All Stories

  1. Design of Wall-Functionalized Hybrid Silicas Containing Diazene Radical Precursors. EPR Investigation of Their Photolysis and Thermolysis

    Article • The Journal of Physical Chemistry C, March 2015, American Chemical Society (ACS)

    Dr Stéphane Gastaldi, Professor Sylvain MARQUE

  2. Arylsulfanyl radical lifetime in nanostructured silica: dramatic effect of the organic monolayer structure

    Article • Chemical Science, January 2014, Royal Society of Chemistry

    Dr Stéphane Gastaldi, Professor Sylvain MARQUE

  3. Speeding-up enzyme-catalyzed synthesis of polyamides using ω-amino-α-alkoxy-acetate as monomer

    Article • Polymer, June 2013, Elsevier

    Dr Stéphane Gastaldi

  4. Axial-to-central chirality transfer in cyclization processes

    Article • Chemical Society Reviews, January 2013, Royal Society of Chemistry

    Dr Stéphane Gastaldi

  5. Kinetic Studies on the Formation of Sulfonyl Radicals and Their Addition to Carbon–Carbon Multiple Bonds

    Article • The Journal of Physical Chemistry A, July 2012, American Chemical Society (ACS)

    Dr Stéphane Gastaldi, Dr Chryssostomos Chatgilialoglu

  6. Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry

    Article • CHIMIA International Journal for Chemistry, June 2012, Swiss Chemical Society

    Dr Stéphane Gastaldi

  7. N‐Octanoyldimethylglycine Trifluoroethyl Ester, an Acyl Donor Leading to Highly Enantioselective Protease‐Catalysed Kinetic Resolution of Amines

    Article • Advanced Synthesis & Catalysis, June 2012, Wiley

    Dr Stéphane Gastaldi

  8. CAL-B catalyzed synthesis of chiral polyamides

    Article • Tetrahedron Asymmetry, June 2012, Elsevier

    Dr Stéphane Gastaldi

  9. Novozym 435-catalyzed synthesis of polyetheramides from amino-esters, or diesters and diamines built on ethylene- and diethylene- glycol moieties

    Article • Polymer, March 2012, Elsevier

    Dr Stéphane Gastaldi

  10. Chemoenzymatic Dynamic Kinetic Resolution of Primary Amines Catalyzed by CAL-B at 38–40 °C

    Article • The Journal of Organic Chemistry, August 2011, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  11. The influence of the molecular system on the performance of heteronuclear decoupling in solid-state NMR

    Article • Journal of Magnetic Resonance, May 2011, Elsevier

    Dr Stéphane Gastaldi

  12. Alkylphenol oxidation with a laccase from a white-rot fungus: Effects of culture induction and of ABTS used as a mediator

    Article • Chemosphere, January 2011, Elsevier

    Dr Stéphane Gastaldi

  13. A new substrate to measure laccase activities in complex environments: Application to litters

    Article • Soil Biology and Biochemistry, June 2010, Elsevier

    Dr Stéphane Gastaldi

  14. Straightforward Access to α-Methylamines through Cross-Metathesis

    Article • Synthesis, February 2010, Thieme Publishing Group

    Dr Stéphane Gastaldi

  15. Switching from (R)- to (S)-selective chemoenzymatic DKR of amines involving sulfanyl radical-mediated racemization

    Article • Organic & Biomolecular Chemistry, January 2010, Royal Society of Chemistry

    Dr Stéphane Gastaldi

  16. Synthesis of tetrahydropyrans and related heterocycles via prins cyclization; extension to aza-prins cyclization

    Article • Tetrahedron, January 2010, Elsevier

    Dr Stéphane Gastaldi

  17. Proteases screening for the kinetic resolution of amines with N-acyl α-amino acid trifluoromethyl esters: automated docking approach of binding energies using Subtilisin Novo as a prototype for serine proteases

    Article • Tetrahedron Asymmetry, December 2009, Elsevier

    Dr Stéphane Gastaldi

  18. En Route to (S)-Selective Chemoenzymatic Dynamic Kinetic Resolution of Aliphatic Amines. One-Pot KR/Racemization/KR Sequence Leading to (S)-Amides

    Article • The Journal of Organic Chemistry, March 2009, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  19. Dicobalt Hexacarbonyl Complexes of Alkynyl Imines in a Sequential Staudinger/Pauson−Khand Process. A Route to New Fused Tricyclic β-Lactams

    Article • The Journal of Organic Chemistry, October 2008, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  20. Methyl Thioglycolate

    Article • September 2008, Wiley

    Dr Stéphane Gastaldi

  21. N-Acyl glycinates as acyl donors in serine protease-catalyzed kinetic resolution of amines. Improvement of selectivity and reaction rate

    Article • Organic & Biomolecular Chemistry, January 2008, Royal Society of Chemistry

    Dr Stéphane Gastaldi

  22. Highly Efficient Photochemically Induced Thiyl Radical-Mediated Racemization of Aliphatic Amines at 30 °C

    Article • The Journal of Organic Chemistry, December 2007, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  23. Protected propargylic acetals. Nicholas–Prins cyclization leading to functionalized 2-alkynyl-tetrahydropyrans. Intramolecular trapping by allenes

    Article • Tetrahedron Letters, October 2007, Elsevier

    Dr Stéphane Gastaldi

  24. Highly Selective Enzymatic Kinetic Resolution of Primary Amines at 80 °C:  A Comparative Study of Carboxylic Acids and Their Ethyl Esters as Acyl Donors

    Article • The Journal of Organic Chemistry, August 2007, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  25. Dynamic Kinetic Resolution of Amines Involving Biocatalysis and in Situ Free Radical Mediated Racemization

    Article • Organic Letters, February 2007, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  26. Unprecedented Cyclization of Nicholas Cations onto Unactivated Terminal Alkenes: Tandem Trapping of Cationic Intermediates

    Article • Synlett, February 2007, Thieme Publishing Group

    Dr Stéphane Gastaldi

  27. Thiyl Radical Mediated Racemization of Nonactivated Aliphatic Amines

    Article • The Journal of Organic Chemistry, August 2006, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  28. Thiyl Radical Mediated Racemization of Benzylic Amines

    Article • European Journal of Organic Chemistry, June 2006, Wiley

    Dr Stéphane Gastaldi

  29. 2,2-Di(tert-butylperoxy)butane

    Article • April 2006, Wiley

    Dr Stéphane Gastaldi

  30. Tris(phenylthio)phosphine

    Article • April 2006, Wiley

    Dr Stéphane Gastaldi

  31. Looking forward: a glance into the future of organic chemistry

    Article • New Journal of Chemistry, January 2006, Royal Society of Chemistry

    Dr Stéphane Gastaldi

  32. Alchimies futures : compte rendu de l'expérience ESYOP

    Article • Comptes Rendus Chimie, January 2006, Cellule MathDoc/CEDRAM

    Dr Stéphane Gastaldi, Professor Sebastien Papot

  33. Dimethyl[3-(1-pyrenyl)propyl]stannane

    Article • October 2005, Wiley

    Dr Stéphane Gastaldi

  34. Methods for the Cleavage of Allylic and Propargylic C–N Bonds in Amines and Amides – Selected Alternative Applications of the 1,3‐Hydrogen Shift

    Article • European Journal of Organic Chemistry, August 2005, Wiley

    Dr Stéphane Gastaldi

  35. Thiyl Radical-Mediated Cleavage of Allylic C−N Bonds: Scope, Limitations, and Theoretical Support to the Mechanism

    Article • Journal of the American Chemical Society, September 2004, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  36. Design of Polyaromatic Hydrocarbon-Supported Tin Reagents:  A New Family of Tin Reagents Easily Removable from Reaction Mixtures

    Article • The Journal of Organic Chemistry, May 2004, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  37. Synthesis of (±)- and (−)-botryodiplodin using stereoselective radical cyclizations of acyclic esters and acetals

    Article • Tetrahedron Asymmetry, October 2003, Elsevier

    Dr Stéphane Gastaldi

  38. Carbonochloridic Acid 17H-Cyclopenta-[1,2-1;3,4-1′]diphenanthren-17-yl Chloroformate

    Article • April 2003, Wiley

    Dr Stéphane Gastaldi

  39. Rate Constants for the β-Elimination of Tosyl Radical from a Variety of Substituted Carbon-Centered Radicals

    Article • The Journal of Organic Chemistry, March 2003, American Chemical Society (ACS)

    Dr Stéphane Gastaldi, Dr Chryssostomos Chatgilialoglu

  40. Synthesis and selective transformation of nitrogen-containing compounds via radical pathways

    Article • Comptes Rendus Chimie, October 2002, Cellule MathDoc/CEDRAM

    Dr Stéphane Gastaldi

  41. PAH-supported tin hydride: a new tin reagent easily removable from reaction mixtures

    Article • Tetrahedron Letters, June 2002, Elsevier

    Dr Stéphane Gastaldi

  42. Tandem radical and non-radical reactions mediated with thiols—a new method of cleavage of allylic amines

    Article • Chemical Communications, January 2002, Royal Society of Chemistry

    Dr Stéphane Gastaldi

  43. Diiodosilane:  A Reagent for Mild, Efficient Conversion of Carbamates to Ureas via Isocyanates

    Article • The Journal of Organic Chemistry, April 2000, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  44. Reaction of sodium cyanide with 5-bromo-1-benzosuberone: a reappraisal

    Article • New Journal of Chemistry, January 2000, Royal Society of Chemistry

    Dr Stéphane Gastaldi

  45. On the Role of Neighboring Group Participation and Ortho Esters in β-Xylosylation:  13C NMR Observation of a Bridging 2-Phenyl-1,3-dioxalenium Ion

    Article • The Journal of Organic Chemistry, June 1999, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  46. Intramolecular radical allylation with allylic sulfones— A synthesis of (±)-botryodiplodin

    Article • Tetrahedron Letters, April 1999, Elsevier

    Dr Stéphane Gastaldi

  47. Diverging Effects of Steric Congestion on the Reaction of Tributylstannyl Radicals with Areneselenols and Aryl Bromides and Their Mechanistic Implications

    Article • The Journal of Organic Chemistry, March 1999, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  48. On the stereochemistry of vicinal nucleophilic substitution of β-(phosphatoxy)alkyl radicals

    Article • Tetrahedron Letters, December 1998, Elsevier

    Dr Stéphane Gastaldi

  49. Influence of quaternization or coordination of nitrogen with a Lewis acid upon the diastereoselectivity of 5-exo ring closure of β-aminoalkyl radicals

    Article • Tetrahedron, October 1998, Elsevier

    Dr Stéphane Gastaldi

  50. Radical Cyclization of Dialkyldiallylammonium Salts. A Stereoselective Route to Pyrrolidines

    Article • Synlett, December 1997, Thieme Publishing Group

    Dr Stéphane Gastaldi

  51. Synthesis of functionalised indolines by radical-polar crossover reactions

    Article • Journal of the Chemical Society Perkin Transactions 1, January 1997, Royal Society of Chemistry

    Dr Stéphane Gastaldi

  52. 4-Isopropenyl-3-tosylmethyl pyrrolidines through radical cyclizations of 4-aza-1,6-dienes - an approach to kainic acids

    Article • Tetrahedron Letters, February 1996, Elsevier

    Dr Stéphane Gastaldi

  53. 1,2- and 1,5-stereocontrols in 5-hexenyl radical intramol cyclocondensations: cooperative or antagonist effect. Confrontation of experimental results with MM2 calculations of transition states

    Article • The Journal of Organic Chemistry, September 1995, American Chemical Society (ACS)

    Dr Stéphane Gastaldi

  54. Chemoselective ring construction from unsymmetrical 1,6-dienes via radical addition of sulfonyl halides

    Article • The Journal of Organic Chemistry, November 1992, American Chemical Society (ACS)

    Dr Stéphane Gastaldi