All Stories

  1. Article
    The unanticipated oxidation of a tertiary amine in a tetracyclic glyoxal-cyclam condensate yielding zinc(II) coordinated to a sterically hindered amine oxide
    Professor Timothy J Hubin
  2. Article
    trans-IV restriction: a new configuration for metal bis-cyclam complexes as potent CXCR4 inhibitors
    Professor Timothy J Hubin
  3. Article
    Earth Abundant Oxidation Catalysts for Removal of Contaminants of Emerging Concern from Wastewater: Homogeneous Catalytic Screening of Monomeric Complexes
    Professor Timothy J Hubin
  4. Article
    A Bridge too Far? Comparison of Transition Metal Complexes of Dibenzyltetraazamacrocycles with and without Ethylene Cross-Bridges: X-ray Crystal Structures, Kinetic Stability, and Electronic Properties
    Professor Timothy J Hubin
  5. Article
    Synthesis and Characterization of Late Transition Metal Complexes of Mono-Acetate Pendant Armed Ethylene Cross-Bridged Tetraazamacrocycles with Promise as Oxidation Catalysts for Dye Bleaching
    Professor Timothy J Hubin
  6. Article
    Zinc-based cyclens containing pyridine and cross-bridges: X-ray and DFT structures, Lewis acidity, gas-phase acidity, and pKa values
    Professor Timothy J Hubin
  7. Article
    Expanding and quantifying the crystal chemistry of the flexible ligand 15aneN5
    Professor Timothy J Hubin
  8. Article
    Mechanistic Insights into Iron-Catalyzed C–H Bond Activation and C–C Coupling
    Professor Timothy J Hubin
  9. Article
    An ethylene cross-bridged pentaazamacrocycle and its Cu2+ complex: constrained ligand topology and excellent kinetic stability
    Professor Timothy J Hubin
  10. Article
    64Cu PET Imaging of the CXCR4 Chemokine Receptor Using a Cross-Bridged Cyclam Bis-Tetraazamacrocyclic Antagonist
    Professor Timothy J Hubin
  11. Article
    Tetraazamacrocyclic derivatives and their metal complexes as antileishmanial leads
    Professor Timothy J Hubin
  12. Article
    Acetate as a model for aspartate-based CXCR4 chemokine receptor binding of cobalt and nickel complexes of cross-bridged tetraazamacrocycles
    Professor Timothy J Hubin
  13. Article
    Increase of Direct C–C Coupling Reaction Yield by Identifying Structural and Electronic Properties of High-Spin Iron Tetra-azamacrocyclic Complexes
    Professor Timothy J Hubin
  14. Article
    Isosteric and Spatial Considerations of Drugs
    Professor Timothy J Hubin
  15. Article
    Synthesis and structural studies of two pyridine-armed reinforced cyclen chelators and their transition metal complexes
    Professor Timothy J Hubin
  16. Article
    Aspartate-Based CXCR4 Chemokine Receptor Binding of Cross-Bridged Tetraazamacrocyclic Copper(II) and Zinc(II) Complexes
    Professor Timothy J Hubin
  17. Article
    Discovery of Antischistosomal Drug Leads Based on Tetraazamacrocyclic Derivatives and Their Metal Complexes
    Professor Timothy J Hubin
  18. Article
    Probing the Limits of Tetraazamacrocycle-Glyoxal Condensates as Bidentate Ligands for Cu2+
    Professor Timothy J Hubin
  19. Article
    Synthesis, structural studies, and oxidation catalysis of the manganese(II), iron(II), and copper(II) complexes of a 2-pyridylmethyl pendant armed side-bridged cyclam
    Professor Timothy J Hubin
  20. Article
    Crystal structure of dichlorido(4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane)iron(III) hexafluoridophosphate
    Dr Timothy J PriorProfessor Timothy J Hubin
  21. Article
    IL-24 Inhibits Lung Cancer Cell Migration and Invasion by Disrupting The SDF-1/CXCR4 Signaling Axis
    Professor Timothy J Hubin
  22. Article
    Synthesis, Structural Studies, and Oxidation Catalysis of the Late-First-Row-Transition-Metal Complexes of a 2-Pyridylmethyl Pendant-Armed Ethylene Cross-Bridged Cyclam
    Professor Timothy J Hubin
  23. Article
    Synthesis, structural studies, kinetic stability, and oxidation catalysis of the late first row transition metal complexes of 4,10-dimethyl-1,4,7,10-tetraazabicyclo[6.5.2]pentadecane
    Professor Timothy J Hubin
  24. Article
    Influence of Calcium(II) and Chloride on the Oxidative Reactivity of a Manganese(II) Complex of a Cross-Bridged Cyclen Ligand
    Professor Timothy J Hubin
  25. Article
    Synthesis of Novel Tetraazamacrocyclic Bisquinoline Derivatives as Potential Antimalarial Agents
    Professor Timothy J Hubin
  26. Article
    Crystal structures of two cross-bridged chromium(III) tetraazamacrocycles
    Dr Timothy J PriorProfessor Timothy J Hubin
  27. Article
    Synthesis and antimalarial activity of metal complexes of cross-bridged tetraazamacrocyclic ligands
    Professor Timothy J Hubin
  28. Article
    Copper(I) and copper(II) complexes with pyrazine-containing pyridylalkylamide ligands N-(pyridin-2-ylmethyl)pyrazine-2-carboxamide and N-(2-(pyridin-2-yl)ethyl)pyrazine-2-carboxamide
    Professor Timothy J Hubin
  29. Article
    CXCR4 chemokine receptor antagonists: nickel(ii) complexes of configurationally restricted macrocycles
    Steve ArchibaldProfessor Timothy J Hubin
  30. Article
    Preparations and applications of synthetic linked azamacrocycle ligands and complexes
    Professor Timothy J Hubin
  31. Article
    ChemInform Abstract: Template Control of Supramolecular Architecture
    Professor Timothy J Hubin
  32. Article
    ChemInform Abstract: An o-Xylyl Cross-Bridged 5,12-Dioxocyclam.
    Professor Timothy J Hubin
  33. Article
    CXCR4 Chemokine Receptor Antagonists from Ultra-rigid Metal Complexes Profoundly Inhibit HIV-1 Replication, and also AMD3100-resistant Strains
    Steve ArchibaldProfessor Timothy J Hubin
  34. Article
    CXCR4 Antagonists: A New Generation of Configurationally Restricted Bis-azamacrocyclic Compounds
    Steve ArchibaldProfessor Timothy J Hubin
  35. Article
    Synthesis and characterization of the chromium(III) complexes of ethylene cross-bridged cyclam and cyclen ligands
    Steve ArchibaldProfessor Timothy J Hubin
  36. Article
    Binding Optimization through Coordination Chemistry: CXCR4 Chemokine Receptor Antagonists from Ultrarigid Metal Complexes
    Steve ArchibaldProfessor Timothy J Hubin
  37. Article
    The design and synthesis of pyrazine amide ligands suitable for the “tiles” approach to molecular weaving with octahedral metal ions
    Steve ArchibaldProfessor Timothy J Hubin
  38. Article
    Dichloro(4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetradecane)iron(III) hexafluorophosphate
    Professor Timothy J Hubin
  39. Article
    Configurationally Restricted Bismacrocyclic CXCR4 Receptor Antagonists
    Steve ArchibaldProfessor Timothy J Hubin
  40. Article
    Synthesis and characterization of the cobalt(III) complexes of two pendant-arm cross-bridged cyclams
    Steve ArchibaldProfessor Timothy J Hubin
  41. Article
    Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediateElectronic supplementary information (ESI) available: Experimental, crystallographic and computational details. See http://...
    Steve ArchibaldProfessor Timothy J Hubin
  42. Article
    Synthesis and coordination chemistry of topologically constrained azamacrocycles
    Professor Timothy J Hubin
  43. Article
    Synthesis, structure, and stability in acid of copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocycles
    Professor Timothy J Hubin
  44. Article
    Synthesis and X-ray crystal structures of iron(II) and manganese(II) complexes of unsubstituted and benzyl substituted cross-bridged tetraazamacrocycles
    Professor Timothy J Hubin
  45. Article
    Synthesis and X-ray Crystal Structure Determination of the First Copper(II) Complexes of Tetraazamacrocycle−Glyoxal Condensates
    Professor Timothy J Hubin
  46. Article
    Synthesis, characterization, and X-ray crystal structures of cobalt(II) and cobalt(III) complexes of four topologically constrained tetraazamacrocycles
    Professor Timothy J Hubin
  47. Article
    trans-Dioxocyclam (1,4,8,11-tetraazacyclotetradecane-2,9-dione) dihydrate and its NiIIcomplex
    Professor Timothy J Hubin
  48. Article
    Potentiometric Titrations and Nickel(II) Complexes of Four Topologically Constrained Tetraazamacrocycles
    Professor Timothy J Hubin
  49. Article
    SYNTHESIS AND CHARACTERIZATION OF THE NOVEL BRIDGED LIGAND 5,8-DIMETHYL-1,5,8,12-TETRAAZABICYCLO[10.3.2]HEPTADECANE AND ITS COMPLEXES WITH IRON(II) AND MANAGANESE(II) IONS
    Professor Timothy J Hubin
  50. Article
    Topologically Constrained Manganese(III) and Iron(III) Complexes of Two Cross-Bridged Tetraazamacrocycles
    Professor Timothy J Hubin
  51. Article
    Template routes to interlocked molecular structures and orderly molecular entanglements
    Professor Timothy J Hubin
  52. Article
    New Iron(II) and Manganese(II) Complexes of Two Ultra-Rigid, Cross-Bridged Tetraazamacrocycles for Catalysis and Biomimicry
    Professor Timothy J Hubin
  53. Article
    Copper(I) and copper(II) complexes of an ethylene cross-bridged cyclam
    Professor Timothy J Hubin
  54. Article
    A cyclam-like macrocycle side-bridged by a propyl chain
    Professor Timothy J Hubin
  55. Article
    Ano-xylyl cross-bridged 5,12-dioxocyclam
    Professor Timothy J Hubin
  56. Article
    Crystallographic Characterization of Stepwise Changes in Ligand Conformations as Their Internal Topology Changes and Two Novel Cross-Bridged Tetraazamacrocyclic Copper(II) Complexes
    Professor Timothy J Hubin
  57. Article
    The square-pyramidal PdIIcomplex of a cross-bridged tetraazamacrocycle
    Professor Timothy J Hubin
  58. Article
    Template control of supramolecular architecture
    Professor Timothy J Hubin
  59. Article
    Synthesis and X-ray Crystal Structure Determination of the First Transition Metal Complexes of the Tetracycles Formed by Tetraazamacrocycle−Glyoxal Condensation:  PdL*Cl 2 (L = Cyclam−Glyoxal Condensate ( 1 ), Cyclen−Glyoxal Condensate ( 2 ))
    Professor Timothy J Hubin
  60. Article
    Ultra rigid cross-bridged tetraazamacrocycles as ligands—the challenge and the solution
    Professor Timothy J Hubin