All Stories

  1. Molecular insights into the selective action of a magnetically removable complexone-grafted adsorbent
  2. Antibacterial and photochemical properties of cellulose nanofiber–titania nanocomposites loaded with two different types of antibiotic medicines
  3. Hybrid silica nanoparticles for sequestration and luminescence detection of trivalent rare-earth ions (Dy3+ and Nd3+) in solution
  4. Ordered Network of Interconnected SnO2 Nanoparticles for Excellent Lithium‐Ion Storage
  5. A family of hexanuclear Mn(III) single-molecule magnets
  6. Molecular design approach to single-source precursors of perovskite stannate materials
  7. General Facile Approach to Transition‐Metal Oxides with Highly Uniform Mesoporosity and Their Application as Adsorbents for Heavy‐Metal‐Ion Sequestration
  8. Study of the curing mechanism of metal alkoxide liquid threads for the synthesis of metal oxide fibers or microtubes
  9. Precursor directed synthesis – “molecular” mechanisms in the Soft Chemistry approaches and their use for template-free synthesis of metal, metal oxide and metal chalcogenide nanoparticles and nanostructures
  10. A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation
  11. Circular serendipity: in situ ligand transformation for the self-assembly of an hexadecametallic [CuII16] wheel
  12. Mesoporous Anatase TiO2 Nanorods as Thermally Robust Anode Materials for Li‐Ion Batteries: Detailed Insight into the Formation Mechanism
  13. Zirconium and hafnium tert-butoxides and tert-butoxo-β-diketonate complexes – Isolation, structural characterization and application in the one-step synthesis of 3D metal oxide nanostructures
  14. Interaction of nickel aminoalkoxide with samarium β-diketonate – Identification of new precursors for MOCVD synthesis of SmNiO3 perovskite films
  15. Solution equilibrium behind the room-temperature synthesis of nanocrystalline titanium dioxide
  16. Facile non-hydrolytic synthesis of highly water dispersible, surfactant free nanoparticles of synthetic MFe2O4 (M–Mn2+, Fe2+, Co2+, Ni2+) ferrite spinel by a modified Bradley reaction
  17. Biocompatible titania hydrogels with chemically triggered release of a photosensitive dye
  18. First principles simulation of reaction steps in the atomic layer deposition of titania: dependence of growth on Lewis acidity of titanocene precursor
  19. High surface area ordered mesoporous nano-titania by a rapid surfactant-free approach
  20. Structural characterization, solution stability, and potential health and environmental effects of the Nano-TiO2 bioencapsulation matrix and the model product of its biodegradation TiBALDH
  21. Visualization of custom-tailored iron oxide nanoparticles chemistry, uptake, and toxicity
  22. Precursor-Directed Assembly of Complex Oxide Nanobeads: The Role of Strongly Coordinated Inorganic Anions
  23. Surface Functionalization of the Metal Oxide Nanoparticles with Biologically Active Molecules Containing Phosphonate Moieties. Case Study of BaTiO3
  24. Crystal Structure and Morphology Evolution in the LaXO3, X = Al, Ga, In Nano-Oxide Series. Consequences for the Synthesis of Luminescent Phosphors
  25. Impact of matrix properties on the survival of freeze‐dried bacteria
  26. Crystal Engineering of Nanomorphology for Complex Oxide Materials via Thermal Decomposition of Metal−Organic Frameworks. Case Study of Sodium Tantalate
  27. High-spin Ni(ii) clusters: triangles and planar tetranuclear complexes
  28. Controlling precursor stability and evaporation through molecular design. Pseudo single source precursor approach to MOCVD SrTiO3 thin films
  29. Straightforward synthesis and structural characterization of the first alkoxy-zircono-silsesquioxanes — Potential models for zirconia–silica epoxidation catalysts
  30. A new concept for titanium oxo-alkoxo-carboxylates’ encapsulated biocompatible time temperature food indicators based on arising, not fading color
  31. Biomimetic Synthesis of Hierarchically Porous Nanostructured Metal Oxide Microparticles—Potential Scaffolds for Drug Delivery and Catalysis
  32. Simple and Efficient Synthesis of a Nd:LaAlO3 NIR Nanophosphor from Rare Earth Alkoxo-Monoaluminates Ln2Al2(OiPr)12(iPrOH)2 Single Source Precursors by Bradley R...
  33. Highly symmetric organic ligand-capped Lindqvist structures derived from 3d-elements
  34. Tripodal Tetrahedral Titanium Coordination in the Silica-Grafted Titania Epoxidation Catalysts: Is Not It Only a Myth? Selective Formation of [Cy7Si7O12Ti]2(μ-OR)2(μ-ROH) Cores on Thermal “Dissocia...
  35. Methodical Thermolysis of [Ba2Ti2(thd)4(OnPr)8(nPrOH)2] under Autogenous Pressure Followed by Combustion for the Synthesis of Dielectric Tetragonal BaTiO3 Nanopowder
  36. The molecular composition of non-modified and acac-modified propoxide and butoxide precursors of zirconium and hafnium dioxides
  37. The chemistry behind the sol–gel synthesis of complex oxide nanoparticles for bio-imaging applications
  38. Transforming the cube: a tetranuclear cobalt(II) cubane cluster and its transformation to a dimer of dimers
  39. Substitution features in the isomorphous replacement series for metal-organic compounds (NbxTa1−x)4O2(OMe)14(ReO4)2, x=0.7, 0.5, 0.3—Single-source precursors of complex oxides with organized porosity
  40. Chemically Triggered Biodelivery Using Metal–Organic Sol–Gel Synthesis
  41. Chemically Triggered Biodelivery Using Metal–Organic Sol–Gel Synthesis
  42. Sol–gel routes for microporous zirconia and titania membranes
  43. Synthesis of highly sterically hindered niobium and tantalum alkoxides and their microhydrolysis in strongly basic medium
  44. Electrochemical Synthesis, Structural Characterization, and Decomposition of Rhenium Oxoethoxide, Re4O4(OEt)12. Ligand Influence on the Structure and Bonding in the High-Valent Tetranuclear Planar Rhenium Alkoxide Clusters
  45. Heteroleptic metal alkoxide “oxoclusters” as molecular models for the sol–gel synthesis of perovskite nanoparticles for bio-imaging applications
  46. Oxoethoxide Chlorides – Representatives of Oligonuclear Alkoxide Complexes of Gallium: Penta‐ and Dodecanuclear Molecules
  47. Molecular structure design of single source precursors and multivariate analysis of their evaporation in dynamic vacuum using EI-Mass spectrometry. An approach to Barium–Strontium Titanate–Niobate as a case study
  48. Isolation and single crystal study of [Nb2(μ-OMe)2(OiPr)8]. Can alcohol interchange provide the homoleptic niobium isopropoxide?
  49. Nona-coordinated MO6N3 centers M=Zr, Hf as a stable building block for the construction of heterometallic alkoxide precursors
  50. Molecular design approach to a highly soluble and volatile bimetallic alkoxide of late transition metal and zirconium. Synthesis, X-ray single crystal and mass-spectral study of NiZr2(acac)(OiPr)9
  51. Mesoporous Nanocrystalline Mixed Metal Oxides from Heterometallic Alkoxide Precursors: Cobalt–Nickel Oxide Spinels for Propane Oxidation
  52. Interaction of barium oxide and hydroxide with methanol: X-ray single crystal study of Ba(OH)2 methanol solvates
  53. New insight in the role of modifying ligands in the sol-gel processing of metal alkoxide precursors: A possibility to approach new classes of materials
  54. Synthesis and characterization of a large heterometallic alkoxide cation: Self-assembly and rational route to
  55. Chemistry of 2,2,6,6,-Tetramethyl-3,5-heptanedione (Hthd) Modification of Zirconium and Hafnium Propoxide Precursors
  56. A Single‐Source‐Precursor Approach to Late Transition Metal Molybdate Materials: The Structural Role of Chelating Ligands in the Formation of Heterometallic Heteroleptic Alkoxide Complexes
  57. Growth of carbon sausages filled with in situ formed tungsten oxide nanorods: thermal dissociation of tungsten(vi) isopropoxide in isopropanol
  58. The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide
  59. Bis-silsesquioxane complex as a molecular model of transition metal oxide–zeolite nanocomposite
  60. Stabilization of Metastable Face-Centered Cubic Cobalt and the Tetragonal Phase of Zirconia by a Carbon Shell:  Reaction under Autogenic Pressure at Elevated Temperature of CoZr2(acac)2(OiPr)8
  61. Powders and dense thin films of late transition metal oxide nanocomposites from structurally characterized single-source precursorsElectronic supplementary information (ESI) available: further figures and crystallographic details. See http://www.rsc.or...
  62. Isolation, X-ray single crystal and theoretical study of quinquevalent metal oxoisopropoxides, Nb6O8(iPrO)14(iPrOH)2 and Re4O6(OiPr)10
  63. Influence of heteroligands on the composition, structure and properties of homo- and heterometallic zirconium alkoxides. Decisive role of thermodynamic factors in their self-assembly
  64. Stabilization and destabilization of zirconium propoxide precursors by acetylacetoneElectronic supplementary information (ESI) available: summary of 1H NMR spectra and CIF files for compounds 1 and 2. See http://www.rsc.org/suppdata/cc/b4/b406012a/
  65. Structure of the hydrated, hydrolysed and solvated zirconium(iv) and hafnium(iv) ions in water and aprotic oxygen donor solvents. A crystallographic, EXAFS spectroscopic and large angle X-ray scattering study
  66. Purposeful construction versus self-assembly in approaches to single source precursors of spinel materials. Synthesis, structure and stability studies of MiiAl2(acac)3(OiPr)4(OAc), Mii= Mn, Co, Zn ? a new class of heterometallic heteroleptic alkoxide c...
  67. The discovery of the N,N-dimethylthioformamidium ion. A structural study of {(CH3)2NCHSH}2[HfCl6] in solid state and solutionElectronic supplementary information (ESI) available: 7 tables and 5 figures of IR, EXAFS and X-ray data as described in the te...
  68. Interaction of some divalent metal acetylacetonates with Al, Ti, Nb and Ta isopropoxides. Factors influencing the formation and stability of heterometallic alkoxide complexesElectronic supplementary information (ESI) available: synthesis details for 5–...
  69. Molecular structure design and synthetic approaches to the heterometallic alkoxide complexes (soft chemistry approach to inorganic materials by the eyes of a crystallographer)
  70. The sonochemical preparation of lamellar MoOx
  71. Solution interaction of O-donor ligand metal complexes with thiocarbonyl compounds—a new general route to metal sulfide materials
  72. Design and synthesis of multifunctional thiacalixarenes and related metal derivatives for the preparation of sol–gel hybrid materials with non-linear optical properties
  73. Synthesis and Structure of the First FeII Heterometallic Alkoxide [(THF)NaFe(OtBu)3]2 − a Possible Precursor for New Materials
  74. Perrhenate ligand as an analog of the methoxide group in alkoxide complexes. Synthesis and X-ray single crystal study of Ta2(OMe)8(ReO4)2
  75. A convenient route to anionic and cyclic aluminosiloxanes: crystal structures of [PyH][Al{OSiPh2(OSiPh2)2O}2] and the first twelve-membered organic aluminosilicate Al2Si4O6 ring
  76. Interaction of Co(acac)2 and Ta(OMe)5: isolation and single crystal study of the products. MII2MV2(acac)2(OMe)12, MII = Co, Ni, Zn or Mg and MV = Ta or Nb: A new class of heterometallic heteroleptic alkoxide complexes
  77. Synthesis and X-ray single crystal study of the bi- and trimetallic alkoxides of molybdenum(VI) and tantalum, Mo2Ta4O8(OMe)16, Mo4Ta4O16(OiPr)12 and LiMo4Ta3O14(OiPr)9(OC2H4OMe)3
  78. The mystery of VO(OEt)3 conversion on microhydrolysis disclosed: the X-ray single crystal study of V6O7(OEt)12
  79. The solution thermolysis approach to molybdenum(V) alkoxides: synthesis, solid state and solution structures of the bimetallic alkoxides of molybdenum(V) and niobium(V), tantalum(V) and tungsten(VI)
  80. MoO(OiPr)4 decomposition pathways on ageing: spontaneous and nearly quantitative transformation into Mo6O10(OiPr)12
  81. A new argument in favor of the ether elimination mechanism: formation of acetals on action of molybdenum alkoxides on carbonyl compounds
  82. Anodic oxidation of molybdenum and tungsten in alcohols: isolation and X-ray single-crystal study of side products
  83. Synthesis, X-ray structure and thermal decomposition of lanthanum [dioxoisopropoxomolybdate] [La2Mo4O4(μ4-O)4(μ-OPri)8(Opri)6]
  84. Synthesis, crystal, molecular and electronic structure of a novel heterobinuclear alkoxide cluster [(MeO)2ReO(µ-OMe)3MoO(OMe)2]
  85. Single-source Precursors for BaTiO3: Synthesis and Characterization of .beta.-Diketonato Alkoxides and Molecular Structure of Ba2Ti2(thd)4(.mu.3-OEt)2(.mu.-OEt)4(OEt)2(EtOH)2
  86. The synthesis, crystal and molecular structures of bimetallic ethoxides of barium and titanium, and calcium and titanium: [M{Ti2(µ3-OEt)2(µ-OEt)3(OEt)4}2](M = Ca, Ba)
  87. Reactions of coordinated ligands: topological and stoichiometric control for mixed-metal alkoxides: synthesis and molecular structure of [La{(OC2H4)3N}2{Nb(OPri)4}3]
  88. The synthesis and X-ray crystal structure of molybdenum oxomethoxide [MoO(OMe)4]2
  89. Synthesis, crystal and molecular structure of calcium oxo ethoxide, [Ca6(µ4-O)2(µ3-OEt)4(OEt)4]·14EtOH