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  1. Frontispiece: Tetrelanes versus Tetrylenes as Precursors to Transition Metal Complexes Featuring Tridentate PEP Tetryl Ligands (E=Si, Ge, Sn)

    Article • Chemistry - A European Journal, March 2023, Wiley

    Professor Javier A. Cabeza

  2. Tetrelanes versus Tetrylenes as Precursors to Transition Metal Complexes Featuring Tridentate PEP Tetryl Ligands (E=Si, Ge, Sn)

    Article • Chemistry - A European Journal, February 2023, Wiley

    Professor Javier A. Cabeza

  3. Dipyrromethane‐Based PGeP Pincer Germyl Rhodium Complexes

    Article • Chemistry - A European Journal, June 2022, Wiley

    Professor Javier A. Cabeza

  4. Advances in the synthesis and reactivity of group 6 metal allenyls

    Article • January 2022, Elsevier

    Professor Javier A. Cabeza

  5. Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid

    Article • Inorganic Chemistry, October 2021, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  6. Cyclometallation of Heavier Tetrylenes: Reported Complexes and Applications in Catalysis

    Article • European Journal of Inorganic Chemistry, July 2021, Wiley

    Professor Javier A. Cabeza

  7. Dipyrromethane‐Based PGeP Pincer Methylgermyl and Methoxidogermyl Nickel and Palladium Complexes

    Article • European Journal of Inorganic Chemistry, April 2021, Wiley

    Professor Javier A. Cabeza

  8. Reactions of Late First‐Row Transition Metal (Fe‐Zn) Dichlorides with a PGeP Pincer Germylene

    Article • Chemistry - A European Journal, February 2021, Wiley

    Professor Javier A. Cabeza

  9. Stannylenes based on pyrrole-phosphane and dipyrromethane-diphosphane scaffolds: syntheses and behavior as precursors to PSnP pincer palladium(ii), palladium(0) and gold(i) complexes

    Article • Dalton Transactions, January 2021, Royal Society of Chemistry

    Professor Javier A. Cabeza

  10. Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe2(η4-cod)]: cis- versus trans-[PtMe2L2] Complexes and Cyclometalation Reactions

    Article • Organometallics, April 2020, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  11. Front Cover: The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes (Eur. J. Inorg. Chem. 10/2020)

    Article • European Journal of Inorganic Chemistry, March 2020, Wiley

    Professor Javier A. Cabeza

  12. The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes

    Article • European Journal of Inorganic Chemistry, March 2020, Wiley

    Professor Javier A. Cabeza

  13. The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes

    Article • European Journal of Inorganic Chemistry, February 2020, Wiley

    Professor Javier A. Cabeza

  14. Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes

    Article • Dalton Transactions, January 2020, Royal Society of Chemistry

    Professor Javier A. Cabeza

  15. A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex

    Article • Chemical Communications, January 2020, Royal Society of Chemistry

    Professor Javier A. Cabeza

  16. Two octahedral σ-borane metal (MnI and RuII) complexes containing a tripod κ3N,H,H-ligand: Synthesis, structural characterization, and theoretical topological study of the charge density

    Article • Journal of Molecular Structure, October 2019, Elsevier

    Professor Javier A. Cabeza

  17. A Germylene Supported by Two 2‐Pyrrolylphosphane Groups as Precursor to PGeP Pincer Square‐Planar Group 10 Metal(II) and T‐Shaped Gold(I) Complexes

    Article • Chemistry - A European Journal, July 2019, Wiley

    Professor Javier A. Cabeza, Dr Israel Fernandez

  18. Two Types of sigma‐Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes

    Article • Chemistry - A European Journal, May 2019, Wiley

    Professor Javier A. Cabeza

  19. Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement

    Article • Chemistry - A European Journal, January 2019, Wiley

    Professor Javier A. Cabeza

  20. Mesityl(amidinato)tetrylenes as ligands in iridium(i) and iridium(iii) complexes: silicon versus germanium and simple κ1-coordination versus cyclometallation

    Article • Dalton Transactions, January 2019, Royal Society of Chemistry

    Professor Javier A. Cabeza

  21. A dipyrromethane-based diphosphane–germylene as precursor to tetrahedral copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes

    Article • Dalton Transactions, January 2019, Royal Society of Chemistry

    Professor Javier A. Cabeza, Dr Israel Fernandez

  22. Reversible Carbene Insertion into a Ge−N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes

    Article • Chemistry - A European Journal, December 2018, Wiley

    Professor Javier A. Cabeza

  23. From a PGeP Pincer-Type Germylene to Metal Complexes Featuring Chelating (Ir) and Tripodal (Ir) PGeP Germyl and Bridging (Mn2) and Chelating (Ru) PGeP Germylene Ligands

    Article • Organometallics, May 2018, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  24. Ruthenium Carbene Complexes Analogous to Grubbs-I Catalysts Featuring Germylenes as Ancillary Ligands

    Article • Organometallics, February 2018, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  25. Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular stru...

    Article • Dalton Transactions, January 2018, Royal Society of Chemistry

    Professor Javier A. Cabeza

  26. From a Diphosphanegermylene to Nickel, Palladium and Platinum Complexes Containing Germyl PGeP Pincer Ligands

    Article • Chemistry - A European Journal, August 2017, Wiley

    Professor Javier A. Cabeza

  27. First Insertions of Carbene Ligands into Ge−N and Si−N Bonds

    Article • Chemistry - A European Journal, March 2017, Wiley

    Professor Javier A. Cabeza

  28. Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene

    Article • Chemical Communications, January 2017, Royal Society of Chemistry

    Professor Javier A. Cabeza

  29. Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine–borane as a tripod κ3N,H,H-ligand

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Professor Javier A. Cabeza

  30. Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes

    Article • Chemical Communications, January 2017, Royal Society of Chemistry

    Professor Javier A. Cabeza

  31. 2-(Methylamido)pyridine–Borane: A Tripod κ 3 -N,H,H Ligand in Trigonal Bipyramidal Rhodium(I) and Iridium(I) Complexes with an Asymmetric Coordination of Its BH 3 Group

    Article • Inorganic Chemistry, September 2016, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  32. Amidinatogermylene Metal Complexes as Homogeneous Catalysts in Alcoholic Media

    Article • Organometallics, August 2016, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  33. [MnBrL(CO)4] (L = Amidinatogermylene): Reductive Dimerization, Carbonyl Substitution, and Hydrolysis Reactions

    Article • Organometallics, May 2016, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  34. Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO

    Article • Angewandte Chemie International Edition, March 2016, Wiley

    Professor Javier A. Cabeza, Professor Todd B. Marder

  35. Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO

    Article • Angewandte Chemie, March 2016, Wiley

    Professor Todd B. Marder, Professor Javier A. Cabeza

  36. A topological analysis of the bonding in [M2(CO)10] and [M3(μ-H)3(CO)12] complexes (M = Mn, Tc, Re)

    Article • Theoretical Chemistry Accounts, February 2016, Springer Science + Business Media

    Professor Javier A. Cabeza

  37. Amidinatogermylene Complexes of Copper, Silver, and Gold

    Article • Organometallics, November 2015, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  38. Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate ­Ligands

    Article • European Journal of Inorganic Chemistry, October 2015, Wiley

    Professor Javier A. Cabeza

  39. The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

    Article • Coordination Chemistry Reviews, September 2015, Elsevier

    Professor Javier A. Cabeza

  40. Reactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ 2 N , Ge -Amidinatogermylene Ligand

    Article • Inorganic Chemistry, May 2015, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  41. Amidinatogermylene Derivatives of Ruthenium Carbonyl: New Insights into the Reactivity of [Ru 3 (CO) 12 ] with Two-Electron-Donor Reagents of High Basicity

    Article • Inorganic Chemistry, March 2015, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  42. ELECTRON DENSITY STUDIES ON THE REGIOSELECTIVITY OF DEPROTONATION REACTIONS

    Article • Acta Crystallographica Section A Foundations and Advances, August 2014, International Union of Crystallography

    Professor Javier A. Cabeza

  43. Conversion of a Monodentate Amidinate–Germylene Ligand into Chelating Imine–Germanate Ligands (on Mononuclear Manganese Complexes)

    Article • Inorganic Chemistry, August 2014, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  44. Ring Opening and Bidentate Coordination of Amidinate Germylenes and Silylenes on Carbonyl Dicobalt Complexes: The Importance of a Slight Difference in Ligand Volume

    Article • Chemistry - A European Journal, June 2014, Wiley

    Professor Javier A. Cabeza

  45. Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative

    Article • RSC Advances, January 2014, Royal Society of Chemistry

    Professor Javier A. Cabeza

  46. Reactivity of a (Bis-NHC)tricarbonylruthenium(0) Complex with Methyl Triflate and Methyl Iodide. Formation of Methyl- and Acetylruthenium(II) Derivatives: Experimental Results and Mechanistic DFT Calculations

    Article • Organometallics, July 2013, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  47. Organic Amides as Suitable Precursors to Stabilize Stannylenes

    Article • Organometallics, June 2013, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  48. Deprotonation ofC‐Alkyl Groups of Cationic Triruthenium Clusters Containing CyclometalatedC‐Alkylpyrazinium Ligands: Experimental and Computational Studies

    Article • Chemistry - A European Journal, May 2013, Wiley

    Professor Javier A. Cabeza

  49. Synthesis and Reactivity of Cationic Triruthenium Clusters Derived from 2‐Methyl‐ and 4‐Methylpyrimidines: From Conventional Cyclometalated Ligands to Novel Types of N‐Heterocyclic Carbenes

    Article • Chemistry - A European Journal, January 2013, Wiley

    Professor Javier A. Cabeza

  50. Easy abstraction of a hydride anion from an alkyl C–H bond of a coordinated bis(N-heterocyclic carbene)

    Article • Chemical Communications, January 2013, Royal Society of Chemistry

    Professor Javier A. Cabeza

  51. Expanding the coordination chemistry of donor-stabilized group-14 metalenes

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Javier A. Cabeza

  52. Reactivity of a Bis(N-heterocyclic carbene) with Ruthenium Carbonyl. Synthesis of Mono- and Trinuclear Derivatives and Ligand Modification via C–H Bond Activation

    Article • Organometallics, November 2012, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  53. Reactivity of a Quinoline-Tethered N-Heterocyclic Carbene with Polynuclear Ruthenium Carbonyls

    Article • Organometallics, November 2012, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  54. Reactivity of [Ru4(μ-H)4(CO)12] with bidentate ligands containing at least one N-heterocyclic carbene moiety

    Article • Journal of Organometallic Chemistry, July 2012, Elsevier

    Professor Javier A. Cabeza

  55. QTAIM Analysis of the Bonding in Mo–Mo Bonded Dimolybdenum Complexes

    Article • Inorganic Chemistry, June 2012, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  56. Reactions of CS2 and C(S)NPh Adducts of N‐Heterocyclic Carbenes with [Ru3(CO)12]: Remarkable Reactivity of These Betaines Involving One or Two C–S Bond Activation Processes

    Article • European Journal of Inorganic Chemistry, April 2012, Wiley

    Professor Javier A. Cabeza

  57. Diaminogermylene and Diaminostannylene Derivatives of Gold(I): Novel AuM and AuM2(M = Ge, Sn) Complexes

    Article • Inorganic Chemistry, February 2012, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  58. Reaction of [Ru3(CO)12] with Phenazine: Synthesis of C-Metalated Derivatives That Formally Arise from a C–H Oxidative Addition or a Long-Distance C-to-N Prototropy

    Article • Organometallics, January 2012, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  59. Synthesis of Mixed Tin–Ruthenium and Tin–Germanium–Ruthenium Carbonyl Clusters from [Ru3(CO)12] and Diaminometalenes (M = Sn, Ge)

    Article • Inorganic Chemistry, January 2012, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  60. Deprotonation of C-alkyl groups of cationic N-heterocyclic ligands

    Article • Dalton Transactions, January 2012, Royal Society of Chemistry

    Professor Javier A. Cabeza

  61. Reactions of phthalazine, quinazoline, 4,7-phenanthroline and 2,3′-bipyridine with ruthenium carbonyl

    Article • Dalton Transactions, January 2012, Royal Society of Chemistry

    Professor Javier A. Cabeza

  62. Reactivity of Phosphine- and Thioether-Tethered N-Heterocyclic Carbenes with Ruthenium Carbonyl

    Article • Organometallics, December 2011, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  63. Theoretical topological analysis of the electron density in a series of triosmium carbonyl clusters: [Os3(CO)12], [Os3(μ-H)2(CO)10], [Os3(μ-H)(μ-OH)(CO)10], and [Os3(μ-H)(μ-Cl)(CO)10]

    Article • Computational and Theoretical Chemistry, August 2011, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  64. Reactivity of Diaminogermylenes with Ruthenium Carbonyl: Ru3Ge3 and RuGe2 Derivatives

    Article • Inorganic Chemistry, June 2011, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  65. Different Reactivities of Pyrid-2-yl- and 6-Picol-2-yl-Functionalized NHC Ligands with [Ru3(CO)12]: C(sp2)−H and Double C(sp3)−H Bond Activation Reactions

    Article • Organometallics, March 2011, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  66. Reactivity of Cationic Triruthenium Carbonyl Clusters: From Pyrimidinium Ligands to N-Heterocyclic Carbenes

    Article • Organometallics, February 2011, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  67. Reactivity of [Ru3(CO)12] with a Phosphine-Functionalized Imidazol-2-ylidene and Its Imidazolium Salt

    Article • Organometallics, January 2011, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  68. The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters

    Article • Chemical Society Reviews, January 2011, Royal Society of Chemistry

    Professor Javier A. Cabeza

  69. Trapping of Pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated Pyrid-2-ylidenes in Triruthenium Clusters

    Article • Organometallics, September 2010, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  70. ChemInform Abstract: Carbonyl Metal Clusters as Homogeneous Catalysts: Hydrogenation of Alkynes Mediated by Hydridotriruthenium Clusters Containing Bridging N- Donor Ligands

    Article • ChemInform, August 2010, Wiley

    Professor Javier A. Cabeza

  71. The Bridging Acetylene to Bridging Vinylidene Rearrangement in a Triruthenium Carbonyl Cluster: A DFT Mechanistic Study

    Article • Organometallics, August 2010, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  72. Reactivity of [Os3(μ-H)2(CO)10] with N-Heterocyclic Carbenes: A Combined Experimental and DFT Computational Study

    Article • Organometallics, August 2010, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  73. Reductive Dimerization of Triruthenium Clusters Containing Cationic Aromatic N‐Heterocyclic Ligands

    Article • Chemistry - A European Journal, May 2010, Wiley

    Professor Javier A. Cabeza

  74. From Allenes to Edge-Bridging Allyl Ligands or Face-Capping Alkenyl Ligands on a Triruthenium Hydrido Carbonyl Cluster: An Experimental and DFT Computational Study

    Article • Organometallics, April 2010, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  75. Cationic Heterocycles as Ligands: Synthesis and Reactivity with Anionic Nucleophiles of Cationic Triruthenium Clusters Containing C‐Metalated N‐Methylquinoxalinium or N‐Methylpyrazinium Ligands

    Article • Chemistry - A European Journal, July 2009, Wiley

    Professor Javier A. Cabeza

  76. DFT Mechanistic Study of the Transformation of Cyclohexa-1,3-diene into a Bridging Allyl Ligand upon Reaction with a Triruthenium Hydrido Carbonyl Cluster

    Article • Organometallics, May 2009, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  77. Topological Analysis of the Electron Density in the N-Heterocyclic Carbene Triruthenium Cluster [Ru3(μ-H)2(μ3-MeImCH)(CO)9] (Me2Im = 1,3-dimethylimidazol-2-ylidene)

    Article • Organometallics, May 2009, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  78. Reactivity of [Ru4(μ-H)4(CO)12] with N-Heterocyclic Carbenes

    Article • Organometallics, February 2009, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  79. Reactivity of Protons, Tertiary Stannanes, and Alkynes with a Triruthenium Dihydrido Cluster Containing a Face-Capping NHC Ligand

    Article • Organometallics, January 2009, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  80. A Simple Preparation of Pyridine‐Derived N‐Heterocyclic Carbenes and Their Transformation into Bridging Ligands by Orthometalation

    Article • Angewandte Chemie, December 2008, Wiley

    Professor Javier A. Cabeza

  81. A Simple Preparation of Pyridine‐Derived N‐Heterocyclic Carbenes and Their Transformation into Bridging Ligands by Orthometalation

    Article • Angewandte Chemie International Edition, December 2008, Wiley

    Professor Javier A. Cabeza

  82. Double C−H Bond Activation of an NHC N-Methyl Group on Triruthenium and Triosmium Carbonyl Clusters: A DFT Mechanistic Study

    Article • Organometallics, August 2008, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  83. Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Carbonyl Clusters: Synthesis, Structure, and Reactivity

    Article • Organometallics, June 2008, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  84. From an N‐Methyl N‐Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple CH and CN Bond Activations

    Article • Angewandte Chemie International Edition, February 2008, Wiley

    Professor Javier A. Cabeza

  85. From an N‐Methyl N‐Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple CH and CN Bond Activations

    Article • Angewandte Chemie, February 2008, Wiley

    Professor Javier A. Cabeza

  86. Reactions of Conjugated Dienes with a Triruthenium Hydrido Carbonyl Cluster: Synthesis and Reactivity of Trinuclear Derivatives Having an Edge-Bridging Allyl Ligand

    Article • Organometallics, January 2008, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  87. Activation of two C–H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Professor Javier A. Cabeza

  88. Reactivity of a triruthenium alkenyl cluster complex with conjugated diynes: Coupling of two diyne molecules via a face-capping diyne intermediate

    Article • Journal of Organometallic Chemistry, January 2008, Elsevier

    Professor Javier A. Cabeza

  89. Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects

    Article • Organometallics, December 2007, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  90. Mononuclear ruthenium complexes containing chiral aminooxazolines: Syntheses, X-ray studies and catalytic activity

    Article • Journal of Organometallic Chemistry, September 2007, Elsevier

    Professor Javier A. Cabeza

  91. Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N′-dipyrid-2-ylurea

    Article • Journal of Organometallic Chemistry, September 2007, Elsevier

    Professor Javier A. Cabeza

  92. A new coordination mode for (pyrid-2-yl)thiolate (L) ligands: Synthesis and characterization of [Ru6(μ3-H)(μ5-κ2-L)(μ-CO)(CO)15]

    Article • Journal of Organometallic Chemistry, July 2007, Elsevier

    Professor Javier A. Cabeza

  93. High-Nuclearity Osmium Carbonyl Cluster Complexes Containing (6-Methylpyrid-2-yl)imido Ligands. Synthesis of Hepta-, Octa-, and Nonanuclear Derivatives

    Article • Organometallics, May 2007, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  94. Ruthenium Cluster Mediated Transformation of Linear Alkenes into Trienyl Ligands. Activation of Five C(sp3)−H Bonds of 1-Octene, 1-Nonene, and 1-Decene

    Article • Organometallics, April 2007, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  95. Reactivity of Indene, Fluorene, Azulene, and Acenaphthylene with a Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Dihydride

    Article • Organometallics, February 2007, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  96. Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I)

    Article • January 2007, Wiley

    Professor Javier A. Cabeza

  97. Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton:  Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms

    Article • Organometallics, October 2006, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  98. Reactions of μ3‐Alkenyl Triruthenium Carbonyl Clusters with Alkynes: Synthesis of Trinuclear μ‐//‐Alkyne, μ‐Vinylidene, and μ‐Dienoyl Derivatives

    Article • Chemistry - A European Journal, September 2006, Wiley

    Professor Javier A. Cabeza

  99. High-Nuclearity Ruthenium Carbonyl Cluster Complexes Derived from 2-Amino-6-methylpyridine:  Synthesis of Nonanuclear Derivatives Containing μ4- and μ5-Oxo Ligands

    Article • Inorganic Chemistry, June 2006, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  100. Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a Basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride

    Article • Organometallics, April 2006, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  101. Methyl Levamisolium Triflate as a Precursor to a Chiral Bifunctional N-Heterocyclic Carbene-Thiolate Ligand:  Palladium(II) Complexes

    Article • Organometallics, February 2006, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  102. Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond

    Article • Organometallics, February 2006, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  103. Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine — Novel coordination modes for 2-imidopyridines

    Article • Canadian Journal of Chemistry, February 2006, Canadian Science Publishing

    Professor Javier A. Cabeza

  104. Ruthenium‐Cluster‐Mediated Activation of All Bonds of a Methyl Group of 6,6′‐Dimethyl‐2,2′‐bipyridine and 2,9‐Dimethyl‐1,10‐phenanthroline: Transformation of the Latter into a 2‐Alkenyl‐9‐methyl‐1,10‐phenanthroline Ligand

    Article • Chemistry - A European Journal, January 2006, Wiley

    Professor Javier A. Cabeza

  105. Triruthenium and triosmium carbonyl clusters containing chiral bidentate NHC-thiolate ligands derived from levamisole

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor Javier A. Cabeza

  106. Triruthenium carbonyl clusters derived from chiral aminooxazolines: synthesis and catalytic activity

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor Javier A. Cabeza

  107. Reactivity of Alkynes Containing α‐Hydrogen Atoms with a Triruthenium Hydrido Carbonyl Cluster: Alkenyl versus Allyl Cluster Derivatives

    Article • Chemistry - A European Journal, September 2005, Wiley

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  108. Dichlorobis[(S)-2,3,5,6-tetrahydro-6-phenylimidazo[2,1-b]thiazole]nickel(II)

    Article • Acta Crystallographica Section E Structure Reports Online, September 2005, International Union of Crystallography

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  109. Can μ4-Alkyne and μ3-Alkenyl Ligands Be Considered as Six- and Five-Electron Donors, Respectively?

    Article • Organometallics, March 2005, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  110. η2-Edge-Bridging and η3-Face-Capping Coordination of Conjugated Ynenyl Ligands in Triruthenium Carbonyl Cluster Complexes Derived from 1,1-Dimethylhydrazine

    Article • Organometallics, January 2005, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  111. Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives

    Article • Organometallics, January 2005, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  112. Easy activation of two C–H bonds of an N-heterocyclic carbene N-methyl group

    Article • Chemical Communications, January 2005, Royal Society of Chemistry

    Professor Javier A. Cabeza

  113. Crystallographic report: [N,N′-Bis-(6-methylpyrid-2-ylium)-(1R,2R)-1,2-diaminocyclohexane] bis-[(p-cymene)- trichlororuthenate(II)]

    Article • Applied Organometallic Chemistry, January 2005, Wiley

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  114. Edge‐Bridging and Face‐Capping Coordination of Alkenyl Ligands in Triruthenium Carbonyl Cluster Complexes Derived from Hydrazines: Synthetic, Structural, Theoretical, and Kinetic Studies

    Article • Chemistry - A European Journal, December 2004, Wiley

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  115. η3-Edge-Bridging versus η3-Face-Capping Coordination of a Conjugated Ynenyl Ligand on a Triruthenium Cluster Core

    Article • Organometallics, October 2004, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  116. Photolysis of diruthenium hexacarbonyl tetrahedrane compounds in Nujol glass matrices

    Article • Journal of Organometallic Chemistry, September 2004, Elsevier

    Professor Javier A. Cabeza

  117. Hexaruthenium Carbonyl Cluster Complexes with Basal Edge-Bridged Square Pyramidal Metallic Skeleton:  Efficient Synthesis of 2-Imidopyridine Derivatives and Determination of Their Reactive Sites in Carbonyl Substitution Reactions

    Article • Inorganic Chemistry, July 2004, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  118. Activation of All Bonds of a Methyl Group Attached to an Organic Fragment

    Article • Angewandte Chemie, June 2004, Wiley

    Professor Javier A. Cabeza

  119. Activation of All Bonds of a Methyl Group Attached to an Organic Fragment

    Article • Angewandte Chemie International Edition, June 2004, Wiley

    Professor Javier A. Cabeza

  120. Reactivity of a Triruthenium Cluster Complex Containing a μ3-η3(C,N2) Ligand Derived from 2-Amino-7,8-benzoquinoline. Coupling of This Ligand with C3 Fragments and Characterization of μ3

    Article • Organometallics, June 2004, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  121. Triruthenium, Hexaruthenium, and Triosmium Carbonyl Derivatives of 2-Amino-6-phenylpyridine

    Article • Organometallics, January 2004, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  122. Di‐ and Trinuclear Ruthenium and Osmium Bis(2‐pyridyl) Ketone Oximate Derivatives

    Article • European Journal of Inorganic Chemistry, November 2003, Wiley

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  123. Influence of the bridging ligand on the substitution chemistry of neutral and cationic triruthenium carbonyl cluster complexes derived from 1,1-dimethylhydrazine

    Article • Inorganica Chimica Acta, July 2003, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  124. Methylidyne–diyne coupling reactions onto a triruthenium cluster core

    Article • Inorganica Chimica Acta, April 2003, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  125. Reactivity of Triosmium and Triruthenium Carbonyls with 2,2‘-Diamino-1,1‘-binaphthalene. Synthesis of C-and N-Metalated Derivatives

    Article • Organometallics, February 2003, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  126. Formation of a Highly Functionalized Azulene Ligand by Metal Cluster-Mediated Coupling of Three Conjugated Diynes

    Article • Organometallics, January 2003, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  127. Hexaruthenium cluster complexes of basal edge-bridged square pyramidal metallic skeleton. First efficient synthesis and reactivity studies

    Article • Dalton Transactions, January 2003, Royal Society of Chemistry

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  128. Reactivity of a Triruthenium Ynenyl Cluster Complex with Diynes: Cluster-Mediated Combination of up to Three Substituted Butadiyne Molecules into a Carbon-Rich Hydrocarbyl Ligand

    Article • European Journal of Inorganic Chemistry, December 2002, Wiley

    Professor Javier A. Cabeza

  129. Carbonyl substitution chemistry of neutral and cationic triruthenium cluster complexes derived from 1,1-dimethylhydrazine.

    Article • Journal of Organometallic Chemistry, December 2002, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  130. Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Bridging Ligands Derived from 2-Amino-7,8-benzoquinoline

    Article • Organometallics, October 2002, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  131. Facile C−S Bond Activation of Levamisole Hydrochloride on a Triruthenium Cluster Core

    Article • European Journal of Inorganic Chemistry, October 2002, Wiley

    Professor Javier A. Cabeza

  132. The Important Role of Some Ancillary Ligands in the Chemistry of Carbonylmetal Cluster Complexes − Selected Reactivity of Triruthenium Clusters Containing Deprotonated 2-Aminopyridines

    Article • European Journal of Inorganic Chemistry, July 2002, Wiley

    Professor Javier A. Cabeza

  133. Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Deprotonated Di(2-pyridyl)amine in Unusual Coordination Modes

    Article • Organometallics, May 2002, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  134. Bis(μ-η2-benzene-1,2-dithiolato-κ3S,S′:S′)bis[(η6-p-cymene)ruthenium(II)]

    Article • Acta Crystallographica Section E Structure Reports Online, April 2002, International Union of Crystallography

    Professor Javier A. Cabeza

  135. Benzophenone iminium tetrafluoroborate

    Article • Acta Crystallographica Section E Structure Reports Online, March 2002, International Union of Crystallography

    Professor Javier A. Cabeza

  136. Reactivity of [Ru3(μ3-NPh)(μ3-CO)(CO)9] towards Activated Alkynes and Diynes − Isolation of a Trinuclear Intermediate During the Formation of Bi- and Tetranuclear Products

    Article • European Journal of Inorganic Chemistry, November 2001, Wiley

    Professor Javier A. Cabeza

  137. Formation of a Diynedienyl Ligand by Coupling of Hexa-2,4-diyne and Hex-2-yn-4-en-4-yl Ligands onto a Triruthenium Cluster Core

    Article • Organometallics, September 2001, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  138. Reactivity of [Ru2(μ-η1:η1-NCPh2)(μ-η1:η2-PhCCHPh)(CO)6] with Alkynes. Insertion Reactions of Nonactivated Alkynes into Ru−C and Ru−N Bonds

    Article • Organometallics, August 2001, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  139. Formation of Cyclopentadienyl and Ruthenacyclopentadienyl Derivatives through Ynenyl-Diyne and Ynenyl-Alkyne Couplings onto a Triruthenium Cluster Core

    Article • Chemistry - A European Journal, June 2001, Wiley

    Professor Javier A. Cabeza

  140. (tert-Butyl isocyanide)tetracarbonyl[N-(1,2,3,4-tetraphenylbutadienyl)benzophenone imine]diruthenium(I)

    Article • Acta Crystallographica Section E Structure Reports Online, April 2001, International Union of Crystallography

    Professor Javier A. Cabeza

  141. (Benzylamine-N)(η5-cyclopentadienyl)bis(triphenylphosphine-P)ruthenium(II) tetrafluoroborate

    Article • Acta Crystallographica Section E Structure Reports Online, March 2001, International Union of Crystallography

    Professor Javier A. Cabeza

  142. (Benzophenone imine-N)nonacarbonyldirhenium(0)(Re—Re)

    Article • Acta Crystallographica Section E Structure Reports Online, February 2001, International Union of Crystallography

    Professor Javier A. Cabeza

  143. Reactivity of [Ru3(μ-H)(μ-Me2pz)(CO)10] with 2,4-hexadiyne. Characterization of the first tetranuclear ynenyl complex

    Article • Inorganic Chemistry Communications, January 2001, Elsevier

    Professor Javier A. Cabeza

  144. Reactivity of Diynes with a 1-Azavinylidene-Bridged Triruthenium Carbonyl Cluster. Insertion Reactions of Diynes into Ru−H, Ru−C, and Ru−N Bonds

    Article • Organometallics, November 2000, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  145. Reactivity of Triosmium Carbonyl Clusters with 1,8-Diaminonaphthalene − Synthesis and Structural Characterization of Amido, Diamido, andC-Metalated Trinuclear Derivatives

    Article • European Journal of Inorganic Chemistry, November 2000, Wiley

    Professor Javier A. Cabeza

  146. Reactivity of Triosmium Carbonyl Clusters with 1,8-Diaminonaphthalene − Synthesis and Structural Characterization of Amido, Diamido, and C-Metalated Trinuclear Derivatives

    Article • European Journal of Inorganic Chemistry, November 2000, Wiley

    Professor Javier A. Cabeza

  147. Approaches to Triosmium Carbonyl Cluster Compounds Derived from Benzophenone Imine. Characterization of Terminal Imino, Bridging Amido, and Orthometalated Imino Derivatives

    Article • Organometallics, September 2000, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  148. Reactivity of the Anionic Carbonyltrirhenium Cluster [Re3(µ-H)3(µ3-ampy)(CO)9]− − Synthesis of Neutral Phosphane and Alkenyl Derivatives

    Article • European Journal of Inorganic Chemistry, August 2000, Wiley

    Professor Javier A. Cabeza

  149. Reactivity of the Anionic Carbonyltrirhenium Cluster [Re3(µ-H)3(µ3-ampy)(CO)9] − Synthesis of Neutral Phosphane and Alkenyl Derivatives

    Article • European Journal of Inorganic Chemistry, August 2000, Wiley

    Professor Javier A. Cabeza

  150. Reactivity of [Re3(μ-H)3(μ3-ampy)(CO)9]-. Preparation of Heteronuclear Re3Au Carbonyl Cluster Complexes Containing Face-Capping and Edge-Bridging Gold Atoms

    Article • Organometallics, April 2000, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  151. Reactivity of 2-(Diphenylphosphanyl)thiophenol (HSC6H4PPh2) with Ruthenium and Osmium Carbonyl Complexes; Breaking of HSC6H4PPh2 into Sulfide, Phenyl and Diphenylphosphanyl Ligands on a Triruthenium Cluster

    Article • European Journal of Inorganic Chemistry, March 2000, Wiley

    Professor Javier A. Cabeza

  152. Homogeneous Catalysis with Ruthenium Carbonyl Cluster Complexes: Hydrogenation of Alkynes

    Article • September 1999, Wiley

    Professor Javier A. Cabeza

  153. Derivative Chemistry of [Ru2(μ-bdt)(CO)6], a Binuclear Ruthenium(I) Carbonyl Complex Containing a Bridging Benzene-1,2-dithiolate Ligand

    Article • European Journal of Inorganic Chemistry, July 1999, Wiley

    Professor Javier A. Cabeza

  154. Derivative Chemistry of [Ru2(μ-bdt)(CO)6], a Binuclear Ruthenium(I) Carbonyl Complex Containing a Bridging Benzene-1,2-dithiolate Ligand

    Article • European Journal of Inorganic Chemistry, July 1999, Wiley

    Professor Javier A. Cabeza

  155. Reactivity of 2-(Diphenylphosphanyl)thiophenol (HSC6H4PPh2) with Ruthenium and Osmium Carbonyl Complexes; Breaking of HSC6H4PPh2 into Sulfide, Phenyl and Diphenylphosphanyl Ligands on a Triruthenium Cluster

    Article • European Journal of Inorganic Chemistry, March 1999, Wiley

    Professor Javier A. Cabeza

  156. Neutral Binuclear and Anionic Trinuclear Rhenium Carbonyl Complexes Containing Bridging Ligands Derived from 2-Amino- and 2-Mercaptopyridines

    Article • Organometallics, November 1998, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  157. Advances in the Reactivity of Amido-Bridged Binuclear Carbonylruthenium Complexes – Derivative Chemistry of the Cationic Complex [Ru2(μ-dan)(μ-H)(CO)6][BF4] (H2dan = 1,8-Diaminonaphthalene)

    Article • European Journal of Inorganic Chemistry, November 1998, Wiley

    Professor Javier A. Cabeza

  158. Reactivity of the 1-azavinylidene cluster [Ru3(μ-H)(μ-NCPh2)(CO)10] with hydrogen, tertiary silanes and tertiary stannanes

    Article • Journal of Organometallic Chemistry, August 1998, Elsevier

    Professor Javier A. Cabeza

  159. Reactivity of a 1-Azavinylidene-Bridged Triruthenium Carbonyl Cluster with Alkynes. Synthesis of Binuclear Derivatives Containing New C−H or C−N and C−C Bonds Formed by Alkyne Insertion into M−H or M−N and M−C Bonds

    Article • Organometallics, June 1998, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  160. Binuclear Iron(I), Ruthenium(I), and Osmium(I) Hexacarbonyl Complexes Containing a Bridging Benzene-1,2-dithiolate Ligand. Synthesis, X-ray Structures, Protonation Reactions, and EHMO Calculations

    Article • Organometallics, March 1998, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  161. Protonation of triruthenium carbonyl cluster complexes containing a bridging 1-azavinylidene ligand. Experimental results and EHMO calculations

    Article • Journal of Organometallic Chemistry, March 1998, Elsevier

    Professor Javier A. Cabeza

  162. Reactivity studies on cationic non-hydridic triruthenium carbonyl clusters. Reactions of [Ru3(μ3-ampy)(CO)10][BF4] with hydrogen, triethylsilane and triphenylstannane

    Article • Inorganica Chimica Acta, February 1998, Elsevier

    Professor Javier A. Cabeza

  163. Neutral and cationic diphenylphosphine and diphenylphosphido derivatives of a trinuclear ruthenium carbonyl cluster containing a bridging 1-azavinylidene ligand

    Article • Journal of Organometallic Chemistry, December 1997, Elsevier

    Professor Javier A. Cabeza

  164. Carbonyl−Metal Clusters with Mixed O,N-Donor Ligands:  Reactivity of the Ureato Cluster [Ru3(μ-H)(μ3-HNCONMe2)(CO)9] with Phosphines. Structural Characterization of a Triphenylphosphine Derivative and of a Bi...

    Article • Organometallics, September 1997, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  165. Reactivity of a 1-Azavinylidene Ligand with Diphenylacetylene on a Ruthenium Carbonyl Cluster. A Remarkable Alkyne Insertion into a Metal−Nitrogen Bond

    Article • Organometallics, June 1997, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  166. Reversible Thermal Activation of a Triphenylphosphine P−C Bond on a Cationic Non-Hydridic Triruthenium Carbonyl Cluster Complex. Structural Characterization of a μ-η1:η2-Benzoyl Derivative

    Article • Organometallics, April 1997, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  167. Reactivity of a Cationic Non-Hydridic Triruthenium Carbonyl Cluster Complex with Anionic Reagents. Synthesis of New Tri- and Hexanuclear Derivatives

    Article • Organometallics, February 1997, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  168. Triosmium carbonyl complexes containing bridging ligands derived from ortho-functionalized anilines

    Article • Journal of Organometallic Chemistry, November 1996, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  169. Neutral and anionic pyrazolyl-bridged triruthenium carbonyl cluster complexes. Reactions with bis(diphenylphosphino) methane, triphenylphosphine and diphenylphosphine

    Article • Journal of Organometallic Chemistry, October 1996, Elsevier

    Professor Javier A. Cabeza

  170. Bi- and trinuclear carbonylruthenium clusters: a crystallographic and electronic comparative study

    Article • Acta Crystallographica Section A Foundations of Crystallography, August 1996, International Union of Crystallography

    Professor Javier A. Cabeza

  171. Synthesis and Reactivity of Triruthenium Carbonyl Cluster Complexes Containing a Bridging 1-Azavinylidene Ligand Derived from Benzophenone Imine

    Article • Organometallics, June 1996, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  172. Tri- and binuclear ruthenium carbonyl complexes containing bridging ligands derived from ortho-substituted anilines. A comparative study of their syntheses using RuCl3 · nH2O or [Ru3(CO)12] as starting materials

    Article • Journal of Organometallic Chemistry, May 1996, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  173. Reactivity of a cationic triruthenium hydridoalkenylcarbonyl cluster complex toward nucleophilic reagents. Carbonyl substitution versus alkene elimination reactions

    Article • Journal of Organometallic Chemistry, April 1996, Elsevier

    Professor Javier A. Cabeza

  174. Homogeneous Hydrogenation of Diphenylacetylene Promoted by a Cationic Hydridoalkenyltriruthenium Cluster Complex. Kinetic Evidence for Cluster Catalysis

    Article • Organometallics, January 1996, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  175. Pyrazolate‐Bridged Ruthenium(I) Carbonyl Complexes

    Article • January 1996, Wiley

    Professor Javier A. Cabeza

  176. IR studies and hydrogenation catalytic activity of heterogeneous catalysts prepared by thermal treatments of a face-bridged triruthenium carbonyl cluster supported on silica and alumina

    Article • Inorganica Chimica Acta, September 1995, Elsevier

    Professor Javier A. Cabeza

  177. Alkyne, Triorganosilyl, and Triorganostannyl Derivatives of Anionic Triruthenium Carbonyl Cluster Complexes Containing Bridging Pyrazolyl Ligands

    Article • Organometallics, July 1995, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  178. Derivative Chemistry of Cationic Triruthenium Carbonyl Cluster Compounds. Reactions Leading to a Neutral Hexanuclear Complex Consisting of Two Vertex-Linked Metal Triangles

    Article • Organometallics, July 1995, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  179. Carbonyl Metal Clusters as Homogeneous Catalysts: Hydrogenation of Alkynes Mediated by Hydridotriruthenium Clusters Containing Bridging N-Donor Ligands

    Article • Synlett, June 1995, Thieme Publishing Group

    Professor Javier A. Cabeza

  180. Carbonyl clusters as homogeneous catalysts. Kinetic and molecular aspects of the hydrogenation of diphenylacetylene promoted by an alkenyl-bridged triruthenium cluster complex. [Erratum to document cited in CA122:9301]

    Article • Organometallics, June 1995, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  181. Synthesis, characterization, reactivity, and catalytic hydrogenation activity of the hexanuclear hexahydrido carbonyl cluster compound [Ru6(μ-H)60(μ3,ν2-ampy)2(CO)14 ] (Hampy = 2-amino-6-methylpyridine)

    Article • Journal of Organometallic Chemistry, May 1995, Elsevier

    Professor Javier A. Cabeza

  182. Cationic Trinuclear 48-Electron Ruthenium Carbonyl Cluster Complexes Containing No Hydride Ligands

    Article • Inorganic Chemistry, March 1995, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  183. Reactivity of [PPN][Ru3(.mu.-NO)(CO)10] with Tertiary Silanes and Stannanes

    Article • Inorganic Chemistry, December 1994, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  184. Carbonyl Clusters as Homogeneous Catalysts. Kinetic and Molecular Aspects of the Hydrogenation of Diphenylacetylene Promoted by an Alkenyl-Bridged Triruthenium Cluster Complex

    Article • Organometallics, November 1994, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  185. Tricyclohexylphosphine- versus Triphenylphosphine-Substituted Derivatives of a Face-Bridged Triruthenium Carbonyl Cluster Complex. A Comparative Study of Their Synthesis, Structure, and Catalytic Activity in the Homogeneous Hydrogenation of Diphenylace...

    Article • Organometallics, November 1994, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  186. Synthesis, structure and hydrogenation catalytic activity of [Ru3(μ3,η2-ampy)(μ,η1:η2-PhCCHPh)(CO)6(PPh3) (Hampy = 2-amino-6-methylpyridine)

    Article • Journal of Organometallic Chemistry, October 1994, Elsevier

    Professor Javier A. Cabeza

  187. [RuCl2(PH2Cy)(η6-p-cymene)]

    Article • Acta Crystallographica Section C Crystal Structure Communications, July 1994, International Union of Crystallography

    Professor Javier A. Cabeza

  188. Synthesis and derivative chemistry of [Ru2(μ-PPh2) (μ-OH) 2(μ6-p-cymene) 2]+

    Article • Journal of Organometallic Chemistry, May 1994, Elsevier

    Professor Javier A. Cabeza

  189. Preparation and Characterization of 92-Electron Hexahydridohexaruthenium Carbonyl Cluster Complexes. Their Potential Significance in Homogeneous Catalytic Hydrogenation

    Article • Organometallics, February 1994, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  190. .eta.1-Aryl-bridged triruthenium cluster complexes

    Article • Organometallics, January 1994, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  191. Reactivity of tertiary silanes and stannanes with an edge-bridged triruthenium carbonyl cluster complex

    Article • Inorganic Chemistry, October 1993, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  192. Molecular clusters in homogeneous catalysis: kinetic and chemical evidence for the participation of triruthenium cluster complexes in a cluster-promoted catalytic hydrogenation of diphenylacetylene

    Article • Organometallics, October 1993, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  193. Structure of μ-[bis(chloroacetato-O)-mercury(II)-κ2Hg]-μ-[1,8-naphthalenediamino-κ2NN':κ2NN']-bis[cis-dicarbonyl(triisopropylphosphine-P)ruthenium(I)](Ru–Ru)

    Article • Acta Crystallographica Section C Crystal Structure Communications, August 1993, International Union of Crystallography

    Professor Javier A. Cabeza

  194. Incorporation of silanes and diphenylacetylene into face-bridged triruthenium carbonyl clusters. Attempted hydrosilylation of diphenylacetylene

    Article • Organometallics, August 1993, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  195. Ruthenium(I) complexes containing bridging N-donor ligands: structure, synthesis and reactivity patterns

    Article • Coordination Chemistry Reviews, July 1993, Elsevier

    Professor Javier A. Cabeza

  196. Synthesis and structural characterization of triruthenium cluster complexes containing bridging .eta.1-phenyl and terminal .eta.1-phenyl ligands arising from the cleavage of triphenylphosphine ligands

    Article • Organometallics, April 1993, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  197. Reactivity of a face-bridged trinuclear ruthenium carbonyl cluster with diphenylacetylene and triorganotin hydrides. Attempted hydrostannation of diphenylacetylene

    Article • Organometallics, January 1993, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  198. Synthesis and reactivity of dithiodiphenylphosphinato-derivatives of rhodium. Crystal structure of the square-pyramidal rhodium(III) complex [RhI(η2-S2PPh2)(COMe)(PPh3)]

    Article • Journal of Organometallic Chemistry, December 1992, Elsevier

    Professor Javier A. Cabeza

  199. Kinetic and chemical evidence for the participation of mononuclear catalytic species in the homogeneous hydrogenation of diphenylacetylene promoted by an edge-bridged triruthenium carbonyl cluster complex

    Article • Organometallics, December 1992, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  200. Incorporation of trialkylsilyl and trialkylstannyl groups into ruthenium carbonyl clusters. Carbonyl substitution versus trialkylsilane or trialkylstannane elimination in these clusters

    Article • Organometallics, October 1992, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  201. Cationic and neutral 50-electron triruthenium carbonyl clusters containing three bridging diphenylphosphido ligands

    Article • Organometallics, August 1992, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  202. Mercury-bridged transition-metal clusters. Synthesis of pentanuclear Ru3HgM (M  Mo, W, or Co) clusters and X-ray structure of [(Ru3(μ3,η2-ampy)(CO)9)-(μ3-Hg)Co(CO)4] (Hampy  2-amino-6-methylpyridine)

    Article • Journal of Organometallic Chemistry, August 1992, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  203. Synthesis and reactivity of triruthenium carbonyl clusters containing bis(diphenylphosphino)methane and the face-bridging ligand 2-amido-6-methylpyridi

    Article • Journal of Organometallic Chemistry, April 1992, Elsevier

    Professor Javier A. Cabeza

  204. Addition of mercury(II) electrophiles to [Ru2(C10H8N2)(CO)4(P-iso-Pr3)2] and selective insertion versus addition in the reactions of mercury(II) electrophiles with trinuclear diruthenium mercury clusters. X-ray structures of [Ru2Hg(O2CCF3)2(C10H8N2)(CO...

    Article • Inorganic Chemistry, April 1992, American Chemical Society (ACS)

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  205. Hydrogenation activity of [Ru3(μ-H)-(μ3-ampy)(CO)9] under homogeneous conditions (Hampy = 2-amino-6-methylpyridine)

    Article • Journal of Molecular Catalysis, January 1992, Elsevier

    Professor Javier A. Cabeza

  206. The chemical and electrochemical oxidation of pyridonate-bridged ruthenium(I) dimers. X-Ray structure of [Ru2(μ-pyO)2(CO)4(pyOH)2] (pyOH = 2-pyridone)

    Article • Journal of Organometallic Chemistry, December 1991, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  207. Extensive substitution, protonation, and methoxidation reactions of triruthenium carbonyl clusters containing 2-amino-6-methylpyridinato (.mu.3-ampy) as a face-bridging ligand. X-ray structures of [Ru3(.mu.-H)(.mu.3-ampy)(CO)7(PPh3)2] and [Ru3(.mu.-H)2...

    Article • Inorganic Chemistry, November 1991, American Chemical Society (ACS)

    Professor Javier A. Cabeza

  208. Synthesis and reactivity of diphenylphosphine derivatives of [Ru3(μ-H)(μ3-ampy)(CO)9] and [Ru3(μ-H)2(μ3-ampy)(CO)9][BF4] (Hampy=2-amino-6-methylpyridine)

    Article • Inorganica Chimica Acta, August 1991, Elsevier

    Professor Javier A. Cabeza

  209. The addition of protons and metallic electrophiles to the electron-rich RuRu bond of [Ru2(μ,-dan)(CO)4(PiPr3)2]. X-ray structure of [Ru2(μ-AgPPh3)(μ-dan)(CO)4(PiPr3)2][BF4]·CH2Cl2 (dan=1,8-diamidonaphthalene)

    Article • Inorganica Chimica Acta, July 1991, Elsevier

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  210. Mercury—ruthenium mixed-metal carbonyl clusters containing 2-amido-6-methylpyridine (ampy) as a μ3,η2-ligand. Crystal structures of [Ru6(μ4-Hg)(μ3-ampy)2(CO)18]·2C4H8O and [Ru3(μ-HgBr)(μ3-ampy)(CO)9]

    Article • Journal of Organometallic Chemistry, February 1991, Elsevier

    Professor Javier A. Cabeza

  211. Synthesis and reactions with electrophiles and nucleophiles of the ruthenium(I) complex [Ru2(µ-C10H8N2)(CO)6]. Crystal structure of [Ru2(µ-C10H8N2...

    Article • Journal of the Chemical Society Dalton Transactions, January 1991, Royal Society of Chemistry

    Professor Javier A. Cabeza

  212. Improved synthesis, solution and solid-state structure, and reactivity of [Ru2(µ-SePh)2(CO)6]

    Article • Journal of the Chemical Society Dalton Transactions, January 1991, Royal Society of Chemistry

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  213. Selective insertion of mercury(II) halides into the ruthenium–mercury bonds of trinuclear Ru2Hg clusters

    Article • Journal of the Chemical Society Chemical Communications, January 1991, Royal Society of Chemistry

    Professor Javier A. Cabeza, Santiago Garcia-Granda

  214. Reactions of [Ru2{μ-1,2-(NH)2C6H4}(CO)4(PPh3)2] with H+, NO+ and group 11 metal fragments. Syntheses of trinuclear Ru2M (M = Cu, Ag, Au) and pentanuclear Ru4Au clusters

    Article • Journal of Organometallic Chemistry, September 1990, Elsevier

    Professor Javier A. Cabeza

  215. Diphenylphosphine and diphenylphosphido derivatives of [Ru3(μ-H)(μ3-ampy)(CO)9] (Hampy = 2-amino-6-methylpyridine)

    Article • Journal of Organometallic Chemistry, August 1990, Elsevier

    Professor Javier A. Cabeza

  216. Selective carbonyl substitution reactions on [Ru3(μ-H)(μ3-ampy)(CO)9] and on its protonated derivative. Crystal structure of [Ru3(μ-H)2(μ3-ampy)(CO)9][BF4] (Hampy = 2-amino-6-methylpyridine)

    Article • Journal of Organometallic Chemistry, February 1990, Elsevier

    Professor Javier A. Cabeza

  217. The thermal and photochemical reactions of [Ru3(CO)12] with tetraethyldiphosphite. X-ray structure of [Ru3(CO)10{μ-(EtO)2POP(OEt)2}]

    Article • Inorganica Chimica Acta, February 1990, Elsevier

    Professor Javier A. Cabeza

  218. Notes. Nuclear magnetic resonance evidence for three different isomers of [Ru3(µ-H)(µ-bzim)(CO)9(PPh3)](bzim = benzimidazolate). Crystal structure of [Ru3(µ-H)(µ-bzim)(CO)10]·Me2CO

    Article • Journal of the Chemical Society Dalton Transactions, January 1990, Royal Society of Chemistry

    Professor Javier A. Cabeza

  219. The different reactivity of 2-aminopyridines and 2-pyridone with [Ru3(CO)12]. X-Ray crystal structure of [Ru3(µ-H)(µ3-anpy)(CO)9](hanpy = 2-anilinopyridine)

    Article • Journal of the Chemical Society Dalton Transactions, January 1990, Royal Society of Chemistry

    Professor Javier A. Cabeza

  220. Synthesis and reactivity of mono-, tri-, and poly-nuclear ruthenium carbonyl complexes containing the pyridine-2-thiolate ligand (pyS). Stepwise preparation of [Ru(pyS)2(CO)2] by reaction of [Ru3(CO)12] with ...

    Article • Journal of the Chemical Society Dalton Transactions, January 1990, Royal Society of Chemistry

    Professor Javier A. Cabeza

  221. Protonation and deprotonation reactions of triruthenium nona- and octa-carbonyl clusters containing a µ3-2-amido-6-methylpyridine (µ3-ampy) ligand. X-Ray structures of [Ru3(µ-H)2(µ3-ampy)(CO)9...

    Article • Journal of the Chemical Society Dalton Transactions, January 1990, Royal Society of Chemistry

    Professor Javier A. Cabeza

  222. μ-Amido complexes of ruthenium carbonyl. Asymmetric versus symmetric bridging preference of the monodeprotonated derivatives of 1,2-arenediamines. Crystal structure of [Ru3(μ-H)(μ-H3N2-4,5-Me2-1,2-phenylene)]

    Article • Journal of Organometallic Chemistry, October 1989, Elsevier

    Professor Javier A. Cabeza

  223. Ru3(CO)9(PPh3)3: a convenient starting material for the synthesis of binuclear ruthenium(I) complexes. Crystal structure of Ru2(μ-L2)(CO)4(PPh3)2 (H2L2 = 1,8-diaminonaphthalene)

    Article • Journal of Organometallic Chemistry, August 1989, Elsevier

    Professor Javier A. Cabeza

  224. Liquid Crystal Derivatives of Transition Metals (I): Tetracoordinated Copper (II) Complexes Derived From Schiffs Bases

    Article • Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics, February 1989, Taylor & Francis

    Professor Javier A. Cabeza

  225. Synthesis and reactivity of binuclear pyrazolate-bridged ruthenium(I) complexes. Crystal structures of bis[µ-(3,5-dimethylpyrazolato-NN′)-tricarbonylruthenium(I)](Ru–Ru) and bis[µ-(3,5-dimethylpyrazolato-NN′)]-µ-iodo-bis[tricarbon...

    Article • Journal of the Chemical Society Dalton Transactions, January 1989, Royal Society of Chemistry

    Professor Javier A. Cabeza

  226. Homogeneous hydrogenation of tetrasubstituted alkene moieties in prochiral didehydro amino acid derivatives catalysed by iridium complexes

    Article • Journal of the Chemical Society Perkin Transactions 1, January 1988, Royal Society of Chemistry

    Professor Javier A. Cabeza

  227. The reactions of [Ru3(CO)12] with nitrogen-containing heterocycles. Crystal structures of [Ru3(µ-H)(µ3-ppy)(CO)9] and [Ru3(µ-napy)(µ-CO)3(CO)7]

    Article • Journal of the Chemical Society Dalton Transactions, January 1988, Royal Society of Chemistry

    Professor Javier A. Cabeza

  228. The synthesis of di- and tetra-nuclear p-cymene–osmium hydride complexes; characterisation by1H(187Os) reverse INEPT two-dimensional nuclear magnetic resonance spectroscopy

    Article • Journal of the Chemical Society Dalton Transactions, January 1988, Royal Society of Chemistry

    Professor Javier A. Cabeza

  229. The reactions of dichloro-bis(μ-chloro)-bis(η6-p-cymene)diosmium(II) and -diruthenium(II) with hexamethyldialuminium

    Article • Inorganica Chimica Acta, October 1987, Elsevier

    Professor Javier A. Cabeza

  230. Pyrazolate bridged ruthenium(I) complexes. A convenient synthesis of ruthenium(I) compounds. The X-ray structure of bis-μ-(3,5-dimethylpyrazolate)bis(tricarbonyl-ruthenium(I)) (RuRu)

    Article • Journal of Organometallic Chemistry, March 1987, Elsevier

    Professor Javier A. Cabeza

  231. The cyclometallation of benzoic acid to give rhodium, iridium, and osmium C,O-benzoates. X-Ray structure determination of the dibenzoate [(C5Me5)Rh(OOCPh)2(H2O)]

    Article • Journal of the Chemical Society Dalton Transactions, January 1987, Royal Society of Chemistry

    Professor Javier A. Cabeza

  232. Dicationic tetranuclear tetrahydrides of iridium, ruthenium, and osmium

    Article • Inorganica Chimica Acta, May 1986, Elsevier

    Professor Javier A. Cabeza

  233. The x-ray molecular structure of (η6-p-Cymene)(dimethylsulphoxide-S)dichloroosmium(II)

    Article • Inorganica Chimica Acta, April 1986, Elsevier

    Professor Javier A. Cabeza

  234. The reactions of the tri-µ-hydroxo-bis[η6-p-cymeneosmium(II)] cation with aldehydes and acids and the homogeneously catalysed oxidation of acetaldehyde and propionaldehyde with water. X-Ray structure of [(p-MeC6H4<...

    Article • Journal of the Chemical Society Dalton Transactions, January 1986, Royal Society of Chemistry

    Professor Javier A. Cabeza

  235. Mononuclear η6-p-cymeneosmium(II) complexes and their reactions with Al2Me6and other methylating reagents

    Article • Journal of the Chemical Society Dalton Transactions, January 1985, Royal Society of Chemistry

    Professor Javier A. Cabeza

  236. The cyclometallation of benzoic acid and the X-ray crystal structure of [C5Me5Ir(O2CC6H4)(Me2SO)]

    Article • Journal of the Chemical Society Chemical Communications, January 1985, Royal Society of Chemistry

    Professor Javier A. Cabeza

  237. Dinuclear p-cymeneosmium hydride complexes; the measurement of 187Os chemical shifts using 1H-{187Os} two-dimensional n.m.r. spectroscopy

    Article • Journal of the Chemical Society Chemical Communications, January 1985, Royal Society of Chemistry

    Professor Javier A. Cabeza

  238. Rhodium(I) and rhodium(III) arene complexes with N-carbazolyltriphenylphosphinegold(I) and other polycyclic arene ligands

    Article • Polyhedron, January 1984, Elsevier

    Professor Javier A. Cabeza

  239. Synthesis and reactivity of mono- and hetero-nuclear rhodium(I) or iridium(I) complexes with 2-(2′-pyridyl)benzimidazole

    Article • Journal of Organometallic Chemistry, May 1983, Elsevier

    Professor Javier A. Cabeza

  240. Rhodium(I) and iridium(I) π-arene complexes of indole and of N-indolylgold(I) derivatives. X-ray structure of [(Me3TFB)Rh(η6-HIn)]ClO4 (TFB = tetrafluorobenzobarrelene)

    Article • Journal of Organometallic Chemistry, April 1983, Elsevier

    Professor Javier A. Cabeza

  241. N-indolyltriarylphosphinegold(I) derivatives as η6-arene ligands in pentamethylcyclopentadienylrhodium(III) complexes. X-ray structure of [(C5Me5)Rh(μ-In)AuP(C6H5)3](ClO4)2·CH2Cl2

    Article • Journal of Organometallic Chemistry, March 1983, Elsevier

    Professor Javier A. Cabeza

  242. 2,2′-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)–rhodium(I) complexes. Crystal structure of [(Ph3P)2Au2(µ-bbzim)Rh(cod)][ClO4]·CHCl3

    Article • Journal of the Chemical Society Dalton Transactions, January 1983, Royal Society of Chemistry

    Professor Javier A. Cabeza

  243. Iridium-catalysed homogeneous hydrogenation of prochiral enamides containing tetrasubstituted alkene moieties

    Article • Journal of the Chemical Society Chemical Communications, January 1983, Royal Society of Chemistry

    Professor Javier A. Cabeza

  244. New biimidazole and bibenzimidazole derivatives: mono and binuclear palladium(II) or platinum(II) complexes and heterobinuclear palladium(II)-rhodium(I) or platinum(II)-rhodium(I) complexes

    Article • Polyhedron, January 1983, Elsevier

    Professor Javier A. Cabeza

  245. Bi-imidazole (H2bim) and bibenzimidazole η3-allylic complexes of palladium(II). Mono- and tetra-nuclear palladium(II) and heteronuclear palladium(II)–rhodium(I) complexes. Crystal struct...

    Article • Journal of the Chemical Society Dalton Transactions, January 1983, Royal Society of Chemistry

    Professor Javier A. Cabeza

  246. Indolylgold(I) derivatives and indole as π-arene ligands in cationic rhodium(I) complexes

    Article • Journal of Organometallic Chemistry, June 1982, Elsevier

    Professor Javier A. Cabeza

  247. Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes

    Article • Journal of Organometallic Chemistry, December 1981, Elsevier

    Professor Javier A. Cabeza