All Stories

  1. A 5,000-fold increase in the HAT reactivity of a nonheme Fe IV =O complex simply by replacing two pyridines of the pentadentate N4Py ligand with pyrazoles
  2. A tale of two topological isomers: Uptuning [Fe IV (O)(Me 4 cyclam)] 2+ for olefin epoxidation
  3. 10 6 -fold faster C–H bond hydroxylation by a Co III,IV 2 (µ-O) 2 complex [via a Co III <...
  4. Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(iv) complexes
  5. Characterization of a heterobimetallic nonheme Fe(iii)–O–Cr(iii) species formed by O2 activation
  6. A chameleon catalyst for nonheme iron-promoted olefin oxidation
  7. H2O2activation with biomimetic non-haem iron complexes and AcOH: connecting the g = 2.7 EPR signal with a visible chromophore
  8. An ultra-stable oxoiron(iv) complex and its blue conjugate base
  9. Nonheme oxoiron(iv) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity
  10. Oxidation of water by a nonhaem diiron(iv) complex via proton-coupled electron transfer
  11. Cyclohexene as a substrate probe for the nature of the high-valent iron-oxo oxidant in Fe(TPA)-catalyzed oxidations
  12. A mononuclear carboxylate-rich oxoiron(iv) complex: a structural and functional mimic of TauD intermediate ‘J’
  13. Prediction of high-valent iron K-edge absorption spectra by time-dependent Density Functional Theory
  14. Oxidative decarboxylation of α-hydroxy acids by a functional model of the nonheme iron oxygenase, CloR