All Stories

  1. ChemInform Abstract: One-Pot Sequential Organocatalytic Michael-Tishchenko-Lactonization Reactions. Synthesis of Enantioenriched 4,5,6-Trisubstituted δ-Lactones.

    Article • ChemInform, March 2015, Wiley

    Professor Rafael Pedrosa

  2. Recoverable organocatalysts for enantioselective transformations

    Article • Green Chemistry, January 2015, Royal Society of Chemistry

    Professor Rafael Pedrosa

  3. The organocatalyzed domino Michael–aldol reaction revisited. Synthesis of enantioenriched 3-hydroxycyclohexanone derivatives by reaction of enals with α,α′-diaryl-substituted acetone

    Article • RSC Advances, January 2015, Royal Society of Chemistry

    Professor Rafael Pedrosa

  4. ChemInform Abstract: Novel Sulfonylpolystyrene-Supported Prolinamides as Catalysts for Enantioselective Aldol Reaction in Water.

    Article • ChemInform, May 2014, Wiley

    Professor Rafael Pedrosa

  5. Novel sulfonylpolystyrene-supported prolinamides as catalysts for enantioselective aldol reaction in water

    Article • Tetrahedron, December 2013, Elsevier

    Professor Rafael Pedrosa

  6. Novel supported and unsupported prolinamides as organocatalysts for enantioselective cyclization of triketones

    Article • Tetrahedron Letters, June 2013, Elsevier

    Professor Rafael Pedrosa

  7. (−)-8-Amino menthol-derived perhydrobenzoxazines as chiral templates and masked aldehydes in the diastereoselective intermolecular Pauson–Khand reaction

    Article • Tetrahedron, November 2012, Elsevier

    Professor Rafael Pedrosa

  8. Direct Experimental Evidence for the Epimerization of Diastereoisomers in the Enantioselective Organocatalyzed Michael Addition of Acetoacetates to Nitroolefins

    Article • Synlett, August 2011, Thieme Publishing Group

    Professor Rafael Pedrosa

  9. ChemInform Abstract: Stereocontrolled Construction of Quaternary Stereocenters by Inter- and Intramolecular Nitro-Michael Additions Catalyzed by Bifunctional Thioureas.

    Article • ChemInform, April 2011, Wiley

    Professor Rafael Pedrosa

  10. Highly diastereo- and enantioselective direct Barbas–List aldol reactions promoted by novel benzamidoethyl and benzamidopropyl prolinamides in water

    Article • Organic & Biomolecular Chemistry, January 2011, Royal Society of Chemistry

    Professor Rafael Pedrosa

  11. Stereocontrolled Construction of Quaternary Stereocenters by Inter- and Intramolecular Nitro-Michael Additions Catalyzed by Bifunctional Thioureas

    Article • Advanced Synthesis & Catalysis, December 2010, Wiley

    Professor Rafael Pedrosa

  12. ChemInform Abstract: Synthesis of Enantiopure Highly Substituted trans-8a-Hydroxydecahydroisoquinolines by Sequential Diastereoselective IMDA Reaction and Oxanorbornene Nucleophilic Ring Opening.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  13. ChemInform Abstract: Tributyltin Radical-Induced Addition-Carbocyclization on Chiral Perhydro-1,3-benzoxazines: A Facile Entry to Enantiopure Tin-Containing Auxiliaries.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  14. ChemInform Abstract: Diastereoselective Aldol Condensation with 2-(β-Ethoxycarbonyl)oxazolidine Derived from Norephedrine. A Chiral Masked Synthon of Ethyl Formylacetate.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  15. ChemInform Abstract: Regio- and Stereoselective 5-exo Radical Cyclizations on a Chiral Perhydro-1,3-benzoxazine Moiety. An Access to Enantiopure 3-Alkylpyrrolidines.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  16. ChemInform Abstract: A Novel Approach to Chiral, Nonracemic Pyrrolidines by 5-exo-trig Diastereoselective Radical Cyclization on Acrylamides Derived from (-)-8-Aminomenthol.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  17. ChemInform Abstract: Thermal and Lewis Acid Catalyzed Diastereoselective Intramolecular Diels-Alder Reaction on α,β-Unsaturated Amides Derived from (-)-8-Aminomenthol.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  18. ChemInform Abstract: Efficient Synthesis of syn-Aziridino Alcohols by Chelation-Controlled Addition of Dialkylzincs and Grignard Reagents to N-Benzylaziridino Aldehydes.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  19. ChemInform Abstract: A Short Diastereoselective Synthesis of Enantiopure Highly Substituted Tetrahydroepoxyisoindolines.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  20. ChemInform Abstract: Synthesis of Chiral, Non-racemic Aldols from Chiral β-Hydroxy-Weinreb Amides Prepared by Enantioselective Reformatsky-Like Reaction Induced by Chiral β-Aminoalcohols.

    Article • ChemInform, June 2010, Wiley

    Professor Rafael Pedrosa

  21. ChemInform Abstract: A Novel Straightforward Synthesis of Enantiopure Tetrahydroisoquinoline Alkaloids.

    Article • ChemInform, May 2010, Wiley

    Professor Rafael Pedrosa

  22. ChemInform Abstract: Synthesis of Enantiopure Mono- and Disubstituted Tetrahydroisoquinolines by 6-exo Radical Cyclizations.

    Article • ChemInform, May 2010, Wiley

    Professor Rafael Pedrosa

  23. ChemInform Abstract: Diastereoselective Synthesis of Enantiopure γ-Amino-β-hydroxy Acids by Reformatsky Reaction of Chiral α-Dibenzylamino Aldehydes.

    Article • ChemInform, May 2010, Wiley

    Professor Rafael Pedrosa

  24. ChemInform Abstract: Stereocontrolled IMDA Reaction of Styrene Derivatives. A Way to Enantiopure 3a,4,9,9a-Tetrahydrobenz[f]isoindolines.

    Article • ChemInform, May 2010, Wiley

    Professor Rafael Pedrosa

  25. ChemInform Abstract: Novel Bifunctional Chiral Urea and Thiourea Derivatives as Organocatalysts: Enantioselective Nitro-Michael Reaction of Malonates and Diketones.

    Article • ChemInform, October 2008, Wiley

    Professor Rafael Pedrosa

  26. Novel Bifunctional Chiral Urea and Thiourea Derivatives as Organocatalysts: Enantioselective Nitro-Michael Reaction of Malonates and Diketones

    Article • Chemistry - A European Journal, June 2008, Wiley

    Professor Rafael Pedrosa

  27. Asymmetric Addition of Chiral 1,3,2-Benzoxazaphosphinine 2-Oxides to Aldehydes: Diastereoselective Synthesis of α-Substituted β-Hydroxyphosphonic Acids.

    Article • ChemInform, October 2007, Wiley

    Professor Rafael Pedrosa

  28. Asymmetric Addition of Chiral 1,3,2-Benzoxazaphosphinine 2-Oxides to Aldehydes: Diastereoselective Synthesis of α-Substituted β-Hydroxyphosphonic Acids

    Article • European Journal of Organic Chemistry, June 2007, Wiley

    Professor Rafael Pedrosa

  29. Synthesis of Enantioenriched 2- and 2,6-Substituted Piperidin-3-ols from α-Dibenzylamino Aldehydes

    Article • European Journal of Organic Chemistry, April 2007, Wiley

    Professor Rafael Pedrosa

  30. Short and Efficient Diastereoselective Synthesis of Enantiopure 1-Substituted 1H-2-Benzopyrans.

    Article • ChemInform, March 2007, Wiley

    Professor Rafael Pedrosa

  31. A Direct Efficient Diastereoselective Synthesis of Enantiopure 3-Substituted-isobenzofuranones.

    Article • ChemInform, February 2007, Wiley

    Professor Rafael Pedrosa

  32. An Efficient and Diastereoselective Intramolecular 1,3-Dipolar Cycloaddition of Cyclic Azomethine Ylides and Nitrones.

    Article • ChemInform, November 2006, Wiley

    Professor Rafael Pedrosa

  33. Diastereoselective Syntheses of 2-Amino Propargyl Alcohols. Chiral Building Blocks for Enantiopure Amino γ-Lactones and 5-Hydroxy-piperidinone Derivatives.

    Article • ChemInform, November 2006, Wiley

    Professor Rafael Pedrosa

  34. Short and Efficient Diastereoselective Synthesis of Enantiopure 1-Substituted 1H-2-Benzopyrans

    Article • European Journal of Organic Chemistry, November 2006, Wiley

    Professor Rafael Pedrosa

  35. A direct efficient diastereoselective synthesis of enantiopure 3-substituted-isobenzofuranones

    Article • Tetrahedron, October 2006, Elsevier

    Professor Rafael Pedrosa

  36. Chiral Perhydro-1,3-benzoxazines: Powerful Auxiliaries in Asymmetric Synthesis of Nitrogen Heterocycles

    Article • ChemInform, September 2006, Wiley

    Professor Rafael Pedrosa

  37. Regio- and Stereoselective Methoxyselenenylation of Chiral 2-Vinyl Perhydro-1,3-benzoxazines Promoted by Selenium-Heteroatom Nonbonded Interactions.

    Article • ChemInform, August 2006, Wiley

    Professor Rafael Pedrosa

  38. Diastereoselective synthesis of enantioenriched homopropargyl amino alcohols from α-dibenzylamino aldehydes and their use as chiral synthons

    Article • Tetrahedron, August 2006, Elsevier

    Professor Rafael Pedrosa

  39. Diastereoselective Ethynylation of Chiral α-(Dibenzylamino) Aldehydes: Synthesis ofmeso- and HomochiralC2-Symmetrical 1,6-Diamino-2,5-diols

    Article • European Journal of Organic Chemistry, August 2006, Wiley

    Professor Rafael Pedrosa

  40. An Efficient Synthesis of Enantiomerically Enriched Trifluoromethylated 1,2-Diols and 1,2-Amino Alcohols with Quaternary Stereocenters by Diastereoselective Addition of TMSCF3 to Chiral 2-Acyl-1,3-perhydrobenzoxazines.

    Article • ChemInform, July 2006, Wiley

    Professor Rafael Pedrosa

  41. Diastereoselective syntheses of 2-amino propargyl alcohols. Chiral building blocks for enantiopure amino γ-lactones and 5-hydroxy-piperidinone derivatives

    Article • Tetrahedron Letters, July 2006, Elsevier

    Professor Rafael Pedrosa

  42. An Efficient and Diastereoselective Intramolecular 1,3-Dipolar Cycloaddition of Cyclic Azomethine Ylides and Nitrones

    Article • European Journal of Organic Chemistry, July 2006, Wiley

    Professor Rafael Pedrosa

  43. An Efficient Synthesis of Enantiomerically Enriched Trifluoromethylated 1,2-Diols and 1,2-Amino Alcohols with Quaternary Stereocenters by Diastereoselective Addition of TMSCF 3 to Chiral 2-Acyl-1,3-perhydrobenzoxazines

    Article • The Journal of Organic Chemistry, March 2006, American Chemical Society (ACS)

    Professor Rafael Pedrosa

  44. Diastereoselective Alkylation of Chiral Perhydro 1,3,2-Oxazabenzophos­phorinane-2-oxides Derived from (-)-8-Amino Menthol

    Article • Synthesis, January 2006, Thieme Publishing Group

    Professor Rafael Pedrosa

  45. Diastereoselective Yang Photocyclization Reactions in Solution. Synthesis of Enantiopure Azetidin-3-ol Derivatives

    Article • The Journal of Organic Chemistry, February 2005, American Chemical Society (ACS)

    Professor Rafael Pedrosa

  46. Diastereoselective Synthesis ofβ-Amino-α-(trifluoromethyl) Alcohols from Homochiralα-Dibenzylamino Aldehydes

    Article • European Journal of Organic Chemistry, April 2004, Wiley

    Professor Rafael Pedrosa

  47. Base-Dependent Regio- and Diastereoselective Alkylation of Chiral Perhydro 1,3,2-Oxazabenzophosphorinane-2-oxides Derived from (-)-8-Benzylamino Menthol

    Article • Synlett, January 2004, Thieme Publishing Group

    Professor Rafael Pedrosa

  48. Diastereoselective Cyclization of γ-δ Epoxyketones with (-)-Phenylglycinol: Synthesis of Both Enantiomers of cis -5-Alkyl-2-hydroxymethyl Pyrrolidines

    Article • Synlett, January 2004, Thieme Publishing Group

    Professor Rafael Pedrosa

  49. Total Regio- and Stereoselective Synthesis of Perhydropyrrolo[3,4-c]pyrazole Derivatives by [3 + 2] Intramolecular Dipolar Cycloaddition Reaction on Chiral Perhydro-1,3-benzoxazines.

    Article • ChemInform, November 2003, Wiley

    Professor Rafael Pedrosa

  50. Manipulating L-Aspartic and L-Glutamic Acids — Diastereoselective Synthesis of Enantiopure β-Amino-γ-hydroxy Acids and γ-Amino-δ-hydroxy Acids.

    Article • ChemInform, November 2003, Wiley

    Professor Rafael Pedrosa

  51. Regio- and diastereoselective tandem addition–carbocyclization promoted by sulfanyl radicals on chiral perhydro-1,3-benzoxazines

    Article • Tetrahedron Asymmetry, October 2003, Elsevier

    Professor Rafael Pedrosa

  52. A Novel and Efficient Oxidation of 1,2-Amino Alcohols to Dialkylamides.

    Article • ChemInform, March 2003, Wiley

    Professor Rafael Pedrosa

  53. Temperature- and Time-Dependent Stereochemical Control in Thermally Induced Keto−Ene Cyclizations

    Article • The Journal of Organic Chemistry, March 2003, American Chemical Society (ACS)

    Professor Rafael Pedrosa

  54. Total Regio- and StereoselectiveSynthesis of Perhydropyrrolo[3,4- c ]pyrazole Derivativesby [3+2] Intramolecular Dipolar CycloadditionReaction on Chiral Perhydro-1,3-benzoxazines

    Article • Synthesis, January 2003, Thieme Publishing Group

    Professor Rafael Pedrosa

  55. A Novel Synthesis of Enantiopure Octahydropyrrolo[3,4‐b]pyrroles by Intramolecular [3 + 2] Dipolar Cycloaddition on Chiral Perhydro‐1,3‐benzoxazines.

    Article • ChemInform, November 2002, Wiley

    Professor Rafael Pedrosa

  56. A Novel Synthesis of Enantiopure Octahydropyrrolo[3,4-b]pyrroles by Intramolecular [3 + 2] Dipolar Cycloaddition on Chiral Perhydro-1,3-benzoxazines

    Article • Organic Letters, July 2002, American Chemical Society (ACS)

    Professor Rafael Pedrosa

  57. Stereocontrolled IMDA Reaction of Styrene Derivatives. A Way to Enantiopure 3a,4,9,9a-Tetrahydrobenz[ f ]isoindolines

    Article • The Journal of Organic Chemistry, February 2002, American Chemical Society (ACS)

    Professor Rafael Pedrosa

  58. Unexpected Rearrangement in the Heck Cyclization of Positional Isomers of Chiral 2,3-Disubstituted Perhydro-1,3-benzoxazines

    Article • Synlett, January 2002, Thieme Publishing Group

    Professor Rafael Pedrosa

  59. Diastereoselective synthesis of enantiopure γ-amino-β-hydroxy acids by Reformatsky reaction of chiral α-dibenzylamino aldehydes

    Article • Tetrahedron, October 2001, Elsevier

    Professor Rafael Pedrosa

  60. Stereoselective synthesis of (5S,6S)- and (5S,6R)-aza-muricatacin from an l-glutamic acid derivative

    Article • Tetrahedron Asymmetry, June 2001, Elsevier

    Professor Rafael Pedrosa

  61. Synthesis of enantiopure mono- and disubstituted tetrahydroisoquinolines by 6-exo radical cyclizations

    Article • Tetrahedron, April 2001, Elsevier

    Professor Rafael Pedrosa

  62. ChemInform Abstract: A Simple Stereoselective Synthesis of Enantiopure 2-Substituted Pyrrolidines and Piperidines from Chiral (R)-Phenylglycinol-Derived Bicyclic 1,3-Oxazolidines.

    Article • ChemInform, January 2001, Wiley

    Professor Rafael Pedrosa

  63. A Novel Straightforward Synthesis of Enantiopure Tetrahydroisoquinoline Alkaloids

    Article • The Journal of Organic Chemistry, January 2001, American Chemical Society (ACS)

    Professor Rafael Pedrosa

  64. A Novel Case of Diastereoselection in 5-exo Radical Cyclization Promoted by Hydrogen Bonding

    Article • European Journal of Organic Chemistry, November 2000, Wiley

    Professor Rafael Pedrosa

  65. ChemInform Abstract: Stereocontrolled Ring Enlargement by Diastereoselective Stevens Rearrangement in Chiral 1,3-Oxazolidinium Salts. A Novel Entry to Enantiopure Morpholines.

    Article • ChemInform, October 2000, Wiley

    Professor Rafael Pedrosa

  66. Regio- and stereoselective 6-exo-trig radical cyclisations onto chiral perhydro-1,3-benzoxazines: synthesis of enantiopure 3-alkylpiperidines

    Article • Tetrahedron Asymmetry, July 2000, Elsevier

    Professor Rafael Pedrosa

  67. A Practical Stereoselective Synthesis of both Enantiomers of Threo- and Erythro-β-Hydroxy Norvaline from (S)-Serine Derivatives

    Article • Tetrahedron, March 2000, Elsevier

    Professor Rafael Pedrosa

  68. Synthesis of Chiral, Non-racemic Aldols from Chiral β-Hydroxy-Weinreb Amides Prepared by Enantioselective Reformatsky-like Reaction Induced by Chiral β-Aminoalcohols

    Article • Tetrahedron, February 2000, Elsevier

    Professor Rafael Pedrosa

  69. A Short Diastereoselective Synthesis of Enantiopure Highly Substituted Tetrahydroepoxyisoindolines †

    Article • The Journal of Organic Chemistry, February 2000, American Chemical Society (ACS)

    Professor Rafael Pedrosa

  70. Efficient synthesis of syn-aziridino alcohols by chelation-controlled addition of dialkylzincs and Grignard reagents to N-benzylaziridino aldehydes

    Article • Tetrahedron, December 1999, Elsevier

    Professor Rafael Pedrosa

  71. Synthesis of enantiopure 3-alkyl-perhydroazepines by diastereoselective 7-endo-radical cyclisation on a chiral 1,3-perhydrobenzoxazine derivative

    Article • Tetrahedron Letters, March 1999, Elsevier

    Professor Rafael Pedrosa

  72. Diastereoselective aldol condensation with 2-(β-ethoxycarbonyl)oxazolidine derived from norephedrine. A chiral masked synthon of ethyl formylacetate

    Article • Tetrahedron, February 1999, Elsevier

    Professor Rafael Pedrosa

  73. Tributyltin radical-induced addition–carbocyclization on chiral perhydro-1,3-benzoxazines: a facile entry to enantiopure tin-containing auxiliaries

    Article • Chemical Communications, January 1999, Royal Society of Chemistry

    Professor Rafael Pedrosa

  74. A facile stereodivergent synthesis of threo- and erythro-N,N-dibenzyl sphingosines from (S)-N,N-dibenzyl-O-TBDMS-serinal

    Article • Tetrahedron Asymmetry, July 1998, Elsevier

    Professor Rafael Pedrosa

  75. Stereodivergent synthesis of all diastereomers of 4-aminoheptane-3,5-diol from (L)-serine

    Article • Tetrahedron, May 1998, Elsevier

    Professor Rafael Pedrosa

  76. Unexpected Stereoselective 6- exo versus 7 -endo Aryl Radical Cyclisation Controlled by Positional Isomers in a Chiral Octahydro-1,3-benzoxazine Moiety

    Article • Synlett, December 1997, Thieme Publishing Group

    Professor Rafael Pedrosa

  77. Enantioselective reformatsky reaction induced by chiral β-amino alcohols

    Article • Tetrahedron, March 1997, Elsevier

    Professor Rafael Pedrosa

  78. Diastereoselective intramolecular Diels-Alder reaction of the furan diene. A facile access to enantiopure epoxy tetrahydroisoindolines

    Article • Tetrahedron Letters, February 1997, Elsevier

    Professor Rafael Pedrosa, Santiago Garcia-Granda

  79. Diastereoselective 5-exo-trig radical cyclisation on N-Acryloyl-tetrahydro-1,3-oxazines. A novel approach to enantiopure 3-substituted pyrrolidines

    Article • Tetrahedron Letters, December 1996, Elsevier

    Professor Rafael Pedrosa

  80. Synthesis of Chiral α,α-Difluoro-β-hydroxy Esters by Enantioselective Reformatsky Reaction

    Article • Synthesis, September 1996, Thieme Publishing Group

    Professor Rafael Pedrosa

  81. A diastereoselective approach to enantiopure 3-substituted pyrrolidines from masked lithium homoenolates derived from norephedrine

    Article • Tetrahedron, August 1996, Elsevier

    Professor Rafael Pedrosa, Santiago Garcia-Granda

  82. Elimination versus diastereoselective alkylation in homochiral 2-(β-ethoxy carbonyl) acetals

    Article • Tetrahedron Asymmetry, January 1996, Elsevier

    Professor Rafael Pedrosa

  83. Synthesis of Enantiopure Primary Amines by Stereoselective Ring Opening of Chiral Octahydro-1,3-benzoxazines by Grignard and Organoaluminum Reagents †

    Article • The Journal of Organic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Rafael Pedrosa

  84. Lithium derivatives from enantiomerically pure 2-(2′-haloethyl) dioxolanes: Formation and use as chiral propanal homoenolate synthons

    Article • Tetrahedron Asymmetry, July 1995, Elsevier

    Professor Rafael Pedrosa

  85. Easy preparation of enantiopure C2-symmetrical aminoalcohols derived from m-xylylene diamine.

    Article • Tetrahedron Asymmetry, January 1994, Elsevier

    Professor Rafael Pedrosa

  86. Enantioselective ethylation of aldehydes catalyzed by chiral C2-symmetrical β-hydroxy-m-xylylene diamines

    Article • Tetrahedron Asymmetry, January 1994, Elsevier

    Professor Rafael Pedrosa

  87. A novel highly diastereoselective synthesis of cyano ethers by regioselective ring opening of chiral oxazolidinium methiodides with sodium cyanide.

    Article • Tetrahedron Letters, December 1993, Elsevier

    Professor Rafael Pedrosa

  88. A new chiral glycine synthon. Synthesis, x-ray structure of (−).(2S,4R)-2-ethoxycarbonyl-4-phenyl-1,3-oxazolidine and diastereoselective nucleophilic ring opening to (R)-ethyl α-amino carboxylates.

    Article • Tetrahedron Letters, August 1992, Elsevier

    Professor Rafael Pedrosa, Santiago Garcia-Granda

  89. Stereoselective ring opening of chiral oxazolidines by reformatsky reagents: an enantioselective entry to β-amino esters.

    Article • Tetrahedron Letters, May 1992, Elsevier

    Professor Rafael Pedrosa

  90. Reductive Ring Opening of Ephedrine and Pseudo-Ephedrine-Derived Oxazolidinium Methiodides by Sodium Borohydride. A Direct Access to New Chiral Amine-Borane Adducts

    Article • Synthetic Communications, March 1992, Taylor & Francis

    Professor Rafael Pedrosa

  91. Regioselective Synthesis of 2-Functionalized Thiophenes by Condensation of α-Mercapto Compounds with β-Aminoenone Derivatives

    Article • Synthetic Communications, August 1990, Taylor & Francis

    Professor Rafael Pedrosa

  92. Alkylation of 3,5-Dimethylisothiazole. A Regioselective Synthesis of S-Alkyl-3-methylisothiazoles

    Article • Synthetic Communications, February 1990, Taylor & Francis

    Professor Rafael Pedrosa

  93. Differential reactivity of β-amino enones and 3-dimethylaminoacrylaldehyde towards α-amino derivatives

    Article • Journal of the Chemical Society Perkin Transactions 1, January 1990, Royal Society of Chemistry

    Professor Rafael Pedrosa

  94. Diastereoselective Ring Opening of 2-Substituted N -Benzyl-4,4, 7α-trimethyl- trans -octahydro-1,3-benzoxazines by Grignard Reagents. Highly Enantioselective Synthesis of Primary Amines

    Article • Synlett, January 1990, Thieme Publishing Group

    Professor Rafael Pedrosa

  95. Nucleophilic Ring Opening of 3-Benzyl-1,3-oxazinanes by Reformatsky Reagents. A Synthesis of β-Amino Ester Derivatives

    Article • Synthesis, January 1990, Thieme Publishing Group

    Professor Rafael Pedrosa

  96. Some Observations on the Regioselective Ring Opening of Tetrahydro-1,3-oxazinium Methiodides by Sodium Borohydride in Alcholic and Etheral Solvents

    Article • Heterocycles, January 1990, Japan Institute of Heterocyclic Chemistry

    Professor Rafael Pedrosa

  97. The Reaction of b-Aminoenones with a-Amino Derivatives. Synthesis of 2-Functionalized Pyrroles

    Article • Heterocycles, January 1990, Japan Institute of Heterocyclic Chemistry

    Professor Rafael Pedrosa

  98. Some Observations on the Reactivity of b-Aminoenones towards Phenacylamine Hydrochloride

    Article • Heterocycles, January 1989, Japan Institute of Heterocyclic Chemistry

    Professor Rafael Pedrosa

  99. Regioselective Synthesis of 2- and 3-Acylpyrroles by Reaction of b-Aminoenones with a-Aminoketone Hydrochloride

    Article • Heterocycles, January 1989, Japan Institute of Heterocyclic Chemistry

    Professor Rafael Pedrosa

  100. Reaction of 2H-1-Benzopyrans with Organometallic Reagents. Synthesis of 4-(a,g-Dialkyl-b-4-methoxyphenylallyl)resorcins

    Article • Heterocycles, January 1988, Japan Institute of Heterocyclic Chemistry

    Professor Rafael Pedrosa

  101. The Reaction of β-Aminoenones with Cyanamide. A High Efficient Synthesis of 2-Aminopyrimidines

    Article • Synthetic Communications, August 1987, Taylor & Francis

    Professor Rafael Pedrosa

  102. The reaction of β-aminoenones with substituted acetonitriles. Regiospecific synthesis of 2(1H)-pyridones

    Article • Journal of Heterocyclic Chemistry, May 1987, Wiley

    Professor Rafael Pedrosa

  103. One-Pot synthesis of unsymmetrically substituted 2,4-dialkylisoflavenes

    Article • Journal of Heterocyclic Chemistry, November 1986, Wiley

    Professor Rafael Pedrosa

  104. Cyanogen Bromide as a Useful Brominating Agent, Synthesis of α-Bromo-β-Aminoenones

    Article • Synthetic Communications, August 1986, Taylor & Francis

    Professor Rafael Pedrosa

  105. Asymmetric syntheses of α-amino acids from α-halogenated 10-sulfonamido-isobornyl esters.

    Article • Tetrahedron Letters, January 1986, Elsevier

    Professor Rafael Pedrosa

  106. Regiospecific synthesis of 1-arylpyrazoles

    Article • Journal of Heterocyclic Chemistry, September 1984, Wiley

    Professor Rafael Pedrosa

  107. Stereoselective Synthesis of Aryl-substituted o - Allylphenols

    Article • Synthesis, January 1984, Thieme Publishing Group

    Professor Rafael Pedrosa