal, January 2010, Wiley

    Professor vincent Louis Pecoraro

  27. Establishing the Binding Affinity of Organic Carboxylates to 15-Metallacrown-5 Complexes

    Article • Inorganic Chemistry, June 2009, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  28. Harnessing natures ability to control metal ion coordination geometry using de novo designed peptides

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Professor vincent Louis Pecoraro

  29. Tuning the Redox Properties of Manganese(II) and Its Implications to the Electrochemistry of Manganese and Iron Superoxide Dismutases

    Article • Inorganic Chemistry, April 2008, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  30. In Search of Elusive High-Valent Manganese Species That Evaluate Mechanisms of Photosynthetic Water Oxidation

    Article • Inorganic Chemistry, March 2008, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  31. Reevaluation of the Kinetics of Polynuclear Mimics for Manganese Catalases

    Article • Inorganic Chemistry, December 2007, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  32. Titelbild: Heterochromia in Designed Metallopeptides: Geometry-Selective Binding of CdII in a De Novo Peptide (Angew. Chem. 35/2007)

    Article • Angewandte Chemie International Edition, September 2007, Wiley

    Professor vincent Louis Pecoraro

  33. Heterochromia in Designed Metallopeptides: Geometry-Selective Binding of CdII in a De Novo Peptide

    Article • Angewandte Chemie, September 2007, Wiley

    Professor vincent Louis Pecoraro

  34. Heterochromia in Designed Metallopeptides: Geometry-Selective Binding of CdII in a De Novo Peptide

    Article • Angewandte Chemie International Edition, September 2007, Wiley

    Professor vincent Louis Pecoraro

  35. Assessing Guest Selectivity within Metallacrown Host Compartments

    Article • European Journal of Inorganic Chemistry, April 2007, Wiley

    Professor vincent Louis Pecoraro

  36. Metallacrown-based compartments: selective encapsulation of three isonicotinate anions in non-centrosymmetric solids

    Article • Chemical Communications, January 2007, Royal Society of Chemistry

    Professor vincent Louis Pecoraro

  37. Insight into the Catalytic Mechanism of Vanadium Haloperoxidases. DFT Investigation of Vanadium Cofactor Reactivity

    Article • Inorganic Chemistry, September 2006, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  38. Quantum Mechanics/Molecular Mechanics Calculations of the Vanadium Dependent Chloroperoxidase

    Article • Journal of Chemical Theory and Computation, November 2005, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  39. Probing metal–protein interactions using a de novo design approach

    Article • Current Opinion in Chemical Biology, April 2005, Elsevier

    Professor vincent Louis Pecoraro

  40. Synthetic and computational modeling of the vanadium-dependent haloperoxidases

    Article • Pure and Applied Chemistry, January 2005, De Gruyter

    Professor vincent Louis Pecoraro

  41. Reactivity of Peroxo Forms of the Vanadium Haloperoxidase Cofactor. A DFT Investigation

    Article • Journal of the American Chemical Society, January 2005, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  42. Understanding Metalloprotein Folding Using a de Novo Design Strategy

    Article • Inorganic Chemistry, December 2004, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  43. Structural, Spectroscopic, and Reactivity Models for the Manganese Catalases

    Article • ChemInform, May 2004, Wiley

    Professor vincent Louis Pecoraro

  44. Structural, Spectroscopic, and Reactivity Models for the Manganese Catalases

    Article • Chemical Reviews, February 2004, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  45. Probing metallopeptide folding mechanisms using de novo design peptides

    Article • Journal of Inorganic Biochemistry, July 2003, Elsevier

    Professor vincent Louis Pecoraro

  46. Preparation of Resolved Fourfold Symmetric Amphiphilic Helices Using Chiral Metallacrown Building Blocks

    Article • Angewandte Chemie, December 2002, Wiley

    Professor vincent Louis Pecoraro

  47. Preparation of Resolved Fourfold Symmetric Amphiphilic Helices Using Chiral Metallacrown Building Blocks

    Article • Angewandte Chemie International Edition, December 2002, Wiley

    Professor vincent Louis Pecoraro

  48. Oxidation of Organic Sulfides by Vanadium Haloperoxidase Model Complexes

    Article • Inorganic Chemistry, December 2002, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  49. Preparation of Highly Efficient Manganese Catalase Mimics ‖

    Article • Inorganic Chemistry, October 2002, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  50. Pseudohalide complexation by manganese 12-metallacrowns-4 complexes

    Article • Inorganica Chimica Acta, March 2002, Elsevier

    Professor Catherine Dendrinou-Samara, Professor vincent Louis Pecoraro

  51. Chiral 15-Metallacrown-5 Complexes Differentially Bind Carboxylate Anions

    Article • Journal of the American Chemical Society, June 2001, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  52. Lanthanide [15]Metallacrown-5 Complexes Form Nitrate-Selective Chiral Cavities

    Article • Angewandte Chemie, August 2000, Wiley

    Professor vincent Louis Pecoraro

  53. Lanthanide [15]Metallacrown-5 Complexes Form Nitrate-Selective Chiral Cavities

    Article • Angewandte Chemie International Edition, August 2000, Wiley

    Professor vincent Louis Pecoraro

  54. Preparation of a Chiral, 2-Dimensional Network Containing Metallacrown and Copper Benzoate Building Blocks

    Article • Inorganic Chemistry, August 2000, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  55. Non-Heme Peroxidases and Catalases: Mechanistic Implications from the Studies of Manganese and Vanadium Model Compounds

    Article • March 2000, World Scientific Pub Co Pte Lt

    Professor vincent Louis Pecoraro

  56. The Preparation, Characterization, and Magnetism of Copper 15-Metallacrown-5 Lanthanide Complexes

    Article • Inorganic Chemistry, June 1999, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  57. Recent advances in the understanding of the biological chemistry of manganese

    Article • Current Opinion in Chemical Biology, April 1999, Elsevier

    Professor vincent Louis Pecoraro

  58. Synthetic Models for Vanadium Haloperoxidases

    Article • December 1998, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  59. Preparation and Characterization of Chiral Copper 12-Metallacrown-4 Complexes, Inorganic Analogues of Tetraphenylporphyrinatocopper(II)

    Article • Inorganic Chemistry, October 1998, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  60. Reactivity of Dioxovanadium(V) Complexes with Hydrogen Peroxide:  Implications for Vanadium Haloperoxidase

    Article • Inorganic Chemistry, March 1998, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  61. Manganese Redox Enzymes and Model Systems: Properties, Structures, and Reactivity

    Article • January 1998, Elsevier

    Professor vincent Louis Pecoraro

  62. Structural and Solution Characterization of Mononuclear Vanadium(IV) Complexes That Help To Elucidate the Active Site Structure of the Reduced Vanadium Haloperoxidases

    Article • Inorganic Chemistry, October 1997, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  63. Modeling the biological chemistry of vanadium: Structural and reactivity studies elucidating biological function

    Article • January 1997, Springer Science + Business Media

    Professor vincent Louis Pecoraro

  64. A Planar[15]Metallacrown-5 That Selectively Binds the Uranyl Cation

    Article • Angewandte Chemie International Edition in English, December 1996, Wiley

    Professor vincent Louis Pecoraro

  65. Reactivity and Mechanism of Manganese Enzymes

    Article • May 1996, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  66. Catalytic Disproportionation of Hydrogen Peroxide by the Tetranuclear Manganese Complex [Mn ll (2-OHpicpn)] 4

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  67. Functional Models for Vanadium Haloperoxidase:  Reactivity and Mechanism of Halide Oxidation

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  68. Facile Preparation of Face Differentiated, Chiral 15-Metallacrown-5 Complexes

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  69. Structural Evaluation and Solution Integrity of Alkali Metal Salt Complexes of the Manganese 12-Metallacrown-4 (12-MC-4) Structural Type

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  70. Synthesis and Crystal Structure of the First Inverse 12-Metallacrown-4

    Article • Inorganic Chemistry, April 1995, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  71. Modeling the Chemistry and Properties of Multinuclear Manganese Enzymes

    Article • January 1995, Springer Science + Business Media

    Professor vincent Louis Pecoraro

  72. Copper(II) 12-Metallacrown-4: Synthesis, Structure, Ligand Variability, and Solution Dynamics in the 12-MC-4 Structural Motif

    Article • Inorganic Chemistry, October 1994, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  73. Interaction of Manganese with Dioxygen and Its Reduced Derivatives

    Article • Chemical Reviews, May 1994, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  74. A functional model for vanadium haloperoxidase

    Article • Journal of the American Chemical Society, April 1994, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  75. Generalizing the metallacrown analogy: ligand variation and solution stability of the VVO 9-metallacrown-3 structure type

    Article • Inorganic Chemistry, December 1993, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  76. [Mn(III)(2-OHsalpn)]2 is an efficient functional model for the manganese catalases

    Article • Journal of the American Chemical Society, August 1993, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  77. High-valent dinuclear manganese complexes as functional models of the catalase-like activity in the oxygen evolving complex

    Article • Journal of Inorganic Biochemistry, July 1993, Elsevier

    Professor vincent Louis Pecoraro

  78. Low valent, dinuclear manganese complexes as functional models for manganese catalases

    Article • Journal of Inorganic Biochemistry, July 1993, Elsevier

    Professor vincent Louis Pecoraro

  79. The synthesis and reactivity of peroxovanadium complexes as models for vanadium haloperoxidase.

    Article • Journal of Inorganic Biochemistry, July 1993, Elsevier

    Professor vincent Louis Pecoraro

  80. The fused metallacrown anion Na2{[Na0.5[Ga(salicylhydroximate)]4]2(.mu.2-OH)4}- is an inorganic analog of a cryptate

    Article • Journal of the American Chemical Society, June 1993, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  81. Structural and magnetic characterization of trinuclear, mixed-valence manganese acetates

    Article • Inorganic Chemistry, December 1992, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  82. Modeling vanadium bromoperoxidase: synthesis, structure, and spectral properties of vanadium(IV) complexes with coordinated imidazole

    Article • Inorganic Chemistry, May 1992, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  83. Structural and spectroscopic characterization of vanadium(V)-oxoimidazole complexes

    Article • Inorganic Chemistry, May 1992, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  84. Manganese-manganese separations in oxide- and alkoxide-bridged complexes: correlation of structure with ligand type and number

    Article • Inorganic Chemistry, February 1992, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  85. Catalytic disproportionation of hydrogen peroxide by manganese complex [Mn(IV)(.mu.2-O)(SALPN)]2

    Article • Journal of the American Chemical Society, September 1991, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  86. Modeling vanadium bromoperoxidase: Synthesis, structure and reactivity of vanadium-imidazole complexes.

    Article • Journal of Inorganic Biochemistry, August 1991, Elsevier

    Professor vincent Louis Pecoraro

  87. The peroxide-dependent .mu.2-O bond formation of manganese complex [Mn(IV)SALPN(O)]2

    Article • Journal of the American Chemical Society, May 1991, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  88. Manganese complexes of .alpha.-hydroxy acids

    Article • Inorganic Chemistry, January 1991, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  89. Development of Metallacrown Ethers: A New Class of Metal Clusters

    Article • Comments on Inorganic Chemistry, December 1990, Taylor & Francis

    Professor vincent Louis Pecoraro

  90. Stepwise, metal-assisted decarboxylation promoted by manganese: reactivity relationship between manganese and vanadium

    Article • Inorganic Chemistry, September 1989, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  91. Structurally diverse manganese(III) Schiff base complexes: chains, dimers, and cages

    Article • Inorganic Chemistry, May 1989, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  92. Structurally diverse manganese(III) Schiff base complexes: solution speciation via paramagnetic proton NMR spectroscopy and electrochemistry

    Article • Inorganic Chemistry, May 1989, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  93. Structural characterization of [VO(salicylhydroximate)(CH3OH)]3: Applications to the biological chemistry of vanadium(V)

    Article • Inorganica Chimica Acta, January 1989, Elsevier

    Professor vincent Louis Pecoraro

  94. Vanadium complexes of the tridentate Schiff base ligand N-salicylidene-N'-(2-hydroxyethyl)ethylenediamine: acid-base and redox conversion between vanadium(IV) and vanadium(V) imino phenolates

    Article • Inorganic Chemistry, December 1988, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  95. STRUCTURAL PROPOSALS FOR THE MANGANESE CENTERS OF THE OXYGEN EVOLVING COMPLEX: AN INORGANIC CHEMIST'S PERSPECTIVE

    Article • Photochemistry and Photobiology, August 1988, Wiley

    Professor vincent Louis Pecoraro

  96. Mononuclear manganese(IV) complexes of hydroxyl-rich Schiff base ligands

    Article • Inorganic Chemistry, July 1987, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  97. Characterization of mono- and binuclear manganese(II) Schiff base complexes with metal-disulfide ligation

    Article • Inorganic Chemistry, February 1987, American Chemical Society (ACS)

    Professor vincent Louis Pecoraro

  98. The acid promoted disproportionation of a vanadium(IV) phenolate: implications for vanadium uptake in tunicates

    Article • Journal of the Chemical Society Chemical Communications, January 1986, Royal Society of Chemistry

    Professor vincent Louis Pecoraro