All Stories

  1. Synthesis and Functionalization of a 1,2-Bis(trimethylsilyl)-1,2-disilacyclohexene That Can Serve as a Unit of cis-1,2-Dialkyldisilene

    Article • Inorganics, January 2018, MDPI AG

    Professor Takeaki Iwamoto

  2. Synthesis and Functionalization of a 1,4-Bis(trimethylsilyl)tetrasila-1,3-diene through the Selective Cleavage of Si(sp2)–Si(sp3) Bonds under Mild Reaction Conditions

    Article • Organometallics, January 2018, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  3. Facile synthesis and bridgehead-functionalization of bicyclo[3.3.3]pentasiloxanes

    Article • Chemical Communications, January 2018, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  4. Stable Push–Pull Disilene: Substantial Donor–Acceptor Interactions through the Si═Si Double Bond

    Article • Journal of the American Chemical Society, December 2017, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  5. Benzodisilacyclobutadienes: 8π-Electron Systems with an Antiaromatic Silicon Ring

    Article • Angewandte Chemie International Edition, October 2017, Wiley

    Professor Takeaki Iwamoto

  6. Benzodisilacyclobutadienes: 8π-Electron Systems with an Antiaromatic Silicon Ring

    Article • Angewandte Chemie International Edition, October 2017, Wiley

    Professor Takeaki Iwamoto

  7. Tethered 1,2-Si-Group Migrations in Radical-Mediated Ring Enlargements of Cyclic Alkoxysilanes: An EPR Spectroscopic and Computational Investigation

    Article • The Journal of Organic Chemistry, June 2017, American Chemical Society (ACS)

    Professor Takeaki Iwamoto, Dr John C. Walton

  8. An Isolable Potassium Salt of a Borasilene-Chloride Adduct

    Article • Angewandte Chemie International Edition, March 2017, Wiley

    Professor Takeaki Iwamoto

  9. Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene

    Article • Angewandte Chemie International Edition, January 2017, Wiley

    Professor Takeaki Iwamoto

  10. Pentasila-1,4-diene: Homoconjugation between Si═Si Double Bonds via a SiMe2 Unit

    Article • Journal of the American Chemical Society, January 2017, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  11. A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: synthesis, molecular structure, and catalytic hydrosilylation activity

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  12. Heteroaryldisilenes: heteroaryl groups serve as electron acceptors for SiSi double bonds in intramolecular charge transfer transitions

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  13. A Dialkylsilylene-Pt(0) Complex with a DVTMS Ligand for the Catalytic Hydrosilylation of Functional Olefins

    Article • Organometallics, December 2016, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  14. A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity

    Article • Angewandte Chemie, November 2016, Wiley

    Professor Takeaki Iwamoto

  15. A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity

    Article • Angewandte Chemie International Edition, November 2016, Wiley

    Professor Takeaki Iwamoto

  16. A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene

    Article • Angewandte Chemie International Edition, August 2016, Wiley

    Professor Takeaki Iwamoto

  17. Recent advances in η2-disilene and η2-disilyne mononuclear transition metal complexes and related compounds

    Article • Coordination Chemistry Reviews, May 2016, Elsevier

    Professor Takeaki Iwamoto

  18. Ferrocenyl-substituted Bicyclo[1.1.1]pentasilanes: Evaluation of Significant Interactions between Ferrocenyl Units and Rigid Silicon Cages

    Article • Chemistry Letters, February 2016, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  19. Hydrogen Bonds-Enabled Design of aC1-Symmetric Chiral Brønsted Acid Catalyst

    Article • ACS Catalysis, February 2016, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  20. Persistent four-coordinate iron-centered radical stabilized by π-donation

    Article • Chemical Science, January 2016, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  21. Wavy carbon: A new series of carbon structures explored by quantum chemical calculations

    Article • Chemical Physics Letters, October 2015, Elsevier

    Professor Takeaki Iwamoto

  22. Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol

    Article • Chemistry - A European Journal, July 2015, Wiley

    Professor Takeaki Iwamoto

  23. Prism-C2n carbon dimer, trimer, and nano-sheets: A quantum chemical study

    Article • Chemical Physics Letters, July 2015, Elsevier

    Professor Takeaki Iwamoto

  24. Redox Reactions of a Stable Dialkylphosphinyl Radical

    Article • Organometallics, June 2015, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  25. A Prism Carbon Molecule C20

    Article • Chemistry Letters, May 2015, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  26. Reactions of a Stable Phosphinyl Radical with Stable Aminoxyl Radicals

    Article • Chemistry Letters, January 2015, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  27. Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  28. Doubly Bonded Silicon Compounds Showing Intramolecular Charge-Transfer Transitions

    Article • January 2015, Springer Science + Business Media

    Professor Takeaki Iwamoto

  29. A heavy analogue of the smallest bridgehead alkene stabilized by a base

    Article • Nature Communications, November 2014, Nature

    Professor Takeaki Iwamoto

  30. Two-coordinate Dialkylsilylene–Coinage Metal Complexes

    Article • Chemistry Letters, October 2014, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  31. Persistent Antimony- and Bismuth-Centered Radicals in Solution

    Article • Angewandte Chemie International Edition, July 2014, Wiley

    Professor Takeaki Iwamoto

  32. Isolable 2,3-Disila-1,3-butadiene from a Double Sila-Peterson Reaction

    Article • Chemistry - A European Journal, July 2014, Wiley

    Professor Takeaki Iwamoto

  33. Germanium-centered free radicals studied by muon spin spectroscopy

    Article • Canadian Journal of Chemistry, June 2014, Canadian Science Publishing

    Professor robert west, Professor Takeaki Iwamoto

  34. Unexpected Formation of Highly Strained 2,5-Dioxa-3-Silabicyclo[2.1.0]Pentane by the Reaction of Isolable Dialkylsilylene with Benzil

    Article • Heteroatom Chemistry, May 2014, Wiley

    Professor Takeaki Iwamoto

  35. Silicon Compounds with Inverted Geometry around Silicon Atoms

    Article • Chemistry Letters, February 2014, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  36. Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole

    Article • Angewandte Chemie International Edition, January 2014, Wiley

    Professor Takeaki Iwamoto

  37. Palladium and Platinum η2-Disilyne Complexes Bearing an Isolable Dialkyldisilyne as a Ligand

    Article • Angewandte Chemie International Edition, November 2013, Wiley

    Professor Takeaki Iwamoto

  38. Anthryl-Substituted 3-Silylene-2-silaaziridine Obtained by Isomerization of Disilacyclopropanimine: An Exocyclic Silene Showing a Distinct Intramolecular Charge Transfer Transition

    Article • Journal of the American Chemical Society, July 2013, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  39. Multiple Bonds with Silicon: Recent Advances in Synthesis, Structure, and Functions of Stable Disilenes

    Article • January 2013, Springer Science + Business Media

    Professor Takeaki Iwamoto

  40. New Isolable Dialkylsilylene and Its Isolable Dimer That Equilibrate in Solution

    Article • Journal of the American Chemical Society, December 2012, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  41. A Two-Coordinate Palladium Complex with Two Dialkylphosphinyl Ligands

    Article • Angewandte Chemie International Edition, October 2012, Wiley

    Professor Takeaki Iwamoto

  42. Siloxy-Substituted Cyclopentadiene Showing Aggregation-Enhanced Emission: An Application of Cycloaddition of Isolable Dialkylsilylene

    Article • Organometallics, September 2012, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  43. Preparation of 4,7-Dibromobenzo[b]thiophene as a Versatile Building Block and Synthetic Application to a Bis(ethynylthienyl)oligoarene System

    Article • Bulletin of the Chemical Society of Japan, May 2012, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  44. Preparation of 1,4-bis(2-ethynyl-3-thienyl)benzene derivatives linked by oligo(ethyleneglycol) Chain

    Article • Heteroatom Chemistry, January 2012, Wiley

    Professor Takeaki Iwamoto

  45. Persilastaffanes: Design, Synthesis, Structure, and Conjugation between Silicon Cages

    Article • Angewandte Chemie International Edition, December 2011, Wiley

    Professor Takeaki Iwamoto

  46. Design of Chiral Bis-phosphoric Acid Catalyst Derived from (R)-3,3′-Di(2-hydroxy-3-arylphenyl)binaphthol: Catalytic Enantioselective Diels–Alder Reaction of α,β-Unsaturated Aldehydes with Amidodienes

    Article • Journal of the American Chemical Society, December 2011, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  47. A Stable Dialkylphosphinyl Radical

    Article • Journal of the American Chemical Society, August 2011, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  48. Addition of a stable dialkylsilylene to carbon-carbon unsaturated bonds

    Article • Heteroatom Chemistry, January 2011, Wiley

    Professor Takeaki Iwamoto

  49. Preparation of 1,4-bis(2-ethynyl-3-thienyl) benzene derivatives linked by oligo(ethyleneglycol) chain

    Article • Heteroatom Chemistry, January 2011, Wiley

    Professor Takeaki Iwamoto

  50. Reactions of an Isolable Dialkylsilylene with Ketones†

    Article • Organometallics, November 2010, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  51. Structure and Reactions of an Isolable Ge=Si Doubly Bonded Compound, Tetra(t-butyldimethylsilyl)germasilene

    Article • Silicon, October 2010, Springer Science + Business Media

    Professor Takeaki Iwamoto

  52. Synthesis and Facile Ring Expansion of Silylenecyclotetrasilane

    Article • Organometallics, April 2010, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  53. A Stable 1,2-Disilacyclohexene and Its 14-Electron Palladium(0) Complex

    Article • Journal of the American Chemical Society, April 2010, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  54. Synthesis and structures of deoxyribonucleoside analogues for triazole-linked DNA (TLDNA)

    Article • Tetrahedron Letters, April 2010, Elsevier

    Professor Takeaki Iwamoto

  55. Synthesis and structures of (dialkylsilylene)bis(phosphine)-nickel, palladium, and platinum complexes and (η6-arene)(dialkylsilylene)nickel complexes

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  56. Synthesis and structure of stable base-free dialkylsilanimines

    Article • New Journal of Chemistry, January 2010, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  57. Unusual Bonding in Trisilaallene and Related Heavy Allenes

    Article • Journal of the American Chemical Society, December 2009, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  58. Concise Synthesis of Halogenated Chrysenes ([4]Phenacenes) that Favor π-Stack Packing in Single Crystals

    Article • Organic Letters, September 2009, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  59. Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charge-Transfer Transition

    Article • Journal of the American Chemical Society, March 2009, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  60. Isomerization of an Isolable Silylene into a Silene via 1,2-Silyl Migration

    Article • Organometallics, February 2009, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  61. Probing the Reactivity of a Stable Silene Using Muonium

    Article • Angewandte Chemie International Edition, December 2008, Wiley

    Professor Takeaki Iwamoto

  62. Fourteen‐Electron Bis(dialkylsilylene)palladium and Twelve‐Electron Bis(dialkylsilyl)palladium Complexes

    Article • Angewandte Chemie International Edition, July 2008, Wiley

    Professor Takeaki Iwamoto

  63. 1,3-Digermabicyclo[1.1.0]butane with an Inverted Bridge Ge–Ge σ Bond

    Article • Chemistry Letters, May 2008, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  64. Synthesis, Structure, and Facile Ring Flipping of a Bicyclo[1.1.0]tetrasilane

    Article • Organometallics, February 2008, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  65. Synthesis and Structure of Ethynylsilyllithiums

    Article • Organometallics, September 2007, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  66. Thermal and Photochemical Cleavage of SiSi Double Bond in Tetrasila-1,3-diene

    Article • Journal of the American Chemical Society, September 2007, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  67. Synthesis of Tricyclo[3.1.0.02,4]hexasilane and Its Photochemical Isomerization to Tricyclo[2.2.0.02,5]hexasilane

    Article • Chemistry Letters, March 2007, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  68. Dinuclear Palladium Complex with a Bridging Dialkylsilylene Ligand

    Article • Chemistry Letters, February 2007, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  69. A Helmeted Dialkylsilylene

    Article • Bulletin of the Chemical Society of Japan, January 2007, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  70. Reactions of trisilaallene and 2-germadisilaallene with various reagents

    Article • Journal of Organometallic Chemistry, January 2007, Elsevier

    Professor Takeaki Iwamoto

  71. Synthesis, Properties, and Reactions of a Series of Stable Dialkyl-Substituted Silicon−Chalcogen Doubly Bonded Compounds

    Article • Journal of the American Chemical Society, December 2006, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  72. Fused Tricyclic Disilenes with Highly Strained SiSi Double Bonds: Addition of a SiSi Single Bond to a SiSi Double Bond

    Article • Angewandte Chemie International Edition, September 2006, Wiley

    Professor Takeaki Iwamoto

  73. Synthesis, Structure, and Bonding of Stable Dialkylsilaketenimines

    Article • Journal of the American Chemical Society, April 2006, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  74. Ligand dependence of π-complex character in disilene–palladium complexes

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  75. Progress in the Chemistry of Stable Disilenes

    Article • January 2006, Elsevier

    Professor Takeaki Iwamoto

  76. A Stable Fused Bicyclic Disilene as a Model for Silicon Surface

    Article • Journal of the American Chemical Society, November 2005, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  77. Novel Stable Silicon-Based π-Electron Systems: Synthesis, Unique Structure, and Properties of Cyclic, Spiroconjugated, and Cumulative Silicon–Silicon Doubly-Bonded Compounds

    Article • Bulletin of the Chemical Society of Japan, March 2005, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  78. A missing allene of heavy Group 14 elements: 2-germadisilaallene

    Article • Chemical Communications, January 2005, Royal Society of Chemistry

    Professor Takeaki Iwamoto

  79. Trigermaallene and 1,3-Digermasilaallene

    Article • Organometallics, January 2005, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  80. Novel group 14 elements-bridged self-assembled supramolecules from pyrimidine derivatives and palladium ions

    Article • Inorganic Chemistry Communications, September 2004, Elsevier

    Professor Takeaki Iwamoto

  81. The Singlet Excited State of a Stable Dialkylsilylene Is Responsible for Its Photoreactions

    Article • Angewandte Chemie International Edition, August 2004, Wiley

    Professor Takeaki Iwamoto

  82. Unusual reactions of isolable dialkylgermylene and -stannylene with galvinoxyl radical

    Article • Russian Chemical Bulletin, May 2004, Springer Science + Business Media

    Professor Takeaki Iwamoto

  83. Diverse reactions of nitroxide-radical adducts of silylene, germylene, and stannylene

    Article • Journal of Organometallic Chemistry, April 2004, Elsevier

    Professor Takeaki Iwamoto

  84. Comparative chemistry of isolable divalent compounds of silicon, germanium, and tin

    Article • The Chemical Record, January 2004, Wiley

    Professor Takeaki Iwamoto

  85. Comparison of structures between platinum and palladium complexes of a tetrasilyldisilene

    Article • Canadian Journal of Chemistry, November 2003, Canadian Science Publishing

    Professor Takeaki Iwamoto

  86. Synthesis, structure and isomerization of A2SiSiB2-type tetrakis(trialkylsilyl)disilenes

    Article • Journal of Organometallic Chemistry, November 2003, Elsevier

    Professor Takeaki Iwamoto

  87. Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements

    Article • Journal of the American Chemical Society, August 2003, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  88. Photochemical Isomerization and X-ray Structure of Stable [Tris(trialkylsilyl)silyl]cyclotrisilene

    Article • Organometallics, May 2003, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  89. Radical Anion of Isolable Dialkylsilylene

    Article • Journal of the American Chemical Society, March 2003, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  90. A stable silicon-based allene analogue with a formally sp-hybridized silicon atom

    Article • Nature, February 2003, Nature

    Professor Takeaki Iwamoto

  91. Insertion of a stable dialkylsilylene into silicon-chlorine bonds

    Article • Silicon Chemistry, January 2003, Springer Science + Business Media

    Professor Takeaki Iwamoto

  92. Sila-metalation Route to Hydrido(trialkylsilyl)silyllithiums

    Article • Journal of the American Chemical Society, October 2002, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  93. Excited-State Reactions of an Isolable Silylene with Aromatic Compounds

    Article • Journal of the American Chemical Society, April 2002, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  94. Synthesis and X-ray Structure of a Platinum η2-Disilene Complex

    Article • Organometallics, January 2002, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  95. The First 1,3-Disilabicyclo[1.1.0]butane with Long-Bridge Silicon−Silicon Bond

    Article • Journal of the American Chemical Society, December 2001, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  96. New synthesis of a stable dialkylstannylene and its reversible complexation with tetrahydrofuran

    Article • Journal of Organometallic Chemistry, November 2001, Elsevier

    Professor Takeaki Iwamoto

  97. A Mechanistic Study of Reactions of Stable Disilenes with Haloalkanes

    Article • Journal of the American Chemical Society, February 2001, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  98. A Stable Bicyclic Compound with Two Si&cjs0811;Si Double Bonds

    Article • Science, October 2000, American Association for the Advancement of Science

    Professor Takeaki Iwamoto

  99. The First Isolable Dialkylsilylene

    Article • Journal of the American Chemical Society, October 1999, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  100. The First Stable Cyclotrisilene

    Article • Journal of the American Chemical Society, January 1999, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  101. Bimolecular Reactions of Tetrakis(trialkylsilyl)disilenes with Various Reagents

    Article • Bulletin of the Chemical Society of Japan, December 1998, The Chemical Society of Japan

    Professor Takeaki Iwamoto

  102. A Solid-State 1 NMR and Theoretical Study of the Chemical Bonding in Disilenes

    Article • Journal of the American Chemical Society, May 1997, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  103. The First Stable Cyclic Disilene:  Hexakis(trialkylsilyl)tetrasilacyclobutene

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor Takeaki Iwamoto

  104. Organosilicon-Based Reactive Intermediates

    Article • Wiley

    Professor Takeaki Iwamoto