All Stories

  1. Solvent-free mechanochemical synthesis of π–π stacked arene–perfluoroarene co-crystals
  2. Infinite stacking of alternating polyfluoroaryl rings and bromide anions
  3. Engineering of a polar crystal structure exclusively by π–π stacking between aryl and polyfluoroaryl groups
  4. Minimizing side reactions in chemoenzymatic dynamic kinetic resolution: organometallic and material strategies
  5. Intramolecular dehydrofluorinative coupling of η6-arene and fluoroarylphosphine ligands in ruthenium complexes
  6. Dinuclear platinum(II) sulfide–thiolate complexes [Pt2(μ-S)(μ-SR)(PPh3)4]+ containing fluorinated substituents and the identification of a S⋯C6F5 π interaction in the crystal structure of [Pt2(μ-S)(μ-SCH2C6F5)(PPh3)4]BPh4·2C6H6
  7. On the importance of π–π stacking and cation–anion interactions in the construction of non-centrosymmetric networks of bromide salts of imidazolium cations bearing arene and polyfluoroarene rings
  8. The effect of trifluoromethyl groups in the para positions of a perfluoroaryl phosphine: A comparison of the structures of [{η5,κP-C5Me4CH2C6F3X-5-P(C6F4X-4)-2-CH2P(C6F4X-4)2}RhCl2], X=F and CF3
  9. Compressed Metal Powders that Remain Superhydrophobic after Abrasion
  10. The structural characterization and hydroformylation activity of the tri-rhodium complex [Rh3(μ2-dppm)2(μ2-CO)3(K1-CO)3]BF4
  11. Sheets of Large Superhydrophobic Metal Particles Self Assembled on Water by the Cheerios Effect
  12. Fluoroarylphosphines as ligands
  13. Assessment of roughness and chemical modification in determining the hydrophobic properties of metals
  14. Pentamethylcyclopentadienyl rhodium(III) trifluorovinyl phosphine complexes and attempted intramolecular dehydrofluorinative coupling of pentamethylcyclopentadienyl and trifluorovinyl phosphine ligands
  15. Base-Free Dynamic Kinetic Resolution of Secondary Alcohols Using “Piano-Stool” Complexes of N-Heterocyclic Carbenes
  16. Remarkably Simple Fabrication of Superhydrophobic Surfaces Using Electroless Galvanic Deposition
  17. Remarkably Simple Fabrication of Superhydrophobic Surfaces Using Electroless Galvanic Deposition
  18. Complexes of η5, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η5-pentamethylcyclopentadienyl in a rhodium complex
  19. Chelating phosphines by nucleophilic substitution of fluorine in 3,4,5-trifluorobenzonitrile and tetrafluorophthalonitrile
  20. Enhanced adsorption of Cd (II) on a hydrous Al (III) floc in the presence of a modified form of polyethylenimine
  21. (Acetonitrile-κN){1,2-bis[bis(pentafluorophenyl)phosphino]ethane-κ2P,P}(η5-pentamethylcyclopentadienyl)ruthenium(II) hexafluorophosphate
  22. Intramolecular dehydrofluorinative coupling of pentamethylcyclopentadienyl and phosphine ligands in iridium complexes
  23. Intramolecular Dehydrofluorinative Coupling of the Asymmetric Diphosphine Ph 2 PCH 2 CH 2 PPh(C 5 F 4 N-4) and Pentamethylcyclopentadienyl Ligands in a Rhodium Complex
  24. Intramolecular Dehydrofluorinative Coupling of η 5 -Pentamethylcyclopentadienyl and Pentafluorophenylphosphine Ligands in Rhodium Complexes
  25. Synthesis of polyfluorodibenz[b,f][1,4]oxazepines by the cyclization of 2-[(polyfluorobenzylidene)amino]phenols
  26. Synthesis of a ruthenium complex of a cyclic trifunctional η6, η1, η1-arene–diphosphine ligand by intramolecular dehydrofluorinative carbon–carbon coupling
  27. Carbon–fluorine bond cleavage as a route to hybrid ligands
  28. Synthesis of rhodium complexes of an asymmetric η5,η1,η1-cyclo-pentadienyl-bis(phosphine) ligand by regioselective intramolecular dehydrofluorinative CC coupling
  29. Intramolecular SNAr reactions as a route to complexes of hybrid cyclopentadienyl–phosphine ligands: synthesis of a rhodium complex of the first η5,η1,η1-cyclopentadienyl–phosphine–thioether ligand
  30. Structural and electronic impact of fluorine in the ortho positions of triphenylphosphine and 1,2-bis(diphenylphosphino)ethane; a comparison of 2,6-difluorophenyl- with pentafluorophenyl-phosphines
  31. Phosphine and isonitrile complexes of η5-tetramethylcyclopentadienylrhodium chlorides; crystal structures of (η5-C5Me4H)RhCl2(PPh2R) (R=Ph or C6F5)
  32. Remarkable regioselectivity in the reaction between [(η5-C5Me4H)RhCl(μ-Cl)]2 and (C6F5)2PCH2CH2P(C6F5)2: synthesis of a chiral-at-metal rhodium complex cation via carbon–fluorine and –hydrogen bond activation and carbon–carbon bond formation
  33. Activation of C–F and C–H bonds by polyalkylcyclopentadienylrhodium complexes: crystal structure of [(η5-C5Me4Et)RhCl{(C6F5)2PCH2CH2P(C6F5)2}]+·BF4−
  34. Adsorption of metal cations by hydrous aluminium(III) or iron(III) hydroxide precipitates: enhancement by EDTA and related chelate molecules†
  35. Carbon–fluorine bond activation in the reactions between 1,2-bis[bis(2,6-difluorophenyl)phosphino]ethane and [{MCl(μ-Cl)(η5-C5Me5)}2] (M = Rh or Ir)
  36. Pentafluorophenylphosphine complexes of platinum(II); crystal structure of trans-[PtCl2(PEt3){PPh2 (C6F5)}]
  37. Preparation and characterisation of dimolybdenum complexes containing fluorophenylimide ligands
  38. Structural and electronic impact of fluorine in the ortho positions of the phenoxy groups of phenyl-phosphonite and -phosphinite ligands in compounds of platinum-group metals
  39. Defluorination of Perfluoroalkanes and Chlorofluorocarbons
  40. Cyclopentadienyl metal teflate (OTeF5) complexes
  41. Carbon–fluorine and –hydrogen bond activation and carbon–carbon bond formation in η5-pentamethylcyclopentadienyl-rhodium and -iridium phosphine complexes; crystal structures of [M(η5-C5Me5)Cl{(C6F<...
  42. Tris(2,6-difluorophenyl)phosphite complexes of platinum group metals: Structure of trans-PtCl2(PEt3){P(O-2,6-C6H3F2)3}
  43. Cleavage of both alkyl C–H bonds and aryl C–F bonds and concomitant C–C bond formation in a pentamethylcyclopentadienylrhodium phosphine complex: X-ray structure of [η5-C5Me3[CH2C6F4P(C<...
  44. Synthesis and structure of η5-pentamethylcyclopentadienyldichloro-iridiumtris(2,6-difuluorophenyl)phosphite
  45. Synthesis and electrochemistry of dimolybdenum crown ether imido complexes
  46. Coordinatively unsaturated σ-aryl iridium(III) complexes containing iridiummercury bonds
  47. Electrochemistry of dimolybdenum complexes containing oxo, imido, and sulphido moieties. A measure of their relative π-donor abilities?
  48. The effect of sodium cations on the molecular dynamics of N-acetylaza-15-crown-5
  49. Synthesis and electrochemistry of crown ether dithiolene complexes
  50. Synthetic and electrochemical studies on electroactive ionophores based on the di-η-cyclopentadienyl-molybendum and -tungsten fragments
  51. Effects of sodium ions on the molecular dynamics of bis(aza-15-crown-5)thiuram disulphide