All Stories

  1. Ruthenium N-Heterocyclic Carbene Complexes for Chemoselective Reduction of Imines and Reductive Amination of Aldehydes and Ketones

    Article • European Journal of Inorganic Chemistry, June 2020, Wiley

    Ashoka Samuelson

  2. N‐Heterocyclic Carbene (NHC)‐Stabilized Ru 0 Nanoparticles: In Situ Generation of an Efficient Transfer Hydrogenation Catalyst

    Article • Chemistry - A European Journal, May 2020, Wiley

    Ashoka Samuelson

  3. Recent advances in soluble ruthenium(0) nanocatalysts and their reactivity

    Article • Applied Catalysis A General, May 2020, Elsevier

    Ashoka Samuelson

  4. Chemoselective Reduction of Imines Catalyzed by Ruthenium(II) Half-Sandwich Complexes: A Mechanistic Study

    Article • European Journal of Inorganic Chemistry, June 2019, Wiley

    Ashoka Samuelson

  5. Asymmetric transfer hydrogenation of ketones using Ru(0) nanoparticles modified by Chiral Thiones

    Article • Applied Organometallic Chemistry, March 2019, Wiley

    Ashoka Samuelson

  6. Reduction of imines catalysed by NHC substituted group 6 metal carbonyls

    Article • Inorganica Chimica Acta, February 2019, Elsevier

    Ashoka Samuelson

  7. In situ reversible redox switching of first hyperpolarizability of bimetallic ruthenium complexes

    Article • Physical Chemistry Chemical Physics, January 2019, Royal Society of Chemistry

    Ashoka Samuelson

  8. A mechanistic study of transfer hydrogenation catalyzed by cyclometallated ruthenium half-sandwich complexes

    Article • Journal of Organometallic Chemistry, July 2018, Elsevier

    Ashoka Samuelson

  9. Targeted and smart delivery of cytotoxic agents using vehicles with EPR capability

    Article • Bioconjugate Chemistry, December 2016, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  10. Synthesis and unexpected reactivity of [Ru(η 6-cymene)Cl2(PPh2Cl)], leading to [Ru(η 6-cymene)Cl2(PPh2H)] and [Ru(η 6-cymene)Cl 2 (PPh2OH)] complexes

    Article • Journal of Chemical Sciences, August 2015, Springer Science + Business Media

    Ashoka Samuelson, Professor Ashoka G Samuelson

  11. Contrasting electronic requirements for CH binding and CH activation in d6half-sandwich complexes of rhenium and tungsten

    Article • Journal of Computational Chemistry, July 2015, Wiley

    Ashoka Samuelson, Professor Ashoka G Samuelson

  12. The anticancer activity of a ruthenium complex containing a modified genetic material

    Article • European Journal of Inorganic Chemistry, October 2014, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  13. Substitution‐Modulated Anticancer Activity of Half‐Sandwich Ruthenium(II) Complexes with Heterocyclic Ancillary Ligands

    Article • European Journal of Inorganic Chemistry, June 2014, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  14. Titanium promoted reduction of imines with Grignards, silanes, and zinc: identification of a new mechanism with silanes

    Article • Tetrahedron, May 2014, Elsevier

    Ashoka Samuelson

  15. Mechanistic studies on the diazo transfer reaction

    Article • Tetrahedron Letters, April 2014, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  16. Anticancer drug 6-thioguanine improved through formation of a ruthenium complex

    Article • RSC Advances, January 2014, Royal Society of Chemistry

    Professor Ashoka G Samuelson, Ashoka Samuelson

  17. Computational Study of the Migration of Rhenium from One Enantioface of an Olefin to the Other Facilitated by (C–H)···Re Interactions

    Article • Organometallics, November 2013, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  18. Dinuclear zinc bis(thiosemicarbazone) complexes: Synthesis, in vitro anticancer activity, cellular uptake and DNA interaction study

    Article • Inorganica Chimica Acta, November 2013, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  19. Visual mapping of zinc concentration in a cell using an organic compound.

    Article • European Journal of Inorganic Chemistry, June 2013, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  20. In Vitro and in Vivo Anticancer Activity of Copper Bis(thiosemicarbazone) Complexes

    Article • Journal of Medicinal Chemistry, January 2013, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  21. Computational tools for mechanistic discrimination in the reductive and metathesis coupling reactions mediated by titanium(IV) isopropoxide

    Article • Journal of Chemical Sciences, November 2012, Springer Science + Business Media

    Professor Ashoka G Samuelson, Ashoka Samuelson

  22. Anticancer Activity of Hydrogen‐Bond‐Stabilized Half‐Sandwich RuII Complexes with Heterocycles

    Article • Chemistry - A European Journal, August 2012, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  23. The Nature of Bond Critical Points in Dinuclear Copper(I) Complexes

    Article • Chemistry - A European Journal, January 2012, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  24. Chelating and bridging bis(diphenylphosphino)aniline complexes of copper(I)

    Article • Inorganica Chimica Acta, June 2011, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  25. A novel zinc bis(thiosemicarbazone) complex for live cell imaging

    Article • JBIC Journal of Biological Inorganic Chemistry, March 2011, Springer Science + Business Media

    Professor Ashoka G Samuelson, Ashoka Samuelson

  26. Metathesis of carbon dioxide and phenyl isocyanate catalysed by group(IV) metal alkoxides: An experimental and computational study

    Article • Journal of Chemical Sciences, January 2011, Springer Science + Business Media

    Professor Ashoka G Samuelson, Ashoka Samuelson

  27. Diastereospecific Coupling of Imines by Low‐Valent Titanium: An Experimental and Computational Study

    Article • European Journal of Organic Chemistry, December 2010, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  28. Mechanistic Aspects of Nucleophilic Substitution at Half-Sandwich Metal Complexes

    Article • Organometallics, November 2010, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  29. Catalytic Reactions of Titanium Alkoxides with Grignard Reagents and Imines: A Mechanistic Study

    Article • Chemistry - An Asian Journal, July 2010, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  30. Room temperature metathesis of aryl isocyanates and aromatic aldehydes catalyzed by group(IV) metal alkoxides: An experimental and computational study

    Article • Journal of Organometallic Chemistry, February 2010, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  31. Cytotoxicity of half sandwich ruthenium(II) complexes with strong hydrogen bond acceptor ligands and their mechanism of action

    Article • Journal of Inorganic Biochemistry, February 2010, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  32. Catalytic cyclopropanation of olefins using copper(I) diphosphinoamines

    Article • Journal of Organometallic Chemistry, April 2009, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  33. Chelating and bridging diphosphinoamine (PPh2)2N(iPr) complexes of copper(I)

    Article • Journal of Organometallic Chemistry, April 2009, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  34. ChemInform Abstract: Asymmetric Allylic Alkylation by Palladium‐Bisphosphinites.

    Article • ChemInform, August 2008, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  35. Chiral C-C bond forming reactions catalysed by palladium catalysts having handedness.

    Article • Tetrahedron Asymmetry, April 2008, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  36. Differing Reactivities of Zirconium and Titanium Alkoxides with Phenyl Isocyanate: An Experimental and Computational Study

    Article • Organometallics, February 2008, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson, Eluvathingal Jemmis

  37. Asymmetric allylation of aldehydes with chiral platinum phosphinite complexes

    Article • Tetrahedron Asymmetry, October 2007, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  38. Enhancement of Quadratic Nonlinearity via Multiple Hydrogen-Bonded Supramolecular Complex Formation

    Article • The Journal of Physical Chemistry B, May 2007, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  39. The effect of halogen atom on the molecular quadratic nonlinearity of half sandwich complexes in the presence of an acceptor

    Article • Inorganica Chimica Acta, May 2007, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  40. Is copper(i) hard or soft? A density functional study of mixed ligand complexes

    Article • New Journal of Chemistry, January 2007, Royal Society of Chemistry

    Professor Sivasankar Chinnappan, Professor Ashoka G Samuelson, Ashoka Samuelson

  41. On the key role of water in the allylic activation catalysed by Pd (II)bisphosphinite complexes

    Article • Journal of Chemical Sciences, November 2006, Springer Science + Business Media

    Professor Ashoka G Samuelson, Ashoka Samuelson

  42. Synthesis, spectroscopic characterization and electronic structure of some new Cu(I) carbene complexes

    Article • Journal of Chemical Sciences, May 2006, Springer Science + Business Media

    Professor Sivasankar Chinnappan, Professor Ashoka G Samuelson, Ashoka Samuelson

  43. Converting carbon dioxide into an useful molecule using energy rich heterocumulene

    Article • ChemInform, August 2005, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  44. First diphosphinoamine ligand bearing a polymerizable side chain: Complexation with copper(I)

    Article • Journal of Polymer Science Part A Polymer Chemistry, June 2005, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  45. Copper-Promoted Synthesis of Diaryl Ethers.

    Article • ChemInform, March 2005, Wiley

    Professor Ashoka G Samuelson, Ashoka Samuelson

  46. Reversible double insertion of aryl isocyanates into the Ti–O bond of titanium(IV) isopropoxide

    Article • Journal of Organometallic Chemistry, March 2005, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  47. Mechanism of Cytotoxicity of Copper(I) Complexes of 1,2-Bis(diphenylphosphino)ethane

    Article • Journal of Medicinal Chemistry, January 2005, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  48. Converting carbon dioxide to an energy rich molecule catalytically with titanium isopropoxide!

    Article • Chemical Communications, January 2005, Royal Society of Chemistry

    Professor Ashoka G Samuelson, Ashoka Samuelson

  49. Synthesis of aryi ethers from phenol and arylbromides with a copper catalyst

    Article • New Journal of Chemistry, January 2004, Royal Society of Chemistry

    Professor Ashoka G Samuelson, Ashoka Samuelson

  50. Carbon dioxide is captured by titanium-oxo-alkoxide complex

    Article • Chemical Communications, January 2003, Royal Society of Chemistry

    Professor Ashoka G Samuelson, Ashoka Samuelson

  51. Non-bonding interactions of anions with nitrogen heterocycles and phenyl rings: a critical Cambridge Structural Database analysis

    Article • CrystEngComm, January 2003, Royal Society of Chemistry

    Professor Ashoka G Samuelson, Ashoka Samuelson

  52. Solid state structural and solution studies on the formation of a flexible cavity for anions by copper(I) and 1,2-bis(diphenylphosphino)ethane

    Article • Polyhedron, October 2002, Elsevier

    Professor Ashoka G Samuelson, Professor Venugopalan Paloth, Ashoka Samuelson

  53. Second harmonic generation in ferrocene based hydrogen bonded assemblies

    Article • Journal of Organometallic Chemistry, December 2001, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  54. The first copper(I) complex of tris(hydroxymethyl)phosphine

    Article • Inorganic Chemistry Communications, September 2001, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  55. Schiff base linked ferrocenyl complexes for second-order nonlinear optics

    Article • Journal of Organometallic Chemistry, June 2000, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  56. Synthesis and Structures of Oxyanion Encapsulated Copper(I)−dppm Complexes (dppm = Bis(diphenylphosphino)methane)

    Article • Inorganic Chemistry, March 1999, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  57. Probing the limits of steric constraints in the oligomerization of copper(I) complexes: structures of two sterically congested oligomers

    Article • Polyhedron, February 1999, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  58. Synthesis and characterization of novel charge transfer complexes formed by N,N′-bis(ferrocenylmethylidene)-p-phenylenediamine and N-(ferrocenylmethylidene)aniline

    Article • Journal of Organometallic Chemistry, February 1999, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  59. Anion-Controlled Nuclearity and Metal−Metal Distances in Copper(I)−dppm Complexes (dppm = Bis(diphenylphosphino)methane)

    Article • Inorganic Chemistry, December 1998, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  60. Amidinato- and triazenido-bridged binuclear complexes of palladium and platinum

    Article • Polyhedron, September 1998, Elsevier

    Professor Ashoka G Samuelson, Professor Ray J Butcher, Ashoka Samuelson

  61. Ab Initio Study of Structures, Energetics, and Bonding in Formally High-Oxidation-State Copper Organometallics

    Article • Organometallics, August 1998, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  62. Reversible Insertion of Methyl Isothiocyanate into Copper(I) Aryloxides

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  63. Variations in the copper(I)-copper(I) distances in multinuclear clusters with identical coordination geometries. Short metal-metal contacts induced by oligomerization

    Article • Inorganic Chemistry, December 1993, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  64. Reactions of copper(I) aryloxides with phenyl isothiocyanate: steric and ligand control in the oligomerization of [N-phenylimino(aryloxy)methanethiolato]copper(I) complexes

    Article • Inorganic Chemistry, April 1993, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  65. Selective debromination of activated vicinal dibromides by copper promoted by copper(II)

    Article • Tetrahedron Letters, January 1992, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson

  66. Allylic amination promoted by copper

    Article • Tetrahedron, November 1991, Elsevier

    Professor Ashoka G Samuelson, Professor Jubaraj Bikash Baruah, Ashoka Samuelson

  67. Cumulative anomeric effect: a theoretical and x-ray diffraction study of orthocarbonates

    Article • Journal of the American Chemical Society, April 1990, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  68. Copper(I) promoted CC bond forming reactions: direct activation of allyl alcohols

    Article • Journal of Organometallic Chemistry, February 1989, Elsevier

    Professor Ashoka G Samuelson, Ashoka Samuelson, Professor Jubaraj Bikash Baruah

  69. Reaction of copper(I) phenoxide with PhNCS: formation and X-ray structure of a novel copper(I) hexameric complex

    Article • Journal of the Chemical Society Chemical Communications, January 1989, Royal Society of Chemistry

    Professor Ashoka G Samuelson, Ashoka Samuelson

  70. Copper(I) promoted allyilic activation

    Article • Journal of the Chemical Society Chemical Communications, January 1987, Royal Society of Chemistry

    Professor Ashoka G Samuelson, Professor Jubaraj Bikash Baruah, Ashoka Samuelson

  71. Experimental evidence for orbital symmetry control of stereochemistry in some (methylenecyclopropane)iron-carbonyl reactions

    Article • Journal of the American Chemical Society, April 1981, American Chemical Society (ACS)

    Professor Ashoka G Samuelson, Ashoka Samuelson

  72. The induced kinetic isotope effect as a tool for mechanistic discrimination

    Article • Journal of the Chemical Society Chemical Communications, January 1981, Royal Society of Chemistry

    Professor Ashoka G Samuelson, Ashoka Samuelson