All Stories

  1. A Metallaanthracene and Derived Metallaanthraquinone
  2. Pt(II) pyridinium amidate (PYA) complexes: Preparation and in vitro anticancer activity studies
  3. Regioselective Nitration and/or Halogenation of Iridabenzofurans through Electrophilic Substitution
  4. Fused-ring metallabenzenes
  5. Controlled translocation of palladium(ii) within a 22 ring atom macrocyclic ligand
  6. Catalytic oxidative degradation of 17α-ethinylestradiol by FeIII-TAML/H2O2: Estrogenicities of the products of partial, and extensive oxidation
  7. Selective Substitution of One of the Substituents on Germanium in Coordinatively Unsaturated Ruthenium Germyl Complexes
  8. Selective palladation of a large (32 ring atom) macrocyclic ligand at a bis(N-heterocyclic carbene) coordination pocket through transmetallation of the corresponding mercury(ii) derivative
  9. Metallabenzenes and Metallabenzenoids
  10. Extending the Range of Neutral N-Donor Ligands Available for Metal Catalysts: N-[1-Alkylpyridin-4(1H)-ylidene]amides in Palladium-Catalyzed Cross-Coupling Reactions
  11. Redox‐Controlled, Reversible Rearrangement of a Tris(2‐pyridylthio)methyl Ligand on Nickel to an Isomer with an “ N , S ‐Confused” 2‐Pyridylthiolate Arm
  12. Regioselective Mono-, Di-, and Trifunctionalization of Iridabenzofurans through Electrophilic Substitution Reactions
  13. Functionalization of Metallabenzenes through Nucleophilic Aromatic Substitution of Hydrogen
  14. Thermal Rearrangement of Osmabenzenes to Osmium Cyclopentadienyl Complexes
  15. Ruthenium complexes of chiral diphosphinite ligands with cyclohexane or chiro -inositol backbones as catalysts for asymmetric hydrogenation reactions
  16. Carbonylchlorido(1-methylsulfanylpenta-1,3-dien-1-yl-5-ylidene)bis(triphenylphosphane)osmium(II)
  17. Annulation of an Iridabenzene through Formal Cycloaddition Reactions with Organonitriles
  18. Bis[(1S*,2S*)-trans-1,2-bis(diphenylphosphinoxy)cyclohexane]chloridoruthenium(II) trifluoromethanesulfonate dichloromethane disolvate
  19. Dimethyl 7a-carbonyl-2-methoxy-7a,7a-bis(triphenylphosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxylate
  20. Stable Cationic and Neutral Ruthenabenzenes
  21. A Stable Iridabenzene Formed from an Iridacyclopentadiene Where the Additional Ring-Carbon Atom Is Derived from a Thiocarbonyl Ligand
  22. Stepwise Reactions of Acetylenes with Iridium Thiocarbonyl Complexes To Produce Isolable Iridacyclobutadienes and Conversion of These to either Cyclopentadienyliridium or Tethered Iridabenzene Complexes
  23. Syntheses, reactions, and structures of osmium(II) stannyl complexes with the simple stannyl ligands SnH3, SnH2Me, and SnHMe2
  24. Ruthenium complexes that incorporate a chiro-inositol derived diphosphinite ligand as catalysts for asymmetric hydrogenation reactions
  25. C–H Activation of 3,3-diphenylcyclopropene in the reaction with Os(CO)2(PPh3)3: 3,3-diphenylcyclopropenyl, 2,2-diphenylcyclopropyl, and 3-phenylindenyl complexes of osmium(II)
  26. A 2-iridafuran from reaction between a 1-iridaindene and methyl propiolate
  27. Similarities and Contrasts between Silyl and Stannyl Derivatives of Ruthenium and Osmium
  28. Syntheses, reactions, and structures of osmium(II) distannyl complexes, LnOs–SnMe2SnR3 (R=Me, Ph), from reaction between LnOs–SnClMe2 and either LiSnMe3 or KSnPh3
  29. Synthesis and structure of Os(η2-3,3-diphenylcyclopropene)Cl(NO)(PPh3)2 and the ring-opening reactions of the π-bound cyclopropene with acids
  30. The structurally characterised silyl complexes, Os(κ2-S2CNMe2)(SiMeCl2)(CO)(PPh3)2 and Os(κ2-S2CNMe2)(SiCl3)(CO)(PPh3)2, which have remarkably unreactive Si–Cl bonds
  31. An Osmabenzofuran from Reaction between Os(PhC⋮CPh)(CS)(PPh3)2 and Methyl Propiolate and the C-Protonation of this Compound to Form a Tethered Osmabenzene
  32. 3,3,6,6-Tetraphenyl-trans-tricyclo[3.1.0.02,4]hexane
  33. Metallabenzenes and metallabenzenoids
  34. A cyclic osmastannyl complex, Os(κ2(Sn,P)-SnMe2C6H4PPh2)(κ2-S2CNMe2)(CO)(PPh3) derived from the osmastannol complex, Os(SnMe2OH)(κ2-S2CNMe2)(CO)(PPh3)2
  35. Metallacyclic complexes with ortho-stannylated triphenylphosphine ligands, LnOs(κ2(Sn,P)-SnMe2C6H4PPh2), derived from thermal reactions of the five-coordinate complex, Os(SnMe3)Cl(CO)(PPh3)2
  36. Metallacyclic complexes with ortho-silylated triphenylphosphine ligands, L Os(κ2(Si,P)-SiMe2C6H4PPh2), derived from thermal reactions of the coordinatively unsaturated trimethylsilyl, methyl complex, Os(SiMe3)(Me)(CO)(PPh3)2
  37. Osmadisiloxane and osmastannasiloxane complexes derived from silanolate complexes of osmium(II)
  38. A 2-iridathiophene from reaction between IrCl(CS)(PPh3)2 and Hg(CHCHPh)2
  39. A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex
  40. Tethered silyl complexes from nucleophilic substitution reactions at the Si–Cl bond of the chloro(diphenyl)silyl ligand in Ru(SiClPh2)(κ2-S2CNMe2)(CO)(PPh3)2
  41. Nucleophilic substitution reactions at the Si–Cl bonds of the dichloro(methyl)silyl ligand in five- and six-coordinate complexes of ruthenium(II) and osmium(II)
  42. Four isomers from the oxidative addition of Me3SnH to Os(CO)2(PPh3)3 and the crystal structure of Os(SnMeI2)I(CO)2(PPh3)2, in which the pairs of CO and PPh3 ligands are mutually trans
  43. Reactions of the dichloroboryl complex of osmium, Os(BCl2)Cl(CO)(PPh3)2, with water, alcohols, and amines
  44. Design and synthesis of copper complexes of novel ligands based on the pyridine thiolate group
  45. Tethered Boryl and Base-Stabilized Borylene Osmium Complexes from the Reaction of Os(BCl2)Cl(CO)(PPh3)2 with 2-Aminopyridine
  46. Tetraamido Macrocyclic Ligand Catalytic Oxidant Activators in the Pulp and Paper Industry
  47. Mononuclear–dinuclear helicate interconversion of dibromo{N,N′-bis[(S)-1-2-(pyridyl)ethyl]pyridine-2,6-dicarboxamidate}copper(ii) via a deprotonation–protonation processElectronic supplementary information (ESI) available: preparation of (R)- and (S)-P...
  48. Tethered Osmium Boryl Complexes from the Reaction of Os(BCl2)Cl(CO)(PPh3)2 with 2-Hydroxypyridine
  49. Syntheses and structures of dimethylamino-bridged bis(silylene)ruthenium and -osmium complexes
  50. Tris(N-pyrrolyl)phosphine complexes of osmium(II) and osmium(0)
  51. Syntheses and reactions of coordinatively unsaturated silyl, aryl osmium(II) complexes and the crystal structures of Os[Si(OEt)3]R(CO)(PPh3)2 and Os[Si(OEt)3]R(CO)2(PPh3)2 (R=phenyl or o-tolyl)
  52. Reaction between the thiocarbonyl complex, Os(CS)(CO)(PPh3)3, and propyne: crystal structure of a new sulfur-substituted osmabenzene
  53. Phenyl derivatives of mercury functionalised in the 2-position with either a formyl or a vinyl group. Crystal structures of Hg[C6H4(CHO)-2]Cl and Hg[C6H4(CHCH2)-2]2
  54. Fe(TSPc)-Catalysed Benzylic Oxidation and Subsequent Dealkylation of a Non-Phenolic Lignin Model
  55. Reactions of cis and trans Bcat, Aryl Osmium Complexes (cat = 1,2-O2C6H4). Bis(Bcat) Complexes of Osmium and Ruthenium and a Structural Comparison of cis and trans Isomers of Os(Bcat)I(CO)
  56. Silatranyl, hydride complexes of osmium(II) and osmium(IV): crystal structure of Os(Si{OCH2CH2}3N)H3(PPh3)3
  57. Syntheses and structural studies of five- and six-coordinate o-halophenyl derivatives of ruthenium(II) and osmium(II)
  58. Boryl complexes of ruthenium and osmium
  59. Stepwise Conversion of an Osmium Trimethylstannyl Complex to a Triiodostannyl Complex and Nucleophilic Substitution Reactions at the Tin−Iodine Bonds
  60. Cyclometallated complexes of ruthenium and osmium containing the o-C6H4PPh2 ligand
  61. Bromination and nitration reactions of metallated (Ru and Os) multiaromatic ligands and crystal structures of selected products
  62. A Base-Stabilized Terminal Borylene Complex of Osmium Derived from Reaction between a Dichloroboryl Complex and 8-Aminoquinoline
  63. Electrophilic Aromatic Substitution Reactions of a Metallabenzene: Nitration and Halogenation of the Osmabenzene [Os{C(SMe)CHCHCHCH}I(CO)(PPh3)2]
  64. Bis(N,N′-dimethylimidazol-2-ylidene)mercury chlorotriiodomercury dimethyl sulfoxide solvate
  65. The synthesis, structure, and reactivity of the osmium(IV) trihydrido silyl complex, OsH3(SiMe3)(CO)(PPh3)2
  66. Electrophilic Substitution Reactions at the Phenyl Ring of the Chelated 2-(2‘-Pyridyl)phenyl Ligand Bound to Ruthenium(II) or Osmium(II)
  67. Synthesis and Structures of cis- and trans-[Os(Bcat)(aryl)(CO)2(PPh3)2]: Compounds of Relevance to the Metal-Catalyzed Hydroboration Reaction and the Metal-Mediated Borylation of Arenes
  68. Reversible methyl group migration between osmium and tin in reactions of osmium trimethylstannyl complexes
  69. The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2: structural comparisons with the analogous silatrane complex Os(Si[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2
  70. Transition Metal−Boryl Compounds:  Synthesis, Reactivity, and Structure
  71. Crystal Structure of Os(Bcat)Cl(CO)(PPh3)2 and the Syntheses and Structural Studies of Derived Cationic and Neutral Osmium Boryl Complexes
  72. 5-Bromination of an η2-8-Quinolyl Ligand Bound to Osmium(II) and Subsequent Lithiation and Derivatization of This Functionalized Ligand1
  73. Vinylidene complexes of osmium(0) derived from 1-naphthyl- or 2-naphthyl-carbyne complexes by hydride addition to the naphthyl substituents. The crystal structure of Os(CC10H8)(CO)2(PPh3)2
  74. Designing ligands to achieve robust oxidation catalysts. Iron based systems
  75. Quaternization of the Bridgehead Nitrogen in Silatranylosmium(II) Complexes and Reestablishment of the Transannular N−Si Bond following Migratory Insertion of the Silatranyl Ligand
  76. Syntheses and reactions of the carbyne complexes, M(CR)Cl(CO)(PPh3)2 (M=Ru, Os; R=1-naphthyl, 2-naphthyl). The crystal structures of [Os(C-1-naphthyl)(CO)2(PPh3)2]ClO4, Os(CH-2-naphthyl)Cl2(CO)(PPh3)2, and Os(2-naphthyl)Cl(CO)2(PPh3)2
  77. Insertion of Ethyne into the Ru−B Bond of a Coordinatively Unsaturated Ruthenium Boryl Complex. X-ray Crystal Structure of Ru(CHCH[BOC6H4O])Cl(CO)(PPh3)2
  78. Acid−Base Control of a Migratory Insertion Reaction:  p-Aminophenyl Derivatives of Ruthenium(II) and the Crystal Structure of Ru(η2-C[O]C6H4NH2-4)Cl(CO)(PPh3)2
  79. Ruthenium Complexes of a Simple Tridentate Ligand Bearing Two “Distal” Pyridine Bases
  80. The Nature of the Metal—Silicon Bond in [M(SiR3)H3(PPh3)3] (M = Ru, Os) And the Crystal Structure of [Os{Si(N‐pyrrolyl)3}H3(PPh3)3]
  81. Osmium nitrosyl complexes with osmium-tin bonds crystal structure of Os[Sn(p-tolyl)3](NO)(CO)2(PPh3)
  82. Tri-N-pyrrolylsilyl Complexes of Ruthenium and Osmium1
  83. Five-Coordinate Ruthenium(II) and Osmium(II) Boryl Complexes
  84. Osmium complexes containing either chelating or non-chelating 8-quinolyl ligands
  85. Compounds containing 3-metallated pyrrole
  86. Reactions of functionalised aryl groups σ-bound to ruthenium(II)
  87. Insertion of Ethyne into the Ru−Si Bonds of Coordinatively Unsaturated Ruthenium Silyl Complexes. X-ray Crystal Structures of Ru(CHCHSiMe2OEt)Cl(CO)2(PPh3)2 and [Ru(CHCHSiMe2OH)(CN-p-tolyl)(...
  88. Synthesis and reactivity of coordinatively unsaturated osmium and ruthenium stannyl complexes
  89. Synthesis of monomercurated N-protected pyrroles and the use of these compounds as pyrrolyl group transfer reagents to ruthenium and osmium. Crystal structures of (2-C4H3NC[O]CH3)HgCl, (2-C4H3NC[O]CH3)2 Hg and
  90. Direct nitration of aryl groups σ-bound to ruthenium(II)
  91. Oxidative addition of Group 14 hydrides to osmium(O), osmium(II) and ruthenium(O) complexes. Crystal structures of Os(SiEt3)H(CO )2 (PPh3) 2 and Os(Ge[p-tolyl]3) H(CO) 2(PPh3) 2
  92. Reactions of Metal Ion Complexes with Lignin Model Compounds Part I. Co(TSPP) as a Single Electron Transfer Catalyst and Implications for the Mechanism of AQ Pulping
  93. Reactions of Metal Ion Complexes with Lignin Model Compounds, Part II. Fe(TSPC) Catalyzed Formation of Oxidized Products in the Absence of Oxygen
  94. Reactions of Metal Ion Complexes with Lignin Model Compounds, Part III. Rh(TSPP) Catalyzed Formation of Guaiacol from β-Aryl Ethers in Exceptionally High Yield
  95. High-valent transition metal chemistry. Moessbauer and EPR studies of high-spin (S = 2) iron(IV) and intermediate-spin (S = 3/2) iron(III) complexes with a macrocyclic tetraamido-N ligand
  96. The diosmium tetrahydroxydisiloxane, [OsCl(CO)(PPh3)2Si(OH)2]2O, from the coordinatively unsaturated trihydroxysilyl complex, Os(Si[OH]3)Cl(CO)(PPh3)2
  97. High valent transition metal chemistry. Synthesis and characterization of an intermediate-spin iron(IV) complex of a strong .pi.-acid ligand
  98. Coordinatively unsaturated σ-aryl complexes of ruthenium(II) and osmium(II)
  99. A stable 6-metallated 1-azafulvene: synthesis and reactions of )(η2-S2CNMe2)(CO)(PPh3) and crystal structure of [)(2-pyrrolyl)}(η2-S2CNMe2)(CO)(PPh3)]+
  100. Catecholate spanning a metal-carbon double bond. Synthesis and crystal structure of -(2-N-methylpyrrolyl)]I(CO)(PPh3)2
  101. Crystal structure of the maleic anhydride complex Ru(η2-C4H2O3)(CO)(CN-p-tolyl)(PPh3)2
  102. Stable terminal methylene complexes of osmium(II) and ruthenium(II). The unexpected preferential migration of aσ-aryl ligand to carbon monoxide rather than to methylene
  103. Transition metal complexes of the dipyrromethylidene (dipyrrol-2-ylmethylene) ligand, LnM[C(C4H4N)2], from reaction between ruthenium- and osmium-bound dichlorocarbene and pyrrole: structures of [RuCl2<...
  104. Syntheses and structures of the chalcocarbonyl complexes OsCl2(CO)(CE)(PPh3)2 (E = S, Se, Te)
  105. Terminal methylene complexes of ruthenium(II) and osmium(II) and intramolecular methylene and acyl ligand combination to form metallaoxetenes: the crystal structures of [OsCl(η2-C[O]-o-tolyl)(CH2)(PPh3<...
  106. Synthesis and some reactions of a terminal carbyne complex of osmium. Crystal structures of Os(CR)Cl(CO)(PPh3)2 and gCl]R)Cl(CO)(PPh3)2
  107. Cleavage of ruthenium and osmium porphyrin dimers: formation of organometallic ruthenium porphyrin complexes and highly reduced metalloporphyrin species
  108. Substitution of divalent cobalt into aluminophosphate molecular sieves
  109. Redox Catalysis of Alkaline Pulping By Organometallic Complexes
  110. Combined decarboxylation of the formato ligand and reductive elimination of hydrido and aryl groups in the synthesis of ruthenium(0) complexes. Methylation of ruthenium(0) with formaldehyde
  111. An unusual vinylidene complex from hydride addition to the aromatic ring of the tolyl—carbyne ligand in a cationic osmium carbyne complex
  112. An osmium-carbyne complex
  113. The interaction of an osmium-carbon triple bond with copper(I), silver(I) and gold(I) to give mixed dimetallocyclopropene species and the structures of Os(AgCl) (CR) Cl(CO) (PPh3)2
  114. Dihapto-acyl derivatives of ruthenium(II). Preparation and structure of Ru[η2-C(O)CH3] I(CO)(PPh3)2 and Ru[η2-C(O)p-tolyl]I(C0) (PPh3) 2
  115. A dihapto-iminoacyl derivative of ruthenium(II). Synthesis and structure of RU[η2-C(NR)R]Cl(CO)(PPh3)2
  116. Five and six CO-ordinate σ-aryl derivatives of Ru(II) and Os(II) and the equilibrium RuRX(CO)2 (PPh3)2⇄ Ru[C(O)R]X(CO) (PPh3)2