All Stories

  1. Elucidating ligand effects in rhodium(III)-catalyzed arene-alkene coupling reactions
  2. Well-Defined Rhodium Diphenylphosphine Oxide Complexes Relevant to Rh(III)-Catalyzed Aryl C–H Phosphorylation
  3. Cyclometalated Platinum(II) Metallomesogens Based on Half-Disc-Shaped β-Diketonate Ligands with Hexacatenar: Crystal Structures, Mesophase Properties, and Semiconductor Devices
  4. Synthesis and characterization of rhena[10]annulynes
  5. Trisulfur radical anion-triggered stitching thienannulation: rapid access to largely π-extended thienoacenes
  6. Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity
  7. Innenrücktitelbild: Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination (Angew. Chem. 47/2019)
  8. Inside Back Cover: Scalable Rhodium(III)-Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination (Angew. Chem. Int. Ed. 47/2019)
  9. Scalable Rhodium(III)-Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination
  10. Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination
  11. Dual Effects of Cyclopentadienyl Ligands on Rh(III)-Catalyzed Dehydrogenative Arylation of Electron-Rich Alkenes
  12. Efficient endo Cycloisomerization of Terminal Alkynols Catalyzed by a New Ruthenium Complex with 8-(Diphenylphosphino)quinoline Ligand and Mechanistic Investigation
  13. Rh(iii)-Catalyzed regio- and stereoselective bisindolylation of vinyl acetate: an efficient approach toward (E)-1,2-bis(2-indolyl)ethenes
  14. Ruthenium and Osmium Germyl Complexes Derived from the Reactions of MXCl(PPh3 )3 (M = Ru, Os; X = Cl, H) with Terphenylchlorogermylene (C6 H3 -2,6-Trip2 )GeCl (Trip = 2,4,6-i Pr3 C6 H2 )
  15. β-Diketiminato-Germylene Complexes of Carbonyl Ruthenium: Synthesis, Structure, and Reactivity
  16. Alkenylcarbyne Complexes Derived from the Reactions of OsXCl-(PPh3)3(X=H,Cl) with Propargyl Chloride and Phosphine Ligand-Controlled Transformation of Hydride-Carbyne to Carbene
  17. Rhodium-Catalyzed β-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C–H Activation
  18. ChemInform Abstract: Rhodium-Catalyzed/Copper-Mediated Selective C2 Alkynylation of Indoles and C1 Alkynylation of Carbazoles with γ-Substituted tert-Propargyl Alcohols.
  19. Rhodium-Catalyzed/Copper-Mediated Selective C2 Alkynylation of Indoles and C1 Alkynylation of Carbazoles withγ-Substitutedtert-Propargyl Alcohols
  20. ChemInform Abstract: Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes.
  21. Synthesis of α-Aminonaphthalenes via Copper-Catalyzed Aminobenzannulation of (o-Alkynyl)arylketones with Amines
  22. Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes
  23. Construction of Isoquinolin-1(2H)-ones by Copper-Catalyzed Tandem Reactions of 2-(1-Alkynyl)benzaldimines with Water
  24. Half-Sandwich B-Oxy Boratabenzene Ruthenium Complexes: Synthesis, Characterization, and Reactivity of (η6-C5H5BOR)RuCl(PPh3)2 (R = Et, Me)
  25. Palladium-Catalyzed Direct C2- and Further C7-Acylation of Indoles with Aldehydes
  26. Highly Active Gold(I)–Silver(I) Oxo Cluster Activating sp3 C–H Bonds of Methyl Ketones under Mild Conditions
  27. Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics
  28. Rearrangement of Metallabenzynes to Chlorocyclopentadienyl Complexes
  29. Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides
  30. Rh/Cu-catalyzed multiple C–H, C–C, and C–N bond cleavage: facile synthesis of pyrido[2,1-a]indoles from 1-(pyridin-2-yl)-1H-indoles and γ-substituted propargyl alcohols
  31. Correction: Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides
  32. Rh(III)-Catalyzed Oxidative Coupling of Benzoic Acids with Geminal-Substituted Vinyl Acetates: Synthesis of 3-Substituted Isocoumarins
  33. ChemInform Abstract: Copper-Catalyzed Solvent-Free Redox Condensation of Benzothiazoles with Aldehydes or Benzylic Alcohols.
  34. Copper-catalyzed solvent-free redox condensation of benzothiazoles with aldehydes or benzylic alcohols
  35. Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes
  36. Stabilization of anti-aromatic and strained five-membered rings with a transition metal
  37. Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization
  38. A half-sandwich 1,2-azaborolyl ruthenium complex: synthesis, characterization, and evaluation of its catalytic activities
  39. Synthesis and Organometallic Properties of Several Osmium Alkenylcarbyne Complexes
  40. From Osmium Hydrido Vinylidene to Osmacycles: The Key Role of Osmabutadiene Intermediates
  41. A rhodamine-deoxylactam based sensor for chromo-fluorogenic detection of nerve agent simulant
  42. Electrophilic Substitution Reactions of Metallabenzynes
  43. Mechanism Investigations of the Endo Cycloisomerization of Alkynols through Isolation and Characterization of Ruthenium Complexes from the Reactions of Alkynes with a Ruthenium Complex
  44. pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene withL- andD-Cysteine
  45. Dimethyl (E)-2-(N-phenylacetamido)but-2-enedioate
  46. cis-Dichloridotetrakis(trimethylphosphane-κP)ruthenium(II) benzene disolvate
  47. Mononuclear Bis(imino)arylcopper(I) N-Heterocyclic Carbene Complex: Synthesis, Structure, and Reaction with Organic Azide
  48. C−H Bond Activation and Subsequent C(sp2)−C(sp3) Bond Formation: Coupling of Bromomethyl and Triphenylphosphine in an Iridium Complex
  49. Synthesis, Characterization, and Electrochemical Properties of Bisosmabenzenes Bridged by Diisocyanides
  50. Selective and Efficient Cycloisomerization of Alkynols Catalyzed by a New Ruthenium Complex with a Tetradentate Nitrogen-Phosphorus Mixed Ligand
  51. Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes
  52. Synthesis of an osmafuran from photochemical hydrolysis of OsCl2(CHC(PPh3)C(O)-η2-CHCH2)(PPh3)2
  53. Visual and fluorogenic detection of a nerve agent simulant via a Lossen rearrangement of rhodamine–hydroxamate
  54. Dichlorido(η4-cycloocta-1,5-diene)bis(triphenylphosphine)osmium(II)
  55. Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole
  56. Osmapyridine and Osmapyridinium from a Formal [4+2] Cycloaddition Reaction
  57. Selective Synthesis of Osmanaphthalene and Osmanaphthalyne by Intramolecular CH Activation
  58. Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin
  59. Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3Substituents
  60. Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran
  61. Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-Coordinated Alkyne Alcohol Complex
  62. Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction
  63. Synthesis and Characterization of an Air-Stablep-Osmaphenol
  64. A Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne Complex
  65. Coupling Reactions of an Allenylcarbene Complex with Alkynes and Styrene
  66. Cyclometalation of 2-Vinylpyridine with MCl2(PPh3)3and MHCl(PPh3)3(M = Ru, Os)
  67. Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
  68. Synthesis and characterization of a bimetallic iridium complex with a ten sp2-carbon chain bridge
  69. Osmabenzenes from the Reactions of a Dicationic Osmabenzyne Complex
  70. Osmium-Mediated Hexamerization of Phenylacetylene
  71. Osmium-Mediated Hexamerization of Phenylacetylene
  72. Synthesis and Characterization of Stable Ruthenabenzenes
  73. A Neutron Diffraction Study of [OsClH3(PPh3)3]: A Complex Containing a Highly “Stretched” Dihydrogen Ligand
  74. Synthesis and Photophysical Properties of Trimetallic Acetylide Complexes with a 1,3,5-Triazine Core
  75. Syntheses of Metallabenzynes from an Allenylcarbene Complex
  76. Synthesis and Characterization of C10H10-Bridged Bimetallic Ruthenium Complexes
  77. Synthesis and Characterization of Trimetallic Ruthenium and Bimetallic Osmium Complexes with Metal−Vinyl Linkages
  78. Synthesis and Characterization of [OsCl2(=C=CHR)(PPh3)2] and Related Complexes
  79. Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3(X = Cl, Br)
  80. Vinylidene, Allenylidene, and Carbyne Complexes from the Reactions of [OsCl2(PPh3)3] with HC⋮CC(OH)Ph2
  81. Coupling Reaction of Phenylacetylene with OsHn(PPh3)(2,6-(PPh2CH2)2C6H3) (n= 1, 3)
  82. Theoretical Studies on the Stabilities of Metallabenzynes
  83. Comparative Study on the Reactivity of H2, PhCHCH2, and PhC⋮CMe with [Cp*Ru(H2O)(NBD)]+
  84. Synthesis and Characterization of Bimetallic Ruthenium Complexes with (CH)6and Related Bridges
  85. Protonation and Bromination of an Osmabenzyne:  Reactions Leading to the Formation of New Metallabenzynes
  86. Synthesis and Characterization of Linear (CH)8-Bridged Bimetallic Ruthenium Complexes
  87. Synthesis and Protonation of [RuH(NBD)(2,6-(Ph2PCH2)2C6H3)]
  88. Reactions of hydrogen with ruthenium and osmium complexes containing tridentate ligands Cy2PCH2CH(CH2)2PCy2 and 2,6-(Ph2PCH2)2C6H3
  89. Protonation Reactions of [MH(Cl)(PPh3)2(norbornadiene)] (M = Ru, Os)
  90. Syntheses, structures and magnetic properties of mono- and di-manganese inclusion compounds
  91. Synthesis and Characterization of a Metallabenzyne
  92. Preparation, Characterization, and Reactivity of an Osmium Alkenyl Dihydrogen Complex
  93. Theoretical Studies of Rotational Barriers of Vinylidene Ligands in the Five-Coordinate Complexes M(X)Cl(CCHR)L2(M = Os, Ru; L = Phosphine)
  94. Reactions of MH(OTf)(NBD)(PPh3)2(M = Ru, Os) with H2
  95. Isomerization of CH3C⋮CPh to Phenylallene Promoted by an Osmium Hydride Complex
  96. Unexpected Formation of Osmium Carbyne and Vinylidene Complexes from the Reaction of OsCl2(PPh3)3with HC⋮CCMe3
  97. Vinylidene and Carbyne Complexes Derived from the Reactions of OsCl(PPh3)(PCP) (PCP = 2,6-(PPh2CH2)2C6H3) with Terminal Acetylenes
  98. Structure and characterization of a mononuclear FeII dialkyldithiocarbamate complex Fe(OC4H8dtc)2(DMF)
  99. 1,2:3,4:5,6-Tri-O-isopropylidene-D-mannitol
  100. A Novel Molybdenum−Iron−Sulfur Cluster. Synthesis, Structure, and Properties of [Et4N]2[MoFe4S4(SC6H11)7]·1/2CH3CN
  101. Chemistry of tripodal ligands. Part III.
  102. Chemistry ofo-Mercaptophenolate: Syntheses, Structures, and Characterization of Titanium(IV) Complexes
  103. Reaction of transition metal thiolato units V. Formation of a binuclear mercury(II) complex with the dithiolato ligand i-mnt (1,1-dicyanoethylene-2,2-dithiolate)
  104. Synthesis and structure of a novel MoFe4S4 cubane-like cluster (Me3PhCH2N)2 [MoFe4S4 (SC6H11)7]
  105. Studies on the Synthetic System of V/Ag/S Cluster Compounds and Structural Characterizations of V2AgS4, V2Ag2S4, and V2O2(μ-S)2Complexes
  106. A novel network of bis(2-mercapto-3-pyridinol)oxovanadium(IV)_ based on hydrogenbond interactions: synthesis, structure and EPR spectroscopic properties
  107. A TITANIUM(IV) DIMER COMPLEX CONTAINING TRLS(2-MERCAPTOPHENOLATO)TITANIUM(IV) FRAGMENTS LINKED BY SODIUM IONS. SYNTHESIS, STRUCTURE AND CHARACTERIZATION OF (Et4N)2[Ti(mp)3Na(MeOH)2]2(H2mp = 2-MERCAPTOPHENOL)
  108. CHIRAL PHOSPHINE LIGANDS DERIVED FROM SUGARS. 8. SYNTHESES OF GOLD(I) COMPLEXES CONTAINING CHIRAL SUGAR PHOSPHINES AND PYRIDINE-1-OXIDE-2-THIOLATE
  109. Chiral phosphine ligands derived from sugars-6. syntheses and spectroscopic studies on rhodium complexes with a new type of chiral phosphines
  110. Tris(2-sulfidopyridine N-oxide-O,S)chromium(III) Acetone Solvate (1/1)
  111. Alkyne activation and carbon-carbon bond formation mediated by osmium complexes