All Stories

  1. Hierarchical Heterogeneity at the CeO x –TiO 2 Interface: Electronic and Geometric Structural Influence on the Photocatalytic Activity of Oxide on Oxide Nanostructures
  2. Mechanism of water oxidation by [Ru(bda)(L)2]: the return of the “blue dimer”
  3. Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes
  4. Theoretical Modeling of Low-Energy Electronic Absorption Bands in Reduced Cobaloximes
  5. Tungsten Carbide-Nitride on Graphene Nanoplatelets as a Durable Hydrogen Evolution Electrocatalyst
  6. New Water Oxidation Chemistry of a Seven-Coordinate Ruthenium Complex with a Tetradentate Polypyridyl Ligand
  7. Formic Acid Dehydrogenation with Bioinspired Iridium Complexes: A Kinetic Isotope Effect Study and Mechanistic Insight
  8. Water Oxidation by Ruthenium Catalysts with Non-Innocent Ligands
  9. Kinetic and Mechanistic Studies of Carbon-to-Metal Hydrogen Atom Transfer Involving Os-Centered Radicals: Evidence for Tunneling
  10. Reactivity of a fac-ReCl(α-diimine)(CO)3complex with an NAD+model ligand toward CO2reduction
  11. Efficient water oxidation with organometallic iridium complexes as precatalysts
  12. Efficient H2generation from formic acid using azole complexes in water
  13. Interconversion of CO2/H2 and Formic Acid Under Mild Conditions in Water
  14. ChemInform Abstract: Recent Developments in Transition Metal Carbides and Nitrides as Hydrogen Evolution Electrocatalysts
  15. Cp*Co(III) Catalysts with Proton-Responsive Ligands for Carbon Dioxide Hydrogenation in Aqueous Media
  16. Diminished photoisomerization of active ruthenium water oxidation catalyst by anchoring to metal oxide electrodes
  17. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
  18. Water Oxidation with Mononuclear Ruthenium(II) Polypyridine Complexes Involving a Direct RuIV═O Pathway in Neutral and Alkaline Media
  19. Interconversion of CO2 and formic acid by bio-inspired Ir complexes with pendent bases
  20. Isolation and X-ray structures of four Rh(PCP) complexes including a Rh(I) dioxygen complex with a short O–O bond
  21. Mechanistic Insight through Factors Controlling Effective Hydrogenation of CO 2 Catalyzed by Bioinspired Proton-Responsive Iridium(III) Complexes
  22. Kinetics and Thermodynamics of Small Molecule Binding to Pincer-PCP Rhodium(I) Complexes
  23. Functionalized cyclopentadienyl rhodium(iii) bipyridine complexes: synthesis, characterization, and catalytic application in hydrogenation of ketones
  24. Biomass-derived electrocatalytic composites for hydrogen evolution
  25. Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts
  26. Enabling light-driven water oxidation via a low-energy RuIVO intermediate
  27. Hydroxy-substituted pyridine-like N-heterocycles: versatile ligands in organometallic catalysis
  28. Thermodynamic and Kinetic Hydricity of Ruthenium(II) Hydride Complexes
  29. Exploring the Structural and Electronic Properties of Pt/Ceria-Modified TiO2and Its Photocatalytic Activity for Water Splitting under Visible Light
  30. Highly Efficient D2 Generation by Dehydrogenation of Formic Acid in D2O through H+/D+ Exchange on an Iridium Catalyst: Application to the Synthesis of Deuterated Compounds by Transfer Deuterogenation
  31. ChemInform Abstract: Thermodynamics and Kinetics of CO2, CO, and H+Binding to the Metal Center of CO2Reduction Catalysts
  32. Mechanisms for CO Production from CO 2 Using Reduced Rhenium Tricarbonyl Catalysts
  33. Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures
  34. Exploring the intermediates of photochemical CO2reduction: reaction of Re(dmb)(CO)3 COOH with CO2
  35. Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts
  36. Second-coordination-sphere and electronic effects enhance iridium(iii)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure
  37. Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO
  38. Steric effect for proton, hydrogen-atom, and hydride transfer reactions with geometric isomers of NADH–model ruthenium complexes
  39. Effects of a Proximal Base on Water Oxidation and Proton Reduction Catalyzed by Geometric Isomers of [Ru(tpy)(pynap)(OH2)]2+
  40. Water Oxidation by a Mononuclear Ruthenium Catalyst: Characterization of the Intermediates
  41. Editorial: A Current Perspective on Photocatalysis
  42. Theoretical studies of the mechanism of catalytic hydrogen production by a cobaloxime
  43. Substituents dependent capability of bis(ruthenium-dioxolene-terpyridine) complexes toward water oxidation
  44. Proton management as a design principle for hydrogenase-inspired catalysts
  45. Iron(II) and Ruthenium(II) Complexes Containing P, N, and H Ligands: Structure, Spectroscopy, Electrochemistry, and Reactivity
  46. New Directions for the Photocatalytic Reduction of CO 2 : Supramolecular, scCO 2 or Biphasic Ionic Liquid−scCO 2 Systems
  47. Differences of pH-Dependent Mechanisms on Generation of Hydride Donors using Ru(II) Complexes Containing Geometric Isomers of NAD+Model Ligands: NMR and Radiolysis Studies in Aqueous Solution
  48. Application of External-Cavity Quantum Cascade Infrared Lasers to Nanosecond Time-Resolved Infrared Spectroscopy of Condensed-Phase Samples following Pulse Radiolysis
  49. ChemInform Abstract: Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
  50. In Situ XRD Studies of ZnO/GaN Mixtures at High Pressure and High Temperature: Synthesis of Zn-Rich (Ga1−xZnx)(N1−xOx) Photocatalysts
  51. Oxidation State Characterization of Ruthenium 2−Iminoquinone Complexes through Experimental and Theoretical Studies
  52. Photochemical Stereospecific Hydrogenation of a Ru Complex with an NAD + /NADH-Type Ligand
  53. Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
  54. Artificial Photosynthesis
  55. Experimental and Computational Studies of Binding of Dinitrogen, Nitriles, Azides, Diazoalkanes, Pyridine, and Pyrazines to M(PR 3 ) 2 (CO) 3 (M = Mo, W; R = Me, i Pr). †
  56. Characterization of Redox States of Ru(OH 2 )(Q)(tpy) 2+ (Q = 3,5-di- tert -butyl-1,2-benzoquinone, tpy = 2,2′:6′,2″-terpyridine) and Related Species through Experimental and Theoretical Studies
  57. Preparation of (Ga 1− x Zn x )(N 1− x O x ) Photocatalysts from the Reaction of NH 3 with Ga 2 O 3 /ZnO and ZnGa 2 O 4 : In Situ Time-Resolved XRD and XAFS Studies
  58. Synthesis of Fluorinated ReCl(4,4′-R 2 -2,2′-bipyridine)(CO) 3 Complexes and Their Photophysical Characterization in CH 3 CN and Supercritical CO 2
  59. Selective decarbonylation by a pincer PCP-rhodium(I) complex
  60. Mechanism of Hydride Donor Generation Using a Ru(II) Complex Containing an NAD + Model Ligand: Pulse and Steady-State Radiolysis Studies
  61. Water Oxidation by a Ruthenium Complex with Noninnocent Quinone Ligands: Possible Formation of an O−O Bond at a Low Oxidation State of the Metal
  62. Catalytic Reactions Using Transition-Metal-Complexes Toward Solar Fuel Generation
  63. Generation of a RuII–Semiquinone–Anilino-Radical Complex through the Deprotonation of a RuIII–Semiquinone–Anilido Complex
  64. Generation of a RuII–Semiquinone–Anilino-Radical Complex through the Deprotonation of a RuIII–Semiquinone–Anilido Complex
  65. Photochemical and Radiolytic Production of an Organic Hydride Donor with a RuII Complex Containing an NAD+ Model Ligand
  66. Photochemical and Radiolytic Production of an Organic Hydride Donor with a RuII Complex Containing an NAD+ Model Ligand
  67. Characterization of transient species and products in photochemical reactions of Re(dmb) (CO)3 Et with and without CO2
  68. Reaction of NH 3 with Titania: N-Doping of the Oxide and TiN Formation
  69. Carbon Dioxide Reduction by Pincer Rhodium η2-Dihydrogen Complexes:  Hydrogen-Binding Modes and Mechanistic Studies by Density Functional Theory Calculations
  70. Direct Measurements of Rate Constants and Activation Volumes for the Binding of H 2 , D 2 , N 2 , C 2 H 4 , and CH 3 CN to W(CO) 3 (PCy 3 ) 2 :  Theoretical and Experimental Studies with Time-Resolved Step-Scan FTIR and UV−Vis Spectroscopy
  71. Transition State Characterization for the Reversible Binding of Dihydrogen to Bis(2,2'-bipyridine)rhodium(I) from Temperature- and Pressure-Dependent Experimental and Theoretical Studies
  72. Carbon-to-Metal Hydrogen Atom Transfer:  Direct Observation Using Time-Resolved Infrared Spectroscopy
  73. Why Is Re−Re Bond Formation/Cleavage in [Re(bpy)(CO)3]2Different from That in [Re(CO)5]2? Experimental and Theoretical Studies on the Dimers and Fragments
  74. Spectroscopic Characterization of Intermediates in CO2 Reduction with Rhenium Photocatalysts
  75. Involvement of a Binuclear Species with the Re−C(O)O−Re Moiety in CO 2 Reduction Catalyzed by Tricarbonyl Rhenium(I) Complexes with Diimine Ligands:  Strikingly Slow Formation of the Re−Re and Re−C(O)O−Re Species from Re(dmb)(CO) 3 S (dmb = 4,4‘-Dimet...
  76. Reduction of Cobalt and Iron Corroles and Catalyzed Reduction of CO 2
  77. Mechanistic Information from Pressure Acceleration of Hydride Formation via Proton Binding to a Cobalt(I) Macrocycle
  78. Characterization of Ru(bpy)2(CO)(COO) prepared by CO2 addition to Ru(bpy)2(CO) in acetonitrile
  79. Characterization of Ru(bpy)2(CO)(COO) prepared by CO2 addition to Ru(bpy)2(CO) in acetonitrile
  80. Crystallization and structure of a binuclear species containing the CoC(OH)OCo moiety
  81. p -Terphenyl-Sensitized Photoreduction of CO 2 with Cobalt and Iron Porphyrins. Interaction between CO and Reduced Metalloporphyrins
  82. The One-Electron Oxidation of an Azazirconacyclobutene in the Presence of B(C 6 F 5 ) 3
  83. Enantioselectivities in Electron-Transfer and Excited State Quenching Reactions of a Chiral Ruthenium Complex Possessing a Helical Structure
  84. High Enantioselectivity in the Electron Transfer Reaction between a Ru(II) Complex of Menbpy Anion Radical, [Ru(menbpy)3]+[menbpy = 4,4′-di{(1R,2S,5R)-(−)-menthoxycarbonyl}-2,2′-bipyridine] and [Co(acac)3]: A Pulse Radiolysis Study
  85. Reversible Formation of Bis(2,2‘-bipyridine)rhodium(III) Dihydride from Bis(2,2‘-bipyridine)rhodium(I) and Dihydrogen. Direct Transfer of Dihydrogen from Rhodium(III) Dihydride to Rhodium(I)
  86. Toward the Photoreduction of CO 2 with Ni(2,2′-bipyridine) n 2+ Complexes
  87. Cobalt Porphyrin Catalyzed Reduction of CO 2 . Radiation Chemical, Photochemical, and Electrochemical Studies
  88. Photochemical carbon dioxide reduction with metal complexes: Differences between cobalt and nickel macrocycles
  89. Effect of Pressure on the Reversible Binding of Acetonitrile to the “Co(I)−CO 2 ” Adduct To Form Cobalt(III) Carboxylate
  90. Direct XANES Evidence for Charge Transfer in Co−CO2Complexes
  91. Photo-Induced Generation of Dihydrogen and Reduction of Carbon Dioxide Using Transition Metal Complexes
  92. Photoreduction of CO{sub 2} using metal complexes
  93. Mechanistic and kinetic studies of cobalt macrocycles in a photochemical CO2 reduction system
  94. Mechanistic and Kinetic Studies of Cobalt Macrocycles in a Photochemical CO2 Reduction System: Evidence of Co-CO2 Adducts as Intermediates
  95. XAS studies of Ni(I), Ni(II), and Ni(III) complexes
  96. Syntheses and Properties of Nickel(I) and Nickel(II) Complexes of a Series of Macrocyclic N4 Ligands: Crystal Structures of C-RSSR-[NiIHTIM](ClO4), C-RSSR-[NiIIHTIM](ClO4)2, C-RRSS-[NiIIHTIM](ClO4)2, and [NiIITIM](ClO4)2 (HTIM = 2,3,9,10-Tetramethyl-1,...
  97. High Electrocatalytic Activity of RRSS-[NiIIHTIM](ClO4)2 and [NiIIDMC](ClO4)2 for Carbon Dioxide Reduction (HTIM = 2,3,9,10-Tetramethyl-1,4,8,11-tetraazacyclotetradecane, DMC = C-meso-5,12-Dimethyl-1,4,8,11-tetraazacyclotetradecane)
  98. C-H Bond Activation by Cobalt(I) Macrocycles: Rapid H/D Exchange between Macrocycle and Acetonitrile Solvent
  99. Carbon dioxide activation by cobalt macrocycles: evidence of hydrogen bonding between bound CO2 and the macrocycle in solution
  100. Efficient and selective electron mediation of cobalt complexes with cyclam and related macrocycles in the p-terphenyl-catalyzed photoreduction of carbon dioxide
  101. Properties and reactivity of metallocarboxylates. Crystal and molecular structure of the -CO22--bridged "polymer" {[CoIII(en)2(CO2)](ClO4).cntdot.H2O}n
  102. Photophysical properties of covalently attached tris(bipyridine)ruthenium(2+) and Mcyclam2+ (M = nickel, H2) complexes
  103. Thermodynamics and kinetics of carbon dioxide binding to two stereoisomers of a cobalt(I) macrocycle in aqueous solution
  104. Carbon dioxide activation by cobalt(I) macrocycles: factors affecting carbon dioxide and carbon monoxide binding
  105. EXAFS studies of nickel(II), nickel(I), and Ni(I)-CO tetraazamacrocycles and the crystal structure of (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(I) perchlorate
  106. Solution studies of the cobalt(II) N-rac- and N-meso-Col2+ isomers and molecular and crystal structures of the low-spin, five-coordinate cobalt(II) macrocyclic complexes N-rac-[CoL(H2O)](ClO4)2.cntdot.0.6H2O (1) and N-rac-[CoL(OC103)]ClO4 (2) (L = 5,7,...
  107. Cobalt(I), -(II), and -(III) complexes of a tetraaza 14-membered macrocycle, 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene (L). Crystal and molecular structures of [CoL(CO)]ClO4, trans-CoLCl2, and cis-[CoL(CO3)]ClO4
  108. A dissociative pathway for equilibration of a hydrido CoL(H)2+ complex with carbon dioxide and carbon monoxide. Ligand binding constants in the macrocyclic [14]-dienecobalt(I) system
  109. Carbon dioxide activation: thermodynamics of carbon dioxide binding and the involvement of two cobalt centers in the reduction of carbon dioxide by a cobalt(I) macrocycle
  110. ESR and ENDOR of bacteriopheophytin a radicals. Implications for bacteriochlorophylls in vivo
  111. Cobalt(II) nitrosyl cation radicals of porphyrins, chlorins, and isobacteriochlorins. Models for nitrite and sulfite reductases and implications for A1u heme radicals
  112. Bridged ferrocenes. 10. Structural phenomena
  113. Models for nitrite reductases. Redox chemistry of iron-nitrosyl porphyrins, chlorins, and isobacteriochlorins and .pi. cation radicals of cobalt-nitrosyl isobacteriochlorins
  114. Bridged ferrocenes. 9. Lithiation and subsequent reactions of 1,1'-trimethyleneferrocene
  115. Bridged Ferrocenes VIII. Correlation of redox potentials with structure
  116. Polynuclear complexes with hydrogen-bonded bridges. 4. Structure and magnetic properties of dinuclear copper(II) complexes of amino alcohols
  117. Bridged ferrocenes. VI. Hydrogenation with Pd/C catalyst
  118. Polynuclear complexes with hydrogen-bonded bridges. 3. Oxygen-oxygen hydrogen bonding between tris chelates of 2-aminoethanol
  119. Structure of tetranuclear cobalt(II)-Cobalt(III) complex of bis(2-hydroxyethyl)amine, [Co4{NH(C2H4OH)2}2{NH(C2H4O)2}4](ClO4)2
  120. Preparation, properties, and crystal structure of dichloro(1,3-dibenzoyl-2-azapropenato)(ethanol)iron(III)
  121. Bridged ferrocenes
  122. Bridged Ferrocenes
  123. Crystal and molecular structure of bis[N(picolinoyl)-3-amino-1-propoxidoaquocopper(II)] dihydrate. Copper(II) dimer containing a bent four-membered ring
  124. Studies on mixed chelates—III
  125. Homogeneous Redox Catalysis in CO2 Fixation